Volume 132
Main Index

Issue 01

Synthesis and Reaction of [(TpiPr2)LnH2]3 (Ln = Y, Lu) with CO: Trinuclear Cluster-Bound Propenolate en Route to Selective Formation of Propene Jianhua Cheng, Michael J. Ferguson and Josef Takats pp 2–3 DOI: 10.1021/ja905679k Supporting Info

The Double [3 + 2] Photocycloaddition Reaction Clive S. Penkett, Jason A. Woolford, Iain J. Day and Martyn P. Coles pp 4–5 DOI: 10.1021/ja906163s Supporting Info

Enamine Catalysis with Low Catalyst Loadings - High Efficiency via Kinetic Studies Markus Wiesner, Grgory Upert, Gaetano Angelici and Helma Wennemers pp 6–7 DOI: 10.1021/ja9068112 Supporting Info

Reduction of Bis(dithiolene)oxo(disulfido)tungsten(VI) Complex with Dihydrogen Related to the Chemical Function of the Fourth Tungsten-Containing Enzyme (WOR4) from Pyrococcus furiosus Hideki Sugimoto, Hiroyuki Tano, Kazuo Toyota, Reiko Tajima, Hiroyuki Miyake, Isao Takahashi, Shun Hirota and Shinobu Itoh pp 8–9 DOI: 10.1021/ja907164s Supporting Info

Zero Thermal Expansion in a Flexible, Stable Framework: Tetramethylammonium Copper(I) Zinc(II) Cyanide Anthony E. Phillips, Gregory J. Halder, Karena W. Chapman, Andrew L. Goodwin and Cameron J. Kepert pp 10–11 DOI: 10.1021/ja906895j Supporting Info

Non-Heme Iron Oxygenases Generate Natural Structural Diversity in Carbapenem Antibiotics Micah J. Bodner, Ryan M. Phelan, Michael F. Freeman, Rongfeng Li and Craig A. Townsend pp 12–13 DOI: 10.1021/ja907320n Supporting Info

Nanoscale Chiral Rod-like Molecular Triads Assembled from Achiral Polyoxometalates Jin Zhang, Jian Hao, Yongge Wei, Fengping Xiao, Panchao Yin and Longsheng Wang pp 14–15 DOI: 10.1021/ja907535g Supporting Info

Critical Size for the Observation of Quantum Confinement in Optically Excited Gold Clusters Oleg Varnavski, Guda Ramakrishna, Junhyung Kim, Dongil Lee and Theodore Goodson pp 16–17 DOI: 10.1021/ja907984r Supporting Info

Larger Spontaneous Polarization Ferroelectric Inorganic−Organic Hybrids: [PbI3]∞ Chains Directed Organic Cations Aggregation to Kagom-Shaped Tubular Architecture Hai-Rong Zhao, Dong-Ping Li, Xiao-Ming Ren, You Song and Wan-Qin Jin pp 18–19 DOI: 10.1021/ja907562m Supporting Info

Nanoscale Heterostructures with Molecular-Scale Single-Crystal Metal Wires Paromita Kundu, Aditi Halder, B. Viswanath, Dipan Kundu, Ganpati Ramanath and N. Ravishankar pp 20–21 DOI: 10.1021/ja907874h Supporting Info

Solution-Processed Inorganic Solar Cell Based on in Situ Synthesis and Film Deposition of CuInS2 Nanocrystals Liang Li, Nelson Coates and Daniel Moses pp 22–23 DOI: 10.1021/ja908371f

Detection of a Transient Intermediate in a Rapid Protein Folding Process by Solid-State Nuclear Magnetic Resonance Kan-Nian Hu, Wai-Ming Yau and Robert Tycko pp 24–25 DOI: 10.1021/ja908471n Supporting Info

Bidirectional Electron Transfer in Molecular Tetrads Andrew C. Benniston, Anthony Harriman and Peiyi Li pp 26–27 DOI: 10.1021/ja908865k Supporting Info

Dioxygen Activation under Ambient Conditions: Cu-Catalyzed Oxidative Amidation−Diketonization of Terminal Alkynes Leading to α-Ketoamides Chun Zhang and Ning Jiao pp 28–29 DOI: 10.1021/ja908911n Supporting Info

A Porous Coordination Network Catalyzes an Olefin Isomerization Reaction in the Pore Kazuaki Ohara, Masaki Kawano, Yasuhide Inokuma and Makoto Fujita pp 30–31 DOI: 10.1021/ja908794n Supporting Info

One-Pot Nucleation, Growth, Morphogenesis, and Passivation of 1.4 nm Au Nanoparticles on Self-Assembled Rosette Nanotubes Rahul Chhabra, Jesus G. Moralez, Jose Raez, Takeshi Yamazaki, Jae-Young Cho, Andrew J. Myles, Andriy Kovalenko and Hicham Fenniri pp 32–33 DOI: 10.1021/ja908775g Supporting Info

Inverse CeO2/CuO Catalyst As an Alternative to Classical Direct Configurations for Preferential Oxidation of CO in Hydrogen-Rich Stream A. Horns, A. B. Hungra, P. Bera, A. Lpez Cmara, M. Fernndez-Garca, A. Martnez-Arias, L. Barrio, M. Estrella, G. Zhou, J. J. Fonseca, J. C. Hanson and J. A. Rodriguez pp 34–35 DOI: 10.1021/ja9089846 Supporting Info

Growth of Crystalline Gd2O3 Thin Films with a High-Quality Interface on Si(100) by Low-Temperature H2O-Assisted Atomic Layer Deposition Andrian P. Milanov, Ke Xu, Apurba Laha, Eberhard Bugiel, Ramadurai Ranjith, Dominik Schwendt, H. Jrg Osten, Harish Parala, Roland A. Fischer and Anjana Devi pp 36–37 DOI: 10.1021/ja909102j Supporting Info

High and Selective CO2 Uptake in a Cobalt Adeninate Metal−Organic Framework Exhibiting Pyrimidine- and Amino-Decorated Pores Jihyun An, Steven J. Geib and Nathaniel L. Rosi pp 38–39 DOI: 10.1021/ja909169x Supporting Info

Free Solution Hydrodynamic Separation of DNA Fragments from 75 to 106000 Base Pairs in A Single Run Xiayan Wang, Vijaykumar Veerappan, Chang Cheng, Xin Jiang, Randy D. Allen, Purnendu K. Dasgupta and Shaorong Liu pp 40–41 DOI: 10.1021/ja909233n Supporting Info

Determination of Leu Side-Chain Conformations in Excited Protein States by NMR Relaxation Dispersion D. Flemming Hansen, Philipp Neudecker, Pramodh Vallurupalli, Frans A. A. Mulder and Lewis E. Kay pp 42–43 DOI: 10.1021/ja909294n Supporting Info

Metal−Metal Multiple Bonds in Early/Late Heterobimetallics Support Unusual Trigonal Monopyramidal Geometries at both Zr and Co Bennett P. Greenwood, Gerard T. Rowe, Chun-Hsing Chen, Bruce M. Foxman and Christine M. Thomas pp 44–45 DOI: 10.1021/ja909310t Supporting Info

Large-Scale Synthesis of SnO2 Nanosheets with High Lithium Storage Capacity Cen Wang, Yun Zhou, Mingyuan Ge, Xiaobin Xu, Zaoli Zhang and J. Z. Jiang pp 46–47 DOI: 10.1021/ja909321d Supporting Info

The Role of the Substrate Lipid in Processive Glycan Polymerization by the Peptidoglycan Glycosyltransferases Deborah L. Perlstein, Tsung-Shing Andrew Wang, Emma H. Doud, Daniel Kahne and Suzanne Walker pp 48–49 DOI: 10.1021/ja909325m Supporting Info

Diarylprolinol Silyl Ether Salts as New, Efficient, Water-Soluble, and Recyclable Organocatalysts for the Asymmetric Michael Addition on Water Zilong Zheng, Benjamin L. Perkins and Bukuo Ni pp 50–51 DOI: 10.1021/ja9093583 Supporting Info

Self-Assembled Tetranuclear Palladium Catalysts That Produce High Molecular Weight Linear Polyethylene Zhongliang Shen and Richard F. Jordan pp 52–53 DOI: 10.1021/ja909473y Supporting Info

Enantioselective Synthesis of 3,4-Dihydroisoquinolin-1(2H)-ones by Nickel-Catalyzed Denitrogenative Annulation of 1,2,3-Benzotriazin-4(3H)-ones with Allenes Motoshi Yamauchi, Masao Morimoto, Tomoya Miura and Masahiro Murakami pp 54–55 DOI: 10.1021/ja909603j Supporting Info

Chiral Lithium(I) Binaphtholate Salts for the Enantioselective Direct Mannich-Type Reaction with a Change of Syn/Anti and Absolute Stereochemistry Manabu Hatano, Takahiro Horibe and Kazuaki Ishihara pp 56–57 DOI: 10.1021/ja909874b Supporting Info

Liesegang Rings Engineered from Charged Nanoparticles Istvn Lagzi, Bartlomiej Kowalczyk and Bartosz A. Grzybowski pp 58–60 DOI: 10.1021/ja906890v Supporting Info

Direct Probing of Spin State Dynamics Coupled with Electronic and Structural Modifications by Picosecond Time-Resolved XAFS Shunsuke Nozawa, Tokushi Sato, Matthieu Chollet, Kouhei Ichiyanagi, Ayana Tomita, Hiroshi Fujii, Shin-ichi Adachi and Shin-ya Koshihara pp 61–63 DOI: 10.1021/ja907460b Supporting Info

Reactivity of TiO2 Rutile and Anatase Surfaces toward Nitroaromatics Shao-Chun Li and Ulrike Diebold pp 64–66 DOI: 10.1021/ja907865t Supporting Info

Optical Imaging of Mammary and Prostate Tumors in Living Animals using a Synthetic Near Infrared Zinc(II)-Dipicolylamine Probe for Anionic Cell Surfaces Bryan A. Smith, Walter J. Akers, W. Matthew Leevy, Andrew J. Lampkins, Shuzhang Xiao, William Wolter, Mark A. Suckow, Samuel Achilefu and Bradley D. Smith pp 67–69 DOI: 10.1021/ja908467y Supporting Info

Size-Dependent Electrochemical Oxidation of Silver Nanoparticles Olga S. Ivanova and Francis P. Zamborini pp 70–72 DOI: 10.1021/ja908780g Supporting Info

Rhodium(0) Metalloradicals in Binuclear C−H Activation Florian F. Puschmann, Hansjrg Grtzmacher and Bas de Bruin pp 73–75 DOI: 10.1021/ja909022p Supporting Info

Highly Permeable Zeolite Imidazolate Framework-8 Membranes for CO2/CH4 Separation Surendar R. Venna and Moises A. Carreon pp 76–78 DOI: 10.1021/ja909263x Supporting Info

Ligandless, Anionic, Arylpalladium Halide Intermediates in the Heck Reaction Brad P. Carrow and John. F. Hartwig pp 79–81 DOI: 10.1021/ja909306f Supporting Info

The Missing Link Between Molecular Triplets and Spin-Polarized Free Radicals: Room Temperature Triplet States of Nanocrystalline Radical Pairs Natalia V. Lebedeva, Valery F. Tarasov, Marino J. E. Resendiz, Miguel A. Garcia-Garibay, Ryan C. White and Malcolm D. E. Forbes pp 82–84 DOI: 10.1021/ja909521u

Single Amino Acid Replacement Makes Aequorea victoria Fluorescent Proteins Reversibly Photoswitchable Ranieri Bizzarri, Michela Serresi, Francesco Cardarelli, Stefania Abbruzzetti, Barbara Campanini, Cristiano Viappiani and Fabio Beltram pp 85–95 DOI: 10.1021/ja9014953 Supporting Info

Why Structurally Different Cyclic Peptides Can Be Glycomimetics of the HNK-1 Carbohydrate Antigen Anirban Bhunia, Subramanian Vivekanandan, Thomas Eckert, Monika Burg-Roderfeld, Rainer Wechselberger, Julija Romanuka, Dirk Bchle, Andrei V. Kornilov, Claus-Wilhelm von der Lieth, Jess Jimnez-Barbero, Nikolay E. Nifantiev, Melitta Schachner, Norbert Sewald, Thomas Ltteke and Hans-Christian Siebert pp 96–105 DOI: 10.1021/ja904334s Supporting Info

User-Loaded SlipChip for Equipment-Free Multiplexed Nanoliter-Scale Experiments Liang Li, Wenbin Du and Rustem Ismagilov pp 106–111 DOI: 10.1021/ja908555n Supporting Info

Multiparameter Screening on SlipChip Used for Nanoliter Protein Crystallization Combining Free Interface Diffusion and Microbatch Methods Liang Li, Wenbin Du and Rustem F. Ismagilov pp 112–119 DOI: 10.1021/ja908558m Supporting Info

Mechanism of Water Splitting and Oxygen−Oxygen Bond Formation by a Mononuclear Ruthenium Complex Xinzheng Yang and Michael B. Hall pp 120–130 DOI: 10.1021/ja9041065 Supporting Info

Dramatic Effect of Lewis Acids on the Rhodium-Catalyzed Hydroboration of Olefins Christopher J. Lata and Cathleen M. Crudden pp 131–137 DOI: 10.1021/ja904142m Supporting Info

Size-Dependent Catalytic Activity and Dynamics of Gold Nanoparticles at the Single-Molecule Level Xiaochun Zhou, Weilin Xu, Guokun Liu, Debashis Panda and Peng Chen pp 138–146 DOI: 10.1021/ja904307n Supporting Info

Recognition and Sensing of Nucleoside Monophosphates by a Dicopper(II) Cryptate Valeria Amendola, Greta Bergamaschi, Armando Buttafava, Luigi Fabbrizzi and Enrico Monzani pp 147–156 DOI: 10.1021/ja9046262 Supporting Info

Influence of the Nitrogen Donors on Nonheme Iron Models of Superoxide Reductase: High-Spin FeIII−OOR Complexes Frances Namuswe, Takahiro Hayashi, Yunbo Jiang, Gary D. Kasper, Amy A. Narducci Sarjeant, Pierre Monne-Loccoz and David P. Goldberg pp 157–167 DOI: 10.1021/ja904818z Supporting Info

Activatable Magnetic Resonance Imaging Agents for Myeloperoxidase Sensing: Mechanism of Activation, Stability, and Toxicity Elisenda Rodrguez, Mark Nilges, Ralph Weissleder and John W. Chen pp 168–177 DOI: 10.1021/ja905274f Supporting Info

Thermal Decomposition Mechanism of Single-Molecule Precursors Forming Metal Sulfide Nanoparticles Yun Ku Jung, Jae Il Kim and Jin-Kyu Lee pp 178–184 DOI: 10.1021/ja905353a Supporting Info

Subnanomolar Inhibitor of Cytochrome bc1 Complex Designed by Optimizing Interaction with Conformationally Flexible Residues Pei-Liang Zhao, Le Wang, Xiao-Lei Zhu, Xiaoqin Huang, Chang-Guo Zhan, Jia-Wei Wu and Guang-Fu Yang pp 185–194 DOI: 10.1021/ja905756c Supporting Info

Vesicle Budding Induced by a Pore-Forming Peptide Yan Yu, Julie A. Vroman, Sung Chul Bae and Steve Granick pp 195–201 DOI: 10.1021/ja9059014 Supporting Info

Accurate Automated Protein NMR Structure Determination Using Unassigned NOESY Data Srivatsan Raman, Yuanpeng J. Huang, Binchen Mao, Paolo Rossi, James M. Aramini, Gaohua Liu, Gaetano T. Montelione and David Baker pp 202–207 DOI: 10.1021/ja905934c Supporting Info

Tailored Electrochemical Synthesis of 2D-Hexagonal, Lamellar, and Cage-Type Mesostructured Pt Thin Films with Extralarge Periodicity Azusa Takai, Yusuke Yamauchi and Kazuyuki Kuroda pp 208–214 DOI: 10.1021/ja9062844 Supporting Info

Vinyl Cations Substituted with β π-Donors Have Triplet Ground States Arthur H. Winter and Daniel E. Falvey pp 215–222 DOI: 10.1021/ja906139m Supporting Info

Probing Molecular Motion by Double-Quantum (13C,13C) Solid-State NMR Spectroscopy: Application to Ubiquitin Robert Schneider, Karsten Seidel, Manuel Etzkorn, Adam Lange, Stefan Becker and Marc Baldus pp 223–233 DOI: 10.1021/ja906283h Supporting Info

Oil/Water Transfer Is Partly Driven by Molecular Shape, Not Just Size Christopher J. Fennell, Charlie Kehoe and Ken A. Dill pp 234–240 DOI: 10.1021/ja906399e Supporting Info

Visualization of the Encounter Ensemble of the Transient Electron Transfer Complex of Cytochrome c and Cytochrome c Peroxidase Qamar Bashir, Alexander N. Volkov, G. Matthias Ullmann and Marcellus Ubbink pp 241–247 DOI: 10.1021/ja9064574 Supporting Info

Chemical Reactions on Surface Molecules Attached to Silicon Quantum Dots Amane Shiohara, Sanshiro Hanada, Sujay Prabakar, Kohki Fujioka, Teck H. Lim, Kenji Yamamoto, Peter T. Northcote and Richard D. Tilley pp 248–253 DOI: 10.1021/ja906501v Supporting Info

Weakening C−O Bonds: Ti(III), a New Reagent for Alcohol Deoxygenation and Carbonyl Coupling Olefination Horacio R. Diguez, Armando Lpez, Victoriano Domingo, Jess F. Arteaga, Jos A. Dobado, M. Mar Herrador, Jos F. Qulez del Moral and Alejandro F. Barrero pp 254–259 DOI: 10.1021/ja906083c Supporting Info

Visualizing Graphene Based Sheets by Fluorescence Quenching Microscopy Jaemyung Kim, Laura J. Cote, Franklin Kim and Jiaxing Huang pp 260–267 DOI: 10.1021/ja906730d Supporting Info

Anisotropic Etching of Silver Nanoparticles for Plasmonic Structures Capable of Single-Particle SERS Martin J. Mulvihill, Xing Yi Ling, Joel Henzie and Peidong Yang pp 268–274 DOI: 10.1021/ja906954f Supporting Info

Enantioselective Synthesis of (+)-Cephalostatin 1 Kevin C. Fortner, Darryl Kato, Yoshiki Tanaka and Matthew D. Shair pp 275–280 DOI: 10.1021/ja906996c Supporting Info

Naphthol Coupling Monitored by Infrared Spectroscopy in the Gas Phase Jana Roithov and Petr Milko pp 281–288 DOI: 10.1021/ja907291d Supporting Info

Size-Dependent Multiple Twinning in Nanocrystal Superlattices Sara M. Rupich, Elena V. Shevchenko, Maryna I. Bodnarchuk, Byeongdu Lee and Dmitri V. Talapin pp 289–296 DOI: 10.1021/ja9074425 Supporting Info

Accumulated Proton-Donating Ability of Solvent Molecules in Proton Transfer Sun-Young Park and Du-Jeon Jang pp 297–302 DOI: 10.1021/ja907491u Supporting Info

Intermediate Rate Atomic Trajectories of RNA by Solid-State NMR Spectroscopy Greg L. Olsen, Michael F. Bardaro, Jr., Dorothy C. Echodu, Gary P. Drobny and Gabriele Varani pp 303–308 DOI: 10.1021/ja907515s Supporting Info

Effect of Glass Dissolution on the Solution Deposition of ZnO Films and Its Exploitation for Deposition of Zn Silicates Michael Kokotov, Shay Bar-Nachum, Eran Edri and Gary Hodes pp 309–314 DOI: 10.1021/ja907580u

Two Axles Threaded Using a Single Template Site: Active Metal Template Macrobicyclic [3]Rotaxanes Stephen M. Goldup, David A. Leigh, Paul R. McGonigal, Vicki E. Ronaldson and Alexandra M. Z. Slawin pp 315–320 DOI: 10.1021/ja9080716 Supporting Info

Protein 19F NMR in Escherichia coli Conggang Li, Gui-Fang Wang, Yaqiang Wang, Rachel Creager-Allen, Evan A. Lutz, Heidi Scronce, Kristin M. Slade, Rebecca A.S. Ruf, Ryan A. Mehl and Gary J. Pielak pp 321–327 DOI: 10.1021/ja907966n Supporting Info

Charge Recombination and Exciton Annihilation Reactions in Conjugated Polymer Blends Ian A. Howard, Justin M. Hodgkiss, Xinping Zhang, Kiril R. Kirov, Hugo A. Bronstein, Charlotte K. Williams, Richard H. Friend, Sebastian Westenhoff and Neil C. Greenham pp 328–335 DOI: 10.1021/ja908046h

Orthogonal Orientation Control of Carbon Nanotube Growth Weiwei Zhou, Lei Ding, Sungwoo Yang and Jie Liu pp 336–341 DOI: 10.1021/ja908414v Supporting Info

Dearomatization Reactions of N-Heterocycles Mediated by Group 3 Complexes Kevin L. Miller, Bryan N. Williams, Diego Benitez, Colin T. Carver, Kevin R. Ogilby, Ekaterina Tkatchouk, William A. Goddard, III and Paula L. Diaconescu pp 342–355 DOI: 10.1021/ja908489p Supporting Info

Gold, Copper, and Platinum Nanoparticles Dispersed on CeOx/TiO2(110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level Joon B. Park, Jesus Graciani, Jaime Evans, Dario Stacchiola, Sanjaya D. Senanayake, Laura Barrio, Ping Liu, Javier Fdez. Sanz, Jan Hrbek and Jos A. Rodriguez pp 356–363 DOI: 10.1021/ja9087677

Design of Liquid Crystals with “de Vries-like” Properties: Frustration between SmA- and SmC-Promoting Elements Jeffrey C. Roberts, Nadia Kapernaum, Qingxiang Song, Dorothee Nonnenmacher, Khurshid Ayub, Frank Giesselmann and Robert P. Lemieux pp 364–370 DOI: 10.1021/ja9087727 Supporting Info

Chemical and Biological Studies of Nakiterpiosin and Nakiterpiosinone Shuanhu Gao, Qiaoling Wang, Lily Jun-Shen Huang, Lawrence Lum and Chuo Chen pp 371–383 DOI: 10.1021/ja908626k Supporting Info

Strongly Nonlinear Optical Glass Fibers from Noncentrosymmetric Phase-Change Chalcogenide Materials In Chung, Joon I. Jang, Christos D. Malliakas, John B. Ketterson and Mercouri G. Kanatzidis pp 384–389 DOI: 10.1021/ja908839s Supporting Info

The Stability of Aryl Carbanions Derived from Pyridine N-Oxide: The Role of Resonance in Stabilizing Aryl Anions Scott K. Koehn, Ngoc L. Tran, Scott Gronert and Weiming Wu pp 390–395 DOI: 10.1021/ja906473v Supporting Info

Enantioselective C−C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement between Donor/Acceptor Carbenoids and Allylic Alcohols Zhanjie Li and Huw M. L. Davies pp 396–401 DOI: 10.1021/ja9075293 Supporting Info

One-Pot Catalytic Enantio- and Diastereoselective Syntheses of anti-, syn-cis-Disubstituted, and syn-Vinyl Cyclopropyl Alcohols Hun Young Kim, Luca Salvi, Patrick J. Carroll and Patrick J. Walsh pp 402–412 DOI: 10.1021/ja907781t Supporting Info

[Ir(COD)Cl]2 as a Catalyst Precursor for the Intramolecular Hydroamination of Unactivated Alkenes with Primary Amines and Secondary Alkyl- or Arylamines: A Combined Catalytic, Mechanistic, and Computational Investigation Kevin D. Hesp, Sven Tobisch and Mark Stradiotto pp 413–426 DOI: 10.1021/ja908316n Supporting Info

Enantioselective Intramolecular Michael Addition of Nitronates onto Conjugated Esters: Access to Cyclic γ-Amino Acids with up to Three Stereocenters William J. Nodes, David R. Nutt, Ann M. Chippindale and Alexander J. A. Cobb p 427 DOI: 10.1021/ja9092083 Supporting Info

Molecular Theory of Water and Aqueous Solutions, Part I: Understanding Water Ralph C. Dougherty p 428 DOI: 10.1021/ja909789d

Issue 02

Surface-Enhanced Raman Scattering Captures Conformational Changes of Single Photoactive Yellow Protein Molecules under Photoexcitation Kushagra Singhal and A. Kaan Kalkan pp 429–431 DOI: 10.1021/ja9028704 Supporting Info

A Tandem Reaction Initiated by 1,4-Addition of Bis(iodozincio)methane for 1,3-Diketone Formation Mutsumi Sada and Seijiro Matsubara pp 432–433 DOI: 10.1021/ja910428y Supporting Info

Cesium Promotion in Styrene Epoxidation on Silver Catalysts Ling Zhou, Craig F. Gorin and Robert J. Madix pp 434–435 DOI: 10.1021/ja9055849 Supporting Info

Practical Asymmetric Conjugate Alkynylation of Meldrum’s Acid-Derived Acceptors: Access to Chiral β-Alkynyl Acids Sheng Cui, Shawn D. Walker, Jacqueline C. S. Woo, Christopher J. Borths, Herschel Mukherjee, Maosheng J. Chen and Margaret M. Faul pp 436–437 DOI: 10.1021/ja909105s Supporting Info

Active-Site Engineering of Benzaldehyde Lyase Shows That a Point Mutation Can Confer Both New Reactivity and Susceptibility to Mechanism-Based Inhibition Gabriel S. Brandt, Malea M. Kneen, Gregory A. Petsko, Dagmar Ringe and Michael J. McLeish pp 438–439 DOI: 10.1021/ja907064w Supporting Info

Rhodium-Catalyzed [3 + 2] Annulation of Indoles Yajing Lian and Huw M. L. Davies pp 440–441 DOI: 10.1021/ja9078094 Supporting Info

Dual Redox Responsive Assemblies Formed from Diselenide Block Copolymers Ning Ma, Ying Li, Huaping Xu, Zhiqiang Wang and Xi Zhang pp 442–443 DOI: 10.1021/ja908124g Supporting Info

Dynamics of Ultrafast Singlet and Triplet Charge Transfer in Anthraquinone−DNA Conjugates Frederick D. Lewis, Arun K. Thazhathveetil, Tarek A. Zeidan, Josh Vura-Weis and Michael R. Wasielewski pp 444–445 DOI: 10.1021/ja908470d Supporting Info

13C ENDOR Reveals That the D1 Polypeptide C-Terminus Is Directly Bound to Mn in the Photosystem II Oxygen Evolving Complex Jamie A. Stull, Troy A. Stich, Rachel J. Service, Richard J. Debus, Sanjay K. Mandal, William H. Armstrong and R. David Britt pp 446–447 DOI: 10.1021/ja908688t Supporting Info

MCM-22/Silica Selective Flake Nanocomposite Membranes for Hydrogen Separations Jungkyu Choi and Michael Tsapatsis pp 448–449 DOI: 10.1021/ja908864g Supporting Info

-Value Analysis for Ultrafast Folding Proteins by NMR Relaxation Dispersion Jae-Hyun Cho, Nichole O’Connell, Daniel P. Raleigh and Arthur G. Palmer, III pp 450–451 DOI: 10.1021/ja909052h Supporting Info

Reactive Intermediates Formed During Olefin Polymerization by Methylalumoxane-Activated ansa-Zirconocene Catalysts: Identification of a Chain-Carrying Intermediate by NMR Methods Dmitrii E. Babushkin and Hans H. Brintzinger pp 452–453 DOI: 10.1021/ja909157r Supporting Info

Cleavage of Both C(sp3)−C(sp2) Bonds of Alkylidenecyclopropanes: Formation of Ethylene−Osmium−Vinylidene Complexes Ruth Castro-Rodrigo, Miguel A. Esteruelas, Ana M. Lpez, Fernando Lpez, Jos L. Mascareas, Montserrat Olivn, Enrique Oate, Luca Saya and Lara Villarino pp 454–455 DOI: 10.1021/ja909240q Supporting Info

Combining Aurophilic Interactions and Halogen Bonding To Control the Luminescence from Bimetallic Gold−Silver Clusters Antonio Laguna, Tania Lasanta, Jos M. Lpez-de-Luzuriaga, Miguel Monge, Pane Naumov and M. Elena Olmos pp 456–457 DOI: 10.1021/ja909241m Supporting Info

Direct Electrochemistry of Drug Metabolizing Human Flavin-Containing Monooxygenase: Electrochemical Turnover of Benzydamine and Tamoxifen Sheila J. Sadeghi, Rita Meirinhos, Gianluca Catucci, Vikash R. Dodhia, Giovanna Di Nardo and Gianfranco Gilardi pp 458–459 DOI: 10.1021/ja909261p Supporting Info

Pd(II)-Catalyzed Enantioselective C−H Olefination of Diphenylacetic Acids Bing-Feng Shi, Yang-Hui Zhang, Jonathan K. Lam, Dong-Hui Wang and Jin-Quan Yu pp 460–461 DOI: 10.1021/ja909571z Supporting Info

Synthesis of the Lantibiotic Lactocin S Using Peptide Cyclizations on Solid Phase Avena C. Ross, Hongqiang Liu, Vijaya R. Pattabiraman and John C. Vederas pp 462–463 DOI: 10.1021/ja9095945 Supporting Info

Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to β-Phthaliminoacrylate Esters toward the Synthesis of β-Amino Acids Takahiro Nishimura, Jun Wang, Makoto Nagaosa, Kazuhiro Okamoto, Ryo Shintani, Fuk-yee Kwong, Wing-yiu Yu, Albert S. C. Chan and Tamio Hayashi pp 464–465 DOI: 10.1021/ja909642h Supporting Info

Pd-Catalyzed Intramolecular Acylation of Aryl Bromides via C−H Functionalization: A Highly Efficient Synthesis of Benzocyclobutenones Paula Álvarez-Bercedo, Areli Flores-Gaspar, Arkaitz Correa and Ruben Martin pp 466–467 DOI: 10.1021/ja909811t Supporting Info

Pd(II)-Catalyzed C−H Activation/Aryl−Aryl Coupling of Phenol Esters Bin Xiao, Yao Fu, Jun Xu, Tian-Jun Gong, Jian-Jun Dai, Jun Yi and Lei Liu pp 468–469 DOI: 10.1021/ja909818n Supporting Info

InAs(ZnCdS) Quantum Dots Optimized for Biological Imaging in the Near-Infrared Peter M. Allen, Wenhao Liu, Vikash P. Chauhan, Jungmin Lee, Alice Y. Ting, Dai Fukumura, Rakesh K. Jain and Moungi G. Bawendi pp 470–471 DOI: 10.1021/ja908250r Supporting Info

Compact Biocompatible Quantum Dots via RAFT-Mediated Synthesis of Imidazole-Based Random Copolymer Ligand Wenhao Liu, Andrew B. Greytak, Jungmin Lee, Cliff R. Wong, Jongnam Park, Lisa F. Marshall, Wen Jiang, Peter N. Curtin, Alice Y. Ting, Daniel G. Nocera, Dai Fukumura, Rakesh K. Jain and Moungi G. Bawendi pp 472–483 DOI: 10.1021/ja908137d Supporting Info

Uncovering Individual Hydrogen Bonds in Rotaxanes by Frequency Shifts Barbara Kirchner, Christian Spickermann, Werner Reckien and Christoph A. Schalley pp 484–494 DOI: 10.1021/ja902628n Supporting Info

Synthesis, Structure, and Bonding of Stable Complexes of Pentavalent Uranyl Grgory Nocton, Pawel Horeglad, Valentina Vetere, Jacques Pcaut, Lionel Dubois, Pascale Maldivi, Norman M. Edelstein and Marinella Mazzanti pp 495–508 DOI: 10.1021/ja9037164 Supporting Info

Stable Holographic Gratings with Small-Molecular Trisazobenzene Derivatives Klaus Kreger, Pascal Wolfer, Hubert Audorff, Lothar Kador, Natalie Stingelin-Stutzmann, Paul Smith and Hans-Werner Schmidt pp 509–516 DOI: 10.1021/ja9091038 Supporting Info

Activation of Molecular Oxygen by a Dioxygenase Pathway by a Ruthenium Bis-bipyridine Compound with a Proximal Selenium Site Alexander Laskavy, Linda J. W. Shimon, Leonid Konstantinovski, Mark A. Iron and Ronny Neumann pp 517–523 DOI: 10.1021/ja9047027 Supporting Info

Direct Space Methods for Powder X-ray Diffraction for Guest−Host Materials: Applications to Cage Occupancies and Guest Distributions in Clathrate Hydrates Satoshi Takeya, Konstantin A. Udachin, Igor L. Moudrakovski, Robin Susilo and John A. Ripmeester pp 524–531 DOI: 10.1021/ja905426e Supporting Info

Oligomers of the Prion Protein Fragment 106−126 Are Likely Assembled from β-Hairpins in Solution, and Methionine Oxidation Inhibits Assembly without Altering the Peptide’s Monomeric Conformation Megan Grabenauer, Chun Wu, Patricia Soto, Joan-Emma Shea and Michael T. Bowers pp 532–539 DOI: 10.1021/ja905595k Supporting Info

Intrinsic Propensities of Amino Acid Residues in GxG Peptides Inferred from Amide I′ Band Profiles and NMR Scalar Coupling Constants Andrew Hagarman, Thomas J. Measey, Daniel Mathieu, Harald Schwalbe and Reinhard Schweitzer-Stenner pp 540–551 DOI: 10.1021/ja9058052 Supporting Info

Uniform Mesoporous Dye-Doped Silica Nanoparticles Decorated with Multiple Magnetite Nanocrystals for Simultaneous Enhanced Magnetic Resonance Imaging, Fluorescence Imaging, and Drug Delivery Ji Eun Lee, Nohyun Lee, Hyoungsu Kim, Jaeyun Kim, Seung Hong Choi, Jeong Hyun Kim, Taeho Kim, In Chan Song, Seung Pyo Park, Woo Kyung Moon and Taeghwan Hyeon pp 552–557 DOI: 10.1021/ja905793q Supporting Info

Mechanistic Detail Revealed via Comprehensive Kinetic Modeling of [rac-C2H4(1-indenyl)2ZrMe2]-Catalyzed 1-Hexene Polymerization Krista A. Novstrup, Nicholas E. Travia, Grigori A. Medvedev, Corneliu Stanciu, Jeffrey M. Switzer, Kendall T. Thomson, W. Nicholas Delgass, Mahdi M. Abu-Omar and James M. Caruthers pp 558–566 DOI: 10.1021/ja906332r Supporting Info

Binding of Coenzyme B Induces a Major Conformational Change in the Active Site of Methyl-Coenzyme M Reductase Sieglinde Ebner, Bernhard Jaun, Meike Goenrich, Rudolf K. Thauer and Jeffrey Harmer pp 567–575 DOI: 10.1021/ja906367h Supporting Info

Control of Muscle Differentiation by a Mitochondria-Targeted Fluorophore Yun Kyung Kim, Hyung-Ho Ha, Jun-Seok Lee, Xuezhi Bi, Young-Hoon Ahn, Siti Hajar, Jae-Jung Lee and Young-Tae Chang pp 576–579 DOI: 10.1021/ja906862g Supporting Info

Electronic Properties of Pentacene versus Triisopropylsilylethynyl-Substituted Pentacene: Environment-Dependent Effects of the Silyl Substituent Olga Lobanova Griffith, John E. Anthony, Adolphus G. Jones and Dennis L. Lichtenberger pp 580–586 DOI: 10.1021/ja906917r Supporting Info

Helical Structure of Xylose-DNA Amutha Ramaswamy, Mathy Froeyen, Piet Herdewijn and Arnout Ceulemans pp 587–595 DOI: 10.1021/ja9065877 Supporting Info

Electrochemical Stability of Nanometer-Scale Pt Particles in Acidic Environments Lei Tang, Byungchan Han, Kristin Persson, Cody Friesen, Ting He, Karl Sieradzki and Gerbrand Ceder pp 596–600 DOI: 10.1021/ja9071496 Supporting Info

Zn2+-Triggered Amide Tautomerization Produces a Highly Zn2+-Selective, Cell-Permeable, and Ratiometric Fluorescent Sensor Zhaochao Xu, Kyung-Hwa Baek, Ha Na Kim, Jingnan Cui, Xuhong Qian, David R. Spring, Injae Shin and Juyoung Yoon pp 601–610 DOI: 10.1021/ja907334j Supporting Info

Tuning the Extent of Chiral Amplification by Temperature in a Dynamic Supramolecular Polymer Maarten M. J. Smulders, Ivo A. W. Filot, Janus M. A. Leenders, Paul van der Schoot, Anja R. A. Palmans, Albertus P. H. J. Schenning and E. W. Meijer pp 611–619 DOI: 10.1021/ja908053d Supporting Info

Probing the Limits of the Majority-Rules Principle in a Dynamic Supramolecular Polymer Maarten M. J. Smulders, Patrick J. M. Stals, Tristan Mes, Tim F. E. Paffen, Albertus P. H. J. Schenning, Anja R. A. Palmans and E. W. Meijer pp 620–626 DOI: 10.1021/ja9080875 Supporting Info

Long-Range Charge Transfer through DNA by Replacing Adenine with Diaminopurine Kiyohiko Kawai, Haruka Kodera and Tetsuro Majima pp 627–630 DOI: 10.1021/ja907409z Supporting Info

A 6-mer Photocontrolled Oligonucleotide as an Effective Telomerase Inhibitor Yan Xu, Kenichiro Ito, Yuta Suzuki and Makoto Komiyama pp 631–637 DOI: 10.1021/ja907417r Supporting Info

Theoretical Analysis of Factors Controlling Pd-Catalyzed Decarboxylative Coupling of Carboxylic Acids with Olefins Song-Lin Zhang, Yao Fu, Rui Shang, Qing-Xiang Guo and Lei Liu pp 638–646 DOI: 10.1021/ja907448t Supporting Info

On the Chalcogenophilicity of Mercury: Evidence for a Strong Hg−Se Bond in [TmBut]HgSePh and Its Relevance to the Toxicity of Mercury Jonathan G. Melnick, Kevin Yurkerwich and Gerard Parkin pp 647–655 DOI: 10.1021/ja907523x Supporting Info

Activity-Based Proteome Profiling of Potential Cellular Targets of Orlistat − An FDA-Approved Drug with Anti-Tumor Activities Peng-Yu Yang, Kai Liu, Mun Hong Ngai, Martin J. Lear, Markus R. Wenk and Shao Q. Yao pp 656–666 DOI: 10.1021/ja907716f Supporting Info

In Situ XAS and XRPD Parametric Rietveld Refinement To Understand Dealumination of Y Zeolite Catalyst Giovanni Agostini, Carlo Lamberti, Luca Palin, Marco Milanesio, Nadiya Danilina, Bin Xu, Markus Janousch and Jeroen A. van Bokhoven pp 667–678 DOI: 10.1021/ja907696h Supporting Info

Long-Range Assembly of DNA into Nanofibers and Highly Ordered Networks Using a Block Copolymer Approach Karina M. M. Carneiro, Faisal A. Aldaye and Hanadi F. Sleiman pp 679–685 DOI: 10.1021/ja907735m Supporting Info

Synthetic Applications of Pd(II)-Catalyzed C−H Carboxylation and Mechanistic Insights: Expedient Routes to Anthranilic Acids, Oxazolinones, and Quinazolinones Ramesh Giri, Jonathan K. Lam and Jin-Quan Yu pp 686–693 DOI: 10.1021/ja9077705 Supporting Info

Ensemble Calculations of Unstructured Proteins Constrained by RDC and PRE Data: A Case Study of Urea-Denatured Ubiquitin Jie-rong Huang and Stephan Grzesiek pp 694–705 DOI: 10.1021/ja907974m Supporting Info

Color-Tuning Mechanism of Firefly Investigated by Multi-Configurational Perturbation Method Isabelle Navizet, Ya-Jun Liu, Nicolas Ferr, Hong-Yan Xiao, Wei-Hai Fang and Roland Lindh pp 706–712 DOI: 10.1021/ja908051h Supporting Info

Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Supported Ru−Monomer Complex Catalyst Mizuki Tada, Satoshi Muratsugu, Mutsuo Kinoshita, Takehiko Sasaki and Yasuhiro Iwasawa pp 713–724 DOI: 10.1021/ja9079513 Supporting Info

Design of Bis-spiropyran Ligands as Dipolar Molecule Receptors and Application to in Vivo Glutathione Fluorescent Probes Na Shao, Jianyu Jin, Hao Wang, Jing Zheng, Ronghua Yang, Winghong Chan and Zeper Abliz pp 725–736 DOI: 10.1021/ja908215t Supporting Info

Kinetically Controlled Photoinduced Electron Transfer Switching in Cu(I)-Responsive Fluorescent Probes Aneese F. Chaudhry, Manjusha Verma, M. Thomas Morgan, Maged M. Henary, Nisan Siegel, Joel M. Hales, Joseph W. Perry and Christoph J. Fahrni pp 737–747 DOI: 10.1021/ja908326z Supporting Info

Compressing the Most Hydrogen-Rich Inorganic Ion Georgios Markopoulos, Peter Kroll and Roald Hoffmann pp 748–755 DOI: 10.1021/ja908345e Supporting Info

Superior Contact for Single-Molecule Conductance: Electronic Coupling of Thiolate and Isothiocyanate on Pt, Pd, and Au Chih-Hung Ko, Min-Jie Huang, Ming-Dung Fu and Chun-hsien Chen pp 756–764 DOI: 10.1021/ja9084012

Selectively Metallized Polymeric Substrates by Microcontact Printing an Aluminum(III) Porphyrin Complex Michael S. Miller, Heather L. Filiatrault, Gregory J. E. Davidson, Minmin Luo and Tricia Breen Carmichael pp 765–772 DOI: 10.1021/ja908433p Supporting Info

Gated Molecular Recognition and Dynamic Discrimination of Guests Stephen Rieth, Xiaoguang Bao, Bao-Yu Wang, Christopher M. Hadad and Jovica D. Badji pp 773–776 DOI: 10.1021/ja908436c Supporting Info

Guest-Encapsulation Properties of a Self-Assembled Capsule by Dynamic Boronic Ester Bonds Naoki Nishimura, Kenji Yoza and Kenji Kobayashi pp 777–790 DOI: 10.1021/ja9084918 Supporting Info

Sonochemical Formation of Methyl Hydroperoxide in Polar Aprotic Solvents and Its Effect on Single-Walled Carbon Nanotube Dispersion Stability Michael W. Forney and Jordan C. Poler pp 791–797 DOI: 10.1021/ja9085462 Supporting Info

Heme-Coordinating Inhibitors of Neuronal Nitric Oxide Synthase. Iron−Thioether Coordination Is Stabilized by Hydrophobic Contacts without Increased Inhibitor Potency Jeffrey D. Martell, Huiying Li, Tzanko Doukov, Pavel Martsek, Linda J. Roman, Michael Soltis, Thomas L. Poulos and Richard B. Silverman pp 798–806 DOI: 10.1021/ja908544f Supporting Info

Cyclization of Arylacetoacetates to Indene and Dihydronaphthalene Derivatives in Strong Acids. Evidence for Involvement of Further Protonation of O,O-Diprotonated β-Ketoester, Leading to Enhancement of Cyclization Hiroaki Kurouchi, Hiromichi Sugimoto, Yuko Otani and Tomohiko Ohwada pp 807–815 DOI: 10.1021/ja908749u Supporting Info

An Antibiotic-Resistance Enzyme from a Deep-Sea Bacterium Marta Toth, Clyde Smith, Hilary Frase, Shahriar Mobashery and Sergei Vakulenko pp 816–823 DOI: 10.1021/ja908850p Supporting Info

Δ12-Prostaglandin J2 as a Product and Ligand of Human Serum Albumin: Formation of an Unusual Covalent Adduct at His146 Satoru Yamaguchi, Giancarlo Aldini, Sohei Ito, Nozomi Morishita, Takahiro Shibata, Giulio Vistoli, Marina Carini and Koji Uchida pp 824–832 DOI: 10.1021/ja908878n Supporting Info

The New Face of Rhodium Alloys: Revealing Ordered Structures from First Principles Ohad Levy, Roman V. Chepulskii, Gus L. W. Hart and Stefano Curtarolo pp 833–837 DOI: 10.1021/ja908879y

Electronic Structures, Hole-Doping, and Superconductivity of the s = 1, 2, 3, and 4 Members of the (Cu,Mo)-12s2 Homologous Series of Superconductive Copper Oxides Inga Grigoraviciute, Maarit Karppinen, Ting-Shan Chan, Ru-Shi Liu, Jin-Ming Chen, Omar Chmaissem and Hisao Yamauchi pp 838–841 DOI: 10.1021/ja9087067 Supporting Info

Effects of Cosolvents on the Hydration of Carbon Nanotubes Lijiang Yang and Yi Qin Gao pp 842–848 DOI: 10.1021/ja9091825

Infrared Spectroscopy of Hydrated Bicarbonate Anion Clusters: HCO3−(H2O)1−10 Etienne Garand, Torsten Wende, Daniel J. Goebbert, Risshu Bergmann, Gerard Meijer, Daniel M. Neumark and Knut R. Asmis pp 849–856 DOI: 10.1021/ja9093132 Supporting Info

Plasmon-Induced Photodegradation of Toxic Pollutants with Ag−AgI/Al2O3 under Visible-Light Irradiation Chun Hu, Tianwei Peng, Xuexiang Hu, Yulun Nie, Xuefeng Zhou, Jiuhui Qu and Hong He pp 857–862 DOI: 10.1021/ja907792d Supporting Info

Tyrosine Analogues for Probing Proton-Coupled Electron Transfer Processes in Peptides and Proteins Susheel J. Nara, Luca Valgimigli, Gian Franco Pedulli and Derek A. Pratt pp 863–872 DOI: 10.1021/ja907921w Supporting Info

Conductive Behavior of High TiO2 Nanoparticle Content of Inorganic/Organic Nanostructured Composites Junkal Gutierrez, Agnieszka Tercjak and Iaki Mondragon pp 873–878 DOI: 10.1021/ja908359k

Palladium-Catalyzed γ-Selective and Stereospecific Allyl−Aryl Coupling between Acyclic Allylic Esters and Arylboronic Acids Hirohisa Ohmiya, Yusuke Makida, Dong Li, Masahito Tanabe and Masaya Sawamura pp 879–889 DOI: 10.1021/ja9092264 Supporting Info

Reductive and Transition-Metal-Free: Oxidation of Secondary Alcohols by Sodium Hydride Xinbo Wang, Bo Zhang and David Zhigang Wang p 890 DOI: 10.1021/ja910615z

Issue 03

DNA-Mediated Charge Transport in Redox Sensing and Signaling Joseph C. Genereux, Amie K. Boal and Jacqueline K. Barton pp 891–905 DOI: 10.1021/ja907669c Supporting Info

Intermetallics as Novel Supports for Pt Monolayer O2 Reduction Electrocatalysts: Potential for Significantly Improving Properties Tanushree Ghosh, Miomir B. Vukmirovic, Francis J. DiSalvo and Radoslav R. Adzic pp 906–907 DOI: 10.1021/ja905850c Supporting Info

A New Pnictide Superconductor without Iron Jian-Tao Han, Jian-Shi Zhou, Jin-Guang Cheng and John B. Goodenough pp 908–909 DOI: 10.1021/ja906883q

Mechanism of Heterolysis of H2 by an Unsaturated d8 Nickel Center: via Tetravalent Nickel? Tao He, Nikolay P. Tsvetkov, Jos G. Andino, Xinfeng Gao, Benjamin C. Fullmer and Kenneth G. Caulton pp 910–911 DOI: 10.1021/ja908674x Supporting Info

Interconversion between a Nonporous Nanocluster and a Microporous Coordination Polymer Showing Selective Gas Adsorption Yan-Juan Zhang, Tao Liu, Shinji Kanegawa and Osamu Sato pp 912–913 DOI: 10.1021/ja908670u Supporting Info

Unexpected CO2 Splitting Reactions To Form CO with N-Heterocyclic Carbenes as Organocatalysts and Aromatic Aldehydes as Oxygen Acceptors Liuqun Gu and Yugen Zhang pp 914–915 DOI: 10.1021/ja909038t Supporting Info

Highly Efficient Cu(I)-Catalyzed Synthesis of N-Heterocycles through a Cyclization-Triggered Addition of Alkynes Junbin Han, Bo Xu and Gerald B. Hammond pp 916–917 DOI: 10.1021/ja908883n Supporting Info

The HN(COCA)HAHB NMR Experiment for the Stereospecific Assignment of Hβ-Protons in Non-native States of Proteins Martin J. Hhnke, Christian Richter, Friederike Heinicke and Harald Schwalbe pp 918–919 DOI: 10.1021/ja909239w Supporting Info

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides with Alkyl Halides Daniel A. Everson, Ruja Shrestha and Daniel J. Weix pp 920–921 DOI: 10.1021/ja9093956 Supporting Info

Porous Phosphorescent Coordination Polymers for Oxygen Sensing Zhigang Xie, Liqing Ma, Kathryn E. deKrafft, Athena Jin and Wenbin Lin pp 922–923 DOI: 10.1021/ja909629f Supporting Info

Catalytic Alkylation of Methyl-N-Heteroaromatics with Alcohols Benot Blank and Rhett Kempe pp 924–925 DOI: 10.1021/ja9095413 Supporting Info

Discovery of 3-Formyl-Tyrosine Metabolites from Pseudoalteromonas tunicata through Heterologous Expression Leah C. Blasiak and Jon Clardy pp 926–927 DOI: 10.1021/ja9097862 Supporting Info

Synthesis and Reactivity of Iron Acyl Complexes Modeling the Active Site of [Fe]-Hydrogenase Dafa Chen, Rosario Scopelliti and Xile Hu pp 928–929 DOI: 10.1021/ja9100485 Supporting Info

Addition of Amines and Hydroborane to the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) Giving Amino- and Boryl-Substituted Disilenes Katsuhiko Takeuchi, Masao Ikoshi, Masaaki Ichinohe and Akira Sekiguchi pp 930–931 DOI: 10.1021/ja910157h Supporting Info

Highly Sequence-Dependent Formation of Fluorescent Silver Nanoclusters in Hybridized DNA Duplexes for Single Nucleotide Mutation Identification Weiwei Guo, Jipei Yuan, Qingzhe Dong and Erkang Wang pp 932–934 DOI: 10.1021/ja907075s Supporting Info

FexOy@C Spheres as an Excellent Catalyst for Fischer−Tropsch Synthesis Guobin Yu, Bo Sun, Yan Pei, Songhai Xie, Shirun Yan, Minghua Qiao, Kangnian Fan, Xiaoxin Zhang and Baoning Zong pp 935–937 DOI: 10.1021/ja906370b Supporting Info

A Small Molecule-Regulated Guanine Nucleotide Exchange Factor Inna Goreshnik and Dustin J. Maly pp 938–940 DOI: 10.1021/ja907886v Supporting Info

Inhibition of Hypoxia Inducible Factor 1—Transcription Coactivator Interaction by a Hydrogen Bond Surrogate α-Helix Laura K. Henchey, Swati Kushal, Ramin Dubey, Ross N. Chapman, Bogdan Z. Olenyuk and Paramjit S. Arora pp 941–943 DOI: 10.1021/ja9082864 Supporting Info

Thickness-Dependent Morphologies of Gold on N-Layer Graphenes Haiqing Zhou, Caiyu Qiu, Zheng Liu, Huaichao Yang, Lijun Hu, Ji Liu, Haifang Yang, Changzhi Gu and Lianfeng Sun pp 944–946 DOI: 10.1021/ja909228n Supporting Info

Upconversion for White Light Generation by a Single Compound Jiwei Wang and Peter A. Tanner pp 947–949 DOI: 10.1021/ja909254u Supporting Info

Control over Catenation in Metal−Organic Frameworks via Rational Design of the Organic Building Block Omar K. Farha, Christos D. Malliakas, Mercouri G. Kanatzidis and Joseph T. Hupp pp 950–952 DOI: 10.1021/ja909519e Supporting Info

Ligand-Controlled Polytypism of Thick-Shell CdSe/CdS Nanocrystals Benot Mahler, Nicolas Lequeux and Benot Dubertret pp 953–959 DOI: 10.1021/ja9034973 Supporting Info

Engineering Double to Quintuple Stacks of a Polarized Aromatic in Confined Cavities Yoshihiro Yamauchi, Michito Yoshizawa, Munetaka Akita and Makoto Fujita pp 960–966 DOI: 10.1021/ja904063r Supporting Info

Conformationally Gated Fragmentations and Rearrangements Promoted by Interception of the Bergman Cyclization through Intramolecular H-Abstraction: A Possible Mechanism of Auto-Resistance to Natural Enediyne Antibiotics? Abdulkader Baroudi, Justin Mauldin and Igor V. Alabugin pp 967–979 DOI: 10.1021/ja905100u Supporting Info

Determination of Penetratin Secondary Structure in Live Cells with Raman Microscopy Jing Ye, Sara A. Fox, Mare Cudic, Evonne M. Rezler, Janelle L. Lauer, Gregg B. Fields and Andrew C. Terentis pp 980–988 DOI: 10.1021/ja9043196 Supporting Info

Successful Stabilization of the Elusive Species {FeNO}8 in a Heme Model Juan Pellegrino, Sara E. Bari, Damin E. Bikiel and Fabio Doctorovich pp 989–995 DOI: 10.1021/ja905062w Supporting Info

Influence of Size on the Rate of Mesoporous Electrodes for Lithium Batteries Yu Ren, A. Robert Armstrong, Feng Jiao and Peter G. Bruce pp 996–1004 DOI: 10.1021/ja905488x Supporting Info

External and Internal Guest Binding of a Highly Charged Supramolecular Host in Water: Deconvoluting the Very Different Thermodynamics Carmelo Sgarlata, Jeffrey S. Mugridge, Michael D. Pluth, Bryan E. F. Tiedemann, Valeria Zito, Giuseppe Arena and Kenneth N. Raymond pp 1005–1009 DOI: 10.1021/ja9056739 Supporting Info

Mapping the Network of Pathways of CO Diffusion in Myoglobin Luca Maragliano, Grazia Cottone, Giovanni Ciccotti and Eric Vanden-Eijnden pp 1010–1017 DOI: 10.1021/ja905671x Supporting Info

Array-Based Sensing of Normal, Cancerous, and Metastatic Cells Using Conjugated Fluorescent Polymers Avinash Bajaj, Oscar R. Miranda, Ronnie Phillips, Ik-Bum Kim, D. Joseph Jerry, Uwe H. F. Bunz and Vincent M. Rotello pp 1018–1022 DOI: 10.1021/ja9061272 Supporting Info

Tailored Synthetic Polyamines for Controlled Biomimetic Silica Formation Anja Bernecker, Ralph Wieneke, Radostan Riedel, Michael Seibt, Armin Geyer and Claudia Steinem pp 1023–1031 DOI: 10.1021/ja9061163 Supporting Info

High-Resolution Solid-State NMR Structure of a 17.6 kDa Protein Ivano Bertini, Anusarka Bhaumik, Gal De Pape, Robert G. Griffin, Moreno Lelli, Jzef R. Lewandowski and Claudio Luchinat pp 1032–1040 DOI: 10.1021/ja906426p Supporting Info

Chemical Control of the Photoluminescence of CdSe Quantum Dot−Organic Complexes with a Series of Para-Substituted Aniline Ligands Kathryn E. Knowles, Daniel B. Tice, Eric A. McArthur, Gemma C. Solomon and Emily A. Weiss pp 1041–1050 DOI: 10.1021/ja907253s Supporting Info

MNAzymes, a Versatile New Class of Nucleic Acid Enzymes That Can Function as Biosensors and Molecular Switches Elisa Mokany, Simon M. Bone, Paul E. Young, Tram B. Doan and Alison V. Todd pp 1051–1059 DOI: 10.1021/ja9076777 Supporting Info

Kinetics of Electron Transfer Reactions of H2-Evolving Cobalt Diglyoxime Catalysts Jillian L. Dempsey, Jay R. Winkler and Harry B. Gray pp 1060–1065 DOI: 10.1021/ja9080259 Supporting Info

Cyclic Tetrathiophenes Planarized by Silicon and Sulfur Bridges Bearing Antiaromatic Cyclooctatetraene Core: Syntheses, Structures, and Properties Takeshi Ohmae, Tohru Nishinaga, Mo Wu and Masahiko Iyoda pp 1066–1074 DOI: 10.1021/ja908161r Supporting Info

Hydrophobic Peptide Channels and Encapsulated Water Wires Upadhyayula S. Raghavender, Kantharaju, Subrayashastry Aravinda, Narayanaswamy Shamala and Padmanabhan Balaram pp 1075–1086 DOI: 10.1021/ja9083978 Supporting Info

Trends in Substrate Hydroxylation Reactions by Heme and Nonheme Iron(IV)-Oxo Oxidants Give Correlations between Intrinsic Properties of the Oxidant with Barrier Height Sam P. de Visser pp 1087–1097 DOI: 10.1021/ja908340j Supporting Info

EPR and Mssbauer Spectroscopy Show Inequivalent Hemes in Tryptophan Dioxygenase Rupal Gupta, Rong Fu, Aimin Liu and Michael P. Hendrich pp 1098–1109 DOI: 10.1021/ja908851e Supporting Info

Probing Donor−Acceptor Interactions and Co-Conformational Changes in Redox Active Desymmetrized [2]Catenanes Dennis Cao, Matteo Amelia, Liana M. Klivansky, Gayane Koshkakaryan, Saeed I. Khan, Monica Semeraro, Serena Silvi, Margherita Venturi, Alberto Credi and Yi Liu pp 1110–1122 DOI: 10.1021/ja909041g Supporting Info

High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene Sakya S. Sen, Herbert W. Roesky, Daniel Stern, Julian Henn and Dietmar Stalke pp 1123–1126 DOI: 10.1021/ja9091374 Supporting Info

Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host−Guest Interactions Thomas Devic, Patricia Horcajada, Christian Serre, Fabrice Salles, Guillaume Maurin, Batrice Moulin, Daniela Heurtaux, Guillaume Clet, Alexandre Vimont, Jean-Marc Grenche, Benjamin Le Ouay, Florian Moreau, Emmanuel Magnier, Yaroslav Filinchuk, Jerme Marrot, Jean-Claude Lavalley, Marco Daturi and Grard Frey pp 1127–1136 DOI: 10.1021/ja9092715 Supporting Info

Solvent Effects on Catalysis by Escherichia coli Dihydrofolate Reductase E. Joel Loveridge, Lai-Hock Tey and Rudolf K. Allemann pp 1137–1143 DOI: 10.1021/ja909353c Supporting Info

Effect of Selective Solvent Addition Rate on the Pathways for Spontaneous Vesicle Formation of ABA Amphiphilic Triblock Copolymers Yuanyuan Han, Haizhou Yu, Hongbo Du and Wei Jiang pp 1144–1150 DOI: 10.1021/ja909379y Supporting Info

Total Synthesis of the N,C-Coupled Naphthylisoquinoline Alkaloids Ancistrocladinium A and B and Related Analogues Gerhard Bringmann, Tanja Gulder, Barbara Hertlein, Yasmin Hemberger and Frank Meyer pp 1151–1158 DOI: 10.1021/ja9097687 Supporting Info

Total Synthesis of the Antimitotic Bicyclic Peptide Celogentin C Bing Ma, Biplab Banerjee, Dmitry N. Litvinov, Liwen He and Steven L. Castle pp 1159–1171 DOI: 10.1021/ja909870g Supporting Info

Enantioselective Hydrogenation of α-Aryloxy and α-Alkoxy α,β-Unsaturated Carboxylic Acids Catalyzed by Chiral Spiro Iridium/Phosphino-Oxazoline Complexes Shen Li, Shou-Fei Zhu, Jian-Hua Xie, Song Song, Can-Ming Zhang and Qi-Lin Zhou pp 1172–1179 DOI: 10.1021/ja909810k Supporting Info

Two-Dimensional Optical Spectroscopy Eric B. Brauns p 1180 DOI: 10.1021/ja910176w

Issue 04

High-Precision Measurement of Isotope Effects on Noncovalent Host−Guest Interactions Jeffrey S. Mugridge, Robert G. Bergman and Kenneth N. Raymond pp 1182–1183 DOI: 10.1021/ja905170x Supporting Info

Highly Enantioselective Intramolecular Copper Catalyzed C−H Insertion Reactions of α-Diazosulfones Christopher J. Flynn, Curtis J. Elcoate, Simon E. Lawrence and Anita R. Maguire pp 1184–1185 DOI: 10.1021/ja909713a Supporting Info

Induction of Amyloid Fibrils by the C-Terminal Fragments of TDP-43 in Amyotrophic Lateral Sclerosis Allan K.-H. Chen, Ryan Y.-Y. Lin, Eva Z.-J. Hsieh, Pang-Hsien Tu, Rita P.-Y. Chen, Tai-Yan Liao, Wenlung Chen, Chih-Hsien Wang and Joseph J.-T. Huang pp 1186–1187 DOI: 10.1021/ja9066207 Supporting Info

Intramolecular Oxamidation of Unsaturated O-Alkyl Hydroxamates: A Remarkably Versatile Entry to Hydroxy Lactams Duncan J. Wardrop, Edward G. Bowen, Raymond E. Forslund, Adam D. Sussman and Samanthi L. Weerasekera pp 1188–1189 DOI: 10.1021/ja9069997 Supporting Info

NHC Catalyzed Oxidations of Aldehydes to Esters: Chemoselective Acylation of Alcohols in Presence of Amines Suman De Sarkar, Stefan Grimme and Armido Studer pp 1190–1191 DOI: 10.1021/ja910540j Supporting Info

Protonic Gating of Excited-State Twisting and Charge Localization in GFP Chromophores: A Mechanistic Hypothesis for Reversible Photoswitching Seth Olsen, Kristina Lamothe and Todd J. Martnez pp 1192–1193 DOI: 10.1021/ja907447k Supporting Info

Visualizing Ascorbate-Triggered Release of Labile Copper within Living Cells using a Ratiometric Fluorescent Sensor Dylan W. Domaille, Li Zeng and Christopher J. Chang pp 1194–1195 DOI: 10.1021/ja907778b Supporting Info

Switching Single Azopyridine Supramolecules in Ordered Arrays on Au(111) Yongfeng Wang, Xin Ge, Guillaume Schull, Richard Berndt, Hao Tang, Claudia Bornholdt, Felix Koehler and Rainer Herges pp 1196–1197 DOI: 10.1021/ja9080277 Supporting Info

Maze Solving by Chemotactic Droplets Istvn Lagzi, Siowling Soh, Paul J. Wesson, Kevin P. Browne and Bartosz A. Grzybowski pp 1198–1199 DOI: 10.1021/ja9076793 Supporting Info

Curvature Sensing by the Epsin N-Terminal Homology Domain Measured on Cylindrical Lipid Membrane Tethers Benjamin R. Capraro, Youngdae Yoon, Wonhwa Cho and Tobias Baumgart pp 1200–1201 DOI: 10.1021/ja907936c Supporting Info

Copper-Promoted Coupling of Vinyl Boronates and Alcohols: A Mild Synthesis of Allyl Vinyl Ethers Ryan E. Shade, Alan M. Hyde, John-Carl Olsen and Craig A. Merlic pp 1202–1203 DOI: 10.1021/ja907982w Supporting Info

Recognition of Patterned Molecular Ink with Phage Displayed Peptides Yue Cui, Anupama Pattabiraman, Bozhena Lisko, Samantha C. Collins and Michael C. McAlpine pp 1204–1205 DOI: 10.1021/ja9081809 Supporting Info

Enantioselective Synthesis of Allylic Esters via Asymmetric Allylic Substitution with Metal Carboxylates Using Planar-Chiral Cyclopentadienyl Ruthenium Catalysts Naoya Kanbayashi and Kiyotaka Onitsuka pp 1206–1207 DOI: 10.1021/ja908456b Supporting Info

Evidence of Double-Walled Al−Ge Imogolite-Like Nanotubes. A Cryo-TEM and SAXS Investigation Perrine Maillet, Clment Levard, Eric Larquet, Clarisse Mariet, Olivier Spalla, Nicolas Menguy, Armand Masion, Emmanuel Doelsch, Jrme Rose and Antoine Thill pp 1208–1209 DOI: 10.1021/ja908707a Supporting Info

Unique Catalytic Mechanism of Phosphatidylinositol-Specific Phospholipase C from Streptomyces antibioticus Chuan Bai, Li Zhao, Ming-Daw Tsai and Karol S. Bruzik pp 1210–1211 DOI: 10.1021/ja908285h Supporting Info

Chemically Programmed Ultrahigh Density Two-Dimensional Semiconductor Superlattice Array Narayan Pradhan, Somobrata Acharya, Katsuhiko Ariga, Niladri S. Karan, D. D. Sarma, Yoshiki Wada, Shlomo Efrima and Yuval Golan pp 1212–1213 DOI: 10.1021/ja908868b Supporting Info

Evidence of Water Adsorption in Hydrophobic Nanospaces of Highly Pure Double-Walled Carbon Nanotubes Yousheng Tao, Hiroyuki Muramatsu, Morinobu Endo and Katsumi Kaneko pp 1214–1215 DOI: 10.1021/ja9091215 Supporting Info

A Two-Photon Fluorescent Probe for Thiols in Live Cells and Tissues Jun Han Lee, Chang Su Lim, Yu Shun Tian, Ji Hee Han and Bong Rae Cho pp 1216–1217 DOI: 10.1021/ja9090676 Supporting Info

Modulation of Buried Ionizable Groups in Proteins with Engineered Surface Charge Angel L. Pey, David Rodriguez-Larrea, Jose A. Gavira, Bertrand Garcia-Moreno and Jose M. Sanchez-Ruiz pp 1218–1219 DOI: 10.1021/ja909298v Supporting Info

Enhanced Conformational Space Sampling Improves the Prediction of Chemical Shifts in Proteins Phineus R. L. Markwick, Carla F. Cervantes, Barrett L. Abel, Elizabeth A. Komives, Martin Blackledge and J. Andrew McCammon pp 1220–1221 DOI: 10.1021/ja9093692 Supporting Info

Analysis of p300/CBP Histone Acetyltransferase Regulation Using Circular Permutation and Semisynthesis Kannan R. Karukurichi, Ling Wang, Lerna Uzasci, Cara Marie Manlandro, Qing Wang and Philip A. Cole pp 1222–1223 DOI: 10.1021/ja909466d Supporting Info

Slow Magnetic Relaxation in a High-Spin Iron(II) Complex Danna E. Freedman, W. Hill Harman, T. David Harris, Gary J. Long, Christopher J. Chang and Jeffrey R. Long pp 1224–1225 DOI: 10.1021/ja909560d Supporting Info

Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboronates Yusuke Sasaki, Chongmin Zhong, Masaya Sawamura and Hajime Ito pp 1226–1227 DOI: 10.1021/ja909640b Supporting Info

Modulation of Electron Injection in CdSe−TiO2 System through Medium Alkalinity Vidhya Chakrapani, Kevin Tvrdy and Prashant V. Kamat pp 1228–1229 DOI: 10.1021/ja909663r Supporting Info

The Structural Basis of Cryptosporidium-Specific IMP Dehydrogenase Inhibitor Selectivity Iain S. MacPherson, Sivapriya Kirubakaran, Suresh Kumar Gorla, Thomas V. Riera, J. Alejandro D’Aquino, Minjia Zhang, Gregory D. Cuny and Lizbeth Hedstrom pp 1230–1231 DOI: 10.1021/ja909947a Supporting Info

On the Absolute Configurational Stability of Bromonium and Chloronium Ions Scott E. Denmark, Matthew T. Burk and Andrew J. Hoover pp 1232–1233 DOI: 10.1021/ja909965h Supporting Info

Electrochemical Proton-Coupled Electron Transfer of an Osmium Aquo Complex: Theoretical Analysis of Asymmetric Tafel Plots and Transfer Coefficients Michelle K. Ludlow, Alexander V. Soudackov and Sharon Hammes-Schiffer pp 1234–1235 DOI: 10.1021/ja910277p Supporting Info

Total Synthesis of (−)-Mersicarpine Rie Nakajima, Tsuyoshi Ogino, Satoshi Yokoshima and Tohru Fukuyama pp 1236–1237 DOI: 10.1021/ja9103233 Supporting Info

Rhodium-Catalyzed Asymmetric Reductive Cyclization of Heteroatom-Linked 5-Alkynals with Heteroatom-Substituted Acetaldehydes Rie Tanaka, Keiichi Noguchi and Ken Tanaka pp 1238–1239 DOI: 10.1021/ja9104655 Supporting Info

Polymer Glass Transitions Switch Electron Transfer in Individual Molecules Joanna R. Siekierzycka, Catharina Hippius, Frank Wrthner, Ren M. Williams and Albert M. Brouwer pp 1240–1242 DOI: 10.1021/ja905667c Supporting Info

Mechanistic Duality in Palladium-Catalyzed Cross-Coupling Reactions of Aryldimethylsilanolates. Intermediacy of an 8-Si-4 Arylpalladium(II) Silanolate Scott E. Denmark and Russell C. Smith pp 1243–1245 DOI: 10.1021/ja907049y Supporting Info

Anisotropic Collective Motion Contributes to Nuclear Spin Relaxation in Crystalline Proteins Jzef R. Lewandowski, Julien Sein, Martin Blackledge and Lyndon Emsley pp 1246–1248 DOI: 10.1021/ja907067j Supporting Info

Metal-Free Highly Regioselective Aminotrifluoroacetoxylation of Alkenes Helena M. Lovick and Forrest E. Michael pp 1249–1251 DOI: 10.1021/ja906648w Supporting Info

On the Binding of Cationic, Water-Soluble Conjugated Polymers to DNA: Electrostatic and Hydrophobic Interactions Fan Xia, Xiaolei Zuo, Renqiang Yang, Yi Xiao, Di Kang, Alexis Valle-Blisle, Xiong Gong, Alan J. Heeger and Kevin W. Plaxco pp 1252–1254 DOI: 10.1021/ja908890q Supporting Info

Catalytic Asymmetric Synthesis of 3-Aminooxindoles: Enantiofacial Selectivity Switch in Bimetallic vs Monometallic Schiff Base Catalysis Shinsuke Mouri, Zhihua Chen, Harunobu Mitsunuma, Makoto Furutachi, Shigeki Matsunaga and Masakatsu Shibasaki pp 1255–1257 DOI: 10.1021/ja908906n Supporting Info

Resistance Switching in Electrodeposited Magnetite Superlattices Jay A. Switzer, Rakesh V. Gudavarthy, Elizabeth A. Kulp, Guojun Mu, Zhen He and Andrew J. Wessel pp 1258–1260 DOI: 10.1021/ja909295y Supporting Info

Design, Synthesis, and Characterization of a Persistent Nonacene Derivative Irvinder Kaur, Mikael Jazdzyk, Nathan N. Stein, Polina Prusevich and Glen P. Miller pp 1261–1263 DOI: 10.1021/ja9095472 Supporting Info

Nickel/Bis(oxazoline)-Catalyzed Asymmetric Kumada Reactions of Alkyl Electrophiles: Cross-Couplings of Racemic α-Bromoketones Sha Lou and Gregory C. Fu pp 1264–1266 DOI: 10.1021/ja909689t Supporting Info

Indolyne and Aryne Distortions and Nucleophilic Regioselectivites Paul H.-Y. Cheong, Robert S. Paton, Sarah M. Bronner, G-Yoon J. Im, Neil K. Garg and K. N. Houk pp 1267–1269 DOI: 10.1021/ja9098643 Supporting Info

Defining Conformational Ensembles of Intrinsically Disordered and Partially Folded Proteins Directly from Chemical Shifts Malene Ringkjøbing Jensen, Loc Salmon, Gabrielle Nodet and Martin Blackledge pp 1270–1272 DOI: 10.1021/ja909973n Supporting Info

Carboxylate as the Protonation Site in (Peroxo)diiron(III) Model Complexes of Soluble Methane Monooxygenase and Related Diiron Proteins Loi H. Do, Takahiro Hayashi, Pierre Monne-Loccoz and Stephen J. Lippard pp 1273–1275 DOI: 10.1021/ja909718f Supporting Info

Polarity-Sensitive Coumarins Tailored to Live Cell Imaging Giovanni Signore, Riccardo Nifos, Lorenzo Albertazzi, Barbara Storti and Ranieri Bizzarri pp 1276–1288 DOI: 10.1021/ja9050444 Supporting Info

High-Throughput Discovery of Synthetic Surfaces That Support Proliferation of Pluripotent Cells Ratmir Derda, Samira Musah, Brendan P. Orner, Joseph R. Klim, Lingyin Li and Laura L. Kiessling pp 1289–1295 DOI: 10.1021/ja906089g Supporting Info

Mechanism of Gold Nanoparticle Formation in the Classical Citrate Synthesis Method Derived from Coupled In Situ XANES and SAXS Evaluation Jrg Polte, T. Torsten Ahner, Friedmar Delissen, Sergey Sokolov, Franziska Emmerling, Andreas F. Thnemann and Ralph Kraehnert pp 1296–1301 DOI: 10.1021/ja906506j Supporting Info

Origin of Intense Chiroptical Effects in Undecagold Subnanometer Particles Makenzie R. Provorse and Christine M. Aikens pp 1302–1310 DOI: 10.1021/ja906884m Supporting Info

The Two Enantiomers of Citalopram Bind to the Human Serotonin Transporter in Reversed Orientations Heidi Koldsø, Kasper Severinsen, Thuy Tien Tran, Leyla Celik, Henrik Helligsø Jensen, Ove Wiborg, Birgit Schiøtt and Steffen Sinning pp 1311–1322 DOI: 10.1021/ja906923j Supporting Info

Ga8Br8·6NEt3: Formation and Structure of Donor-Stabilized GaBr. A Nanoscaled Step on the Way to β-Gallium? Taike Duan, Patrick Henke, Gregor Stβer, Qian-Feng Zhang and Hansgeorg Schnckel pp 1323–1327 DOI: 10.1021/ja907060q Supporting Info

2D Assembly of Metallacycles on HOPG by Shape-Persistent Macrocycle Templates Ting Chen, Ge-Bo Pan, Henning Wettach, Martin Fritzsche, Sigurd Hger, Li-Jun Wan, Hai-Bo Yang, Brian H. Northrop and Peter J. Stang pp 1328–1333 DOI: 10.1021/ja907220f Supporting Info

Presentation of Membrane-Anchored Glycosphingolipids Determined from Molecular Dynamics Simulations and NMR Paramagnetic Relaxation Rate Enhancement Mari L. DeMarco, Robert J. Woods, James H. Prestegard and Fang Tian pp 1334–1338 DOI: 10.1021/ja907518x Supporting Info

Three-Dimensional Chemical Profile Manipulation Using Two-Dimensional Autonomous Microfluidic Control YongTae Kim, Kerem Pekkan, William C. Messner and Philip R. LeDuc pp 1339–1347 DOI: 10.1021/ja9079572 Supporting Info

Ultrafast Optical Excitations In Supramolecular Metallacycles with Charge Transfer Properties Daniel C. Flynn, Guda Ramakrishna, Hai-Bo Yang, Brian H. Northrop, Peter J. Stang and Theodore Goodson, III pp 1348–1358 DOI: 10.1021/ja9082655

A Substructure Combination Strategy To Create Potent and Selective Transthyretin Kinetic Stabilizers That Prevent Amyloidogenesis and Cytotoxicity Sungwook Choi, Natlia Reixach, Stephen Connelly, Steven M. Johnson, Ian A. Wilson and Jeffery W. Kelly pp 1359–1370 DOI: 10.1021/ja908562q Supporting Info

Direct Evidence of the Amino Acid Side Chain and Backbone Contributions to Protein Anharmonicity Giorgio Schir, Chiara Caronna, Francesca Natali and Antonio Cupane pp 1371–1376 DOI: 10.1021/ja908611p

Indene−C60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells Youjun He, Hsiang-Yu Chen, Jianhui Hou and Yongfang Li pp 1377–1382 DOI: 10.1021/ja908602j Supporting Info

Rapid Intramolecular Hole Hopping in meso−meso and meta-Phenylene Linked Linear and Cyclic Multiporphyrin Arrays Thea M. Wilson, Takaaki Hori, Min-Chul Yoon, Naoki Aratani, Atsuhiro Osuka, Dongho Kim and Michael R. Wasielewski pp 1383–1388 DOI: 10.1021/ja908605s Supporting Info

Thermal Chemistry of Methylene- and Phenyl-Functionalized Carbon Nanotubes Janie Cabana, Stphane Lavoie and Richard Martel pp 1389–1394 DOI: 10.1021/ja908729y Supporting Info

Cooperative Metal Ion Binding to a Cucurbit[7]uril−Thioflavin T Complex: Demonstration of a Stimulus-Responsive Fluorescent Supramolecular Capsule Sharmistha Dutta Choudhury, Jyotirmayee Mohanty, Haridas Pal and Achikanath C. Bhasikuttan pp 1395–1401 DOI: 10.1021/ja908795y

Synthesis of Dispersible Pd@CeO2 Core−Shell Nanostructures by Self-Assembly Matteo Cargnello, Noah L. Wieder, Tiziano Montini, Raymond J. Gorte and Paolo Fornasiero pp 1402–1409 DOI: 10.1021/ja909131k Supporting Info

Large All-Hydrocarbon Spoked Wheels of High Symmetry: Modular Synthesis, Photophysical Properties, and Surface Assembly Dennis Mssinger, Debangshu Chaudhuri, Tibor Kudernac, Shengbin Lei, Steven De Feyter, John M. Lupton and Sigurd Hger pp 1410–1423 DOI: 10.1021/ja909229y Supporting Info

Liquid-Crystalline Self-Organization of Isocyanide-Containing Dendrimers Induced by Coordination to Gold(I) Fragments Carlos Cordovilla, Silverio Coco, Pablo Espinet and Bertrand Donnio pp 1424–1431 DOI: 10.1021/ja909435e Supporting Info

Anguinomycins and Derivatives: Total Syntheses, Modeling, and Biological Evaluation of the Inhibition of Nucleocytoplasmic Transport Simone Bonazzi, Oliv Eidam, Stephan Gttinger, Jean-Yves Wach, Ivo Zemp, Ulrike Kutay and Karl Gademann pp 1432–1442 DOI: 10.1021/ja9097093 Supporting Info

Transition Metals in the Synthesis of Complex Organic Molecules, 3rd ed James Green p 1443 DOI: 10.1021/ja9105545

Bionanodesign: Following Nature’s Touch Bogdan Dragnea pp 1443–1444 DOI: 10.1021/ja910674m

Engineering the Bioelectronic Interface: Applications to Analyte Biosensing and Protein Detection Peter T. Kissinger p 1444 DOI: 10.1021/ja9108648

Issue 05

Light-Mediated Spatial Control via Photolabile Fluorescently Quenched Peptide Cassettes Hsien-Ming Lee, Melanie A. Priestman and David S. Lawrence pp 1446–1447 DOI: 10.1021/ja907427p Supporting Info

Infrared Induced Reactivity on the Surface of Isolated Size-Selected Clusters: Dissociation of N2O on Rhodium Clusters Suzanne M. Hamilton, W. Scott Hopkins, Dan J. Harding, Tiffany R. Walsh, Philipp Gruene, Marko Haertelt, Andr Fielicke, Gerard Meijer and Stuart R. Mackenzie pp 1448–1449 DOI: 10.1021/ja907496c Supporting Info

Dipolar Molecules as Impellers Achieving Electric-Field-Stimulated Release Yingchun Zhu, Huijuan Liu, Fang Li, Qichao Ruan, Hua Wang, Masahiro Fujiwara, Lianzhou Wang and G. Q. (Max) Lu pp 1450–1451 DOI: 10.1021/ja907560y Supporting Info

Ultrafast Dynamics of Protein Proton Transfer on Short Hydrogen Bond Potential Energy Surfaces: S65T/H148D GFP. Minako Kondo, Ismael A. Heisler, Deborah Stoner-Ma, Peter J. Tonge and Stephen R. Meech pp 1452–1453 DOI: 10.1021/ja907690g Supporting Info

PELDOR Spectroscopy Reveals Preorganization of the Neomycin-Responsive Riboswitch Tertiary Structure Ivan Krsti, Olga Frolow, Deniz Sezer, Burkhard Endeward, Julia E. Weigand, Beatrix Suess, Joachim W. Engels and Thomas F. Prisner pp 1454–1455 DOI: 10.1021/ja9077914 Supporting Info

Tailoring Phthalocyanine Metalation Reaction by Quantum Size Effect Can-Li Song, Yi-Lin Wang, Yan-Xiao Ning, Jin-Feng Jia, Xi Chen, Bo Sun, Ping Zhang, Qi-Kun Xue and Xucun Ma pp 1456–1457 DOI: 10.1021/ja908040g Supporting Info

Low-Coordinate and Neutral Nitrido Complexes of Vanadium Ba L. Tran, Maren Pink, Xinfeng Gao, Hyunsoo Park and Daniel J. Mindiola pp 1458–1459 DOI: 10.1021/ja908303k Supporting Info

Quantum Dot FRET-Based Probes in Thin Films Grown in Microfluidic Channels Georgeta Crivat, Sandra Maria Da Silva, Darwin R. Reyes, Laurie E. Locascio, Michael Gaitan, Nitsa Rosenzweig and Zeev Rosenzweig pp 1460–1461 DOI: 10.1021/ja908784b Supporting Info

Virus-Templated Assembly of Porphyrins into Light-Harvesting Nanoantennae Yoon Sung Nam, Taeho Shin, Heechul Park, Andrew P. Magyar, Katherine Choi, Georg Fantner, Keith A. Nelson and Angela M. Belcher pp 1462–1463 DOI: 10.1021/ja908812b Supporting Info

Visible-Light Photoredox Catalysis: Aza-Henry Reactions via C−H Functionalization Allison G. Condie, Jos C. Gonzlez-Gmez and Corey R. J. Stephenson pp 1464–1465 DOI: 10.1021/ja909145y Supporting Info

Protein Surface Interactions Probed by Magnetic Field Effects on Chemical Reactions Kiminori Maeda, Alexander J. Robinson, Kevin B. Henbest, Emma J. Dell and Christiane R. Timmel pp 1466–1467 DOI: 10.1021/ja908988u Supporting Info

Monodisperse Nickel Nanoparticles and Their Catalysis in Hydrolytic Dehydrogenation of Ammonia Borane nder Metin, Vismadeb Mazumder, Saim zkar and Shouheng Sun pp 1468–1469 DOI: 10.1021/ja909243z Supporting Info

Near-Infrared Photoluminescent Ag2S Quantum Dots from a Single Source Precursor Yaping Du, Bing Xu, Tao Fu, Miao Cai, Feng Li, Yan Zhang and Qiangbin Wang pp 1470–1471 DOI: 10.1021/ja909490r Supporting Info

Enantioselective Synthesis of Substituted Indanones from Silyloxyallenes Jonathan A. Brekan, Troy E. Reynolds and Karl A. Scheidt pp 1472–1473 DOI: 10.1021/ja909669e Supporting Info

Homogeneous Gold-Catalyzed Oxidative Carboheterofunctionalization of Alkenes Guozhu Zhang, Li Cui, Yanzhao Wang and Liming Zhang pp 1474–1475 DOI: 10.1021/ja909555d Supporting Info

Silver Dendrites from Galvanic Displacement on Commercial Aluminum Foil As an Effective SERS Substrate Albert Guts, Carlo Carraro and Roya Maboudian pp 1476–1477 DOI: 10.1021/ja909806t Supporting Info

Anodic Formation of Thick Anatase TiO2 Mesosponge Layers for High-Efficiency Photocatalysis Kiyoung Lee, Doohun Kim, Poulomi Roy, Indhumati Paramasivam, Balaji Ishwarrao Birajdar, Erdmann Spiecker and Patrik Schmuki pp 1478–1479 DOI: 10.1021/ja910045x Supporting Info

Pharmacophore Mapping via Cross-Relaxation during Adiabatic Fast Passage Renate Auer, Karin Kloiber, Andrea Vavrinska, Leonhard Geist, Nicolas Coudevylle and Robert Konrat pp 1480–1481 DOI: 10.1021/ja910098s Supporting Info

Valence Tautomerism in Titanium Enolates: Catalytic Radical Haloalkylation and Application in the Total Synthesis of Neodysidenin Stphane Beaumont, Elizabeth A. Ilardi, Lucas R. Monroe and Armen Zakarian pp 1482–1483 DOI: 10.1021/ja910154f Supporting Info

The Structure of the Hydrogen Ion (Haq+) in Water Evgenii S. Stoyanov, Irina V. Stoyanova and Christopher A. Reed pp 1484–1485 DOI: 10.1021/ja9101826 Supporting Info

Chemical Synthesis and Biological Activity of the Neopetrosiamides and Their Analogues: Revision of Disulfide Bond Connectivity Hongqiang Liu, Marc A. Boudreau, Jing Zheng, Randy M. Whittal, Pamela Austin, Calvin D. Roskelley, Michel Roberge, Raymond J. Andersen and John C. Vederas pp 1486–1487 DOI: 10.1021/ja9102925 Supporting Info

Total Synthesis of (+)-Chinensiolide B via Tandem Allylboration/Lactonization Tim G. Elford and Dennis G. Hall pp 1488–1489 DOI: 10.1021/ja9104478 Supporting Info

Ammonia Borane Confined by a Metal−Organic Framework for Chemical Hydrogen Storage: Enhancing Kinetics and Eliminating Ammonia Zhongyue Li, Guangshan Zhu, Gaoqing Lu, Shilun Qiu and Xiangdong Yao pp 1490–1491 DOI: 10.1021/ja9103217 Supporting Info

Periodic Mesoporous Organometallic Silicas with Unary or Binary Organometals inside the Channel Walls as Active and Reusable Catalysts in Aqueous Organic Reactions Jianlin Huang, Fengxia Zhu, Wenhan He, Fang Zhang, Wei Wang and Hexing Li pp 1492–1493 DOI: 10.1021/ja909596a Supporting Info

Defining the Structural Consequences of Mechanism-Based Inactivation of Mammalian Cytochrome P450 2B4 Using Resonance Raman Spectroscopy Piotr J. Mak, Haoming Zhang, Paul F. Hollenberg and James R. Kincaid pp 1494–1495 DOI: 10.1021/ja910276s Supporting Info

Unusually Large Tunneling Effect on Highly Efficient Generation of Hydrogen and Hydrogen Isotopes in pH-Selective Decomposition of Formic Acid Catalyzed by a Heterodinuclear Iridium−Ruthenium Complex in Water Shunichi Fukuzumi, Takeshi Kobayashi and Tomoyoshi Suenobu pp 1496–1497 DOI: 10.1021/ja910349w Supporting Info

Activation of Fluorescent Protein Chromophores by Encapsulation Anthony Baldridge, Shampa R. Samanta, Nithyanandhan Jayaraj, V. Ramamurthy and Laren M. Tolbert pp 1498–1499 DOI: 10.1021/ja908870k Supporting Info

pH-Responsive Nanogated Ensemble Based on Gold-Capped Mesoporous Silica through an Acid-Labile Acetal Linker Rui Liu, Ying Zhang, Xiang Zhao, Arun Agarwal, Leonard J. Mueller and Pingyun Feng pp 1500–1501 DOI: 10.1021/ja907838s Supporting Info

Tracing the Reaction Steps Involving Oxygen and IR Observable Species in Ethanol Photocatalytic Oxidation on TiO2 Felipe Guzman and Steven S. C. Chuang pp 1502–1503 DOI: 10.1021/ja907256x Supporting Info

On the Origin of the Optical Activity Displayed by Chiral-Ligand-Protected Metallic Nanoclusters Ariadna Snchez-Castillo, Cecilia Noguez and Ignacio L. Garzn pp 1504–1505 DOI: 10.1021/ja907365f Supporting Info

Potassium Is Critical for the Ni(II)-Responsive DNA-Binding Activity of Escherichia coli NikR Sheila C. Wang, Yanjie Li, Carol V. Robinson and Deborah B. Zamble pp 1506–1507 DOI: 10.1021/ja909136h Supporting Info

A Strong Second-Harmonic Generation Material Cd4BiO(BO3)3 Originating from 3-Chromophore Asymmetric Structures Wei-Long Zhang, Wen-Dan Cheng, Hao Zhang, Lei Geng, Chen-Sheng Lin and Zhang-Zhen He pp 1508–1509 DOI: 10.1021/ja9091209 Supporting Info

Microscopic Theory of Hysteretic Hydrogen Adsorption in Nanoporous Materials Joongoo Kang, Su-Huai Wei and Yong-Hyun Kim pp 1510–1511 DOI: 10.1021/ja9092133 Supporting Info

Gold-Catalyzed Ethynylation of Arenes Teresa de Haro and Cristina Nevado pp 1512–1513 DOI: 10.1021/ja909726h Supporting Info

Iron-Catalyzed Direct Arylation through an Aryl Radical Transfer Pathway Frdric Valle, James J. Mousseau and Andr B. Charette pp 1514–1516 DOI: 10.1021/ja910687u Supporting Info

Nuclear Targeting of Gold Nanoparticles in Cancer Cells Induces DNA Damage, Causing Cytokinesis Arrest and Apoptosis Bin Kang, Megan A. Mackey and Mostafa A. El-Sayed pp 1517–1519 DOI: 10.1021/ja9102698 Supporting Info

Very Low Temperature CO Oxidation over Colloidally Deposited Gold Nanoparticles on Mg(OH)2 and MgO Chun-Jiang Jia, Yong Liu, Hans Bongard and Ferdi Schth pp 1520–1522 DOI: 10.1021/ja909351e Supporting Info

Tyrosine Bioconjugation through Aqueous Ene-Type Reactions: A Click-Like Reaction for Tyrosine Hitoshi Ban, Julia Gavrilyuk and Carlos F. Barbas,, III pp 1523–1525 DOI: 10.1021/ja909062q Supporting Info

Molecular Simulation of ab Initio Protein Folding for a Millisecond Folder NTL9(1−39) Vincent A. Voelz, Gregory R. Bowman, Kyle Beauchamp and Vijay S. Pande pp 1526–1528 DOI: 10.1021/ja9090353 Supporting Info

Porphyrin Macrocyclic Catalysts for the Processive Oxidation of Polymer Substrates Cyrille Monnereau, Pilar Hidalgo Ramos, Alexander B. C. Deutman, Johannes A. A. W. Elemans, Roeland J. M. Nolte and Alan E. Rowan pp 1529–1531 DOI: 10.1021/ja908524x Supporting Info

Control of Charge Transfer in a Series of Ru2II,II/TCNQ Two-Dimensional Networks by Tuning the Electron Affinity of TCNQ Units: A Route to Synergistic Magnetic/Conducting Materials Hitoshi Miyasaka, Natsuko Motokawa, Satoshi Matsunaga, Masahiro Yamashita, Kunihisa Sugimoto, Tatsuya Mori, Naoki Toyota and Kim R. Dunbar pp 1532–1544 DOI: 10.1021/ja909489s Supporting Info

Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts Javier J. Concepcion, Ming-Kang Tsai, James T. Muckerman and Thomas J. Meyer pp 1545–1557 DOI: 10.1021/ja904906v Supporting Info

Solvent-Induced Transformation of Single Crystals of a Spin-Crossover (SCO) Compound to Single Crystals with Two Distinct SCO Centers Bao Li, Rong-Jia Wei, Jun Tao, Rong-Bin Huang, Lan-Sun Zheng and Zhiping Zheng pp 1558–1566 DOI: 10.1021/ja909695f Supporting Info

Sortase A-Catalyzed Transpeptidation of Glycosylphosphatidylinositol Derivatives for Chemoenzymatic Synthesis of GPI-Anchored Proteins Zhimeng Wu, Xueqing Guo, Qianli Wang, Benjamin M. Swarts and Zhongwu Guo pp 1567–1571 DOI: 10.1021/ja906611x Supporting Info

Cause and Consequence of Carbon Nanotube Doping in Water and Aqueous Media Kevin R. Moonoosawmy and Peter Kruse pp 1572–1577 DOI: 10.1021/ja906820n Supporting Info

Simultaneous Fluorescent Monitoring of Proteasomal Subunit Catalysis Aya Wakata, Hsien-Ming Lee, Philipp Rommel, Alexei Toutchkine, Marion Schmidt and David S. Lawrence pp 1578–1582 DOI: 10.1021/ja907226n Supporting Info

NMR, IR/Raman, and Structural Properties in HNO and RNO (R = Alkyl and Aryl) Metalloporphyrins with Implication for the HNO−Myoglobin Complex Yan Ling, Christopher Mills, Rebecca Weber, Liu Yang and Yong Zhang pp 1583–1591 DOI: 10.1021/ja907342s Supporting Info

Regulation of DNA Methylation Using Different Tensions of Double Strands Constructed in a Defined DNA Nanostructure Masayuki Endo, Yousuke Katsuda, Kumi Hidaka and Hiroshi Sugiyama pp 1592–1597 DOI: 10.1021/ja907649w Supporting Info

Role of Copper Ion in Regulating Ligand Binding in a Myoglobin-Based Cytochrome c Oxidase Model Changyuan Lu, Xuan Zhao, Yi Lu, Denis L. Rousseau and Syun-Ru Yeh pp 1598–1605 DOI: 10.1021/ja907777f Supporting Info

New Insights into the Vacuum UV Photodissociation of Peptides Ramakrishnan Parthasarathi, Yi He, James P. Reilly and Krishnan Raghavachari pp 1606–1610 DOI: 10.1021/ja907975v Supporting Info

Probing E/Z Isomerization on the C10H8 Potential Energy Surface with Ultraviolet Population Transfer Spectroscopy Josh J. Newby, Christian W. Mller, Ching-Ping Liu and Timothy S. Zwier pp 1611–1620 DOI: 10.1021/ja908103u Supporting Info

NMR Spectroscopy Reveals that RNase A is Chiefly Denatured in 40% Acetic Acid: Implications for Oligomer Formation by 3D Domain Swapping Jorge Pedro Lpez-Alonso, Marta Bruix, Josep Font, Marc Rib, Maria Vilanova, Mara Angeles Jimnez, Jorge Santoro, Carlos Gonzlez and Douglas V. Laurents pp 1621–1630 DOI: 10.1021/ja9081638 Supporting Info

Spontaneous Formation of Nanosized Unilamellar Polyion Complex Vesicles with Tunable Size and Properties Yasutaka Anraku, Akihiro Kishimura, Makoto Oba, Yuichi Yamasaki and Kazunori Kataoka pp 1631–1636 DOI: 10.1021/ja908350e Supporting Info

Supramolecular ABC Triblock Copolymers via One-Pot, Orthogonal Self-Assembly Si Kyung Yang, Ashootosh V. Ambade and Marcus Weck pp 1637–1645 DOI: 10.1021/ja908429e Supporting Info

Thermodynamics of Halogen Bonding in Solution: Substituent, Structural, and Solvent Effects Mohammed G. Sarwar, Bojan Dragisic, Lee J. Salsberg, Christina Gouliaras and Mark S. Taylor pp 1646–1653 DOI: 10.1021/ja9086352 Supporting Info

Interaction of Molecular Hydrogen with Microporous Metal Organic Framework Materials at Room Temperature Nour Nijem, Jean-Franois Veyan, Lingzhu Kong, Kunhao Li, Sanhita Pramanik, Yonggang Zhao, Jing Li, David Langreth and Yves J. Chabal pp 1654–1664 DOI: 10.1021/ja908817n Supporting Info

Bilability is Defined when One Electron is Used to Switch between Concerted and Stepwise Pathways in Cu(I)-Based Bistable [2/3]Pseudorotaxanes Andrew I. Share, Kumar Parimal and Amar H. Flood pp 1665–1675 DOI: 10.1021/ja908877d Supporting Info

Synthesis and Molecular and Electronic Structures of Reduced Bis(imino)pyridine Cobalt Dinitrogen Complexes: Ligand versus Metal Reduction Amanda C. Bowman, Carsten Milsmann, Crisita Carmen Hojilla Atienza, Emil Lobkovsky, Karl Wieghardt and Paul J. Chirik pp 1676–1684 DOI: 10.1021/ja908955t Supporting Info

Nazarov Cyclizations of an Allenyl Vinyl Ketone with Interception of the Oxyallyl Cation Intermediate for the Formation of Carbon−Carbon Bonds Vanessa M. Marx and D. Jean Burnell pp 1685–1689 DOI: 10.1021/ja909073r Supporting Info

Host−Guest Complexation: A Convenient Route for the Electroreduction of Diazonium Salts in Aqueous Media and the Formation of Composite Materials Lus Santos, Jalal Ghilane, Pascal Martin, Pierre-Camille Lacaze, Hyacinthe Randriamahazaka and Jean-Christophe Lacroix pp 1690–1698 DOI: 10.1021/ja9096187

Hydrogenation: A Simple Approach To Realize Semiconductor−Half-Metal−Metal Transition in Boron Nitride Nanoribbons Wei Chen, Yafei Li, Guangtao Yu, Chen-Zhong Li, Shengbai B. Zhang, Zhen Zhou and Zhongfang Chen pp 1699–1705 DOI: 10.1021/ja908475v Supporting Info

Evolution of Linear Absorption and Nonlinear Optical Properties in V-Shaped Ruthenium(II)-Based Chromophores Benjamin J. Coe, Simon P. Foxon, Elizabeth C. Harper, Madeleine Helliwell, James Raftery, Catherine A. Swanson, Bruce S. Brunschwig, Koen Clays, Edith Franz, Javier Garn, Jess Orduna, Peter N. Horton and Michael B. Hursthouse pp 1706–1723 DOI: 10.1021/ja908667p Supporting Info

Synthesis of Cyclic β-Glucan Using Laminarinase 16A Glycosynthase Mutant from the Basidiomycete Phanerochaete chrysosporium Jonas Vasur, Rie Kawai, K. Hanna M. Jonsson, Gran Widmalm, Åke Engstrm, Martin Frank, Evalena Andersson, Henrik Hansson, Zarah Forsberg, Kiyohiko Igarashi, Masahiro Samejima, Mats Sandgren and Jerry Ståhlberg pp 1724–1730 DOI: 10.1021/ja909129b Supporting Info

Synthesis and Characterization of a Carbon Nanotube−Dendron Series for Efficient siRNA Delivery M. Antonia Herrero, Francesca M. Toma, Khuloud T. Al-Jamal, Kostas Kostarelos, Alberto Bianco, Tatiana Da Ros, Fouzia Bano, Loredana Casalis, Giacinto Scoles and Maurizio Prato p 1731 DOI: 10.1021/ja910087w

Ion-Pair Chromatography and Related Techniques Jan Ståhlberg p 1732 DOI: 10.1021/ja1000455

Issue 06

Measurement of Long-Range Interatomic Distances by Solid-State Tritium-NMR Spectroscopy Alexander K. L. Yuen, Olivier Lafon, Thibault Charpentier, Myriam Roy, Francine Brunet, Patrick Berthault, Dimitrios Sakellariou, Bruno Robert, Sylvie Rimsky, Florence Pillon, Jean-Christophe Cintrat and Bernard Rousseau pp 1734–1735 DOI: 10.1021/ja908915v Supporting Info

Binding Bacteria to Highly Branched Poly(N-isopropyl acrylamide) Modified with Vancomycin Induces the Coil-to-Globule Transition Joanna Shepherd, Prodip Sarker, Kathryn Swindells, Ian Douglas, Sheila MacNeil, Linda Swanson and Stephen Rimmer pp 1736–1737 DOI: 10.1021/ja907466y Supporting Info

Geometry and Electronic Coupling in Perylenediimide Stacks: Mapping Structure−Charge Transport Relationships Josh Vura-Weis, Mark A. Ratner and Michael R. Wasielewski pp 1738–1739 DOI: 10.1021/ja907761e Supporting Info

Amide-Directed Catalytic Asymmetric Hydroboration of Trisubstituted Alkenes Sean M. Smith and James M. Takacs pp 1740–1741 DOI: 10.1021/ja908257x Supporting Info

Orange−Blue−Orange Triblock One-Dimensional Heterostructures of Organic Microrods for White-Light Emission Yilong Lei, Qing Liao, Hongbing Fu and Jiannian Yao pp 1742–1743 DOI: 10.1021/ja9084435 Supporting Info

Spatiotemporal Characterization of Phagocytic NADPH Oxidase and Oxidative Destruction of Intraphagosomal Organisms in Vivo Using Autofluorescence Imaging and Raman Microspectroscopy Wei-Tien Chang, Yi-Cyun Yang, Hsueh-Han Lu, I-Lin Li and Ian Liau pp 1744–1745 DOI: 10.1021/ja9086038 Supporting Info

Microsensors Based on GaN Semiconductors Covalently Functionalized with Luminescent Ru(II) Complexes Juan Lpez-Gejo, Antonio Arranz, lvaro Navarro, Carlos Palacio, Elas Muoz and Guillermo Orellana pp 1746–1747 DOI: 10.1021/ja908848c Supporting Info

Designed Semisynthetic Protein Inhibitors of Ub/Ubl E1 Activating Enzymes Xuequan Lu, Shaun K. Olsen, Allan D. Capili, Justin S. Cisar, Christopher D. Lima and Derek S. Tan pp 1748–1749 DOI: 10.1021/ja9088549 Supporting Info

Random Copolymerization of ε-Caprolactone with Lactide Using a Homosalen−Al Complex Nobuyoshi Nomura, Azusa Akita, Ryohei Ishii and Mitsunori Mizuno pp 1750–1751 DOI: 10.1021/ja9089395 Supporting Info

Zinc Porphyrin as a Donor for FRET in Zn(II)cytochrome c Andrea J. Lee, Amy A. Ensign, Todd D. Krauss and Kara L. Bren pp 1752–1753 DOI: 10.1021/ja909106p Supporting Info

Improved Performance of Proton Exchange Membrane Fuel Cells with p-Toluenesulfonic Acid-Doped Co-PPy/C as Cathode Electrocatalyst Xianxia Yuan, Xin Zeng, Hui-Juan Zhang, Zi-Feng Ma and Chao-Yang Wang pp 1754–1755 DOI: 10.1021/ja909537g Supporting Info

Probing the Magnetic Properties of Three Interconvertible Redox States of a Single-Molecule Magnet with Magnetic Circular Dichroism Spectroscopy Mathieu Gonidec, E. Stephen Davies, Jonathan McMaster, David B. Amabilino and Jaume Veciana pp 1756–1757 DOI: 10.1021/ja9095895 Supporting Info

The Importance of Hydrogen Bonding between the Glutamine Side Chains to the Formation of Amyloid VQIVYK Parallel β-Sheets: An ONIOM DFT/AM1 Study Joshua A. Plumley and J. J. Dannenberg pp 1758–1759 DOI: 10.1021/ja909690a Supporting Info

Diastereo- and Enantioselective anti-Alkoxyallylation Employing Allylic gem-Dicarboxylates as Allyl Donors via Iridium-Catalyzed Transfer Hydrogenation Soo Bong Han, Hoon Han and Michael J. Krische pp 1760–1761 DOI: 10.1021/ja9097675 Supporting Info

The Hunt for 8-Oxoguanine Deaminase Richard S. Hall, Alexander A. Fedorov, Ricardo Marti-Arbona, Elena V. Fedorov, Peter Kolb, J. Michael Sauder, Stephen K. Burley, Brian K. Shoichet, Steven C. Almo and Frank M. Raushel pp 1762–1763 DOI: 10.1021/ja909817d Supporting Info

Thermochemistry and Molecular Structure of a Remarkable Agostic Interaction in a Heterobifunctional Ruthenium−Boron Complex Brian L. Conley and Travis J. Williams pp 1764–1765 DOI: 10.1021/ja909858a Supporting Info

Nanoscale Ionic Diodes with Tunable and Switchable Rectifying Behavior Michael X. Macrae, Steven Blake, Michael Mayer and Jerry Yang pp 1766–1767 DOI: 10.1021/ja909876h Supporting Info

Fabrication of Highly b-Oriented MFI Film with Molecular Sieving Properties by Controlled In-Plane Secondary Growth Yi Liu, Yanshuo Li and Weishen Yang pp 1768–1769 DOI: 10.1021/ja909888v Supporting Info

Zinc-Catalyzed Reduction of Amides: Unprecedented Selectivity and Functional Group Tolerance Shoubhik Das, Daniele Addis, Shaolin Zhou, Kathrin Junge and Matthias Beller pp 1770–1771 DOI: 10.1021/ja910083q Supporting Info

A Bis-exTTF Macrocyclic Receptor That Associates C60 with Micromolar Affinity Helena Isla, Mara Gallego, Emilio M. Prez, Rafael Viruela, Enrique Ort and Nazario Martn pp 1772–1773 DOI: 10.1021/ja910107m Supporting Info

Systematic Cross-Linking Changes within a Self-Assembled Monolayer in a Nanogap Junction: A Tool for Investigating the Intermolecular Electronic Coupling Yair Paska and Hossam Haick pp 1774–1775 DOI: 10.1021/ja910126s Supporting Info

A Role for Old Yellow Enzyme in Ergot Alkaloid Biosynthesis Johnathan Z. Cheng, Christine M. Coyle, Daniel G. Panaccione and Sarah E. O’Connor pp 1776–1777 DOI: 10.1021/ja910193p Supporting Info

Recyclization Rate of a Photocleaved Peptide from Multiscale Simulation Harald Nieber, Arnim Hellweg and Nikos L. Doltsinis pp 1778–1779 DOI: 10.1021/ja9100497

Developing Chemical Strategies for the Assembly of Nanoparticles into Mesoscopic Objects Weerakanya Maneeprakorn, Mohammad A. Malik and Paul O’Brien pp 1780–1781 DOI: 10.1021/ja910022q Supporting Info

DNA Methylation Increases Nucleosome Compaction and Rigidity John S. Choy, Sijie Wei, Ju Yeon Lee, Song Tan, Steven Chu and Tae-Hee Lee pp 1782–1783 DOI: 10.1021/ja910264z Supporting Info

Hyperpolarized 89Y Complexes as pH Sensitive NMR Probes Ashish K. Jindal, Matthew E. Merritt, Eul Hyun Suh, Craig R. Malloy, A. Dean Sherry and Zoltn Kovcs pp 1784–1785 DOI: 10.1021/ja910278e Supporting Info

One-Pot Synthesis of 1,3-Disubstituted Allenes from 1-Alkynes, Aldehydes, and Morpholine Jinqiang Kuang and Shengming Ma pp 1786–1787 DOI: 10.1021/ja910503k Supporting Info

Pt-Catalyzed Tandem 1,2-Acyloxy Migration/Intramolecular [3 + 2] Cycloaddition of Enynyl Esters Huaiji Zheng, Jiyue Zheng, Binxun Yu, Qiang Chen, Xiaolei Wang, Yongping He, Zhen Yang and Xuegong She pp 1788–1789 DOI: 10.1021/ja910346m Supporting Info

Significantly Enhanced Red Photoluminescence Properties of Nanocomposite Films Composed of a Ferroelectric Bi3.6Eu0.4Ti3O12 Matrix and Highly c-Axis-Oriented ZnO Nanorods on Si Substrates Prepared by a Hybrid Chemical Solution Method Hong Zhou, Xinman Chen, Guangheng Wu, Feng Gao, Ni Qin and Dinghua Bao pp 1790–1791 DOI: 10.1021/ja910388f Supporting Info

Domino Process in Silver-Catalyzed Reactions of N-Arylformimidates and Active Methylene Compounds Involving Cycloisomerization and 1,3-Alkenyl Shift Chang Ho Oh, Swastik Karmakar, HyoSeung Park, YoungCheon Ahn and Jung Wook Kim pp 1792–1793 DOI: 10.1021/ja9106226 Supporting Info

Ring-Opening Polymerization of a Galla[1]ferrocenophane: A Gallium-Bridged Polyferrocene with Observable Tacticity Bidraha Bagh, Joe B. Gilroy, Anne Staubitz and Jens Mller pp 1794–1795 DOI: 10.1021/ja910648k Supporting Info

Room Temperature Reduction of CO2 to Methanol by Al-Based Frustrated Lewis Pairs and Ammonia Borane Gabriel Mnard and Douglas W. Stephan pp 1796–1797 DOI: 10.1021/ja9104792 Supporting Info

Nontraditional Reactions of Azomethine Ylides: Decarboxylative Three-Component Couplings of α-Amino Acids Chen Zhang and Daniel Seidel pp 1798–1799 DOI: 10.1021/ja910719x Supporting Info

Neopentylglycolborylation of Aryl Mesylates and Tosylates Catalyzed by Ni-Based Mixed-Ligand Systems Activated with Zn Daniela A. Wilson, Christopher J. Wilson, Costel Moldoveanu, Ana-Maria Resmerita, Patrick Corcoran, Lisa M. Hoang, Brad M. Rosen and Virgil Percec pp 1800–1801 DOI: 10.1021/ja910808x Supporting Info

Annulation of Thioimidates and Vinyl Carbodiimides to Prepare 2-Aminopyrimidines, Competent Nucleophiles for Intramolecular Alkyne Hydroamination. Synthesis of (−)-Crambidine Nicholas R. Perl, Nathan D. Ide, Sudeep Prajapati, Hahdi H. Perfect, Sergio G. Durn and David Y. Gin pp 1802–1803 DOI: 10.1021/ja910831k Supporting Info

Analysis of the Reaction Coordinate of α-l-Fucosidases: A Combined Structural and Quantum Mechanical Approach Alicia Lammerts van Bueren, Albert Ardvol, Jennifer Fayers-Kerr, Bo Luo, Yongmin Zhang, Matthieu Sollogoub, Yves Blriot, Carme Rovira and Gideon J Davies pp 1804–1806 DOI: 10.1021/ja908908q Supporting Info

Visualizing the Reaction Coordinate of an O-GlcNAc Hydrolase Yuan He, Matthew S. Macauley, Keith A Stubbs, David J Vocadlo and Gideon J Davies pp 1807–1809 DOI: 10.1021/ja9086769 Supporting Info

Weakly Coordinating Amphiphilic Organoborate Block Copolymers Chengzhong Cui, Edward M. Bonder and Frieder Jkle pp 1810–1812 DOI: 10.1021/ja908996e Supporting Info

Indirect Detection of Labile Solute Proton Spectra via the Water Signal Using Frequency-Labeled Exchange (FLEX) Transfer Joshua I. Friedman, Michael T. McMahon, James T. Stivers and Peter C. M. Van Zijl pp 1813–1815 DOI: 10.1021/ja909001q Supporting Info

Sensitive and Selective Amplified Fluorescence DNA Detection Based on Exonuclease III-Aided Target Recycling Xiaolei Zuo, Fan Xia, Yi Xiao and Kevin W. Plaxco pp 1816–1818 DOI: 10.1021/ja909551b Supporting Info

Direct Synthesis of Water-Soluble Ultrathin CdS Nanorods and Reversible Tuning of the Solubility by Alkalinity Zhongbin Zhuang, Xiaotang Lu, Qing Peng and Yadong Li pp 1819–1821 DOI: 10.1021/ja909776g Supporting Info

Palladium(II)-Catalyzed Oxidative C−H/C−H Cross-Coupling of Heteroarenes Peihua Xi, Fan Yang, Song Qin, Dongbing Zhao, Jingbo Lan, Ge Gao, Changwei Hu and Jingsong You pp 1822–1824 DOI: 10.1021/ja909807f Supporting Info

Light Emitting Diode Irradiation Can Control the Morphology and Optical Properties of Silver Nanoparticles Kevin G. Stamplecoskie and Juan C. Scaiano pp 1825–1827 DOI: 10.1021/ja910010b Supporting Info

Practical and Highly Selective Sulfur Ylide Mediated Asymmetric Epoxidations and Aziridinations Using an Inexpensive, Readily Available Chiral Sulfide. Applications to the Synthesis of Quinine and Quinidine Ona Illa, Muhammad Arshad, Abel Ros, Eoghan M. McGarrigle and Varinder K. Aggarwal pp 1828–1830 DOI: 10.1021/ja9100276 Supporting Info

Structure and Excitonic Coupling in Self-Assembled Monolayers of Azobenzene-Functionalized Alkanethiols Cornelius Gahl, Roland Schmidt, Daniel Brete, Erik R. McNellis, Wolfgang Freyer, Robert Carley, Karsten Reuter and Martin Weinelt pp 1831–1838 DOI: 10.1021/ja903636q Supporting Info

Nature of Bonding in Complexes Containing “Supershort” Metal−Metal Bonds. Raman and Theoretical Study of M2(dmp)4 [M = Cr (Natural Abundance Cr, 50Cr, and 54Cr) and Mo; dmp = 2,6-Dimethoxyphenyl] Ryan E. Da Re, Judith L. Eglin, Christin N. Carlson, Kevin D. John, David E. Morris, William H. Woodruff, James A. Bailey, Enrique Batista, Richard L. Martin, F. Albert Cotton, Elizabeth A. Hillard, Carlos A. Murillo, Alfred P. Sattelberger and Robert J. Donohoe pp 1839–1847 DOI: 10.1021/ja9055504 Supporting Info

Time-resolved IR Studies on the Mechanism for the Functionalization of Primary C−H Bonds by Photoactivated Cp*W(CO)3(Bpin) Karma R. Sawyer, James F. Cahoon, Jennifer E. Shanoski, Elizabeth A. Glascoe, Matthias F. Kling, Jacob P. Schlegel, Matthew C. Zoerb, Marko Hapke, John F. Hartwig, Charles Edwin Webster and Charles B. Harris pp 1848–1859 DOI: 10.1021/ja906438a Supporting Info

Formation and Assembly−Disassembly Processes of ZnO Hexagonal Pyramids Driven by Dipolar and Excluded Volume Interactions Ming Yang, Kai Sun and Nicholas A. Kotov pp 1860–1872 DOI: 10.1021/ja906868h

A Controllable Molecular Sieve for Na+ and K+ Ions Xiaojing Gong, Jichen Li, Ke Xu, Jianfeng Wang and Hui Yang pp 1873–1877 DOI: 10.1021/ja905753p Supporting Info

Monitoring the Escape of DNA from a Nanopore Using an Alternating Current Signal Daniel K. Lathrop, Eric N. Ervin, Geoffrey A. Barrall, Michael G. Keehan, Ryuji Kawano, Michael A. Krupka, Henry S. White and Andrew H. Hibbs pp 1878–1885 DOI: 10.1021/ja906951g Supporting Info

A Water-Soluble Ruthenium Glycosylated Porphyrin Catalyst for Carbenoid Transfer Reactions in Aqueous Media with Applications in Bioconjugation Reactions Chi-Ming Ho, Jun-Long Zhang, Cong-Ying Zhou, On-Yee Chan, Jessie Jing Yan, Fu-Yi Zhang, Jie-Sheng Huang and Chi-Ming Che pp 1886–1894 DOI: 10.1021/ja9077254 Supporting Info

Intramolecular Simmons−Smith Cyclopropanation. Studies into the Reactivity of Alkyl-Substituted Zinc Carbenoids, Effect of Directing Groups and Synthesis of Bicyclo[n.1.0]alkanes James A. Bull and Andr B. Charette pp 1895–1902 DOI: 10.1021/ja907504w Supporting Info

Quantitative Study of the Association Thermodynamics and Kinetics of DNA-Coated Particles for Different Functionalization Schemes Mirjam E. Leunissen, Remi Dreyfus, Roujie Sha, Nadrian C. Seeman and Paul M. Chaikin pp 1903–1913 DOI: 10.1021/ja907919j Supporting Info

Selective para-Halogenation and Dimerization of N,C,N′-Arylruthenium(II) and -(III) 2,2′:6′,2′′-Terpyridine Cations Sipke H. Wadman, Remco W. A. Havenith, Martin Lutz, Anthony L. Spek, Gerard P. M. van Klink and Gerard van Koten pp 1914–1924 DOI: 10.1021/ja9073276 Supporting Info

Thermal Expansion, Ferroelectric and Magnetic Properties in (1 − x)PbTiO3−xBi(Ni1/2Ti1/2)O3 Penghao Hu, Jun Chen, Jinxia Deng and Xianran Xing pp 1925–1928 DOI: 10.1021/ja908014u Supporting Info

Self-Assembly Synthesis, Tumor Cell Targeting, and Photothermal Capabilities of Antibody-Coated Indocyanine Green Nanocapsules Jie Yu, David Javier, Mohammad A. Yaseen, Nitin Nitin, Rebecca Richards-Kortum, Bahman Anvari and Michael S. Wong pp 1929–1938 DOI: 10.1021/ja908139y Supporting Info

Design and Synthesis of Potent Quillaja Saponin Vaccine Adjuvants Michelle M. Adams, Payal Damani, Nicholas R. Perl, Annie Won, Feng Hong, Philip O. Livingston, Govind Ragupathi and David Y. Gin pp 1939–1945 DOI: 10.1021/ja9082842 Supporting Info

Enzymatic Processing of Platinated RNAs Erich G. Chapman and Victoria J. DeRose pp 1946–1952 DOI: 10.1021/ja908419j Supporting Info

Crystallographic Characterization of N-Oxide Tripod Amphiphiles Pil Seok Chae, Ilia A. Guzei and Samuel H. Gellman pp 1953–1959 DOI: 10.1021/ja9085148 Supporting Info

Protein Modification, Bioconjugation, and Disulfide Bridging Using Bromomaleimides Mark E. B. Smith, Felix F. Schumacher, Chris P. Ryan, Lauren M. Tedaldi, Danai Papaioannou, Gabriel Waksman, Stephen Caddick and James R. Baker pp 1960–1965 DOI: 10.1021/ja908610s Supporting Info

Claisen Rearrangements: Insight into Solvent Effects and “on Water” Reactivity from QM/MM Simulations Orlando Acevedo and Kira Armacost pp 1966–1975 DOI: 10.1021/ja908680c Supporting Info

Solid-State NMR Studies of HIV-1 Capsid Protein Assemblies Yun Han, Jinwoo Ahn, Jason Concel, In-Ja L. Byeon, Angela M. Gronenborn, Jun Yang and Tatyana Polenova pp 1976–1987 DOI: 10.1021/ja908687k Supporting Info

Strain-Induced Cleavage of Carbon−Carbon Bonds: Bridge Rupture Reactions of Group 8 Dicarba[2]metallocenophanes David E. Herbert, Joe B. Gilroy, Anne Staubitz, Mairi F. Haddow, Jeremy N. Harvey and Ian Manners pp 1988–1998 DOI: 10.1021/ja9087049 Supporting Info

Combined Single-Molecule Photon-Stamping Spectroscopy and Femtosecond Transient Absorption Spectroscopy Studies of Interfacial Electron Transfer Dynamics Lijun Guo, Yuanmin Wang and H. Peter Lu pp 1999–2004 DOI: 10.1021/ja909168e

Reaction Mechanisms of the Multicopper Oxidase CueO from Escherichia coli Support Its Functional Role as a Cuprous Oxidase Karrera Y. Djoko, Lee Xin Chong, Anthony G. Wedd and Zhiguang Xiao pp 2005–2015 DOI: 10.1021/ja9091903 Supporting Info

Paramagnetic, Silicon Quantum Dots for Magnetic Resonance and Two-Photon Imaging of Macrophages Chuqiao Tu, Xuchu Ma, Periklis Pantazis, Susan M. Kauzlarich and Angelique Y. Louie pp 2016–2023 DOI: 10.1021/ja909303g Supporting Info

Highly Specific Dual Enzyme-Mediated Payload Release from Peptide-Coated Silica Particles Paul D. Thornton and Andreas Heise pp 2024–2028 DOI: 10.1021/ja9094439 Supporting Info

Electrochemically Stimulated pH Changes: A Route To Control Chemical Reactivity Marco Frasconi, Ran Tel-Vered, Johann Elbaz and Itamar Willner pp 2029–2036 DOI: 10.1021/ja9094796 Supporting Info

Binding of Histidine in the (Cys)3(His)1-Coordinated [2Fe−2S] Cluster of Human mitoNEET Michelle M. Dicus, Andrea Conlan, Rachel Nechushtai, Patricia A. Jennings, Mark L. Paddock, R. David Britt and Stefan Stoll pp 2037–2049 DOI: 10.1021/ja909359g Supporting Info

Origins of Regioselectivity and Alkene-Directing Effects in Nickel-Catalyzed Reductive Couplings of Alkynes and Aldehydes Peng Liu, Patrick McCarren, Paul Ha-Yeon Cheong, Timothy F. Jamison and K. N. Houk pp 2050–2057 DOI: 10.1021/ja909562y Supporting Info

Interfacial Ion Transfers between a Monolayer Phase of Cationic Au Nanoparticles and Contacting Organic Solvent Rajesh Sardar, Christopher A. Beasley and Royce W. Murray pp 2058–2063 DOI: 10.1021/ja909584p Supporting Info

Fullerenium Salts: A New Class of C60-Based Compounds Mauro Ricc, Daniele Pontiroli, Marcello Mazzani, Fabio Gianferrari, Massimo Pagliari, Angelo Goffredi, Michela Brunelli, Giorgia Zandomeneghi, Beat H. Meier and Toni Shiroka pp 2064–2068 DOI: 10.1021/ja909614x Supporting Info

Capture of the [Mo3S4]4+ Cluster within a {Mo18} Macrocycle Yielding a Supramolecular Assembly Stabilized by a Dynamic H-Bond Network Sylvain Duval, Sbastien Floquet, Corine Simonnet-Jgat, Jrme Marrot, Rosa Ngo Biboum, Bineta Keita, Louis Nadjo, Mohamed Haouas, Francis Taulelle and Emmanuel Cadot pp 2069–2077 DOI: 10.1021/ja909762p Supporting Info

Proximity Effects in Nucleophilic Addition Reactions to Medium-Bridged Twisted Lactams: Remarkably Stable Tetrahedral Intermediates Michal Szostak, Lei Yao and Jeffrey Aub pp 2078–2084 DOI: 10.1021/ja909792h Supporting Info

Amide-I and -II Vibrations of the Cyclic β-Sheet Model Peptide Gramicidin S in the Gas Phase Peter Kupser, Kevin Pagel, Jos Oomens, Nick Polfer, Beate Koksch, Gerard Meijer and Gert von Helden pp 2085–2093 DOI: 10.1021/ja909842j Supporting Info

Palladium-Catalyzed Intermolecular Addition of Formamides to Alkynes Tetsuaki Fujihara, Yuko Katafuchi, Tomohiro Iwai, Jun Terao and Yasushi Tsuji pp 2094–2098 DOI: 10.1021/ja910038p Supporting Info

Asymmetry of the “Strongest” OHO Hydrogen Bond, in the Monoanion of (±)-α,α′-Di-tert-butylsuccinate Charles L. Perrin, Jonathan S. Lau, Yeong-Joon Kim, Phaneendrasai Karri, Curtis Moore and Arnold L. Rheingold pp 2099–2100 DOI: 10.1021/ja9104733 Supporting Info

Issue 07

NMR Dynamics Investigation of Ligand-Induced Changes of Main and Side-Chain Arginine N−H’s in Human Phosphomevalonate Kinase Andrew L. Olson, Sheng Cai, Timothy J. Herdendorf, Henry M. Miziorko and Daniel S. Sem pp 2102–2103 DOI: 10.1021/ja906244j Supporting Info

Photoinitiated Growth of Sub-7 nm Silver Nanowires within a Chemically Active Organic Nanotubular Template Drthe M. Eisele, Hans v. Berlepsch, Christoph Bttcher, Keith J. Stevenson, David A. Vanden Bout, Stefan Kirstein and Jrgen P. Rabe pp 2104–2105 DOI: 10.1021/ja907373h Supporting Info

Lanthanide N,N-Dimethylaminodiboranates: Highly Volatile Precursors for the Deposition of Lanthanide-Containing Thin Films Scott R. Daly, Do Young Kim, Yu Yang, John R. Abelson and Gregory S. Girolami pp 2106–2107 DOI: 10.1021/ja9098005 Supporting Info

Rhodium Catalyzed Allene Amination: Diastereoselective Synthesis of Aminocyclopropanes via a 2-Amidoallylcation Intermediate Armin H. Stoll and Simon B. Blakey pp 2108–2109 DOI: 10.1021/ja908538t Supporting Info

Substrate Catalysis Enhances Single-Enzyme Diffusion Hari S. Muddana, Samudra Sengupta, Thomas E. Mallouk, Ayusman Sen and Peter J. Butler pp 2110–2111 DOI: 10.1021/ja908773a Supporting Info

Effect of a Quaternary Ammonium Salt on Propylene Carbonate Structure in Slit-Shape Carbon Nanopores Akimi Tanaka, Taku Iiyama, Tomonori Ohba, Sumio Ozeki, Koki Urita, Toshihiko Fujimori, Hirofumi Kanoh and Katsumi Kaneko pp 2112–2113 DOI: 10.1021/ja9087874 Supporting Info

Diffusion of Gold from the Inner Core to the Surface of Ag2S Nanocrystals Jun Yang and Jackie Y. Ying pp 2114–2115 DOI: 10.1021/ja909078p Supporting Info

Equimolar CO2 Absorption by Anion-Functionalized Ionic Liquids Burcu E. Gurkan, Juan C. de la Fuente, Elaine M. Mindrup, Lindsay E. Ficke, Brett F. Goodrich, Erica A. Price, William F. Schneider and Joan F. Brennecke pp 2116–2117 DOI: 10.1021/ja909305t Supporting Info

Electroosmotic Flow Rectification in Pyramidal-Pore Mica Membranes Pu Jin, Hitomi Mukaibo, Lloyd P. Horne, Gregory W. Bishop and Charles R. Martin pp 2118–2119 DOI: 10.1021/ja909335r Supporting Info

High Fidelity of Base Pairing by 2-Selenothymidine in DNA Abdalla E. A. Hassan, Jia Sheng, Wen Zhang and Zhen Huang pp 2120–2121 DOI: 10.1021/ja909330m Supporting Info

The Interfacial Tension of Nanoscopic Oil Droplets in Water Is Hardly Affected by SDS Surfactant Hilton B. de Aguiar, Alex G. F. de Beer, Matthew L. Strader and Sylvie Roke pp 2122–2123 DOI: 10.1021/ja9095158 Supporting Info

Iridium−Monodentate Phosphoramidite-Catalyzed Asymmetric Hydrogenation of Substituted Benzophenone N−H Imines Guohua Hou, Ran Tao, Yongkui Sun, Xumu Zhang and Francis Gosselin pp 2124–2125 DOI: 10.1021/ja909583s Supporting Info

Direct Observation of 1,2-Hydrogen Migration in the Excited States of Alkyl Diazo Esters by Ultrafast Time Resolved IR Spectroscopy Gotard Burdzinski, Yunlong Zhang, Peter Selvaraj, Michel Sliwa and Matthew S. Platz pp 2126–2127 DOI: 10.1021/ja909687g Supporting Info

Fully π-Conjugated Helices from Oxidative Cleavage of meso-Aryl-Substituted Expanded Porphyrins Shohei Saito, Ko Furukawa and Atsuhiro Osuka pp 2128–2129 DOI: 10.1021/ja909929s Supporting Info

CdSe/ZnS Core/Shell Quantum Dot Sensitization of Low Index TiO2 Single Crystal Surfaces Justin B. Sambur and B. A. Parkinson pp 2130–2131 DOI: 10.1021/ja9098577 Supporting Info

Efficient and Clean Photoreduction of CO2 to CO by Enzyme-Modified TiO2 Nanoparticles Using Visible Light Thomas W. Woolerton, Sally Sheard, Erwin Reisner, Elizabeth Pierce, Stephen W. Ragsdale and Fraser A. Armstrong pp 2132–2133 DOI: 10.1021/ja910091z Supporting Info

Near-Stoichiometric Conversion of H2O2 to FeIV=O at a Nonheme Iron(II) Center. Insights into the O−O Bond Cleavage Step Feifei Li, Jason England and Lawrence Que, Jr. pp 2134–2135 DOI: 10.1021/ja9101908 Supporting Info

Enantioselective Synthesis of Planar-Chiral Phosphaferrocenes by Molybdenum-Catalyzed Asymmetric Interannular Ring-Closing Metathesis Masamichi Ogasawara, Susumu Watanabe, Kiyohiko Nakajima and Tamotsu Takahashi pp 2136–2137 DOI: 10.1021/ja910348z Supporting Info

Diagonal-Free 3D/4D HN,HN-TROSY-NOESY-TROSY Tammo Diercks, Vincent Truffault, Murray Coles and Oscar Millet pp 2138–2139 DOI: 10.1021/ja910523q Supporting Info

Neutral and Cation-Free LTA-Type Aluminophosphate (AlPO4) Molecular Sieve Membrane with High Hydrogen Permselectivity Aisheng Huang, Fangyi Liang, Frank Steinbach, Thorsten M. Gesing and Jrgen Caro pp 2140–2141 DOI: 10.1021/ja100042x Supporting Info

De Novo Generation of Mutually Orthogonal Aminoacyl-tRNA Synthetase/tRNA Pairs Heinz Neumann, Adrian L. Slusarczyk and Jason W. Chin pp 2142–2144 DOI: 10.1021/ja9068722 Supporting Info

Poisson-Gap Sampling and Forward Maximum Entropy Reconstruction for Enhancing the Resolution and Sensitivity of Protein NMR Data Sven G. Hyberts, Koh Takeuchi and Gerhard Wagner pp 2145–2147 DOI: 10.1021/ja908004w Supporting Info

α-Oligofurans Ori Gidron, Yael Diskin-Posner and Michael Bendikov pp 2148–2150 DOI: 10.1021/ja9093346 Supporting Info

Synthesis of Supported Platinum Nanoparticles from Li−Pt Solid Solution Tao Xu, Chikai Lin, Chao Wang, Dale L. Brewe, Yasuo Ito and Jun Lu pp 2151–2153 DOI: 10.1021/ja909442c Supporting Info

All-Liquid Photonic Microcavity Stabilized by Quantum Dots Tae-Jin Yim, Thomas Zentgraf, Bumki Min and Xiang Zhang pp 2154–2156 DOI: 10.1021/ja909483w Supporting Info

Total Synthesis, Assignment of the Relative and Absolute Stereochemistry, and Structural Reassignment of Phostriecin (aka Sultriecin) Christopher P. Burke, Nadia Haq and Dale L. Boger pp 2157–2159 DOI: 10.1021/ja9097252 Supporting Info

Polymorphism and Reversible Mechanochromic Luminescence for Solid-State Difluoroboron Avobenzone Guoqing Zhang, Jiwei Lu, Michal Sabat and Cassandra L. Fraser pp 2160–2162 DOI: 10.1021/ja9097719 Supporting Info

Oriented Aggregation: Formation and Transformation of Mesocrystal Intermediates Revealed Virany M. Yuwono, Nathan D. Burrows, Jennifer A. Soltis and R. Lee Penn pp 2163–2165 DOI: 10.1021/ja909769a Supporting Info

Unexpected Facile Redistribution of Adsorbed Silica Nanoparticles Between Latexes Jennifer A. Balmer, Oleksandr O. Mykhaylyk, J. Patrick A. Fairclough, Anthony J. Ryan, Steven P. Armes, Martin W. Murray, Kenneth A. Murray and Neal S. J. Williams pp 2166–2168 DOI: 10.1021/ja910139a Supporting Info

Ligand-Based Reduction of CO2 to CO Mediated by an Anionic Niobium Nitride Complex Jared S. Silvia and Christopher C. Cummins pp 2169–2171 DOI: 10.1021/ja910445r Supporting Info

Aptamer-Controlled Biofuel Cells in Logic Systems and Used as Self-Powered and Intelligent Logic Aptasensors Ming Zhou, Yan Du, Chaogui Chen, Bingling Li, Dan Wen, Shaojun Dong and Erkang Wang pp 2172–2174 DOI: 10.1021/ja910634e Supporting Info

Positive Charge States and Possible Polymorphism of Gold Nanoclusters on Reduced Ceria Changjun Zhang, Angelos Michaelides, David A. King and Stephen J. Jenkins pp 2175–2182 DOI: 10.1021/ja906687f Supporting Info

Structure-Relaxation Interplay of a New Nanostructured Membrane Based on Tetraethylammonium Trifluoromethanesulfonate Ionic Liquid and Neutralized Nafion 117 for High-Temperature Fuel Cells Vito Di Noto, Enrico Negro, Jean-Yves Sanchez and Christina Iojoiu pp 2183–2195 DOI: 10.1021/ja906975z Supporting Info

CASSCF Molecular Orbital Calculations Reveal a Purely Pseudopericyclic Mechanism for a [3,3] Sigmatropic Rearrangement Lila Forte, Marie C. Lafortune, Irena R. Bierzynski and James A. Duncan pp 2196–2201 DOI: 10.1021/ja906679g Supporting Info

Coverage Effects on the Palladium-Catalyzed Synthesis of Vinyl Acetate: Comparison between Theory and Experiment Florencia Calaza, Dario Stacchiola, Matthew Neurock and Wilfred T. Tysoe pp 2202–2207 DOI: 10.1021/ja907061m

Orbital-Specific Energy Transfer Troy E. Knight and James K. McCusker pp 2208–2221 DOI: 10.1021/ja907303t Supporting Info

Oxysterols from Free Radical Chain Oxidation of 7-Dehydrocholesterol: Product and Mechanistic Studies Libin Xu, Zeljka Korade and Ned A. Porter pp 2222–2232 DOI: 10.1021/ja9080265 Supporting Info

Electrochemical Reactivity of Aromatic Molecules at Nanometer-Sized Surface Domains: From Pt(hkl) Single Crystal Electrodes to Preferentially Oriented Platinum Nanoparticles Margarita Rodríguez-López, Jose Solla-Gulln, Enrique Herrero, Paulino Tun, Juan M. Feliu, Antonio Aldaz and Arnaldo Carrasquillo, Jr. pp 2233–2242 DOI: 10.1021/ja909082s Supporting Info

Understanding Blue-to-Red Conversion in Monomeric Fluorescent Timers and Hydrolytic Degradation of Their Chromophores Sergei Pletnev, Fedor V. Subach, Zbigniew Dauter, Alexander Wlodawer and Vladislav V. Verkhusha pp 2243–2253 DOI: 10.1021/ja908418r Supporting Info

Interfacial Reactions of Ozone with Surfactant Protein B in a Model Lung Surfactant System Hugh I. Kim, Hyungjun Kim, Young Shik Shin, Luther W. Beegle, Seung Soon Jang, Evan L. Neidholdt, William A. Goddard, James R. Heath, Isik Kanik and J. L. Beauchamp pp 2254–2263 DOI: 10.1021/ja908477w Supporting Info

Unusual Relaxation Pathway from the Two-Photon Excited First Singlet State of Carotenoids Yoonsoo Pang, Garth A. Jones, Matthew A. Prantil and Graham R. Fleming pp 2264–2273 DOI: 10.1021/ja908472y Supporting Info

Efficient Regio- and Stereoselective Formation of Azocan-2-ones via 8-Endo Cyclization of α-Carbamoyl Radicals Xinqiang Fang, Kun Liu and Chaozhong Li pp 2274–2283 DOI: 10.1021/ja9082649 Supporting Info

Separation of C5-Hydrocarbons on Microporous Materials: Complementary Performance of MOFs and Zeolites Michael Maes, Luc Alaerts, Frederik Vermoortele, Rob Ameloot, Sarah Couck, Vincent Finsy, Joeri F. M. Denayer and Dirk E. De Vos pp 2284–2292 DOI: 10.1021/ja9088378 Supporting Info

Crystallographic Analysis of Counterion Effects on Subtilisin Enzymatic Action in Acetonitrile Michele Cianci, Bartlomiej Tomaszewski, John R. Helliwell and Peter J. Halling pp 2293–2300 DOI: 10.1021/ja908703c Supporting Info

Mixed Anion (Phosphate/Oxalate) Bonding to Iron(III) Materials Fiona R. Kizewski, Paul Boyle, Dean Hesterberg and James D. Martin pp 2301–2308 DOI: 10.1021/ja908807b Supporting Info

Monitoring Self-Sorting by Electrospray Ionization Mass Spectrometry: Formation Intermediates and Error-Correction during the Self-Assembly of Multiply Threaded Pseudorotaxanes Wei Jiang, Andreas Schfer, Parveen Choudhary Mohr and Christoph A. Schalley pp 2309–2320 DOI: 10.1021/ja9101369 Supporting Info

Factors Governing the Na+ vs K+ Selectivity in Sodium Ion Channels Todor Dudev and Carmay Lim pp 2321–2332 DOI: 10.1021/ja909280g Supporting Info

Rapid Separation and Purification of Nanoparticles in Organic Density Gradients Lu Bai, Xiuju Ma, Junfeng Liu, Xiaoming Sun, Dongyuan Zhao and David G. Evans pp 2333–2337 DOI: 10.1021/ja908971d Supporting Info

Equilibrium Study of Protein Denaturation by Urea Deepak R. Canchi, Dietmar Paschek and Angel E. Garca pp 2338–2344 DOI: 10.1021/ja909348c

Role of Ceria in Oxidative Dehydrogenation on Supported Vanadia Catalysts Maria Veronica Ganduglia-Pirovano, Cristina Popa, Joachim Sauer, Heather Abbott, Alexander Uhl, Martin Baron, Dario Stacchiola, Oleksandr Bondarchuk, Shamil Shaikhutdinov and Hans-Joachim Freund pp 2345–2349 DOI: 10.1021/ja910574h

EPR Studies of the Generation, Structure, and Reactivity of N-Heterocyclic Carbene Borane Radicals John C. Walton, Malika Makhlouf Brahmi, Louis Fensterbank, Emmanuel Lacte, Max Malacria, Qianli Chu, Shau-Hua Ueng, Andrey Solovyev and Dennis P. Curran pp 2350–2358 DOI: 10.1021/ja909502q Supporting Info

Stoichiometry of the Redox Neutral Deamination and Oxidative Dehydrogenation Reactions Catalyzed by the Radical SAM Enzyme DesII Mark W. Ruszczycky, Sei-hyun Choi and Hung-wen Liu pp 2359–2369 DOI: 10.1021/ja909451a Supporting Info

Uniting Polypeptides with Sequence-Designed Peptides: Synthesis and Assembly of Poly(γ-benzyl l-glutamate)-b-Coiled-Coil Peptide Copolymers Hana Robson Marsden, Jan-Willem Handgraaf, Fabio Nudelman, Nico A. J. M. Sommerdijk and Alexander Kros pp 2370–2377 DOI: 10.1021/ja909540a Supporting Info

Conformational Changes of an Ion Channel Detected Through Water−Protein Interactions Using Solid-State NMR Spectroscopy Wenbin Luo and Mei Hong pp 2378–2384 DOI: 10.1021/ja9096219 Supporting Info

Crystal Structure, Diffusion Path, and Oxygen Permeability of a Pr2NiO4-Based Mixed Conductor (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ Masatomo Yashima, Nuansaeng Sirikanda and Tatsumi Ishihara pp 2385–2392 DOI: 10.1021/ja909820h Supporting Info

Conformational Flexibility of Y145Stop Human Prion Protein Amyloid Fibrils Probed by Solid-State Nuclear Magnetic Resonance Spectroscopy Jonathan J. Helmus, Krystyna Surewicz, Witold K. Surewicz and Christopher P. Jaroniec pp 2393–2403 DOI: 10.1021/ja909827v Supporting Info

Single-Molecule Redox Blinking of Perylene Diimide Derivatives in Water Thorben Cordes, Jan Vogelsang, Milena Anaya, Carla Spagnuolo, Andreas Gietl, Wolfram Summerer, Andreas Herrmann, Klaus Mllen and Philip Tinnefeld pp 2404–2409 DOI: 10.1021/ja9099714 Supporting Info

Metalation of Pyridines with nBuLi−Li−Aminoalkoxide Mixed Aggregates: The Origin of Chemoselectivity Hassan K. Khartabil, Philippe C. Gros, Yves Fort and Manuel F. Ruiz-Lpez pp 2410–2416 DOI: 10.1021/ja910350q Supporting Info

Phase Diagram of NdFeAsO1−xFx: Essential Role of Chemical Composition Lorenzo Malavasi, Gianluca A. Artioli, Clemens Ritter, M. Cristina Mozzati, Beatrice Maroni, Bholanath Pahari and Andrea Caneschi pp 2417–2420 DOI: 10.1021/ja910426d Supporting Info

Nature of N−N Bonding within High-Pressure Noble-Metal Pernitrides and the Prediction of Lanthanum Pernitride Michael Wessel and Richard Dronskowski pp 2421–2429 DOI: 10.1021/ja910570t

Hydrolytic Decarboxylation of Carboxylic Acids and the Formation of Protonated Carbonic Acid Scott O. C. Mundle, Georges Lacrampe-Couloume, Barbara Sherwood Lollar and Ronald Kluger pp 2430–2436 DOI: 10.1021/ja910608m

Architectural Control of Seeded-Grown Magnetic−Semicondutor Iron Oxide−TiO2 Nanorod Heterostructures: The Role of Seeds in Topology Selection Raffaella Buonsanti, Vincenzo Grillo, Elvio Carlino, Cinzia Giannini, Fabia Gozzo, Mar Garcia-Hernandez, Miguel Angel Garcia, Roberto Cingolani and P. Davide Cozzoli pp 2437–2464 DOI: 10.1021/ja910322a Supporting Info

Lanthanide-Containing Polymer Microspheres by Multiple-Stage Dispersion Polymerization for Highly Multiplexed Bioassays Ahmed I. Abdelrahman, Sheng Dai, Stuart C. Thickett, Olga Ornatsky, Dmitry Bandura, Vladimir Baranov and Mitchell A. Winnik p 2465 DOI: 10.1021/ja910402c

ChemBioOffice Ultra 2010 Suite Sean M. Kerwin pp 2466–2467 DOI: 10.1021/ja1005306

Mass Spectrometry and Gas-Phase Chemistry of Non-Covalent Complexes Victor Ryzhov p 2468 DOI: 10.1021/ja100672v

Issue 08

Natural Products Version 2.0: Connecting Genes to Molecules Christopher T. Walsh and Michael A. Fischbach pp 2469–2493 DOI: 10.1021/ja909118a Supporting Info

Electrochemical Scanning Tunneling Spectroscopy of Redox-Active Molecules Bound by Au−C Bonds Alejandra M. Ricci, Ernesto J. Calvo, Santiago Martin and Richard J. Nichols pp 2494–2495 DOI: 10.1021/ja907867b Supporting Info

Ligand-Controlled Regioselectivity in Palladium-Catalyzed Cross Coupling Reactions Franziska Schoenebeck and K. N. Houk pp 2496–2497 DOI: 10.1021/ja9077528 Supporting Info

Na-Doped p-Type ZnO Microwires Wei Liu, Faxian Xiu, Ke Sun, Ya-Hong Xie, Kang L Wang, Yong Wang, Jin Zou, Zheng Yang and Jianlin Liu pp 2498–2499 DOI: 10.1021/ja908521s Supporting Info

Chemical Degradation of Drinking Water Disinfection Byproducts by Millimeter-Sized Particles of Iron−Silicon and Magnesium−Aluminum Alloys Tianyu Li, Yongmei Chen, Pingyu Wan, Maohong Fan and X. Jin Yang pp 2500–2501 DOI: 10.1021/ja908821d Supporting Info

Surface Plasmon Coupled Circular Dichroism of Au Nanoparticles on Peptide Nanotubes Jino George and K. George Thomas pp 2502–2503 DOI: 10.1021/ja908574j Supporting Info

Approach to Profile Proteins That Recognize Post-Translationally Modified Histone “Tails” Xiang Li and Tarun M. Kapoor pp 2504–2505 DOI: 10.1021/ja909741q Supporting Info

Synthesis of Pd−Au Bimetallic Nanocrystals via Controlled Overgrowth Byungkwon Lim, Hirokazu Kobayashi, Taekyung Yu, Jinguo Wang, Moon J. Kim, Zhi-Yuan Li, Matthew Rycenga and Younan Xia pp 2506–2507 DOI: 10.1021/ja909787h Supporting Info

Optimizing the Polarization Matrix for ex Situ Dynamic Nuclear Polarization Christian Ludwig, Ildefonso Marin-Montesinos, Martin G. Saunders and Ulrich L. Gnther pp 2508–2509 DOI: 10.1021/ja909984w Supporting Info

Synthesis and Reactivity of Rhodium(II) N-Triflyl Azavinyl Carbenes Neil Grimster, Li Zhang and Valery V. Fokin pp 2510–2511 DOI: 10.1021/ja910187s Supporting Info

Polyacrylamide Gel Photopatterning Enables Automated Protein Immunoblotting in a Two-Dimensional Microdevice Mei He and Amy E. Herr pp 2512–2513 DOI: 10.1021/ja910164d Supporting Info

Much of the Microcin J25 Leader Peptide is Dispensable Wai Ling Cheung, Si Jia Pan and A. James Link pp 2514–2515 DOI: 10.1021/ja910191u Supporting Info

Chemical Solution Deposition of Epitaxial Carbide Films Guifu Zou, Haiyan Wang, Nathan Mara, Hongmei Luo, Nan Li, Zengfeng Di, Eve Bauer, Yongqiang Wang, Thomas McCleskey, Anthony Burrell, Xinghang Zhang, Michael Nastasi and Quanxi Jia pp 2516–2517 DOI: 10.1021/ja9102315 Supporting Info

Development of an Activity Assay for Discovery of Inhibitors of Lipopolysaccharide Transport Luisa S. Gronenberg and Daniel Kahne pp 2518–2519 DOI: 10.1021/ja910361r Supporting Info

Selective Pairwise Encapsulation Using Directional Interactions Guzmn Gil-Ramrez, Marcos Chas and Pablo Ballester pp 2520–2521 DOI: 10.1021/ja910436v Supporting Info

Copper-Catalyzed Direct Alkynylation of Electron-Deficient Polyfluoroarenes with Terminal Alkynes Using O2 as an Oxidant Ye Wei, Huaiqing Zhao, Jian Kan, Weiping Su and Maochun Hong pp 2522–2523 DOI: 10.1021/ja910461e Supporting Info

Stereospecific Suzuki Cross-Coupling of Alkyl α-Cyanohydrin Triflates Anyu He and J. R. Falck pp 2524–2525 DOI: 10.1021/ja910582n Supporting Info

Is Mo Involved in Hydride Binding by the Four-Electron Reduced (E4) Intermediate of the Nitrogenase MoFe Protein? Dmitriy Lukoyanov, Zhi-Yong Yang, Dennis R. Dean, Lance C. Seefeldt and Brian M. Hoffman pp 2526–2527 DOI: 10.1021/ja910613m

Total Synthesis of the Ammosamides Chambers C. Hughes and William Fenical pp 2528–2529 DOI: 10.1021/ja9106572 Supporting Info

Synthesis, Structural Analysis, and Reactivity of Bridged Orthoamides by Intramolecular Schmidt Reaction Michal Szostak and Jeffrey Aub pp 2530–2531 DOI: 10.1021/ja910654t Supporting Info

A Metal-Catalyzed Intermolecular [5+2] Cycloaddition/Nazarov Cyclization Sequence and Cascade Paul A. Wender, Ren T. Stemmler and Lauren E. Sirois pp 2532–2533 DOI: 10.1021/ja910696x Supporting Info

Regio- and Stereoselective Ni-Catalyzed 1,4-Hydroboration of 1,3-Dienes: Access to Stereodefined (Z)-Allylboron Reagents and Derived Allylic Alcohols Robert J. Ely and James P. Morken pp 2534–2535 DOI: 10.1021/ja910750b Supporting Info

Iridium-Catalyzed α-Alkylation of Acetates with Primary Alcohols and Diols Yosuke Iuchi, Yasushi Obora and Yasutaka Ishii pp 2536–2537 DOI: 10.1021/ja9106989 Supporting Info

Selective Growth of Monoclinic and Tetragonal Zirconia Nanocrystals Kazuyoshi Sato, Hiroya Abe and Satoshi Ohara pp 2538–2539 DOI: 10.1021/ja910712r Supporting Info

Development of a Convergent Entry to the Diazofluorene Antitumor Antibiotics: Enantioselective Synthesis of Kinamycin F Christina M. Woo, Liang Lu, Shivajirao L. Gholap, Devin R. Smith and Seth B. Herzon pp 2540–2541 DOI: 10.1021/ja910769j Supporting Info

A Concise Enantioselective Synthesis of the Chlorosulfolipid Malhamensilipin A D. Karl Bedke, Grant M. Shibuya, Alban R. Pereira, William H. Gerwick and Christopher D. Vanderwal pp 2542–2543 DOI: 10.1021/ja910809c Supporting Info

Coronene Nanophase within Coordination Spheres: Increased Solubility of C60 Kosuke Suzuki, Kiyotaka Takao, Sota Sato and Makoto Fujita pp 2544–2545 DOI: 10.1021/ja910836h Supporting Info

Reactivity of an Aryl-Substituted Silicon−Silicon Triple Bond: Reactions of a 1,2-Diaryldisilyne with Alkenes Joon Soo Han, Takahiro Sasamori, Yoshiyuki Mizuhata and Norihiro Tokitoh pp 2546–2547 DOI: 10.1021/ja9108566 Supporting Info

Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives Noriyuki Iwadate and Michinori Suginome pp 2548–2549 DOI: 10.1021/ja1000642 Supporting Info

2-(Acetoxymethyl)buta-2,3-dienoate, a Versatile 1,4-Biselectrophile for Phosphine-Catalyzed (4 + n) Annulations with 1,n-Bisnucleophiles (n = 1, 2) Qiongmei Zhang, Lei Yang and Xiaofeng Tong pp 2550–2551 DOI: 10.1021/ja100432m Supporting Info

Phthalocyanine Blends Improve Bulk Heterojunction Solar Cells Alessandro Varotto, Chang-Yong Nam, Ivana Radivojevic, Joao P. C. Tom, Jos A. S. Cavaleiro, Charles T. Black and Charles Michael Drain pp 2552–2554 DOI: 10.1021/ja907851x Supporting Info

In Situ Characterization of the 5d Density of States of Pt Nanoparticles upon Adsorption of CO Pieter Glatzel, Jagdeep Singh, Kristina O. Kvashnina and Jeroen A. van Bokhoven pp 2555–2557 DOI: 10.1021/ja907760p Supporting Info

Cyclobutanone Analogues of β-Lactams Revisited: Insights into Conformational Requirements for Inhibition of Serine- and Metallo-β-Lactamases Jarrod W. Johnson, Michael Gretes, Valerie J. Goodfellow, Laura Marrone, Miriam L. Heynen, Natalie C. J. Strynadka and Gary I. Dmitrienko pp 2558–2560 DOI: 10.1021/ja9086374 Supporting Info

Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity Ming-Hua Zeng, Qiang-Xin Wang, Yan-Xi Tan, Sheng Hu, Hai-Xia Zhao, La-Sheng Long and Mohamedally Kurmoo pp 2561–2563 DOI: 10.1021/ja908293n Supporting Info

Powder Crystallography by Combined Crystal Structure Prediction and High-Resolution 1H Solid-State NMR Spectroscopy Elodie Salager, Graeme M. Day, Robin S. Stein, Chris J. Pickard, Bndicte Elena and Lyndon Emsley pp 2564–2566 DOI: 10.1021/ja909449k Supporting Info

Dynamic Copper(I) Imaging in Mammalian Cells with a Genetically Encoded Fluorescent Copper(I) Sensor Seraphine V. Wegner, Hasan Arslan, Murat Sunbul, Jun Yin and Chuan He pp 2567–2569 DOI: 10.1021/ja9097324 Supporting Info

Easy Access to a Family of Polymer Catalysts from Modular Star Polymers Valentin Rodionov, Haifeng Gao, Steven Scroggins, David A. Unruh, Alyssa-Jennifer Avestro and Jean M. J. Frchet pp 2570–2572 DOI: 10.1021/ja9104842 Supporting Info

Glycodynamers: Dynamic Polymers Bearing Oligosaccharides Residues − Generation, Structure, Physicochemical, Component Exchange, and Lectin Binding Properties Yves Ruff, Eric Buhler, Sauveur-Jean Candau, Ellina Kesselman, Yeshayahu Talmon and Jean-Marie Lehn pp 2573–2584 DOI: 10.1021/ja9082733 Supporting Info

Live-Cell One- and Two-Photon Uncaging of a Far-Red Emitting Acridinone Fluorophore David Warther, Frdric Bolze, Jrmie Lonard, Sylvestre Gug, Alexandre Specht, David Puliti, Xiao-Hua Sun, Pascal Kessler, Yves Lutz, Jean-Luc Vonesch, Barbara Winsor, Jean-Franois Nicoud and Maurice Goeldner pp 2585–2590 DOI: 10.1021/ja9074562 Supporting Info

Characterization of Radicals Formed Following Enzymatic Reduction of 3-Substituted Analogues of the Hypoxia-Selective Cytotoxin 3-Amino-1,2,4-Benzotriazine 1,4-Dioxide (Tirapazamine) Sujata S. Shinde, Andrej Maroz, Michael P. Hay, Adam V. Patterson, William A. Denny and Robert F. Anderson pp 2591–2599 DOI: 10.1021/ja908689f Supporting Info

Ultrafast X-ray Solution Scattering Reveals Different Reaction Pathways in the Photolysis of Triruthenium Dodecacarbonyl (Ru3(CO)12) after Ultraviolet and Visible Excitation Qingyu Kong, Jae Hyuk Lee, Kyung Hwan Kim, Joonghan Kim, Michael Wulff, Hyotcherl Ihee and Michel H. J. Koch pp 2600–2607 DOI: 10.1021/ja9097548 Supporting Info

Mesoporous Co3O4 and Au/Co3O4 Catalysts for Low-Temperature Oxidation of Trace Ethylene Chun Yan Ma, Zhen Mu, Jin Jun Li, Yong Gang Jin, Jie Cheng, Gao Qing Lu, Zheng Ping Hao and Shi Zhang Qiao pp 2608–2613 DOI: 10.1021/ja906274t Supporting Info

Tailored Electroactive and Quantitative Ligand Density Microarrays Applied to Stem Cell Differentiation Wei Luo, Eugene W.L. Chan and Muhammad N. Yousaf pp 2614–2621 DOI: 10.1021/ja907187f Supporting Info

Photoelectrochemical Processes in Polymer-Tethered CdSe Nanocrystals R. Clayton Shallcross, Gemma D. D’Ambruoso, Jeffrey Pyun and Neal R. Armstrong pp 2622–2632 DOI: 10.1021/ja907782f Supporting Info

Plasmonic Field Enhancement of the Exciton−Exciton Annihilation Process in a Poly(p-phenyleneethynylene) Fluorescent Polymer by Ag Nanocubes Mahmoud A. Mahmoud, Adam J. Poncheri, Ronnie L. Phillips and Mostafa A. El-Sayed pp 2633–2641 DOI: 10.1021/ja907657j Supporting Info

Intracellular Delivery of a Membrane-Impermeable Enzyme in Active Form Using Functionalized Gold Nanoparticles Partha Ghosh, Xiaochao Yang, Rochelle Arvizo, Zheng-Jiang Zhu, Sarit S. Agasti, Zhihong Mo and Vincent M. Rotello pp 2642–2645 DOI: 10.1021/ja907887z Supporting Info

Anthracene−BODIPY Dyads as Fluorescent Sensors for Biocatalytic Diels−Alder Reactions Alexander Nierth, Andrei Yu. Kobitski, G. Ulrich Nienhaus and Andres Jschke pp 2646–2654 DOI: 10.1021/ja9084397 Supporting Info

Molecular Electrocatalysis for Oxygen Reduction by Cobalt Porphyrins Adsorbed at Liquid/Liquid Interfaces Bin Su, Imren Hatay, Antonn Trojnek, Zdenk Samec, Tony Khoury, Claude P. Gros, Jean-Michel Barbe, Antoine Daina, Pierre-Alain Carrupt and Hubert H. Girault pp 2655–2662 DOI: 10.1021/ja908488s Supporting Info

A Contractile Electronic Switch Made of DNA Yu Chuan Huang and Dipankar Sen pp 2663–2671 DOI: 10.1021/ja908508j Supporting Info

Formation of the Phenyl Radical [C6H5(X2A1)] under Single Collision Conditions: A Crossed Molecular Beam and ab Initio Study Fangtong Zhang, Brant Jones, Pavlo Maksyutenko, Ralf I. Kaiser, Christine Chin, Vadim V. Kislov and Alexander M. Mebel pp 2672–2683 DOI: 10.1021/ja908559v Supporting Info

Resonating Valence Bond and σ-Charge Density Wave Phases in a Benzannulated Phenalenyl Radical Pradip Bag, Mikhail E. Itkis, Sushanta K. Pal, Bruno Donnadieu, Fook S. Tham, Hyunsoo Park, John A. Schlueter, Theo Siegrist and Robert C. Haddon pp 2684–2694 DOI: 10.1021/ja908768a Supporting Info

Catalyst-Site-Controlled Coordination Polymerization of Polar Vinyl Monomers to Highly Syndiotactic Polymers Yuetao Zhang, Yalan Ning, Lucia Caporaso, Luigi Cavallo and Eugene Y.-X. Chen pp 2695–2709 DOI: 10.1021/ja908818y Supporting Info

Silicon Nanosheets and Their Self-Assembled Regular Stacking Structure Hirotaka Okamoto, Yoko Kumai, Yusuke Sugiyama, Takuya Mitsuoka, Koji Nakanishi, Toshiaki Ohta, Hiroshi Nozaki, Satoshi Yamaguchi, Soichi Shirai and Hideyuki Nakano pp 2710–2718 DOI: 10.1021/ja908827z Supporting Info

Aromatic−Aromatic Interactions Induce the Self-Assembly of Pentapeptidic Derivatives in Water To Form Nanofibers and Supramolecular Hydrogels Manlung Ma, Yi Kuang, Yuan Gao, Yan Zhang, Ping Gao and Bing Xu pp 2719–2728 DOI: 10.1021/ja9088764 Supporting Info

Encapsulation and Stabilization of Gold Nanoparticles with “Click” Polyethyleneglycol Dendrimers Elodie Boisselier, Abdou K. Diallo, Lionel Salmon, Ctia Ornelas, Jaime Ruiz and Didier Astruc pp 2729–2742 DOI: 10.1021/ja909133f Supporting Info

Transient Optical Studies of Interfacial Charge Transfer at Nanostructured Metal Oxide/PbS Quantum Dot/Organic Hole Conductor Heterojunctions Henry C. Leventis, Flannan O’Mahony, Javeed Akhtar, Mohammad Afzaal, Paul O’Brien and Saif A. Haque pp 2743–2750 DOI: 10.1021/ja909172p Supporting Info

Editing Mechanism of Aminoacyl-tRNA Synthetases Operates by a Hybrid Ribozyme/Protein Catalyst Yohsuke Hagiwara, Martin J. Field, Osamu Nureki and Masaru Tateno pp 2751–2758 DOI: 10.1021/ja9095208 Supporting Info

Effects of Ce3+ Codoping and Annealing on Phase Transformation and Luminescence of Eu3+-Doped YPO4 Nanorods: D2O Solvent Effect M. Niraj Luwang, R. S. Ningthoujam, Jagannath, S. K. Srivastava and R. K. Vatsa pp 2759–2768 DOI: 10.1021/ja909578s Supporting Info

Multiplexed DNA-Modified Electrodes Jason D. Slinker, Natalie B. Muren, Alon A. Gorodetsky and Jacqueline K. Barton pp 2769–2774 DOI: 10.1021/ja909915m Supporting Info

Acyl Phosphonates: Good Hydrogen Bond Acceptors and Ester/Amide Equivalents in Asymmetric Organocatalysis Hao Jiang, Mrcio W. Paixo, David Monge and Karl Anker Jørgensen pp 2775–2783 DOI: 10.1021/ja9097803 Supporting Info

Kinetic and Thermodynamic Analysis of Processes Relevant to Initiation of Olefin Metathesis by Ruthenium Phosphonium Alkylidene Catalysts Erin M. Leitao, Edwin F. van der Eide, Patricio E. Romero, Warren, E. Piers and Robert McDonald pp 2784–2794 DOI: 10.1021/ja910112m Supporting Info

Development and Application of a Near-Infrared Fluorescence Probe for Oxidative Stress Based on Differential Reactivity of Linked Cyanine Dyes Daihi Oushiki, Hirotatsu Kojima, Takuya Terai, Makoto Arita, Kenjiro Hanaoka, Yasuteru Urano and Tetsuo Nagano pp 2795–2801 DOI: 10.1021/ja910090v Supporting Info

Topotactic Reduction of YBaCo2O5 and LaBaCo2O5: Square-Planar Co(I) in an Extended Oxide James Seddon, Emmanuelle Suard and Michael A. Hayward pp 2802–2810 DOI: 10.1021/ja910103d Supporting Info

Ultrafast Dynamics of Diatomic Ligand Binding to Nitrophorin 4 Abdelkrim Benabbas, Xiong Ye, Minoru Kubo, Zhenyu Zhang, Estelle M. Maes, William R. Montfort and Paul M. Champion pp 2811–2820 DOI: 10.1021/ja910005b Supporting Info

A Series of Peroxomanganese(III) Complexes Supported by Tetradentate Aminopyridyl Ligands: Detailed Spectroscopic and Computational Studies Robert A. Geiger, Swarup Chattopadhyay, Victor W. Day and Timothy A. Jackson pp 2821–2831 DOI: 10.1021/ja910235g Supporting Info

2D IR Line Shapes Probe Ovispirin Peptide Conformation and Depth in Lipid Bilayers Ann Marie Woys, Yu-Shan Lin, Allam S. Reddy, Wei Xiong, Juan J. de Pablo, James L. Skinner and Martin T. Zanni pp 2832–2838 DOI: 10.1021/ja9101776 Supporting Info

Intramolecular Anodic Olefin Coupling Reactions and the Synthesis of Cyclic Amines Hai-Chao Xu and Kevin D. Moeller pp 2839–2844 DOI: 10.1021/ja910586v Supporting Info

Adiabatic and Non-adiabatic Concerted Proton−Electron Transfers. Temperature Effects in the Oxidation of Intramolecularly Hydrogen-Bonded Phenols Cyrille Costentin, Marc Robert and Jean-Michel Savant p 2845 DOI: 10.1021/ja100377g

Polyvalent Oligonucleotide Gold Nanoparticle Conjugates as Delivery Vehicles for Platinum(IV) Warheads Shanta Dhar, Weston L. Daniel, David A. Giljohann, Chad A. Mirkin and Stephen J. Lippard p 2845 DOI: 10.1021/ja100560g

Noncovalent Cell Surface Engineering with Cationic Graft Copolymers John T. Wilson, Venkata R. Krishnamurthy, Wanxing Cui, Zheng Qu and Elliot L. Chaikof p 2845 DOI: 10.1021/ja9109264

Eco-Friendly Synthesis of Fine Chemicals Joseph M. Fortunak p 2846 DOI: 10.1021/ja1000483

Issue 09

Directed Formation of an Organotin Sulfide Cavitand and Its Transformation into a Rugby-Ball-like Capsule Zohreh Hassanzadeh Fard, Mohammad Reza Halvagar and Stefanie Dehnen pp 2848–2849 DOI: 10.1021/ja908917w Supporting Info

Fabrication of Ag@SiO2@Y2O3:Er Nanostructures for Bioimaging: Tuning of the Upconversion Fluorescence with Silver Nanoparticles Fan Zhang, Gary B. Braun, Yifeng Shi, Yichi Zhang, Xiaohong Sun, Norbert O. Reich, Dongyuan Zhao and Galen Stucky pp 2850–2851 DOI: 10.1021/ja909108x Supporting Info

RNA Conformation in Catalytically Active Human Telomerase Justin A. Yeoman, Angel Orte, Beth Ashbridge, David Klenerman and Shankar Balasubramanian pp 2852–2853 DOI: 10.1021/ja909383n Supporting Info

Counting the Atoms in Supported, Monolayer-Protected Gold Clusters Z. W. Wang, O. Toikkanen, F. Yin, Z. Y. Li, B. M. Quinn and R. E. Palmer pp 2854–2855 DOI: 10.1021/ja909598g Supporting Info

Palladium-Catalyzed Intermolecular Aminofluorination of Styrenes Shuifa Qiu, Tao Xu, Juan Zhou, Yinlong Guo and Guosheng Liu pp 2856–2857 DOI: 10.1021/ja909716k Supporting Info

Room-Temperature Reaction of Oxygen with Gold: An In situ Ambient-Pressure X-ray Photoelectron Spectroscopy Investigation Peng Jiang, Soeren Porsgaard, Ferenc Borondics, Mariana Kber, Alfonso Caballero, Hendrik Bluhm, Flemming Besenbacher and Miquel Salmeron pp 2858–2859 DOI: 10.1021/ja909987j

N-Heterocyclic Carbene Catalyzed Asymmetric Hydration: Direct Synthesis of α-Protio and α-Deuterio α-Chloro and α-Fluoro Carboxylic Acids Harit U. Vora and Tomislav Rovis pp 2860–2861 DOI: 10.1021/ja910281s Supporting Info

Single-Crystal Membrane for Anisotropic and Efficient Gas Permeation Satoshi Takamizawa, Yuichi Takasaki and Ryosuke Miyake pp 2862–2863 DOI: 10.1021/ja910492d Supporting Info

Main-Chain Ionic Chiral Polymers: Synthesis of Optically Active Quaternary Ammonium Sulfonate Polymers and Their Application in Asymmetric Catalysis Shinichi Itsuno, Devproshad K. Paul, M. A. Salam and Naoki Haraguchi pp 2864–2865 DOI: 10.1021/ja909972d Supporting Info

Naphthalene Diels−Alder in a Self-Assembled Molecular Flask Takashi Murase, Shinnosuke Horiuchi and Makoto Fujita pp 2866–2867 DOI: 10.1021/ja9107275 Supporting Info

Botulinum Neurotoxin A Protease: Discovery of Natural Product Exosite Inhibitors Peter ilhr, Kateina apková, Nicholas T. Salzameda, Joseph T. Barbieri, Mark S. Hixon and Kim D. Janda pp 2868–2869 DOI: 10.1021/ja910761y Supporting Info

Peptide-Catalyzed Kinetic Resolution of Formamides and Thioformamides as an Entry to Nonracemic Amines Brandon S. Fowler, Peter J. Mikochik and Scott J. Miller pp 2870–2871 DOI: 10.1021/ja9107897 Supporting Info

On-Chip Functionalization of Carbon Nanotubes with Photosystem I Simone M. Kaniber, Matthias Brandstetter, Friedrich C. Simmel, Itai Carmeli and Alexander W. Holleitner pp 2872–2873 DOI: 10.1021/ja910790x

Generation of Absolute Controlled Crystal Chirality by the Removal of Crystal Water from Achiral Crystal of Nucleobase Cytosine Tsuneomi Kawasaki, Yuko Hakoda, Hiroko Mineki, Kenta Suzuki and Kenso Soai pp 2874–2875 DOI: 10.1021/ja1000938 Supporting Info

Multifunctional Porous Graphene for Nanoelectronics and Hydrogen Storage: New Properties Revealed by First Principle Calculations Aijun Du, Zhonghua Zhu and Sean C. Smith pp 2876–2877 DOI: 10.1021/ja100156d Supporting Info

Aryl−CF3 Bond-Forming Reductive Elimination from Palladium(IV) Nicholas D. Ball, Jeff W. Kampf and Melanie S. Sanford pp 2878–2879 DOI: 10.1021/ja100955x Supporting Info

Bifunctional Asymmetric Catalysis: Amplification of Brønsted Basicity Can Orthogonally Increase the Reactivity of a Chiral Brønsted Acid Tyler A. Davis, Jeremy C. Wilt and Jeffrey N. Johnston pp 2880–2882 DOI: 10.1021/ja908814h Supporting Info

Role of Secondary Sialic Acid Binding Sites in Influenza N1 Neuraminidase Jeffrey C. Sung, Adam W. Van Wynsberghe, Rommie E. Amaro, Wilfred W. Li and J. Andrew McCammon pp 2883–2885 DOI: 10.1021/ja9073672 Supporting Info

Reversible Photoswitchable Fluorescence in Thin Films of Inorganic Nanoparticle and Polyoxometalate Assemblies Bing Qin, Hongyue Chen, Hui Liang, Lei Fu, Xinfeng Liu, Xiaohui Qiu, Shaoqin Liu, Rui Song and Zhiyong Tang pp 2886–2888 DOI: 10.1021/ja908201x Supporting Info

Macrocyclization of Linear Peptides Enabled by Amphoteric Molecules Ryan Hili, Vishal Rai and Andrei K. Yudin pp 2889–2891 DOI: 10.1021/ja910544p Supporting Info

Solar Driven Water Oxidation by a Bioinspired Manganese Molecular Catalyst Robin Brimblecombe, Annette Koo, G. Charles Dismukes, Gerhard F. Swiegers and Leone Spiccia pp 2892–2894 DOI: 10.1021/ja910055a Supporting Info

Copper-Catalyzed γ-Selective Allyl−Alkyl Coupling between Allylic Phosphates and Alkylboranes Hirohisa Ohmiya, Umi Yokobori, Yusuke Makida and Masaya Sawamura pp 2895–2897 DOI: 10.1021/ja9109105 Supporting Info

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes Kang-sang Lee and Amir H. Hoveyda pp 2898–2900 DOI: 10.1021/ja910989n Supporting Info

Biosynthesis of Spinosyn in Saccharopolyspora spinosa: Synthesis of Permethylated Rhamnose and Characterization of the Functions of SpnH, SpnI, and SpnK Hak Joong Kim, Jess A. White-Phillip, Yasushi Ogasawara, Nara Shin, Eta A. Isiorho and Hung-wen Liu pp 2901–2903 DOI: 10.1021/ja910223x Supporting Info

Bridged β3-Peptide Inhibitors of p53-hDM2 Complexation: Correlation between Affinity and Cell Permeability Arjel D. Bautista, Jacob S. Appelbaum, Cody J. Craig, Julien Michel and Alanna Schepartz pp 2904–2906 DOI: 10.1021/ja910715u Supporting Info

How Solvent Modulates Hydroxyl Radical Reactivity in Hydrogen Atom Abstractions Susan Mitroka, Stephanie Zimmeck, Diego Troya and James M. Tanko pp 2907–2913 DOI: 10.1021/ja903856t Supporting Info

Contact Geometry Symmetry Dependence of Field Effect Gating in Single-Molecule Transistors Trilisa M. Perrine and Barry D. Dunietz pp 2914–2918 DOI: 10.1021/ja906234v Supporting Info

Magnetic Behavior of Odd- and Even-Electron Metal Carbonyl Clusters: The Case Study of [Co8Pt4C2(CO)24]n− (n = 1, 2) Carbide Cluster Cristina Femoni, Maria Carmela Iapalucci, Giuliano Longoni, Joanna Wolowska, Stefano Zacchini, Piero Zanello, Serena Fedi, Mauro Ricc, Daniele Pontiroli and Marcello Mazzani pp 2919–2927 DOI: 10.1021/ja907608c Supporting Info

A Combined Solid-State NMR and Synchrotron X-ray Diffraction Powder Study on the Structure of the Antioxidant (+)-Catechin 4.5-hydrate. James K. Harper, Jennifer A. Doebbler, Elisabeth Jacques, David M. Grant and Robert B. Von Dreele pp 2928–2937 DOI: 10.1021/ja907671p Supporting Info

The Crystalline Nanocluster Phase as a Medium for Structural and Spectroscopic Studies of Light Absorption of Photosensitizer Dyes on Semiconductor Surfaces Jason B. Benedict and Philip Coppens pp 2938–2944 DOI: 10.1021/ja909600w Supporting Info

High-Resolution 3D CANCA NMR Experiments for Complete Mainchain Assignments Using Cα Direct Detection Koh Takeuchi, Dominique P. Frueh, Sven G. Hyberts, Zhen-Yu J. Sun and Gerhard Wagner pp 2945–2951 DOI: 10.1021/ja907717b Supporting Info

Comprehensive and Cost-Effective NMR Spectroscopy of Methyl Groups in Large Proteins Renee Otten, Byron Chu, Karla D. Krewulak, Hans J. Vogel and Frans A. A. Mulder pp 2952–2960 DOI: 10.1021/ja907706a Supporting Info

Optical Monitoring of Gases with Cholesteric Liquid Crystals Yang Han, Katherine Pacheco, Cees W. M. Bastiaansen, Dirk J. Broer and Rint P. Sijbesma pp 2961–2967 DOI: 10.1021/ja907826z Supporting Info

Atomistic Simulation of NO Dioxygenation in Group I Truncated Hemoglobin Sabyashachi Mishra and Markus Meuwly pp 2968–2982 DOI: 10.1021/ja9078144 Supporting Info

Mechanistic Insights on Riboflavin Synthase Inspired by Selective Binding of the 6,7-Dimethyl-8-ribityllumazine Exomethylene Anion Ryu-Ryun Kim, Boris Illarionov, Monika Joshi, Mark Cushman, Chan Yong Lee, Wolfgang Eisenreich, Markus Fischer and Adelbert Bacher pp 2983–2990 DOI: 10.1021/ja908395r Supporting Info

Pd Nanoparticles Embedded into a Metal-Organic Framework: Synthesis, Structural Characteristics, and Hydrogen Sorption Properties Claudia Zlotea, Renato Campesi, Fermin Cuevas, Eric Leroy, Philippe Dibandjo, Christophe Volkringer, Thierry Loiseau, Grard Frey and Michel Latroche pp 2991–2997 DOI: 10.1021/ja9084995

Doubly Deuterium-Labeled Patchouli Alcohol from Cyclization of Singly Labeled [2-2H1]Farnesyl Diphosphate Catalyzed by Recombinant Patchoulol Synthase Juan A. Faraldos, Shuiqin Wu, Joe Chappell and Robert M. Coates pp 2998–3008 DOI: 10.1021/ja909251r Supporting Info

Total Synthesis of (+)-Fendleridine (Aspidoalbidine) and (+)-1-Acetylaspidoalbidine Erica L. Campbell, Andrea M. Zuhl, Christopher M. Liu and Dale L. Boger pp 3009–3012 DOI: 10.1021/ja908819q Supporting Info

Phenylacetylene One-Dimensional Nanostructures on the Si(100)-2 × 1:H Surface Michael A. Walsh, Stephanie R. Walter, Kirk H. Bevan, Franz M. Geiger and Mark C. Hersam pp 3013–3019 DOI: 10.1021/ja909139n

Versatile Phosphate Phosphors ABPO4 in White Light-Emitting Diodes: Collocated Characteristic Analysis and Theoretical Calculations Chun Che Lin, Zhi Ren Xiao, Guang-Yu Guo, Ting-Shan Chan and Ru-Shi Liu pp 3020–3028 DOI: 10.1021/ja9092456 Supporting Info

Dynamics of 1,3-Dipolar Cycloadditions: Energy Partitioning of Reactants and Quantitation of Synchronicity Lai Xu, Charles E. Doubleday and K. N. Houk pp 3029–3037 DOI: 10.1021/ja909372f Supporting Info

Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Different Addition of H2S, NH3, and Organoamines on a Silicon(II) Ligand versus Its Si(II)→Ni(CO)3 Complex Antje Meltzer, Shigeyoshi Inoue, Carsten Prsang and Matthias Driess pp 3038–3046 DOI: 10.1021/ja910305p Supporting Info

Electrochemical Responses and Electrocatalysis at Single Au Nanoparticles Yongxin Li, Jonathan T. Cox and Bo Zhang pp 3047–3054 DOI: 10.1021/ja909408q Supporting Info

Boron Esters as Tunable Anion Carriers for Non-Aqueous Batteries Electrochemistry Devaraj Shanmukaraj, Sylvie Grugeon, Grgory Gachot, Stphane Laruelle, David Mathiron, Jean-Marie Tarascon and Michel Armand pp 3055–3062 DOI: 10.1021/ja9093814

Synthesis and Structure−Activity Correlation of Natural-Product Inspired Cyclodepsipeptides Stabilizing F-Actin Ren Tannert, Lech-Gustav Milroy, Bernhard Ellinger, Tai-Shan Hu, Hans-Dieter Arndt and Herbert Waldmann pp 3063–3077 DOI: 10.1021/ja9095126 Supporting Info

Origins of the Selectivity for Borylation of Primary over Secondary C−H Bonds Catalyzed by Cp*-Rhodium Complexes Carolyn S. Wei, Carlos A. Jimnez-Hoyos, Marcelo F. Videa, John F. Hartwig and Michael B. Hall pp 3078–3091 DOI: 10.1021/ja909453g Supporting Info

Multistimuli Responsive Organogels Based on a New Gelator Featuring Tetrathiafulvalene and Azobenzene Groups: Reversible Tuning of the Gel−Sol Transition by Redox Reactions and Light Irradiation Cheng Wang, Qun Chen, Fei Sun, Deqing Zhang, Guanxin Zhang, Yanyan Huang, Rui Zhao and Daoben Zhu pp 3092–3096 DOI: 10.1021/ja910721s Supporting Info

Quantum Mechanical/Molecular Mechanical Modeling Finds Diels−Alder Reactions Are Accelerated Less on the Surface of Water Than in Water Laura L. Thomas, Julian Tirado-Rives and William L. Jorgensen pp 3097–3104 DOI: 10.1021/ja909740y

Protonated [4n]π and [4n+2]π Octaphyrins Choose Their Mbius/Hckel Aromatic Topology Jong Min Lim, Jae-Yoon Shin, Yasuo Tanaka, Shohei Saito, Atsuhiro Osuka and Dongho Kim pp 3105–3114 DOI: 10.1021/ja909744z Supporting Info

Electronic Communication in Dinuclear C4-Bridged Tungsten Complexes Sergey N. Semenov, Olivier Blacque, Thomas Fox, Koushik Venkatesan and Heinz Berke pp 3115–3127 DOI: 10.1021/ja909764x Supporting Info

Evolution of Catalysts Directed by Genetic Algorithms in a Plug-Based Microfluidic Device Tested with Oxidation of Methane by Oxygen Jason E. Kreutz, Anton Shukhaev, Wenbin Du, Sasha Druskin, Olafs Daugulis and Rustem F. Ismagilov pp 3128–3132 DOI: 10.1021/ja909853x Supporting Info

Study of Ion-Paired Iridium Complexes (Soft Salts) and Their Application in Organic Light Emitting Diodes Chao Wu, Hsiao-Fan Chen, Ken-Tsung Wong and Mark E. Thompson pp 3133–3139 DOI: 10.1021/ja9097725 Supporting Info

Three-Level Topology Switching in a Molecular Mbius Band Marcin Stpie, Bartosz Szyszko and Lechosław Latos-Grayski pp 3140–3152 DOI: 10.1021/ja909913y Supporting Info

Base-Induced Mechanistic Variation in Palladium-Catalyzed Carbonylation of Aryl Iodides Yanhe Hu, Jing Liu, Zhixin L, Xiancai Luo, Heng Zhang, Yu Lan and Aiwen Lei pp 3153–3158 DOI: 10.1021/ja909962f Supporting Info

Adsorption of β-Lactoglobulin on Spherical Polyelectrolyte Brushes: Direct Proof of Counterion Release by Isothermal Titration Calorimetry Katja Henzler, Bjrn Haupt, Karlheinz Lauterbach, Alexander Wittemann, Oleg Borisov and Matthias Ballauff pp 3159–3163 DOI: 10.1021/ja909938c Supporting Info

Comparative Analysis of Small Molecules and Histone Substrate Analogues as LSD1 Lysine Demethylase Inhibitors Jeffrey C. Culhane, Dongqing Wang, Paul M. Yen and Philip A. Cole pp 3164–3176 DOI: 10.1021/ja909996p

Role of Au−C Interactions on the Catalytic Activity of Au Nanoparticles Supported on TiC(001) toward Molecular Oxygen Dissociation Jos A. Rodrguez, Leticia Feria, Tomas Jirsak, Yoshiro Takahashi, Kenichi Nakamura and Francesc Illas pp 3177–3186 DOI: 10.1021/ja910146g

Identification of Hydroxyl Protons, Determination of Their Exchange Dynamics, and Characterization of Hydrogen Bonding in a Microcrystallin Protein Vipin Agarwal, Rasmus Linser, Uwe Fink, Katja Faelber and Bernd Reif pp 3187–3195 DOI: 10.1021/ja910167q Supporting Info

Side-Chain χ1 Conformations in Urea-Denatured Ubiquitin and Protein G from 3J Coupling Constants and Residual Dipolar Couplings Navratna Vajpai, Martin Gentner, Jie-rong Huang, Martin Blackledge and Stephan Grzesiek pp 3196–3203 DOI: 10.1021/ja910331t Supporting Info

Large Scale Crystallinity in Kinetically Stable Polythiophene-Based Langmuir−Blodgett Films Jusroop S. Mattu and Gary W. Leach pp 3204–3210 DOI: 10.1021/ja910390g Supporting Info

Study of On-Resin Convergent Synthesis of N-Linked Glycopeptides Containing a Large High Mannose N-Linked Oligosaccharide Rui Chen and Thomas J. Tolbert pp 3211–3216 DOI: 10.1021/ja9104073 Supporting Info

Self-Assembling Multidomain Peptide Hydrogels: Designed Susceptibility to Enzymatic Cleavage Allows Enhanced Cell Migration and Spreading Kerstin M. Galler, Lorenzo Aulisa, Katherine R. Regan, Rena N. D’Souza and Jeffrey D. Hartgerink pp 3217–3223 DOI: 10.1021/ja910481t Supporting Info

Diverted Total Synthesis Leads to the Generation of Promising Cell-Migration Inhibitors for Treatment of Tumor Metastasis: In vivo and Mechanistic Studies on the Migrastatin Core Ether Analog Thordur Oskarsson, Pavel Nagorny, Isaac J. Krauss, Lucy Perez, Mihirbaran Mandal, Guangli Yang, Ouathek Ouerfelli, Danhua Xiao, Malcolm A. S. Moore, Joan Massagu and Samuel J. Danishefsky pp 3224–3228 DOI: 10.1021/ja9101503 Supporting Info

The Nature of the Hydrogen Bond: Outline of a Comprehensive Hydrogen Bond Theory J. J. Dannenberg p 3229 DOI: 10.1021/ja100200z

Comprehensive Organic Name Reactions and Reagents, Volume 1−3 Dionicio Siegel pp 3229–3230 DOI: 10.1021/ja100316g

Wiley Guide to Chemical Incompatibilities, 3rd ed. p 3230 DOI: 10.1021/ja100892b

Fluorinated Heterocyclic Compounds: Synthesis, Chemistry, and Applications Darryl DesMarteau p 3230 DOI: 10.1021/ja100496w

Issue 10

Molecular Mechanism of Long-Range Diffusion in Phospholipid Membranes Studied by Quasielastic Neutron Scattering Sebastian Busch, Christoph Smuda, Luis Carlos Pardo and Tobias Unruh pp 3232–3233 DOI: 10.1021/ja907581s Supporting Info

Synthesis and Colloidal Polymerization of Ferromagnetic Au−Co Nanoparticles into Au−Co3O4 Nanowires Bo Yun Kim, In-Bo Shim, Zeynep O. Araci, S. Scott Saavedra, Oliver L.A. Monti, Neal R. Armstrong, Rabindra Sahoo, Divesh N. Srivastava and Jeffrey Pyun pp 3234–3235 DOI: 10.1021/ja908481z Supporting Info

Electroactuation of Alkoxysilane-Functionalized Polyferrocenylsilane Microfibers Jeffrey J. McDowell, Nicole S. Zacharia, Danny Puzzo, Ian Manners and Geoffrey A. Ozin pp 3236–3237 DOI: 10.1021/ja9089236 Supporting Info

Small Molecule Colorimetric Probes for Specific Detection of Human Arylamine N-Acetyltransferase 1, a Potential Breast Cancer Biomarker Nicola Laurieri, Matthew H. J. Crawford, Akane Kawamura, Isaac M. Westwood, James Robinson, Ai M. Fletcher, Stephen G. Davies, Edith Sim and Angela J. Russell pp 3238–3239 DOI: 10.1021/ja909165u Supporting Info

Octafluorocalix[4]pyrrole: A Chloride/Bicarbonate Antiport Agent Philip A. Gale, Christine C. Tong, Cally J. E. Haynes, Olubukunola Adeosun, Dustin E. Gross, Elizabeth Karnas, Elaine M. Sedenberg, Roberto Quesada and Jonathan L. Sessler pp 3240–3241 DOI: 10.1021/ja9092693 Supporting Info

Selective Assembly of a High Stability AAB Collagen Heterotrimer Lesley E. Russell, Jorge A. Fallas and Jeffrey D. Hartgerink pp 3242–3243 DOI: 10.1021/ja909720g Supporting Info

Catalytic Carbon−Carbon Bond-Forming Reactions of Aminoalkane Derivatives with Imines Yi-Jing Chen, Kazutaka Seki, Yasuhiro Yamashita and Sh Kobayashi pp 3244–3245 DOI: 10.1021/ja909909q Supporting Info

Radical Cation of Helical, Cross-Conjugated β-Oligothiophene Jerzy K. Zak, Makoto Miyasaka, Suchada Rajca, Mieczyslaw Lapkowski and Andrzej Rajca pp 3246–3247 DOI: 10.1021/ja910076n Supporting Info

Gold Nanoparticle Self-Similar Chain Structure Organized by DNA Origami Baoquan Ding, Zhengtao Deng, Hao Yan, Stefano Cabrini, Ronald N. Zuckermann and Jeffrey Bokor pp 3248–3249 DOI: 10.1021/ja9101198 Supporting Info

Uranium−Nitrogen Multiple Bonding: Isostructural Anionic, Neutral, and Cationic Uranium Nitride Complexes Featuring a Linear U═N═U Core Alexander R. Fox, Polly L. Arnold and Christopher C. Cummins pp 3250–3251 DOI: 10.1021/ja910364u Supporting Info

Tailoring the Pore Alignment for Rapid Ion Transport in Microporous Carbons Adam Kajdos, Alexander Kvit, Frank Jones, Jacek Jagiello and Gleb Yushin pp 3252–3253 DOI: 10.1021/ja910307x Supporting Info

DNA (6-4) Photolyases Reduce Dewar Isomers for Isomerization into (6-4) Lesions Andreas F. Glas, Emine Kaya, Sabine Schneider, Korbinian Heil, Danila Fazio, Melanie J. Maul and Thomas Carell pp 3254–3255 DOI: 10.1021/ja910917f Supporting Info

Mechanical Reconfiguration of Stereoisomers Kelly M. Wiggins, Todd W. Hudnall, Qilong Shen, Matthew J. Kryger, Jeffrey S. Moore and Christopher W. Bielawski pp 3256–3257 DOI: 10.1021/ja910716s Supporting Info

Alkynes as Equivalents of α-Diazo Ketones in Generating α-Oxo Metal Carbenes: A Gold-Catalyzed Expedient Synthesis of Dihydrofuran-3-ones Longwu Ye, Li Cui, Guozhu Zhang and Liming Zhang pp 3258–3259 DOI: 10.1021/ja100041e Supporting Info

Low-Temperature Rapid Synthesis and Superconductivity of Fe-Based Oxypnictide Superconductors Ai-Hua Fang, Fu-Qiang Huang, Xiao-Ming Xie and Mian-Heng Jiang pp 3260–3261 DOI: 10.1021/ja100055k Supporting Info

Chiral Silver Amide-Catalyzed Enantioselective [3 + 2] Cycloaddition of α-Aminophosphonates with Olefins Yasuhiro Yamashita, Xun-Xiang Guo, Ryuta Takashita and Sh Kobayashi pp 3262–3263 DOI: 10.1021/ja100101n Supporting Info

Activity-Based Probes That Target Functional Subclasses of Phospholipases in Proteomes Sarah E. Tully and Benjamin F. Cravatt pp 3264–3265 DOI: 10.1021/ja1000505 Supporting Info

Superelectrophiles and the Effects of Trifluoromethyl Substituents Matthew J. O’Connor, Kenneth N. Boblak, Michael J. Topinka, Patrick J. Kindelin, Jason M. Briski, Chong Zheng and Douglas A. Klumpp pp 3266–3267 DOI: 10.1021/ja1001482 Supporting Info

Enantioselective Ring Opening of Epoxides by Fluoride Anion Promoted by a Cooperative Dual-Catalyst System Julia A. Kalow and Abigail G. Doyle pp 3268–3269 DOI: 10.1021/ja100161d Supporting Info

Nanocrystal Growth on Graphene with Various Degrees of Oxidation Hailiang Wang, Joshua Tucker Robinson, Georgi Diankov and Hongjie Dai pp 3270–3271 DOI: 10.1021/ja100329d Supporting Info

Enantioselective Synthesis of Angularly Substituted 1-Azabicyclic Ring Systems: Dynamic Kinetic Resolution Using Aza-Cope Rearrangements Tatsuya Ito, Larry E. Overman and Jocelyn Wang pp 3272–3273 DOI: 10.1021/ja100607z Supporting Info

Actuator Prototype: Capture and Release of a Self-Entangled [1]Rotaxane Zheng Xue and Michael F. Mayer pp 3274–3276 DOI: 10.1021/ja9077655 Supporting Info

Structure and Absolute Configuration of Karlotoxin-2, an Ichthyotoxin from the Marine Dinoflagellate Karlodinium veneficum Jiangnan Peng, Allen R. Place, Wesley Yoshida, Clemens Anklin and Mark T. Hamann pp 3277–3279 DOI: 10.1021/ja9091853 Supporting Info

Drastic Structural Transformation of Cadmium Chalcogenide Nanoparticles Using Chloride Ions and Surfactants Masaki Saruyama, Masayuki Kanehara and Toshiharu Teranishi pp 3280–3282 DOI: 10.1021/ja9095285 Supporting Info

Assembly of Supertetrahedral T5 Copper−Indium Sulfide Clusters into a Super-Supertetrahedron of Infinite Order Le Wang, Tao Wu, Fan Zuo, Xiang Zhao, Xianhui Bu, Jianzhong Wu and Pingyun Feng pp 3283–3285 DOI: 10.1021/ja9100672 Supporting Info

Anisotropic Strain-Induced Curvature in Type-II CdSe/CdTe Nanorod Heterostructures Hunter McDaniel, Jian-Min Zuo and Moonsub Shim pp 3286–3288 DOI: 10.1021/ja910233a Supporting Info

Hydrogen Storage by Boron−Nitrogen Heterocycles: A Simple Route for Spent Fuel Regeneration Patrick G. Campbell, Lev N. Zakharov, Daniel J. Grant, David A. Dixon and Shih-Yuan Liu pp 3289–3291 DOI: 10.1021/ja9106622 Supporting Info

Shape-Directed Assembly of a “Macromolecular Barb” into Nanofibers: Stereospecific Cyclopolymerization of Isopropylidene Diallylmalonate Yasunao Miyamura, Kazushi Kinbara, Yohei Yamamoto, Vakayil K. Praveen, Kenichi Kato, Masaki Takata, Atsushi Takano, Yushu Matsushita, Eunji Lee, Myongsoo Lee and Takuzo Aida pp 3292–3294 DOI: 10.1021/ja910901e Supporting Info

Asymmetric Hydrovinylation of Unactivated Linear 1,3-Dienes Rakesh K. Sharma and T. V. RajanBabu pp 3295–3297 DOI: 10.1021/ja1004703 Supporting Info

An Organocatalytic Asymmetric Chlorolactonization Daniel C. Whitehead, Roozbeh Yousefi, Arvind Jaganathan and Babak Borhan pp 3298–3300 DOI: 10.1021/ja100502f Supporting Info

Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex Alexander J. M. Miller, Jay A. Labinger and John E. Bercaw pp 3301–3303 DOI: 10.1021/ja100574n Supporting Info

Probing Substituent Effects in Aryl−Aryl Interactions Using Stereoselective Diels−Alder Cycloadditions Steven E. Wheeler, Anne J. McNeil, Peter Mller, Timothy M. Swager and K. N. Houk pp 3304–3311 DOI: 10.1021/ja903653j Supporting Info

Polarizable Water Molecules in Ligand−Macromolecule Recognition. Impact on the Relative Affinities of Competing Pyrrolopyrimidine Inhibitors for FAK Kinase Benoit de Courcy, Jean-Philip Piquemal, Christiane Garbay and Nohad Gresh pp 3312–3320 DOI: 10.1021/ja9059156 Supporting Info

Crystal Structures and Properties of Large Protonated Water Clusters Encapsulated by Metal−Organic Frameworks Chunying Duan, Meilin Wei, Dong Guo, Cheng He and Qingjin Meng pp 3321–3330 DOI: 10.1021/ja907023c Supporting Info

Structure-Based Calculations of Optical Spectra of Photosystem I Suggest an Asymmetric Light-Harvesting Process Julian Adolphs, Frank Mh, Mohamed El-Amine Madjet, Marcel Schmidt am Busch and Thomas Renger pp 3331–3343 DOI: 10.1021/ja9072222 Supporting Info

Size- and Site-Dependent Reconstruction in CdSe QDs Evidenced by 77Se{1H} CP-MAS NMR Spectroscopy Derek D. Lovingood, Randall Achey, Anant K. Paravastu and Geoffrey F. Strouse pp 3344–3354 DOI: 10.1021/ja907511r Supporting Info

Sequence-Specific Ni(II)-Dependent Peptide Bond Hydrolysis for Protein Engineering. Combinatorial Library Determination of Optimal Sequences Artur Krel, Edyta Kopera, Anna Maria Protas, Jarosław Poznaski, Aleksandra Wysłouch-Cieszyska and Wojciech Bal pp 3355–3366 DOI: 10.1021/ja907567r

Synthesis and Structural Determination of Multidentate 2,3-Dithiol-Stabilized Au Clusters Zhenghua Tang, Bin Xu, Baohua Wu, Markus W. Germann and Gangli Wang pp 3367–3374 DOI: 10.1021/ja9076149 Supporting Info

Tuning the Charge-Transport Parameters of Perylene Diimide Single Crystals via End and/or Core Functionalization: A Density Functional Theory Investigation M. Carmen Ruiz Delgado, Eung-Gun Kim, Demtrio A. da Silva Filho and Jean-Luc Bredas pp 3375–3387 DOI: 10.1021/ja908173x Supporting Info

Structural Characterization of Formaldehyde-Induced Cross-Links Between Amino Acids and Deoxynucleosides and Their Oligomers Kun Lu, Wenjie Ye, Li Zhou, Leonard B. Collins, Xian Chen, Avram Gold, Louise M Ball and James A. Swenberg pp 3388–3399 DOI: 10.1021/ja908282f Supporting Info

Tunable High Performance Cross-Linked Alkaline Anion Exchange Membranes for Fuel Cell Applications Nicholas J. Robertson, Henry A. Kostalik, IV, Timothy J. Clark, Paul F. Mutolo, Hctor D. Abrua and Geoffrey W. Coates pp 3400–3404 DOI: 10.1021/ja908638d Supporting Info

Synthesis of a Molecular Charm Bracelet via Click Cyclization and Olefin Metathesis Clipping Paul G. Clark, Erin N. Guidry, Wing Yan Chan, Wayne E. Steinmetz and Robert H. Grubbs pp 3405–3412 DOI: 10.1021/ja9090337 Supporting Info

Reaction Pathways and Possible Path Bifurcation for the Schmidt Reaction Tetsuji Katori, Shuhei Itoh, Makoto Sato and Hiroshi Yamataka pp 3413–3422 DOI: 10.1021/ja908899u Supporting Info

Enhanced Cell Surface Polymer Grafting in Concentrated and Nonreactive Aqueous Polymer Solutions Nicholas A. A. Rossi, Iren Constantinescu, Donald E. Brooks, Mark D. Scott and Jayachandran N. Kizhakkedathu pp 3423–3430 DOI: 10.1021/ja909174x Supporting Info

Interpretation of the Ultrafast Photoinduced Processes in Pentacene Thin Films Thomas S. Kuhlman, Jacob Kongsted, Kurt V. Mikkelsen, Klaus B. Møller and Theis I. Sølling pp 3431–3439 DOI: 10.1021/ja909166s Supporting Info

Clar’s Theory, π-Electron Distribution, and Geometry of Graphene Nanoribbons Tobias Wassmann, Ari P. Seitsonen, A. Marco Saitta, Michele Lazzeri and Francesco Mauri pp 3440–3451 DOI: 10.1021/ja909234y Supporting Info

Mechanism and Kinetics of Peptide Partitioning into Membranes from All-Atom Simulations of Thermostable Peptides Martin B. Ulmschneider, Jacques P. F. Doux, J. Antoinette Killian, Jeremy C. Smith and Jakob P. Ulmschneider pp 3452–3460 DOI: 10.1021/ja909347x

In Situ Transformation of TON Silica Zeolite into the Less Dense ITW: Structure-Direction Overcoming Framework Instability in the Synthesis of SiO2 Zeolites Claudio M. Zicovich-Wilson, Felipe Gndara, Angeles Monge and Miguel A. Camblor pp 3461–3471 DOI: 10.1021/ja9094318 Supporting Info

Probing the Solvent Shell with 195Pt Chemical Shifts: Density Functional Theory Molecular Dynamics Study of PtII and PtIV Anionic Complexes in Aqueous Solution Lionel A. Truflandier and Jochen Autschbach pp 3472–3483 DOI: 10.1021/ja9096863 Supporting Info

Soluble Semiconductors AAsSe2 (A = Li, Na) with a Direct-Band-Gap and Strong Second Harmonic Generation: A Combined Experimental and Theoretical Study Tarun K. Bera, Joon I. Jang, Jung-Hwan Song, Christos D. Malliakas, Arthur J. Freeman, John B. Ketterson and Mercouri G. Kanatzidis pp 3484–3495 DOI: 10.1021/ja9094846 Supporting Info

Combining Very Large Quadratic and Cubic Nonlinear Optical Responses in Extended, Tris-Chelate Metallochromophores with Six π-Conjugated Pyridinium Substituents Benjamin J. Coe, John Fielden, Simon P. Foxon, Bruce S. Brunschwig, Inge Asselberghs, Koen Clays, Anna Samoc and Marek Samoc pp 3496–3513 DOI: 10.1021/ja910538s Supporting Info

Solving the α-Conotoxin Folding Problem: Efficient Selenium-Directed On-Resin Generation of More Potent and Stable Nicotinic Acetylcholine Receptor Antagonists Markus Muttenthaler, Simon T. Nevin, Anton A. Grishin, Shyuan. T. Ngo, Peng T. Choy, Norelle L. Daly, Shu-Hong Hu, Christopher J. Armishaw, Ching-I. A. Wang, Richard J. Lewis, Jennifer L. Martin, Peter G. Noakes, David J. Craik, David J. Adams and Paul F. Alewood pp 3514–3522 DOI: 10.1021/ja910602h Supporting Info

Synthetic and Mechanistic Studies on Pd(0)-Catalyzed Diamination of Conjugated Dienes Baoguo Zhao, Haifeng Du, Sunliang Cui and Yian Shi pp 3523–3532 DOI: 10.1021/ja909459h Supporting Info

A Rare Example of a Krypton Difluoride Coordination Compound: [BrOF2][AsF6]·2KrF2 David S. Brock, Jonathan J. Casalis de Pury, Hlne P. A. Mercier, Gary J. Schrobilgen and Bernard Silvi pp 3533–3542 DOI: 10.1021/ja9098559 Supporting Info

Hydroalkylation of Alkynyl Ethers via a Gold(I)-Catalyzed 1,5-Hydride Shift/Cyclization Sequence Igor Dias Jurberg, Yann Odabachian and Fabien Gagosz pp 3543–3552 DOI: 10.1021/ja9100134 Supporting Info

Multiple Bistability and Tristability with Dual Spin-State Conversions in [Fe(dpp)2][Ni(mnt)2]2·MeNO2 Masayuki Nihei, Hirotaka Tahira, Nobukazu Takahashi, Yusuke Otake, Yasuhisa Yamamura, Kazuya Saito and Hiroki Oshio pp 3553–3560 DOI: 10.1021/ja910122r Supporting Info

Demonstration of Prominent Cu(II)-Promoted Leaving Group Stabilization of the Cleavage of a Homologous Set of Phosphate Mono-, Di-, and Triesters in Methanol C. Tony Liu, Alexei A. Neverov, Christopher I. Maxwell and R. Stan Brown pp 3561–3573 DOI: 10.1021/ja910111q Supporting Info

Diastereoisomerically Pure Fulleropyrrolidines as Chiral Platforms for the Design of Optically Active Liquid Crystals Stphane Campidelli, Philippe Bourgun, Boris Guintchin, Julien Furrer, Helen Stoeckli-Evans, Isabel M. Saez, John W. Goodby and Robert Deschenaux pp 3574–3581 DOI: 10.1021/ja910128e Supporting Info

CO2 Binding by Dynamic Combinatorial Chemistry: An Environmental Selection Julien Leclaire, Guillaume Husson, Nathalie Devaux, Vincent Delorme, Laurence Charles, Fabio Ziarelli, Perrine Desbois, Alexandra Chaumonnot, Marc Jacquin, Frdric Fotiadu and Grard Buono pp 3582–3593 DOI: 10.1021/ja909975q Supporting Info

Toward Structural Dynamics: Protein Motions Viewed by Chemical Shift Modulations and Direct Detection of C′N Multiple-Quantum Relaxation Mirko Mori, Fatiha Kateb, Geoffrey Bodenhausen, Mario Piccioli and Daniel Abergel pp 3594–3600 DOI: 10.1021/ja9103556 Supporting Info

Molecular Recognitive Photocatalysis Driven by the Selective Adsorption on Layered Titanates Yusuke Ide, Yuri Nakasato and Makoto Ogawa pp 3601–3604 DOI: 10.1021/ja910591v

In Situ Single-Crystal Diffraction Studies of the Structural Transition of Metal−Organic Framework Copper 5-Sulfoisophthalate, Cu-SIP-3 Phoebe K. Allan, Bo Xiao, Simon J. Teat, Jason W. Knight and Russell E. Morris pp 3605–3611 DOI: 10.1021/ja910600b Supporting Info

On the Stereochemical Course of Palladium-Catalyzed Cross-Coupling of Allylic Silanolate Salts with Aromatic Bromides Scott E. Denmark and Nathan S. Werner pp 3612–3620 DOI: 10.1021/ja910804u Supporting Info

Silver Ion Incorporation and Nanoparticle Formation inside the Cavity of Pyrococcus furiosus Ferritin: Structural and Size-Distribution Analyses Oksana Kasyutich, Andrea Ilari, Annarita Fiorillo, Dragomir Tatchev, Armin Hoell and Pierpaolo Ceci pp 3621–3627 DOI: 10.1021/ja910918b Supporting Info

Measuring the Energetics of Membrane Protein Dimerization in Mammalian Membranes Lirong Chen, Lawrence Novicky, Mikhail Merzlyakov, Tihomir Hristov and Kalina Hristova pp 3628–3635 DOI: 10.1021/ja910692u Supporting Info

Why Structurally Different Cyclic Peptides Can Be Glycomimetics of the HNK-1 Carbohydrate Antigen [] Anirban Bhunia, Subramanian Vivekanandan, Thomas Eckert, Monika Burg-Roderfeld, Rainer Wechselberger, Julija Romanuka, Dirk Bchle, Andrei V. Kornilov, Claus-Wilhelm von der Lieth, Jess Jimnez-Barbero, Nikolay E. Nifantiev, Melitta Schachner, Norbert Sewald, Thomas Ltteke, Hans-Joachim Gabius and Hans-Christian Siebert p 3636 DOI: 10.1021/ja100344v

Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides with Alkyl Halides Daniel A. Everson, Ruja Shrestha and Daniel J. Weix p 3636 DOI: 10.1021/ja100564b

From Enzyme Models to Model Enzymes Ralph M. Pollack p 3637 DOI: 10.1021/ja100854r

Optical Properties and Spectroscopy of Nanomaterials Andre J. Gesquiere pp 3637–3638 DOI: 10.1021/ja101350v

Issue 11

Bioorthogonal Chemical Reporters for Monitoring Protein Acetylation Yu-Ying Yang, Janice M. Ascano and Howard C. Hang pp 3640–3641 DOI: 10.1021/ja908871t Supporting Info

Enzyme-Catalyzed Transfer of a Ketone Group from an S-Adenosylmethionine Analogue: A Tool for the Functional Analysis of Methyltransferases Bobby W.K. Lee, He G. Sun, Tianzhu Zang, Byung Ju Kim, Joshua F. Alfaro and Zhaohui Sunny Zhou pp 3642–3643 DOI: 10.1021/ja908995p Supporting Info

Measuring Ensemble-Averaged Surface-Enhanced Raman Scattering in the Hotspots of Colloidal Nanoparticle Dimers and Trimers Gang Chen, Yong Wang, Miaoxin Yang, Jun Xu, Sook Jin Goh, Ming Pan and Hongyu Chen pp 3644–3645 DOI: 10.1021/ja9090885 Supporting Info

The Unusual Electronic Structure of Dinitrosyl Iron Complexes Shengfa Ye and Frank Neese pp 3646–3647 DOI: 10.1021/ja9091616 Supporting Info

Pd(II)-Catalyzed ortho-Trifluoromethylation of Arenes Using TFA as a Promoter Xisheng Wang, Larry Truesdale and Jin-Quan Yu pp 3648–3649 DOI: 10.1021/ja909522s Supporting Info

Palladium-Catalyzed Benzylic Addition of 2-Methyl Azaarenes to N-Sulfonyl Aldimines via C−H Bond Activation Bo Qian, Shengmei Guo, Jianping Shao, Qiming Zhu, Lei Yang, Chungu Xia and Hanmin Huang pp 3650–3651 DOI: 10.1021/ja910104n Supporting Info

Asymmetric Diels−Alder Reactions of Unsaturated β-Ketoesters Catalyzed by Chiral Ruthenium PNNP Complexes Christoph Schotes and Antonio Mezzetti pp 3652–3653 DOI: 10.1021/ja910039e Supporting Info

Modular Synthesis of Biodegradable Diblock Copolymers for Designing Functional Polymersomes Joshua S. Katz, Sheng Zhong, Brendon G. Ricart, Darrin J. Pochan, Daniel A. Hammer and Jason A. Burdick pp 3654–3655 DOI: 10.1021/ja910606y Supporting Info

MnII-based MIL-53 Analogues: Synthesis Using Neutral Bridging μ2-Ligands and Application in Liquid-Phase Adsorption and Separation of C6−C8 Aromatics Guohai Xu, Xiaoguang Zhang, Peng Guo, Chengling Pan, Hongjie Zhang and Cheng Wang pp 3656–3657 DOI: 10.1021/ja910818a Supporting Info

β-Peptide Bundles with Fluorous Cores Matthew A. Molski, Jessica L. Goodman, Cody J. Craig, He Meng, Krishna Kumar and Alanna Schepartz pp 3658–3659 DOI: 10.1021/ja910903c Supporting Info

Fluorescent Indicator Displacement Assay for Ligand−RNA Interactions Jinhua Zhang, Shiori Umemoto and Kazuhiko Nakatani pp 3660–3661 DOI: 10.1021/ja100089u Supporting Info

Challenging the Limit: NMR Assignment of a 31 kDa Helical Membrane Protein Chengdong Huang and Smita Mohanty pp 3662–3663 DOI: 10.1021/ja100078z Supporting Info

Enantioselective Bromolactonization of Conjugated (Z)-Enynes Wei Zhang, Suqing Zheng, Na Liu, Jenny B. Werness, Ilia A. Guzei and Weiping Tang pp 3664–3665 DOI: 10.1021/ja100173w Supporting Info

Direct Catalytic Asymmetric Vinylogous Mannich-Type and Michael Reactions of an α,β-Unsaturated γ-Butyrolactam under Dinuclear Nickel Catalysis Nicholas E. Shepherd, Hirooki Tanabe, Yingjie Xu, Shigeki Matsunaga and Masakatsu Shibasaki pp 3666–3667 DOI: 10.1021/ja1002636 Supporting Info

Direct Strand Scission from a Nucleobase Radical in RNA Aaron C. Jacobs, Marino J. E. Resendiz and Marc M. Greenberg pp 3668–3669 DOI: 10.1021/ja100281x Supporting Info

Parallel-Stacked Aromatic Hosts for Orienting Small Molecules in a Magnetic Field: Induced Residual Dipolar Coupling by Encapsulation Sota Sato, Osamu Morohara, Daishi Fujita, Yoshiki Yamaguchi, Koichi Kato and Makoto Fujita pp 3670–3671 DOI: 10.1021/ja100325b Supporting Info

Formation of an End-On Ferric Peroxo Intermediate upon One-Electron Reduction of a Ferric Superoxo Heme Jin-Gang Liu, Yuta Shimizu, Takehiro Ohta and Yoshinori Naruta pp 3672–3673 DOI: 10.1021/ja1001955 Supporting Info

A Highly Efficient Palladium/Copper Cocatalytic System for Direct Arylation of Heteroarenes: An Unexpected Effect of Cu(Xantphos)I Jinkun Huang, Johann Chan, Ying Chen, Christopher J. Borths, Kyle D. Baucom, Robert D. Larsen and Margaret M. Faul pp 3674–3675 DOI: 10.1021/ja100354j Supporting Info

Palladium-Catalyzed Amination of Aromatic C−H Bonds with Oxime Esters Yichen Tan and John F. Hartwig pp 3676–3677 DOI: 10.1021/ja100676r Supporting Info

Following the Kinetics of a Chemical Reaction in Ultrathin Supported Polymer Films by Reliable Mass Density Determination with X-ray Reflectivity Eero Kontturi and Aapo Lankinen pp 3678–3679 DOI: 10.1021/ja100669w Supporting Info

Pd(II)-Catalyzed Olefination of sp3 C−H Bonds Masayuki Wasa, Keary M. Engle and Jin-Quan Yu pp 3680–3681 DOI: 10.1021/ja1010866 Supporting Info

Organic Radicals As Spin Filters Carmen Herrmann, Gemma C. Solomon and Mark A. Ratner pp 3682–3684 DOI: 10.1021/ja910483b Supporting Info

Asymmetric Total Synthesis of Vindoline Daisuke Kato, Yoshikazu Sasaki and Dale L. Boger pp 3685–3687 DOI: 10.1021/ja910695e Supporting Info

Rapid Cu-Free Click Chemistry with Readily Synthesized Biarylazacyclooctynones John C. Jewett, Ellen M. Sletten and Carolyn R. Bertozzi pp 3688–3690 DOI: 10.1021/ja100014q Supporting Info

Phosphinidene Complexes of Scandium: Powerful PAr Group-Transfer Vehicles to Organic and Inorganic Substrates Benjamin F. Wicker, Jennifer Scott, Jos G. Andino, Xinfeng Gao, Hyunsoo Park, Maren Pink and Daniel J. Mindiola pp 3691–3693 DOI: 10.1021/ja100214e Supporting Info

Superoxide Ions Entrapped in Water Cages of Ionic Clathrate Hydrates Minjun Cha, Kyuchul Shin, Minchul Kwon, Dong-Yeun Koh, Boram Sung and Huen Lee pp 3694–3696 DOI: 10.1021/ja1004762 Supporting Info

Core-Expanded Naphthalene Diimides Fused with 2-(1,3-Dithiol-2-Ylidene)Malonitrile Groups for High-Performance, Ambient-Stable, Solution-Processed n-Channel Organic Thin Film Transistors Xike Gao, Chong-an Di, Yunbin Hu, Xiaodi Yang, Hongyu Fan, Feng Zhang, Yunqi Liu, Hongxiang Li and Daoben Zhu pp 3697–3699 DOI: 10.1021/ja910667y Supporting Info

Polymer-Induced Self-Assembly of Small Organic Molecules into Ultralong Microbelts with Electronic Conductivity Minghua Huang, Uwe Schilde, Michael Kumke, Markus Antonietti and Helmut Clfen pp 3700–3707 DOI: 10.1021/ja906667x Supporting Info

Synthesis and Photophysical Properties of Stilbeneoctasilsesquioxanes. Emission Behavior Coupled with Theoretical Modeling Studies Suggest a 3-D Excited State Involving the Silica Core R. M. Laine, S. Sulaiman, C. Brick, M. Roll, R. Tamaki, M. Z. Asuncion, M. Neurock, J.-S. Filhol, C.-Y. Lee, J. Zhang, T. Goodson, III, M. Ronchi, M. Pizzotti, S. C. Rand and Y. Li pp 3708–3722 DOI: 10.1021/ja9087709 Supporting Info

Fluoride Rearrangement Reactions of Polyphenyl- and Polyvinylsilsesquioxanes as a Facile Route to Mixed Functional Phenyl, Vinyl T10 and T12 Silsesquioxanes M. Z. Asuncion and R. M. Laine pp 3723–3736 DOI: 10.1021/ja9087743 Supporting Info

Just a Proton: Distinguishing the Two Electronic States of Five-Coordinate High-Spin Iron(II) Porphyrinates with Imidazole/ate Coordination Chuanjiang Hu, Corinne D. Sulok, Florian Paulat, Nicolai Lehnert, Anna I. Twigg, Michael P. Hendrich, Charles E. Schulz and W. Robert Scheidt pp 3737–3750 DOI: 10.1021/ja907584x Supporting Info

Layer-by-Layer Polymer Coating of Carbon Nanotubes: Tuning of Electrical Conductivity in Random Networks F. Rivadulla, C. Mateo-Mateo and M. A. Correa-Duarte pp 3751–3755 DOI: 10.1021/ja910572b

Effect of Hydrogen-Bond Strength on the Vibrational Relaxation of Interfacial Water Ali Eftekhari-Bafrooei and Eric Borguet pp 3756–3761 DOI: 10.1021/ja907745r

Self-Assembly of Linear−Dendritic Diblock Copolymers: From Nanofibers to Polymersomes Jess del Barrio, Luis Oriol, Carlos Snchez, Jos Luis Serrano, Aurlie Di Cicco, Patrick Keller and Min-Hui Li pp 3762–3769 DOI: 10.1021/ja9083946 Supporting Info

CopK from Cupriavidus metallidurans CH34 Binds Cu(I) in a Tetrathioether Site: Characterization by X-ray Absorption and NMR Spectroscopy Graldine Sarret, Adrien Favier, Jacques Covs, Jean-Louis Hazemann, Max Mergeay and Beate Bersch pp 3770–3777 DOI: 10.1021/ja9083896 Supporting Info

A Chiral Wedge Molecule Inhibits Telomerase Activity Ken-ichi Shinohara, Yuta Sannohe, Shuji Kaieda, Ken-ichi Tanaka, Hideji Osuga, Hidetoshi Tahara, Yan Xu, Takashi Kawase, Toshikazu Bando and Hiroshi Sugiyama pp 3778–3782 DOI: 10.1021/ja908897j Supporting Info

Crystal Transformation and Host Molecular Motions in CO2 Adsorption Process of a Metal Benzoate Pyrazine (MII = Rh, Cu) Satoshi Takamizawa, Ei-ichi Nataka, Takamasa Akatsuka, Ryosuke Miyake, Yoshiki Kakizaki, Hirotoshi Takeuchi, Goro Maruta and Sadamu Takeda pp 3783–3792 DOI: 10.1021/ja9091598 Supporting Info

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides Takeru Furuya, Diego Benitez, Ekaterina Tkatchouk, Alexandra E. Strom, Pingping Tang, William A. Goddard, III and Tobias Ritter pp 3793–3807 DOI: 10.1021/ja909371t Supporting Info

A Direct Comparison of Reactivity and Mechanism in the Gas Phase and in Solution John M. Garver, Yao-ren Fang, Nicole Eyet, Stephanie M. Villano, Veronica M. Bierbaum and Kenneth Charles Westaway pp 3808–3814 DOI: 10.1021/ja909399u Supporting Info

Total Synthesis of Echinopines A and B K. C. Nicolaou, Hanfeng Ding, Jean-Alexandre Richard and David Y.-K. Chen pp 3815–3818 DOI: 10.1021/ja9093988 Supporting Info

Expanding the Dipeptidyl Peptidase 4-Regulated Peptidome via an Optimized Peptidomics Platform Arthur D. Tinoco, Debarati M. Tagore and Alan Saghatelian pp 3819–3830 DOI: 10.1021/ja909524e Supporting Info

Homogeneous Catalytic Dehydrocoupling/Dehydrogenation of Amine−Borane Adducts by Early Transition Metal, Group 4 Metallocene Complexes Matthew E. Sloan, Anne Staubitz, Timothy J. Clark, Christopher A. Russell, Guy C. Lloyd-Jones and Ian Manners pp 3831–3841 DOI: 10.1021/ja909535a Supporting Info

Intermolecular Protein−RNA Interactions Revealed by 2D 31P−15N Magic Angle Spinning Solid-State NMR Spectroscopy Stefan Jehle, Melanie Falb, John P. Kirkpatrick, Hartmut Oschkinat, Barth-Jan van Rossum, Gerhard Althoff and Teresa Carlomagno pp 3842–3846 DOI: 10.1021/ja909723f Supporting Info

[2]Catenanes Decorated with Porphyrin and [60]Fullerene Groups: Design, Convergent Synthesis, and Photoinduced Processes Jackson D. Megiatto, Jr., David I. Schuster, Silke Abwandner, Gustavo de Miguel and Dirk M. Guldi pp 3847–3861 DOI: 10.1021/ja910149f

Base−Base Recognition of Nonionic Dinucleotide Analogues in an Apolar Environment Studied by Low-Temperature NMR Spectroscopy Zhou Xiao and Klaus Weisz pp 3862–3869 DOI: 10.1021/ja910220s Supporting Info

Carbamate Transport in Carbamoyl Phosphate Synthetase: A Theoretical and Experimental Investigation Liliya Lund, Yubo Fan, Qiang Shao, Yi Qin Gao and Frank M. Raushel pp 3870–3878 DOI: 10.1021/ja910441v Supporting Info

Redox-Active Ligands Facilitate Bimetallic O2 Homolysis at Five-Coordinate Oxorhenium(V) Centers Cameron A. Lippert, Stephen A. Arnstein, C. David Sherrill and Jake D. Soper pp 3879–3892 DOI: 10.1021/ja910500a Supporting Info

Capsule Formation, Carboxylate Exchange, and DFT Exploration of Cadmium Cluster Metallocavitands: Highly Dynamic Supramolecules Peter D. Frischmann, Glenn A. Facey, Phuong Y. Ghi, Amanda J. Gallant, David L. Bryce, Francesco Lelj and Mark J. MacLachlan pp 3893–3908 DOI: 10.1021/ja910419h Supporting Info

Synthesis of Monodisperse PbSe Nanorods: A Case for Oriented Attachment Weon-kyu Koh, Adam C. Bartnik, Frank W. Wise and Christopher B. Murray pp 3909–3913 DOI: 10.1021/ja9105682 Supporting Info

Physical Evidence for Substrate Binding in Preventing Cyclooxygenase Inactivation under Nitrative Stress Ruba S. Deeb, Cynthia Cheung, Tal Nuriel, Brian D. Lamon, Rita K. Upmacis, Steven S. Gross and David P. Hajjar pp 3914–3922 DOI: 10.1021/ja910578y Supporting Info

Strain-Promoted Alkyne Azide Cycloaddition for the Functionalization of Poly(amide)-Based Dendrons and Dendrimers Ctia Ornelas, Johannes Broichhagen and Marcus Weck pp 3923–3931 DOI: 10.1021/ja910581d Supporting Info

Outer Wall Selectively Oxidized, Water-Soluble Double-Walled Carbon Nanotubes Alexandra H. Brozena, Jessica Moskowitz, Beiyue Shao, Shunliu Deng, Hongwei Liao, Karen J. Gaskell and YuHuang Wang pp 3932–3938 DOI: 10.1021/ja910626u Supporting Info

Excimer Formation Dynamics of Intramolecular π-Stacked Perylenediimides Probed by Single-Molecule Fluorescence Spectroscopy Hyejin Yoo, Jaesung Yang, Andrew Yousef, Michael R. Wasielewski and Dongho Kim pp 3939–3944 DOI: 10.1021/ja910724x Supporting Info

Two-Component Dendritic Chain Reactions: Experiment and Theory Eran Sella, Ariel Lubelski, Joseph Klafter and Doron Shabat pp 3945–3952 DOI: 10.1021/ja910839n Supporting Info

RlmN and Cfr are Radical SAM Enzymes Involved in Methylation of Ribosomal RNA Feng Yan, Jacqueline M. LaMarre, Rene Rhrich, Jochen Wiesner, Hassan Jomaa, Alexander S. Mankin and Danica Galoni Fujimori pp 3953–3964 DOI: 10.1021/ja910850y Supporting Info

Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 Carbon−Hydrogen Bonds Dmitry Shabashov and Olafs Daugulis pp 3965–3972 DOI: 10.1021/ja910900p Supporting Info

A Proteome-Wide Perspective on Peroxisome Targeting Signal 1(PTS1)-Pex5p Affinities Debdip Ghosh and Jeremy M. Berg pp 3973–3979 DOI: 10.1021/ja9109049 Supporting Info

[ReCl4(CN)2]2−: A High Magnetic Anisotropy Building Unit Giving Rise to the Single-Chain Magnets (DMF)4MReCl4(CN)2 (M = Mn, Fe, Co, Ni) T. David Harris, Miriam V. Bennett, Rodolphe Clrac and Jeffrey R. Long pp 3980–3988 DOI: 10.1021/ja910963x Supporting Info

Phospholipid Encapsulated Semiconducting Polymer Nanoparticles: Their Use in Cell Imaging and Protein Attachment Philip Howes, Mark Green, James Levitt, Klaus Suhling and Mary Hughes pp 3989–3996 DOI: 10.1021/ja1002179

Computational Design and Elaboration of a de Novo Heterotetrameric α-Helical Protein That Selectively Binds an Emissive Abiological (Porphinato)zinc Chromophore H. Christopher Fry, Andreas Lehmann, Jeffery G. Saven, William F. DeGrado and Michael J. Therien pp 3997–4005 DOI: 10.1021/ja907407m Supporting Info

Fe L-Edge X-ray Absorption Spectroscopy Determination of Differential Orbital Covalency of Siderophore Model Compounds: Electronic Structure Contributions to High Stability Constants Rosalie K. Hocking, Serena DeBeer George, Kenneth N. Raymond, Keith O. Hodgson, Britt Hedman and Edward I. Solomon pp 4006–4015 DOI: 10.1021/ja9090098 Supporting Info

Oligonucleotide Duplexes and Multistrand Assemblies with 8-Aza-2′-deoxyisoguanosine: A Fluorescent isoGd Shape Mimic Expanding the Genetic Alphabet and Forming Ionophores Dawei Jiang and Frank Seela pp 4016–4024 DOI: 10.1021/ja910020n Supporting Info

Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent In Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry Martin Althaus, Adeem Mahmood, Jos Ramn Surez, Stephen P. Thomas and Varinder K. Aggarwal pp 4025–4028 DOI: 10.1021/ja910593w Supporting Info

Molecular Tweezer and Clip in Aqueous Solution: Unexpected Self-Assembly, Powerful Host−Guest Complex Formation, Quantum Chemical 1H NMR Shift Calculation Frank-Gerrit Klrner, Bjrn Kahlert, Anke Nellesen, Jan Zienau, Christian Ochsenfeld and Thomas Schrader p 4029 DOI: 10.1021/ja1008695

Molecular Networks Dmitrii F. Perepichka p 4030 DOI: 10.1021/ja100897n

Proteins: Energy, Heat, and Signal Flow Harry A. Stern p 4030 DOI: 10.1021/ja101022v

Issue 12

Selective Insertion of Oxygen and Selenium into an Electron-Precise Paramagnetic Selenium−Manganese Carbonyl Cluster [Se6Mn6(CO)18]4− Minghuey Shieh, Chia-Hua Ho, Wen-Shyan Sheu and Horng-Wen Chen pp 4032–4033 DOI: 10.1021/ja9091566 Supporting Info

Transparent and Flexible Field Electron Emitters Based on the Conical Nanocarbon Structures Pradip Ghosh, M. Zamri Yusop, Syunsaku Satoh, Munisamy Subramanian, Akari Hayashi, Yasuhiko Hayashi and Masaki Tanemura pp 4034–4035 DOI: 10.1021/ja909346e

Diastereo- and Enantioselective Conjugate Addition of α-Ketoesters to Nitroalkenes Catalyzed by a Chiral Ni(OAc)2 Complex under Mild Conditions Ayako Nakamura, Sylvain Lectard, Daisuke Hashizume, Yoshitaka Hamashima and Mikiko Sodeoka pp 4036–4037 DOI: 10.1021/ja909457b Supporting Info

Freezing of Dynamics of a Methyl Group in a Protein Hydrophobic Core at Cryogenic Temperatures by Deuteron NMR Spectroscopy Liliya Vugmeyster, Dmitry Ostrovsky, Joseph J. Ford and Andrew S. Lipton pp 4038–4039 DOI: 10.1021/ja909599k Supporting Info

Highly Resolved Spectra of Gas-Phase Gramicidin S: A Benchmark for Peptide Structure Calculations Natalia S. Nagornova, Thomas R. Rizzo and Oleg V. Boyarkin pp 4040–4041 DOI: 10.1021/ja910118j Supporting Info

A Magnetic Switch for Spin-Catalyzed Interconversion of Nuclear Spin Isomers Yongjun Li, Xuegong Lei, Steffen Jockusch, Judy Y.-C. Chen, Michael Frunzi, Jeremiah A. Johnson, Ronald G. Lawler, Yasujiro Murata, Michihisa Murata, Koichi Komatsu and Nicholas J. Turro pp 4042–4043 DOI: 10.1021/ja910282p Supporting Info

Nanoscale Homochiral C3-Symmetric Mixed-Valence Manganese Cluster Complexes with Both Ferromagnetic and Ferroelectric Properties Cai-Ming Liu, Ren-Gen Xiong, De-Qing Zhang and Dao-Ben Zhu pp 4044–4045 DOI: 10.1021/ja910310p Supporting Info

A Simple and Highly Sensitive Colorimetric Detection Method for Gaseous Formaldehyde Liang Feng, Christopher J. Musto and Kenneth S. Suslick pp 4046–4047 DOI: 10.1021/ja910366p Supporting Info

UV-Induced Grafting of Alkenes to Silicon Surfaces: Photoemission versus Excitons Xiaoyu Wang, Rose E. Ruther, Jeremy A. Streifer and Robert J. Hamers pp 4048–4049 DOI: 10.1021/ja910498z Supporting Info

Addition-Elimination Reactions across the M−C Bond of Metal N-Heterocyclic Carbenes Zo R. Turner, Ronan Bellabarba, Robert P. Tooze and Polly L. Arnold pp 4050–4051 DOI: 10.1021/ja910673q Supporting Info

Ester to Amide Switch Peptides Provide a Simple Method for Preparing Monomeric Islet Amyloid Polypeptide under Physiologically Relevant Conditions and Facilitate Investigations of Amyloid Formation Ping Cao and Daniel P. Raleigh pp 4052–4053 DOI: 10.1021/ja910763m Supporting Info

Enhancement of Incident Photon-to-Current Conversion Efficiency for Phthalocyanine-Sensitized Solar Cells by 3D Molecular Structuralization Shogo Mori, Morio Nagata, Yuki Nakahata, Kazumasa Yasuta, Ryota Goto, Mutsumi Kimura and Minoru Taya pp 4054–4055 DOI: 10.1021/ja9109677 Supporting Info

Desymmetrization of Cyclohexadienones via Brønsted Acid-Catalyzed Enantioselective Oxo-Michael Reaction Qing Gu, Zi-Qiang Rong, Chao Zheng and Shu-Li You pp 4056–4057 DOI: 10.1021/ja100207s Supporting Info

Persistent Photoinduced Magnetism in Heterostructures of Prussian Blue Analogues Daniel M. Pajerowski, Matthew J. Andrus, Justin E. Gardner, Elisabeth S. Knowles, Mark W. Meisel and Daniel R. Talham pp 4058–4059 DOI: 10.1021/ja100246n Supporting Info

Solution-Phase Synthesis of SnSe Nanocrystals for Use in Solar Cells Matthew A. Franzman, Cody W. Schlenker, Mark E. Thompson and Richard L. Brutchey pp 4060–4061 DOI: 10.1021/ja100249m Supporting Info

Dialkyl Chloronium Ions Evgenii S. Stoyanov, Irina V. Stoyanova, Fook S. Tham and Christopher A. Reed pp 4062–4063 DOI: 10.1021/ja100297b Supporting Info

Enhanced Stability of Gold Clusters Supported on Hydroxylated MgO(001) Surfaces Matthew A. Brown, Esther Carrasco, Martin Sterrer and Hans-Joachim Freund pp 4064–4065 DOI: 10.1021/ja100343m Supporting Info

Hydroformylation Reaction of Alkylidenecyclopropane Derivatives: A New Pathway for the Formation of Acyclic Aldehydes Containing Quaternary Stereogenic Carbons Samah Simaan and Ilan Marek pp 4066–4067 DOI: 10.1021/ja100544c Supporting Info

Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles Daniel W. Robbins, Timothy A. Boebel and John F. Hartwig pp 4068–4069 DOI: 10.1021/ja1006405 Supporting Info

Flow Induced Dispersion Analysis Quantifies Noncovalent Interactions in Nanoliter Samples Henrik Jensen and Jesper Østergaard pp 4070–4071 DOI: 10.1021/ja100484d Supporting Info

Silver-Catalyzed Enantioselective Carbon Dioxide Incorporation into Bispropargylic Alcohols Shunsuke Yoshida, Kosuke Fukui, Satoshi Kikuchi and Tohru Yamada pp 4072–4073 DOI: 10.1021/ja1007118 Supporting Info

Marked Alkyl- vs Alkenyl-Substitutent Effects on Squaraine Dye Solid-State Structure, Carrier Mobility, and Bulk-Heterojunction Solar Cell Efficiency Diego Bagnis, Luca Beverina, Hui Huang, Fabio Silvestri, Yan Yao, Henry Yan, Giorgio A. Pagani, Tobin J. Marks and Antonio Facchetti pp 4074–4075 DOI: 10.1021/ja100520q Supporting Info

Catalytic Enantioselective 1,3-Dipolar Cycloaddition of C,N-Cyclic Azomethine Imines with α,β-Unsaturated Aldehydes Takuya Hashimoto, Yuko Maeda, Masato Omote, Hiroki Nakatsu and Keiji Maruoka pp 4076–4077 DOI: 10.1021/ja100787a Supporting Info

Total Synthesis of (+)-Chaetocin and its Analogues: Their Histone Methyltransferase G9a Inhibitory Activity Eriko Iwasa, Yoshitaka Hamashima, Shinya Fujishiro, Eisuke Higuchi, Akihiro Ito, Minoru Yoshida and Mikiko Sodeoka pp 4078–4079 DOI: 10.1021/ja101280p Supporting Info

A Stable Lipid-Induced Aggregate of α-Synuclein Malte Drescher, Bart D. van Rooijen, Gertjan Veldhuis, Vinod Subramaniam and Martina Huber pp 4080–4082 DOI: 10.1021/ja909247j Supporting Info

Catalytic N−N Coupling of Aryl Azides To Yield Azoarenes via Trigonal Bipyramid Iron−Nitrene Intermediates Neal P. Mankad, Peter Mller and Jonas C. Peters pp 4083–4085 DOI: 10.1021/ja910224c Supporting Info

Genetically Encoded Photocontrol of Protein Localization in Mammalian Cells Arnaud Gautier, Duy P. Nguyen, Hrvoje Lusic, Wenlin An, Alexander Deiters and Jason W. Chin pp 4086–4088 DOI: 10.1021/ja910688s Supporting Info

Insights into Heterocyclization from Two Highly Similar Enzymes John A. McIntosh, Mohamed S. Donia and Eric W. Schmidt pp 4089–4091 DOI: 10.1021/ja9107116 Supporting Info

Metal−Organic Polyhedral Frameworks: High H2 Adsorption Capacities and Neutron Powder Diffraction Studies Yong Yan, Irvin Telepeni, Sihai Yang, Xiang Lin, Winfried Kockelmann, Anne Dailly, Alexander J. Blake, William Lewis, Gavin S. Walker, David R. Allan, Sarah A. Barnett, Neil R. Champness and Martin Schrder pp 4092–4094 DOI: 10.1021/ja1001407 Supporting Info

Energy Crosstalk between DNA Lesions: Implications for Allosteric Coupling of DNA Repair and Triplet Repeat Expansion Pathways Jens Vlker, G. Eric Plum, Horst H. Klump and Kenneth J. Breslauer pp 4095–4097 DOI: 10.1021/ja1002857 Supporting Info

Total Synthesis of Cyclosporine: Access to N-Methylated Peptides via Isonitrile Coupling Reactions Xiangyang Wu, Jennifer L. Stockdill, Ping Wang and Samuel J. Danishefsky pp 4098–4100 DOI: 10.1021/ja100517v Supporting Info

Palladium-Catalyzed Aerobic Oxidative Cross-Coupling Reactions of Terminal Alkynes with Alkylzinc Reagents Mao Chen, Xiaolong Zheng, Wenqing Li, Jun He and Aiwen Lei pp 4101–4103 DOI: 10.1021/ja100630p Supporting Info

Mild Two-Step Process for the Transition-Metal-Free Synthesis of Carbon−Carbon Bonds from Allylic Alcohols/Ethers and Grignard Reagents Xinping Han, Yanhua Zhang and Jimmy Wu pp 4104–4106 DOI: 10.1021/ja100747n Supporting Info

Evidence for Ligand Non-innocence in a Formally Ruthenium(I) Hydride Complex Noah L. Wieder, Michelle Gallagher, Patrick J. Carroll and Donald H. Berry pp 4107–4109 DOI: 10.1021/ja100894h Supporting Info

Elucidation of the Structure of the Membrane Anchor of Penicillin-Binding Protein 5 of Escherichia coli Peter I. O’Daniel, Jaroslav Zajicek, Weilie Zhang, Qicun Shi, Jed F. Fisher and Shahriar Mobashery pp 4110–4118 DOI: 10.1021/ja9094445 Supporting Info

A Guest-Responsive Fluorescent 3D Microporous Metal−Organic Framework Derived from a Long-Lifetime Pyrene Core Kyriakos C. Stylianou, Romain Heck, Samantha Y. Chong, John Bacsa, James T. A. Jones, Yaroslav Z. Khimyak, Darren Bradshaw and Matthew J. Rosseinsky pp 4119–4130 DOI: 10.1021/ja906041f Supporting Info

Proteins as Electronic Materials: Electron Transport through Solid-State Protein Monolayer Junctions Izhar Ron, Lior Sepunaru, Stella Itzhakov, Tatyana Belenkova, Noga Friedman, Israel Pecht, Mordechai Sheves and David Cahen pp 4131–4140 DOI: 10.1021/ja907328r Supporting Info

Expanding the Chemistry of DNA for in Vitro Selection Jonathan D. Vaught, Chris Bock, Jeff Carter, Tim Fitzwater, Matt Otis, Dan Schneider, Justin Rolando, Sheela Waugh, Sheri K. Wilcox and Bruce E. Eaton pp 4141–4151 DOI: 10.1021/ja908035g

Fluorophore Labeling of the Glycine-Rich Loop as a Method of Identifying Inhibitors That Bind to Active and Inactive Kinase Conformations Jeffrey R. Simard, Matthus Getlik, Christian Grtter, Ralf Schneider, Sabine Wulfert and Daniel Rauh pp 4152–4160 DOI: 10.1021/ja908083e Supporting Info

Expressed Peptide Assay for DNA Detection Xin Zhou, Peng Cao, Yuan Tian and Jin Zhu pp 4161–4168 DOI: 10.1021/ja9081827 Supporting Info

Pillared MFI Zeolite Nanosheets of a Single-Unit-Cell Thickness Kyungsu Na, Minkee Choi, Woojin Park, Yasuhiro Sakamoto, Osamu Terasaki and Ryong Ryoo pp 4169–4177 DOI: 10.1021/ja908382n Supporting Info

Mechanistic Investigation of the Hydrogenation of O2 by a Transfer Hydrogenation Catalyst Sugata Chowdhury, Fahmi Himo, Nino Russo and Emilia Sicilia pp 4178–4190 DOI: 10.1021/ja908453k Supporting Info

Photoswitchable Intramolecular H-Stacking of Perylenebisimide Jiaobing Wang, Artem Kulago, Wesley R. Browne and Ben L. Feringa pp 4191–4196 DOI: 10.1021/ja910829b Supporting Info

Electrically Driven Redox Process in Cerium Oxides Peng Gao, Zhenchuan Kang, Wangyang Fu, Wenlong Wang, Xuedong Bai and Enge Wang pp 4197–4201 DOI: 10.1021/ja9086616 Supporting Info

Photoelectrochemical Water Oxidation by Cobalt Catalyst (“Co−Pi”)/α-Fe2O3 Composite Photoanodes: Oxygen Evolution and Resolution of a Kinetic Bottleneck Diane K. Zhong and Daniel R. Gamelin pp 4202–4207 DOI: 10.1021/ja908730h Supporting Info

Tri-N-annulated Hexarylene: An Approach to Well-Defined Graphene Nanoribbons with Large Dipoles Yan Li, Jing Gao, Simone Di Motta, Fabrizia Negri and Zhaohui Wang pp 4208–4213 DOI: 10.1021/ja100276x Supporting Info

Insight into the Electronic Structure of the CP47 Antenna Protein Complex of Photosystem II: Hole Burning and Fluorescence Study Bhanu Neupane, Nhan C. Dang, Khem Acharya, Mike Reppert, Valter Zazubovich, Rafael Picorel, Michael Seibert and Ryszard Jankowiak pp 4214–4229 DOI: 10.1021/ja908510w

Elucidation of the Self-Assembly Pathway of Lanreotide Octapeptide into β-Sheet Nanotubes: Role of Two Stable Intermediates Emilie Pouget, Nicolas Fay, Erik Dujardin, Nadge Jamin, Patrick Berthault, Lionel Perrin, Anjali Pandit, Thierry Rose, Cline Valry, Daniel Thomas, Mat Paternostre and Franck Artzner pp 4230–4241 DOI: 10.1021/ja9088023 Supporting Info

Relation between Serum Amyloid A Truncated Peptides and Their Suprastructure Chirality Noa Rubin, Emanuel Perugia, Sharon G. Wolf, Eugenia Klein, Mati Fridkin and Lia Addadi pp 4242–4248 DOI: 10.1021/ja909345p Supporting Info

Flexibility of N-Heterocyclic Carbene Ligands in Ruthenium Complexes Relevant to Olefin Metathesis and Their Impact in the First Coordination Sphere of the Metal Francesco Ragone, Albert Poater and Luigi Cavallo pp 4249–4258 DOI: 10.1021/ja909441x Supporting Info

Prodrugs Forming High Drug Loading Multifunctional Nanocapsules for Intracellular Cancer Drug Delivery Youqing Shen, Erlei Jin, Bo Zhang, Caitlin J. Murphy, Meihua Sui, Jian Zhao, Jinqiang Wang, Jianbin Tang, Maohong Fan, Edward Van Kirk and William J. Murdoch pp 4259–4265 DOI: 10.1021/ja909475m Supporting Info

Elucidation of Amyloid β-Protein Oligomerization Mechanisms: Discrete Molecular Dynamics Study B. Urbanc, M. Betnel, L. Cruz, G. Bitan and D. B. Teplow pp 4266–4280 DOI: 10.1021/ja9096303 Supporting Info

Bisabolyl-Derived Sesquiterpenes from Tobacco 5-Epi-aristolochene Synthase-Catalyzed Cyclization of (2Z,6E)-Farnesyl Diphosphate Juan A. Faraldos, Paul E. O’Maille, Nikki Dellas, Joseph P. Noel and Robert M. Coates pp 4281–4289 DOI: 10.1021/ja909886q Supporting Info

14N Quadrupolar Coupling of Amide Nitrogen and Peptide Secondary Structure As Studied by Solid-State NMR Spectroscopy Jun Fukazawa, Shin-ichi Kato, Takuo Ozaki, Akira Shoji and K. Takegoshi pp 4290–4294 DOI: 10.1021/ja909931j Supporting Info

Site-Specific Backbone Amide 15N Chemical Shift Anisotropy Tensors in a Small Protein from Liquid Crystal and Cross-Correlated Relaxation Measurements Lishan Yao, Alexander Grishaev, Gabriel Cornilescu and Ad Bax pp 4295–4309 DOI: 10.1021/ja910186u Supporting Info

Molecular-Mechanical Switching at the Nanoparticle−Solvent Interface: Practice and Theory Ali Coskun, Paul J. Wesson, Rafal Klajn, Ali Trabolsi, Lei Fang, Mark A. Olson, Sanjeev K. Dey, Bartosz A. Grzybowski and J. Fraser Stoddart pp 4310–4320 DOI: 10.1021/ja9102327 Supporting Info

Cooperative Effects in Ternary Cu−Ni−Fe Catalysts Lead to Enhanced Alkene Selectivity in Alkyne Hydrogenation Blaise Bridier and Javier Prez-Ramrez pp 4321–4327 DOI: 10.1021/ja9101997 Supporting Info

Continuous Symmetry Breaking Induced by Ion Pairing Effect in Heptamethine Cyanine Dyes: Beyond the Cyanine Limit Pierre-Antoine Bouit, Christophe Aronica, Loc Toupet, Boris Le Guennic, Chantal Andraud and Olivier Maury pp 4328–4335 DOI: 10.1021/ja9100886 Supporting Info

Probing ‘Spin-Forbidden’ Oxygen-Atom Transfer: Gas-Phase Reactions of Chromium−Porphyrin Complexes Maria Elisa Crestoni, Simonetta Fornarini, Francesco Lanucara, Jeffrey J. Warren and James M. Mayer pp 4336–4343 DOI: 10.1021/ja9103638 Supporting Info

Probing the Interactions of O2 with Small Gold Cluster Anions (Aun−, n = 1−7): Chemisorption vs Physisorption Wei Huang, Hua-Jin Zhai and Lai-Sheng Wang pp 4344–4351 DOI: 10.1021/ja910401x Supporting Info

DNA Scissors Device Used to Measure MutS Binding to DNA Mis-pairs Hongzhou Gu, Wei Yang and Nadrian C. Seeman pp 4352–4357 DOI: 10.1021/ja910188p Supporting Info

Transition from Tunneling to Hopping Transport in Long, Conjugated Oligo-imine Wires Connected to Metals Seong Ho Choi, Chad Risko, M. Carmen Ruiz Delgado, BongSoo Kim, Jean-Luc Brdas and C. Daniel Frisbie pp 4358–4368 DOI: 10.1021/ja910547c Supporting Info

Si−H Bond Activation of Alkynylsilanes by Group 4 Metallocene Complexes Martin Lama, Anke Spannenberg, Wolfgang Baumann, Haijun Jiao, Christine Fischer, Sven Hansen, Perdita Arndt and Uwe Rosenthal pp 4369–4380 DOI: 10.1021/ja910527w Supporting Info

Radical Migration of Substituents of Aryl Groups on Quinazolinones Derived from N-Acyl Cyanamides Marie-Hlne Larraufie, Christine Courillon, Cyril Ollivier, Emmanuel Lacte, Max Malacria and Louis Fensterbank pp 4381–4387 DOI: 10.1021/ja910653k Supporting Info

Nanomagnetic Competition Assay for Low-Abundance Protein Biomarker Quantification in Unprocessed Human Sera Yuanpeng Li, Balasubramanian Srinivasan, Ying Jing, Xiaofeng Yao, Marie A. Hugger, Jian-Ping Wang and Chengguo Xing pp 4388–4392 DOI: 10.1021/ja910406a Supporting Info

Electrochemically Triggered Double Translocation of Two Different Metal Ions with a Ditopic Calix[6]arene Ligand Benoit Colasson, Nicolas Le Poul, Yves Le Mest and Olivia Reinaud pp 4393–4398 DOI: 10.1021/ja910676z Supporting Info

Overriding Felkin Control: A General Method for Highly Diastereoselective Chelation-Controlled Additions to α-Silyloxy Aldehydes Gretchen R. Stanton, Corinne N. Johnson and Patrick J. Walsh pp 4399–4408 DOI: 10.1021/ja910717p Supporting Info

Coordination Chemistry-Assembled Porphyrinic Catenanes Maryline Beyler, Valrie Heitz and Jean-Pierre Sauvage pp 4409–4417 DOI: 10.1021/ja910747h Supporting Info

Mechanistic Insights on Acrylate Insertion Polymerization Damien Guironnet, Lucia Caporaso, Boris Neuwald, Inigo Gttker-Schnetmann, Luigi Cavallo and Stefan Mecking pp 4418–4426 DOI: 10.1021/ja910760n Supporting Info

Cascade Resulting in the Reductive Ethynylation of Aldehydes: Dissection of Its Components Dongjoo Lee and Samuel J. Danishefsky pp 4427–4430 DOI: 10.1021/ja910825g Supporting Info

Phytochrome as Molecular Machine: Revealing Chromophore Action during the Pfr → Pr Photoconversion by Magic-Angle Spinning NMR Spectroscopy Thierry Rohmer, Christina Lang, Christian Bongards, Karthick Babu Sai Sankar Gupta, Johannes Neugebauer, Jon Hughes, Wolfgang Grtner and Jrg Matysik pp 4431–4437 DOI: 10.1021/ja9108616 Supporting Info

Synthesis of Monodisperse Mesoporous Titania Beads with Controllable Diameter, High Surface Areas, and Variable Pore Diameters (14−23 nm) Dehong Chen, Lu Cao, Fuzhi Huang, Paolo Imperia, Yi-Bing Cheng and Rachel A. Caruso pp 4438–4444 DOI: 10.1021/ja100040p Supporting Info

Biological Catalysis Regulated by Cucurbit[7]uril Molecular Containers Soumyadip Ghosh and Lyle Isaacs pp 4445–4454 DOI: 10.1021/ja910915k Supporting Info

Organelle-Targetable Fluorescent Probes for Imaging Hydrogen Peroxide in Living Cells via SNAP-Tag Protein Labeling Duangkhae Srikun, Aaron E. Albers, Christine I. Nam, Anthony T. Iavarone and Christopher J. Chang pp 4455–4465 DOI: 10.1021/ja100117u Supporting Info

Photodeoxygenation of Dibenzothiophene S-Oxide Derivatives in Aqueous Media James Korang, Whitney R. Grither and Ryan D. McCulla pp 4466–4476 DOI: 10.1021/ja100147b Supporting Info

Efficient Photoinduced Electron Transfer in a Porphyrin Tripod−Fullerene Supramolecular Complex via π−π Interactions in Nonpolar Media Atsuro Takai, Mohammed Chkounda, Antoine Eggenspiller, Claude P. Gros, Mohammed Lachkar, Jean-Michel Barbe and Shunichi Fukuzumi pp 4477–4489 DOI: 10.1021/ja100192x Supporting Info

Magnetic Glyco-Nanoparticles: A Tool To Detect, Differentiate, and Unlock the Glyco-Codes of Cancer via Magnetic Resonance Imaging Kheireddine El-Boubbou, David C. Zhu, Chrysoula Vasileiou, Babak Borhan, Davide Prosperi, Wei Li and Xuefei Huang pp 4490–4499 DOI: 10.1021/ja100455c Supporting Info

Intrinsically Chiral Aromaticity. Rules Incorporating Linking Number, Twist, and Writhe for Higher-Twist Mbius Annulenes Shay M. Rappaport and Henry S. Rzepa p 4500 DOI: 10.1021/ja100035p

The Aqueous Chemistry of the Elements p 4501 DOI: 10.1021/ja101400c

Reactions at Solid Surfaces p 4501 DOI: 10.1021/ja1014019

Metal Catalysts in Olefin Polymerization. Topics in Organometallic Chemistry, Vol. 26 Richard A. Jones p 4501 DOI: 10.1021/ja101590z

Electrochemistry of Porous Materials Diego J. Daz pp 4501–4502 DOI: 10.1021/ja101710r

Issue 13

Harnessing Energy for a Sustainable World John C. Crittenden and Henry S. White pp 4503–4505 DOI: 10.1021/ja1017738

Pd(OAc)2 Catalyzed Olefination of Highly Electron-Deficient Perfluoroarenes Xingang Zhang, Shilu Fan, Chun-Yang He, Xiaolong Wan, Qiao-Qiao Min, Jie Yang and Zhong-Xing Jiang pp 4506–4507 DOI: 10.1021/ja908434e Supporting Info

Design of Short Linear Peptides That Show Hydrogen Bonding Constraints in Water Benben Song, Patrick Kibler, Alpeshkumar Malde, Krishna Kodukula and Amit K. Galande pp 4508–4509 DOI: 10.1021/ja905341p Supporting Info

Iridium(III)-Catalyzed Enantioselective Si−H Bond Insertion and Formation of an Enantioenriched Silicon Center Yoichi Yasutomi, Hidehiro Suematsu and Tsutomu Katsuki pp 4510–4511 DOI: 10.1021/ja100833h Supporting Info

Quantum Refinement of [FeFe] Hydrogenase Indicates a Dithiomethylamine Ligand Ulf Ryde, Claudio Greco and Luca De Gioia pp 4512–4513 DOI: 10.1021/ja909194f Supporting Info

Synthesis of Quaternary Chalcogenide Nanocrystals: Stannite Cu2ZnxSnySe1+x+2y Alexey Shavel, Jordi Arbiol and Andreu Cabot pp 4514–4515 DOI: 10.1021/ja909498c Supporting Info

Near UV Excited Line and Broad Band Photoluminescence of an Anion-Ordered Oxyfluoride Sangmoon Park and Thomas Vogt pp 4516–4517 DOI: 10.1021/ja909486j

Generic Postfunctionalization Route from Amino-Derived Metal−Organic Frameworks Marie Savonnet, Delphine Bazer-Bachi, Nicolas Bats, Javier Perez-Pellitero, Erwann Jeanneau, Vincent Lecocq, Catherine Pinel and David Farrusseng pp 4518–4519 DOI: 10.1021/ja909613e Supporting Info

Net Hydrogenation of Pt−NHPh Bond Is Catalyzed by Elemental Pt Joanna R. Webb, Aaron W. Pierpont, Colleen Munro-Leighton, T. Brent Gunnoe, Thomas R. Cundari and Paul D. Boyle pp 4520–4521 DOI: 10.1021/ja9102309 Supporting Info

Catalytic Dicyanative [4+2] Cycloaddition Triggered by Cyanopalladation of Conjugated Enynes under Aerobic Conditions Shigeru Arai, Yuka Koike, Hirohiko Hada and Atsushi Nishida pp 4522–4523 DOI: 10.1021/ja910451j Supporting Info

Surface Junction Effects on the Electron Conduction of Molecular Wires Tomochika Kurita, Yoshihiko Nishimori, Fumiyuki Toshimitsu, Satoshi Muratsugu, Shoko Kume and Hiroshi Nishihara pp 4524–4525 DOI: 10.1021/ja910462x Supporting Info

Spontaneous Intermolecular Amide Bond Formation between Side Chains for Irreversible Peptide Targeting Bijan Zakeri and Mark Howarth pp 4526–4527 DOI: 10.1021/ja910795a Supporting Info

Influence of Magnetic Field upon the Conductance of a Unicomponent Crystal of a Tetrathiafulvalene-Based Nitronyl Nitroxide Hideji Komatsu, Michio M. Matsushita, Shigefumi Yamamura, Yoko Sugawara, Kentaro Suzuki and Tadashi Sugawara pp 4528–4529 DOI: 10.1021/ja9109538 Supporting Info

Enzymatic Synthesis of Resorcylic Acid Lactones by Cooperation of Fungal Iterative Polyketide Synthases Involved in Hypothemycin Biosynthesis Hui Zhou, Kangjian Qiao, Zhizeng Gao, Michael J. Meehan, Jesse W.-H. Li, Xiling Zhao, Pieter C. Dorrestein, John C. Vederas and Yi Tang pp 4530–4531 DOI: 10.1021/ja100060k Supporting Info

Serial and Parallel Dip-Pen Nanolithography Using a Colloidal Probe Tip Marcus A. Kramer, Hamsa Jaganathan and Albena Ivanisevic pp 4532–4533 DOI: 10.1021/ja1003137 Supporting Info

Proton-Catalyzed Hydrogenation of a d8 Ir(I) Complex Yields a trans Ir(III) Dihydride Michael Findlater, Wesley H. Bernskoetter and Maurice Brookhart pp 4534–4535 DOI: 10.1021/ja100168w Supporting Info

Helical Chiral 2-Aminopyridinium Ions: A New Class of Hydrogen Bond Donor Catalysts Norito Takenaka, Jinshui Chen, Burjor Captain, Robindro Singh Sarangthem and Appayee Chandrakumar pp 4536–4537 DOI: 10.1021/ja100539c Supporting Info

Highly Enantioselective Hydrogenation of α-Arylmethylene Cycloalkanones Catalyzed by Iridium Complexes of Chiral Spiro Aminophosphine Ligands Jian-Bo Xie, Jian-Hua Xie, Xiao-Yan Liu, Wei-Ling Kong, Shen Li and Qi-Lin Zhou pp 4538–4539 DOI: 10.1021/ja100652f Supporting Info

Combining Time-Resolved Hard X-ray Diffraction and Diffuse Reflectance Infrared Spectroscopy To Illuminate CO Dissociation and Transient Carbon Storage by Supported Pd Nanoparticles during CO/NO Cycling Mark A. Newton, Marco Di Michiel, Anna Kubacka and Marcos Fernndez-Garca pp 4540–4541 DOI: 10.1021/ja9107512 Supporting Info

Conjugated Diene-Assisted Allylic C−H Bond Activation: Cationic Rh(I)-Catalyzed Syntheses of Polysubstituted Tetrahydropyrroles, Tetrahydrofurans, and Cyclopentanes from Ene-2-Dienes Qian Li and Zhi-Xiang Yu pp 4542–4543 DOI: 10.1021/ja100409b Supporting Info

Optimization of the Interligand Overhauser Effect for Fragment Linking: Application to Inhibitor Discovery against Mycobacterium tuberculosis Pantothenate Synthetase Pawel Sledz, H. Leonardo Silvestre, Alvin W. Hung, Alessio Ciulli, Tom L. Blundell and Chris Abell pp 4544–4545 DOI: 10.1021/ja100595u Supporting Info

Copper(I)-Catalyzed Addition of Grignard Reagents to in Situ-Derived N-Sulfonyl Azoalkenes: An Umpolung Alkylation Procedure Applicable to the Formation of Up to Three Contiguous Quaternary Centers John M. Hatcher and Don M. Coltart pp 4546–4547 DOI: 10.1021/ja100932q Supporting Info

N- versus C-Terminal Control over the Screw-Sense Preference of the Configurationally Achiral, Conformationally Helical Peptide Motif Aib8GlyAib8 Jordi Sol, Madeleine Helliwell and Jonathan Clayden pp 4548–4549 DOI: 10.1021/ja100662d Supporting Info

Disassembly of Dendritic Micellar Containers Due to Protein Binding Malar A. Azagarsamy, Volkan Yesilyurt and S. Thayumanavan pp 4550–4551 DOI: 10.1021/ja100746d Supporting Info

A C2-Symmetric Chiral Bis-Sulfoxide Ligand in a Rhodium-Catalyzed Reaction: Asymmetric 1,4-Addition of Sodium Tetraarylborates to Chromenones Jun Chen, Junmin Chen, Feng Lang, Xiangyang Zhang, Linfeng Cun, Jin Zhu, Jingen Deng and Jian Liao pp 4552–4553 DOI: 10.1021/ja1005477 Supporting Info

Evidence of Harvesting Electricity by Exciton Recombination in an n−n Type Solar Cell Qun Liang Song, Hong Bin Yang, Ye Gan, Cheng Gong and Chang Ming Li pp 4554–4555 DOI: 10.1021/ja1003735 Supporting Info

Small and Stable Sulfobetaine Zwitterionic Quantum Dots for Functional Live-Cell Imaging Eleonora Muro, Thomas Pons, Nicolas Lequeux, Alexandra Fragola, Nicolas Sanson, Zsolt Lenkei and Benoit Dubertret pp 4556–4557 DOI: 10.1021/ja1005493 Supporting Info

Masked Cyanoacrylates Unveiled by Mechanical Force Matthew J. Kryger, Mitchell T. Ong, Susan A. Odom, Nancy R. Sottos, Scott R. White, Todd J. Martinez and Jeffrey S. Moore pp 4558–4559 DOI: 10.1021/ja1008932 Supporting Info

Moisture-Resistant and Superhydrophobic Metal−Organic Frameworks Obtained via Postsynthetic Modification Joseph G. Nguyen and Seth M. Cohen pp 4560–4561 DOI: 10.1021/ja100900c Supporting Info

anti-Diastereo- and Enantioselective Carbonyl (Hydroxymethyl)allylation from the Alcohol or Aldehyde Oxidation Level: Allyl Carbonates as Allylmetal Surrogates Yong Jian Zhang, Jin Haek Yang, Sang Hoon Kim and Michael J. Krische pp 4562–4563 DOI: 10.1021/ja100949e Supporting Info

Polycavernoside A: The Prins Macrocyclization Approach Sang Kook Woo and Eun Lee pp 4564–4565 DOI: 10.1021/ja1009579 Supporting Info

Phosphorus Can Also Be a “Photocopy” Marlena P. Washington, Vittal B. Gudimetla, Feng L. Laughlin, Nihal Deligonul, Susan He, John L. Payton, M. Cather Simpson and John D. Protasiewicz pp 4566–4567 DOI: 10.1021/ja1009426 Supporting Info

Phosphine-Catalyzed Formation of Carbon−Sulfur Bonds: Catalytic Asymmetric Synthesis of γ-Thioesters Jianwei Sun and Gregory C. Fu pp 4568–4569 DOI: 10.1021/ja101251d Supporting Info

Iron-Catalyzed Aminohydroxylation of Olefins Kevin S. Williamson and Tehshik P. Yoon pp 4570–4571 DOI: 10.1021/ja1013536 Supporting Info

Self-Assembly of Molecular Cylinders from Polycarbene Ligands and AgI or AuI Arnab Rit, Tania Pape and F. Ekkehardt Hahn pp 4572–4573 DOI: 10.1021/ja101490d Supporting Info

Sensitized NIR Erbium(III) Emission in Confined Geometries: A New Strategy for Light Emitters in Telecom Applications Agnieszka Mech, Angelo Monguzzi, Francesco Meinardi, Jakub Mezyk, Giorgio Macchi and Riccardo Tubino pp 4574–4576 DOI: 10.1021/ja907927s Supporting Info

Bioinspired Modular Synthesis of Elastin-Mimic Polymers To Probe the Mechanism of Elastin Elasticity Yulin Chen and Zhibin Guan pp 4577–4579 DOI: 10.1021/ja9104446 Supporting Info

Ni(III)/(IV) Bis(dicarbollide) as a Fast, Noncorrosive Redox Shuttle for Dye-Sensitized Solar Cells Tina C. Li, Alexander M. Spokoyny, Chunxing She, Omar K. Farha, Chad A. Mirkin, Tobin J. Marks and Joseph T. Hupp pp 4580–4582 DOI: 10.1021/ja100396n Supporting Info

Isolation of Ubiquitous Au40(SR)24 Clusters from the 8 kDa Gold Clusters Huifeng Qian, Yan Zhu and Rongchao Jin pp 4583–4585 DOI: 10.1021/ja1006383 Supporting Info

Generation of Cationic Two-Coordinate Group-13 Ligand Systems by Spontaneous Halide Ejection: Remarkably Nucleophile-Resistant (Dimethylamino)borylene Complexes David A. Addy, Glesni A. Pierce, Dragoslav Vidovic, Dibyendu Mallick, Eluvathingal D. Jemmis, Jose M. Goicoechea and Simon Aldridge pp 4586–4588 DOI: 10.1021/ja101192e Supporting Info

Concurrent Synergism and Inhibition in Bimetallic Catalysis: Catalytic Binuclear Elimination, Solute−Solute Interactions and a Hetero-Bimetallic Hydrogen-Bonded Complex in Rh−Mo Hydroformylations Chuanzhao Li, Shuying Cheng, Martin Tjahjono, Martin Schreyer and Marc Garland pp 4589–4599 DOI: 10.1021/ja909696b Supporting Info

Selective Synthesis of N-Substituted 1,2-Dihydropyridines from Furans by Copper-Induced Concurrent Tandem Catalysis Manuel R. Fructos, Eleuterio lvarez, M. Mar Daz-Requejo and Pedro J. Prez pp 4600–4607 DOI: 10.1021/ja1006614 Supporting Info

Palladium Nanoparticles Captured in Microporous Polymers: A Tailor-Made Catalyst for Heterogeneous Carbon Cross-Coupling Reactions Shin Ogasawara and Shinji Kato pp 4608–4613 DOI: 10.1021/ja9062053 Supporting Info

New Light on NO Bonding in Fe(III) Heme Proteins from Resonance Raman Spectroscopy and DFT Modeling Alexandra V. Soldatova, Mohammed Ibrahim, John S. Olson, Roman S. Czernuszewicz and Thomas G. Spiro pp 4614–4625 DOI: 10.1021/ja906233m Supporting Info

Refinement of Ensembles Describing Unstructured Proteins Using NMR Residual Dipolar Couplings Santi Esteban-Martn, Robert Bryn Fenwick and Xavier Salvatella pp 4626–4632 DOI: 10.1021/ja906995x Supporting Info

Electron Hydration and Ion−Electron Pairs in Water Clusters Containing Trivalent Metal Ions William A. Donald, Maria Demireva, Ryan D. Leib, M. Jeannette Aiken and Evan R. Williams pp 4633–4640 DOI: 10.1021/ja9079385 Supporting Info

Amide Cis−Trans Isomerization in Aqueous Solutions of Methyl N-Formyl-d-glucosaminides and Methyl N-Acetyl-d-glucosaminides: Chemical Equilibria and Exchange Kinetics Xiaosong Hu, Wenhui Zhang, Ian Carmichael and Anthony S. Serianni pp 4641–4652 DOI: 10.1021/ja9086787 Supporting Info

DFT-NMR Investigation and 51V 3QMAS Experiments for Probing Surface OH Ligands and the Hydrogen-Bond Network in a Polyoxovanadate Cluster: The Case of Cs4[H2V10O28]·4H2O Lionel A. Truflandier, Florent Boucher, Christophe Payen, Redouane Hajjar, Yannick Millot, Christian Bonhomme and Nathalie Steunou pp 4653–4668 DOI: 10.1021/ja908973y Supporting Info

The Cold Denatured State of the C-terminal Domain of Protein L9 Is Compact and Contains Both Native and Non-native Structure Bing Shan, Sebastian McClendon, Carla Rospigliosi, David Eliezer and Daniel P. Raleigh pp 4669–4677 DOI: 10.1021/ja908104s Supporting Info

Gold Nanoparticles for the Improved Anticancer Drug Delivery of the Active Component of Oxaliplatin Sarah D. Brown, Paola Nativo, Jo-Ann Smith, David Stirling, Paul R. Edwards, Balaji Venugopal, David J. Flint, Jane A. Plumb, Duncan Graham and Nial J. Wheate pp 4678–4684 DOI: 10.1021/ja908117a

Monitoring a Coordinated Exchange Process in a Four-Component Biological Interaction System: Development of a Time-Resolved Terbium-Based One-Donor/Three-Acceptor Multicolor FRET System Sung Hoon Kim, Jillian R. Gunther and John A. Katzenellenbogen pp 4685–4692 DOI: 10.1021/ja100248q Supporting Info

Reactions of the Terminal NiII−OH Group in Substitution and Electrophilic Reactions with Carbon Dioxide and Other Substrates: Structural Definition of Binding Modes in an Intramolecular NiII···FeII Bridged Site Deguang Huang and R. H. Holm pp 4693–4701 DOI: 10.1021/ja1003125 Supporting Info

Unfolded-State Dynamics and Structure of Protein L Characterized by Simulation and Experiment Vincent A. Voelz, Vijay R. Singh, William J. Wedemeyer, Lisa J. Lapidus and Vijay S. Pande pp 4702–4709 DOI: 10.1021/ja908369h Supporting Info

Persistent, Well-Defined, Monodisperse, π-Conjugated Organic Nanoparticles via G-Quadruplex Self-Assembly David Gonzlez-Rodrguez, Pim G. A. Janssen, Rafael Martn-Rapn, Inge De Cat, Steven De Feyter, Albertus P. H. J. Schenning and E. W. Meijer pp 4710–4719 DOI: 10.1021/ja908537k Supporting Info

Mechanistic Insights in Gold-Stabilized Nonclassical Carbocations: Gold-Catalyzed Rearrangement of 3-Cyclopropyl Propargylic Acetates David Garayalde, Enrique Gmez-Bengoa, Xiaogen Huang, Andreas Goeke and Cristina Nevado pp 4720–4730 DOI: 10.1021/ja909013j Supporting Info

Single-Pot Biofabrication of Zinc Sulfide Immuno-Quantum Dots Weibin Zhou, Daniel T. Schwartz and Franois Baneyx pp 4731–4738 DOI: 10.1021/ja909406n Supporting Info

Cryoreduction of the NO-Adduct of Taurine:α-Ketoglutarate Dioxygenase (TauD) Yields an Elusive {FeNO}8 Species Shengfa Ye, John C. Price, Eric W. Barr, Michael T. Green, J. Martin Bollinger, Jr., Carsten Krebs and Frank Neese pp 4739–4751 DOI: 10.1021/ja909715g Supporting Info

Facile Activation of Dihydrogen by a Phosphinito-Bridged Pt(I)−Pt(I) Complex Piero Mastrorilli, Mario Latronico, Vito Gallo, Flavia Polini, Nazzareno Re, Alessandro Marrone, Roberto Gobetto and Silvano Ellena pp 4752–4765 DOI: 10.1021/ja909747r Supporting Info

GaN Nanowire Arrays for High-Output Nanogenerators Chi-Te Huang, Jinhui Song, Wei-Fan Lee, Yong Ding, Zhiyuan Gao, Yue Hao, Lih-Juann Chen and Zhong Lin Wang pp 4766–4771 DOI: 10.1021/ja909863a

Dynamic Active-Site Protection by the M. tuberculosis Protein Tyrosine Phosphatase PtpB Lid Domain E. Megan Flynn, Jeffrey A. Hanson, Tom Alber and Haw Yang pp 4772–4780 DOI: 10.1021/ja909968n Supporting Info

Hierarchical Self-Assembly on Silicon Francesca Tancini, Damiano Genovese, Marco Montalti, Luigi Cristofolini, Lucia Nasi, Luca Prodi and Enrico Dalcanale pp 4781–4789 DOI: 10.1021/ja9099938 Supporting Info

Hydroxyl-Rich β-Sheet Adhesion to the Gold Surface in Water by First-Principle Simulations Arrigo Calzolari, Giancarlo Cicero, Carlo Cavazzoni, Rosa Di Felice, Alessandra Catellani and Stefano Corni pp 4790–4795 DOI: 10.1021/ja909823n Supporting Info

Nucleophilicity and Nucleofugality of Phenylsulfinate (PhSO2−): A Key to Understanding its Ambident Reactivity Mahiuddin Baidya, Shinjiro Kobayashi and Herbert Mayr pp 4796–4805 DOI: 10.1021/ja9102056 Supporting Info

Effects of Dyes, Gold Nanocrystals, pH, and Metal Ions on Plasmonic and Molecular Resonance Coupling Weihai Ni, Huanjun Chen, Jing Su, Zhenhua Sun, Jianfang Wang and Hongkai Wu pp 4806–4814 DOI: 10.1021/ja910239b Supporting Info

Sequential Rearrangement of Interhelical Networks Upon Rhodopsin Activation in Membranes: The Meta IIa Conformational Substate Ekaterina Zaitseva, Michael F. Brown and Reiner Vogel pp 4815–4821 DOI: 10.1021/ja910317a

Electronic Tuning of Two Metals and Colossal Magnetoresistances in EuWO1+xN2−x Perovskites Minghui Yang, Judith Or-Sol, Anna Kusmartseva, Amparo Fuertes and J. Paul Attfield pp 4822–4829 DOI: 10.1021/ja910745b Supporting Info

Uncovering Compounds by Synergy of Cluster Expansion and High-Throughput Methods Ohad Levy, Gus L. W. Hart and Stefano Curtarolo pp 4830–4833 DOI: 10.1021/ja9105623

Impacts of Mesoporous Silica Nanoparticle Size, Pore Ordering, and Pore Integrity on Hemolytic Activity Yu-Shen Lin and Christy L. Haynes pp 4834–4842 DOI: 10.1021/ja910846q Supporting Info

Phase-Equilibrium-Dominated Vapor−Liquid−Solid Growth Mechanism Chengyu He, Xizhang Wang, Qiang Wu, Zheng Hu, Yanwen Ma, Jijiang Fu and Yi Chen pp 4843–4847 DOI: 10.1021/ja910874x Supporting Info

“Two-Step” Chronoamperometric Method for Studying the Anaerobic Inactivation of an Oxygen Tolerant NiFe Hydrogenase Vincent Fourmond, Pascale Infossi, Marie-Thrse Giudici-Orticoni, Patrick Bertrand and Christophe Lger pp 4848–4857 DOI: 10.1021/ja910685j Supporting Info

Multiple Exciton Dissociation in CdSe Quantum Dots by Ultrafast Electron Transfer to Adsorbed Methylene Blue Jier Huang, Zhuangqun Huang, Ye Yang, Haiming Zhu and Tianquan Lian pp 4858–4864 DOI: 10.1021/ja100106z Supporting Info

Anion-Vacancy-Induced Magneto−Crystalline Anisotropy in Fluorine-Doped Hexagonal Cobaltites Olivier Mentr, Houria Kabbour, Ghislaine Ehora, Grgory Tricot, Sylvie Daviero-Minaud and Myung-Hwan Whangbo pp 4865–4875 DOI: 10.1021/ja100170m Supporting Info

Metallization of a Hypervalent Radical Dimer: Molecular and Band Perspectives John S. Tse, Alicea A. Leitch, Xueyang Yu, Xuezhao Bao, Sijia Zhang, Qingqing Liu, Changqing Jin, Richard A. Secco, Serge Desgreniers, Yasuo Ohishi and Richard T. Oakley pp 4876–4886 DOI: 10.1021/ja100216c Supporting Info

Highly Efficient and Stable Inverted Polymer Solar Cells Integrated with a Cross-Linked Fullerene Material as an Interlayer Chao-Hsiang Hsieh, Yen-Ju Cheng, Pei-Jung Li, Chiu-Hsiang Chen, Martin Dubosc, Ru-Meng Liang and Chain-Shu Hsu pp 4887–4893 DOI: 10.1021/ja100236b Supporting Info

Total Synthesis of (±)- and (−)-Actinophyllic Acid Connor L. Martin, Larry E. Overman and Jason M. Rohde pp 4894–4906 DOI: 10.1021/ja100178u Supporting Info

Switchable Nile Red-Based Probe for Cholesterol and Lipid Order at the Outer Leaflet of Biomembranes Oleksandr A. Kucherak, Sule Oncul, Zeinab Darwich, Dmytro A. Yushchenko, Youri Arntz, Pascal Didier, Yves Mly and Andrey S. Klymchenko pp 4907–4916 DOI: 10.1021/ja100351w Supporting Info

Functionalization of Coordination Nanochannels for Controlling Tacticity in Radical Vinyl Polymerization Takashi Uemura, Yukari Ono, Yuh Hijikata and Susumu Kitagawa pp 4917–4924 DOI: 10.1021/ja100406k Supporting Info

Heterobimetallic Transition Metal/Rare Earth Metal Bifunctional Catalysis: A Cu/Sm/Schiff Base Complex for Syn-Selective Catalytic Asymmetric Nitro-Mannich Reaction Shinya Handa, Vijay Gnanadesikan, Shigeki Matsunaga and Masakatsu Shibasaki pp 4925–4934 DOI: 10.1021/ja100514y Supporting Info

Spectro−Temporal Characterization of the Photoactivation Mechanism of Two New Oxidized Cryptochrome/Photolyase Photoreceptors Johanna Brazard, Anwar Usman, Fabien Lacombat, Christian Ley, Monique M. Martin, Pascal Plaza, Laetitia Mony, Marc Heijde, Grald Zabulon and Chris Bowler pp 4935–4945 DOI: 10.1021/ja1002372 Supporting Info

Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon−Halogen Bonds Using Silylium Catalysis Christos Douvris, C. M. Nagaraja, Chun-Hsing Chen, Bruce M. Foxman and Oleg V. Ozerov pp 4946–4953 DOI: 10.1021/ja100605m Supporting Info

Sequence Isomerism in [3]Rotaxanes Anne-Marie L. Fuller, David A. Leigh and Paul J. Lusby pp 4954–4959 DOI: 10.1021/ja1006838 Supporting Info

Highly Efficient Dimerization of Ethylene by (Imido)vanadium Complexes Containing (2-Anilidomethyl)pyridine Ligands: Notable Ligand Effect toward Activity and Selectivity Shu Zhang and Kotohiro Nomura pp 4960–4965 DOI: 10.1021/ja100573d Supporting Info

Fluorinated β-Diketonate Diglyme Lanthanide Complexes as New Second-Order Nonlinear Optical Chromophores: The Role of f Electrons in the Dipolar and Octupolar Contribution to Quadratic Hyperpolarizability Adriana Valore, Elena Cariati, Stefania Righetto, Dominique Roberto, Francesca Tessore, Renato Ugo, Ignazio L. Fragal, Maria Elena Fragal, Graziella Malandrino, Filippo De Angelis, Leonardo Belpassi, Isabelle Ledoux-Rak, Khuyen Hoang Thi and Joseph Zyss pp 4966–4970 DOI: 10.1021/ja101081q Supporting Info

Zinc-Catalyzed Reduction of Amides: Unprecedented Selectivity and Functional Group Tolerance Shoubhik Das, Daniele Addis, Shaolin Zhou, Kathrin Junge and Matthias Beller p 4971 DOI: 10.1021/ja101189c

Bimetallic Effects for Enhanced Polar Comonomer Enchainment Selectivity in Catalytic Ethylene Polymerization Brandon A. Rodriguez, Massimiliano Delferro and Tobin J. Marks p 4971 DOI: 10.1021/ja1011977

On the Binding of Cationic, Water-Soluble Conjugated Polymers to DNA: Electrostatic and Hydrophobic Interactions Fan Xia, Xiaolei Zuo, Renqiang Yang, Yi Xiao, Di Kang, Alexis Valle-Blisle, Xiong Gong, Alan J. Heeger and Kevin W. Plaxco p 4971 DOI: 10.1021/ja101470a

Cavity Ring-Down Spectroscopy: Techniques and Applications Dean B. Atkinson p 4972 DOI: 10.1021/ja101779c

Issue 14

Aberrant Attachment of Heme to Cytochrome by the Ccm System Results in a Cysteine Persulfide Linkage Elizabeth B. Sawyer, Elaine Stephens, Stuart J. Ferguson, James W. A. Allen and Paul D. Barker pp 4974–4975 DOI: 10.1021/ja908241v Supporting Info

Isolation of Individual Boron Nitride Nanotubes via Peptide Wrapping Zhenghong Gao, Chunyi Zhi, Yoshio Bando, Dmitri Golberg and Takeshi Serizawa pp 4976–4977 DOI: 10.1021/ja910244b Supporting Info

Cationic Palladium(II) Catalysis: C−H Activation/Suzuki−Miyaura Couplings at Room Temperature Takashi Nishikata, Alexander R. Abela, Shenlin Huang and Bruce H. Lipshutz pp 4978–4979 DOI: 10.1021/ja910973a Supporting Info

Encapsulation of a Radiolabeled Cluster Inside a Fullerene Cage, 177LuxLu(3−x)N@C80: An Interleukin-13-Conjugated Radiolabeled Metallofullerene Platform Michael D. Shultz, James C. Duchamp, John D. Wilson, Chun-Ying Shu, Jiechao Ge, Jianyuan Zhang, Harry W. Gibson, Helen L. Fillmore, Jerry I. Hirsch, Harry C. Dorn and Panos P. Fatouros pp 4980–4981 DOI: 10.1021/ja9093617 Supporting Info

Enhancing Thermoelectric Performance of Ternary Nanocrystals through Adjusting Carrier Concentration Yixin Zhao, Jeffrey S. Dyck, Brett M. Hernandez and Clemens Burda pp 4982–4983 DOI: 10.1021/ja100020m Supporting Info

Truncated Octahedral Pt3Ni Oxygen Reduction Reaction Electrocatalysts Jianbo Wu, Junliang Zhang, Zhenmeng Peng, Shengchun Yang, Frederick T. Wagner and Hong Yang pp 4984–4985 DOI: 10.1021/ja100571h Supporting Info

The Productive Merger of Iodonium Salts and Organocatalysis: A Non-photolytic Approach to the Enantioselective α-Trifluoromethylation of Aldehydes Anna E. Allen and David W. C. MacMillan pp 4986–4987 DOI: 10.1021/ja100748y Supporting Info

A Unique Fluorescent Base Analogue for the Expansion of the Genetic Alphabet Michiko Kimoto, Tsuneo Mitsui, Shigeyuki Yokoyama and Ichiro Hirao pp 4988–4989 DOI: 10.1021/ja100806c Supporting Info

The Low-Temperature Inflection Observed in Neutron Scattering Measurements of Proteins Is Due to Methyl Rotation: Direct Evidence Using Isotope Labeling and Molecular Dynamics Simulations Kathleen Wood, Douglas J. Tobias, Brigitte Kessler, Frank Gabel, Dieter Oesterhelt, Frans A. A. Mulder, Giuseppe Zaccai and Martin Weik pp 4990–4991 DOI: 10.1021/ja910502g Supporting Info

Functionally Relevant Interplay between the Fe4S4 Cluster and CN− Ligands in the Active Site of [FeFe]-Hydrogenases Maurizio Bruschi, Claudio Greco, Luca Bertini, Piercarlo Fantucci, Ulf Ryde and Luca De Gioia pp 4992–4993 DOI: 10.1021/ja1008773 Supporting Info

A Prochelator Activated by β-Secretase Inhibits Aβ Aggregation and Suppresses Copper-Induced Reactive Oxygen Species Formation Drew S. Folk and Katherine J. Franz pp 4994–4995 DOI: 10.1021/ja100943r Supporting Info

Structurally Ordered FePt Nanoparticles and Their Enhanced Catalysis for Oxygen Reduction Reaction Jaemin Kim, Youngmin Lee and Shouheng Sun pp 4996–4997 DOI: 10.1021/ja1009629 Supporting Info

Thermally Stable Pt/CeO2 Hetero-Nanocomposites with High Catalytic Activity Huan-Ping Zhou, Hao-Shuai Wu, Jie Shen, An-Xiang Yin, Ling-Dong Sun and Chun-Hua Yan pp 4998–4999 DOI: 10.1021/ja101110m Supporting Info

High-Mobility Semiconducting Naphthodithiophene Copolymers Itaru Osaka, Toru Abe, Shoji Shinamura, Eigo Miyazaki and Kazuo Takimiya pp 5000–5001 DOI: 10.1021/ja101125p Supporting Info

Nucleophilic Acyl Substitution via Aromatic Cation Activation of Carboxylic Acids: Rapid Generation of Acid Chlorides under Mild Conditions David J. Hardee, Lyudmila Kovalchuke and Tristan H. Lambert pp 5002–5003 DOI: 10.1021/ja101292a Supporting Info

Irreversible Inhibition of DNA Polymerase β by an Oxidized Abasic Lesion Lirui Guan and Marc M. Greenberg pp 5004–5005 DOI: 10.1021/ja101372c Supporting Info

Kinetics of Yttrium−Ligand Complexation Monitored Using Hyperpolarized 89Y as a Model for Gadolinium in Contrast Agents Pascal Miville, Sami Jannin, Lothar Helm and Geoffrey Bodenhausen pp 5006–5007 DOI: 10.1021/ja1013954 Supporting Info

A Stable 1,2-Disilacyclohexene and Its 14-Electron Palladium(0) Complex Takashi Abe, Takeaki Iwamoto and Mitsuo Kira pp 5008–5009 DOI: 10.1021/ja101654b Supporting Info

Enantioselective Alkenylation via Nickel-Catalyzed Cross-Coupling with Organozirconium Reagents Sha Lou and Gregory C. Fu pp 5010–5011 DOI: 10.1021/ja1017046 Supporting Info

pH-Responsive Quantum Dots via an Albumin Polymer Surface Coating Yuzhou Wu, Sabyasachi Chakrabortty, Radu A. Gropeanu, Joerg Wilhelmi, Yang Xu, Kai Shih Er, Seah Ling Kuan, Kaloian Koynov, Yinthai Chan and Tanja Weil pp 5012–5014 DOI: 10.1021/ja909570v Supporting Info

Comparison of Solid-State Dipolar Couplings and Solution Relaxation Data Provides Insight into Protein Backbone Dynamics Veniamin Chevelkov, Yi Xue, Rasmus Linser, Nikolai R. Skrynnikov and Bernd Reif pp 5015–5017 DOI: 10.1021/ja100645k Supporting Info

A Highly Tunable Stereoselective Olefination of Semistabilized Triphenylphosphonium Ylides with N-Sulfonyl Imines De-Jun Dong, Hai-Hua Li and Shi-Kai Tian pp 5018–5020 DOI: 10.1021/ja910238f Supporting Info

Spectroscopic Rationale for Efficient Stimulated-Emission Depletion Microscopy Fluorophores Jun-ichi Hotta, Eduard Fron, Peter Dedecker, Kris P. F. Janssen, Chen Li, Klaus Mllen, Benjamin Harke, Johanna Bckers, Stefan W. Hell and Johan Hofkens pp 5021–5023 DOI: 10.1021/ja100079w Supporting Info

Single-Walled Carbon Nanotube-Based Chemiresistive Affinity Biosensors for Small Molecules: Ultrasensitive Glucose Detection Lakshmi N. Cella, Wilfred Chen, Nosang V. Myung and Ashok Mulchandani pp 5024–5026 DOI: 10.1021/ja100503b Supporting Info

Enantioselective Polyene Cyclization via Organo-SOMO Catalysis Sebastian Rendler and David W. C. MacMillan pp 5027–5029 DOI: 10.1021/ja100185p Supporting Info

Enantioselective Thiourea-Catalyzed Cationic Polycyclizations Robert R. Knowles, Song Lin and Eric N. Jacobsen pp 5030–5032 DOI: 10.1021/ja101256v Supporting Info

Isocyano Analogues of [Co(CO)4]n: A Tetraisocyanide of Cobalt Isolated in Three States of Charge Grant W. Margulieux, Nils Weidemann, David C. Lacy, Curtis E. Moore, Arnold L. Rheingold and Joshua S. Figueroa pp 5033–5035 DOI: 10.1021/ja1012382 Supporting Info

Contiguous O-Galactosylation of 4(R)-Hydroxy-l-proline Residues Forms Very Stable Polyproline II Helices Neil W. Owens, Jrg Stetefeld, Erika Lattov and Frank Schweizer pp 5036–5042 DOI: 10.1021/ja905724d Supporting Info

Platinum-Catalyzed Intramolecular Hydrohydrazination: Evidence for Alkene Insertion into a Pt−N Bond Jessica M. Hoover, Antonio DiPasquale, James M. Mayer and Forrest E. Michael pp 5043–5053 DOI: 10.1021/ja906563z Supporting Info

An STM Study of the pH Dependent Redox Activity of a Two-Dimensional Hydrogen Bonding Porphyrin Network at an Electrochemical Interface Qunhui Yuan, Yangjun Xing and Eric Borguet pp 5054–5060 DOI: 10.1021/ja907397u

Controlled Storage of Ferrocene Derivatives as Redox-Active Molecules in Dendrimers Yousuke Ochi, Mana Suzuki, Takane Imaoka, Masaki Murata, Hiroshi Nishihara, Yasuaki Einaga and Kimihisa Yamamoto pp 5061–5069 DOI: 10.1021/ja9064377 Supporting Info

De Novo Designed Coiled-Coil Proteins with Variable Conformations as Components of Molecular Electronic Devices Clara Shlizerman, Alexander Atanassov, Inbal Berkovich, Gonen Ashkenasy and Nurit Ashkenasy pp 5070–5076 DOI: 10.1021/ja907902h

Thermodynamic Changes in Mechanochemically Synthesized Magnesium Hydride Nanoparticles Mark Paskevicius, Drew A. Sheppard and Craig E. Buckley pp 5077–5083 DOI: 10.1021/ja908398u Supporting Info

Reversible Phase Transitions in Self-Assembled Monolayers at the Liquid−Solid Interface: Temperature-Controlled Opening and Closing of Nanopores Rico Gutzler, Thomas Sirtl, Jrgen F. Dienstmaier, Kingsuk Mahata, Wolfgang M. Heckl, Michael Schmittel and Markus Lackinger pp 5084–5090 DOI: 10.1021/ja908919r Supporting Info

Screening for Unknown Mutations by a Bioluminescent Protein Truncation Test with Homogeneous Detection Evangelos C. Petrakis, Ioannis A. Trantakis, Despina P. Kalogianni and Theodore K. Christopoulos pp 5091–5095 DOI: 10.1021/ja909200p Supporting Info

CyDNA: Synthesis and Replication of Highly Cy-Dye Substituted DNA by an Evolved Polymerase Nicola Ramsay, Ann-Sofie Jemth, Anthony Brown, Neal Crampton, Paul Dear and Philipp Holliger pp 5096–5104 DOI: 10.1021/ja909180c Supporting Info

Pterin-Centered Radical as a Mechanistic Probe of the Second Step of Nitric Oxide Synthase Joshua J. Woodward, Yaser NejatyJahromy, R. David Britt and Michael A. Marletta pp 5105–5113 DOI: 10.1021/ja909378n Supporting Info

An Active-Site Phenylalanine Directs Substrate Binding and C−H Cleavage in the α-Ketoglutarate-Dependent Dioxygenase TauD Kevin P. McCusker and Judith P. Klinman pp 5114–5120 DOI: 10.1021/ja909416z

Scanning Electrochemical Microscopy: Surface Interrogation of Adsorbed Hydrogen and the Open Circuit Catalytic Decomposition of Formic Acid at Platinum Joaqun Rodrguez-Lpez and Allen J. Bard pp 5121–5129 DOI: 10.1021/ja9090319 Supporting Info

Directed Self-Assembly of Dipeptides to Form Ultrathin Hydrogel Membranes Eleanor K. Johnson, Dave J. Adams and Petra J. Cameron pp 5130–5136 DOI: 10.1021/ja909579p Supporting Info

Electrostatic Polarization Makes a Substantial Contribution to the Free Energy of Avidin−Biotin Binding Yan Tong, Ye Mei, Yong L. Li, Chang G. Ji and John Z. H. Zhang pp 5137–5142 DOI: 10.1021/ja909575j Supporting Info

Solid-State 17O NMR and Computational Studies of C-Nitrosoarene Compounds Gang Wu, Jianfeng Zhu, Xin Mo, Ruiyao Wang and Victor Terskikh pp 5143–5155 DOI: 10.1021/ja909656w Supporting Info

Heme Proteins: The Role of Solvent in the Dynamics of Gates and Portals Mariano Andrea Scorciapino, Arturo Robertazzi, Mariano Casu, Paolo Ruggerone and Matteo Ceccarelli pp 5156–5163 DOI: 10.1021/ja909822d Supporting Info

Efficient Electron Transfer and Sensitizer Regeneration in Stable π-Extended Tetrathiafulvalene-Sensitized Solar Cells Sophie Wenger, Pierre-Antoine Bouit, Qianli Chen, Jol Teuscher, Davide Di Censo, Robin Humphry-Baker, Jaques-E. Moser, Juan Luis Delgado, Nazario Martn, Shaik M. Zakeeruddin and Michael Grtzel pp 5164–5169 DOI: 10.1021/ja909291h Supporting Info

Protein Aggregation in Crowded Environments Duncan A. White, Alexander K. Buell, Tuomas P. J. Knowles, Mark E. Welland and Christopher M. Dobson pp 5170–5175 DOI: 10.1021/ja909997e

Total Synthesis of the Lycorenine-Type Amaryllidaceae Alkaloid (±)-Clivonine via a Biomimetic Ring-Switch from a Lycorine-Type Progenitor Carles Gir Maas, Victoria L. Paddock, Christian G. Bochet, Alan C. Spivey, Andrew J. P. White, Inderjit Mann and Wolfgang Oppolzer pp 5176–5178 DOI: 10.1021/ja910184j Supporting Info

Elucidation of Structure and Dynamics in Solid Octafluoronaphthalene from Combined NMR, Diffraction, And Molecular Dynamics Studies Andrew J. Ilott, Sebastian Palucha, Andrei S. Batsanov, Mark R. Wilson and Paul Hodgkinson pp 5179–5185 DOI: 10.1021/ja910526z Supporting Info

Enantioselective ProPhenol-Catalyzed Addition of 1,3-Diynes to Aldehydes to Generate Synthetically Versatile Building Blocks and Diyne Natural Products Barry M. Trost, Vincent S. Chan and Daisuke Yamamoto pp 5186–5192 DOI: 10.1021/ja910656b Supporting Info

Solution and Computed Structure of o-Lithium N,N-Diisopropyl-P,P-diphenylphosphinic Amide. Unprecedented Li−O−Li−O Self-Assembly of an Aryllithium Ignacio Fernndez, Pascual Oa-Burgos, Josep M. Oliva and Fernando Lpez Ortiz pp 5193–5204 DOI: 10.1021/ja910556a Supporting Info

Computational Mapping of the Conformational Transitions in Agonist Selective Pathways of a G-Protein Coupled Receptor Supriyo Bhattacharya and Nagarajan Vaidehi pp 5205–5214 DOI: 10.1021/ja910700y Supporting Info

Anatomy of a Red Copper Center: Spectroscopic Identification and Reactivity of the Copper Centers of Bacillus subtilis Sco and Its Cys-to-Ala Variants Gnana S. Siluvai, Mary Mayfield, Mark J. Nilges, Serena DeBeer George and Ninian J. Blackburn pp 5215–5226 DOI: 10.1021/ja910759v Supporting Info

Exploring Resonance Levels and Nanostructuring in the PbTe−CdTe System and Enhancement of the Thermoelectric Figure of Merit Kyunghan Ahn, Mi-Kyung Han, Jiaqing He, John Androulakis, Sedat Ballikaya, Ctirad Uher, Vinayak P. Dravid and Mercouri G. Kanatzidis pp 5227–5235 DOI: 10.1021/ja910762q Supporting Info

Synthesis of Mono-ADP-Ribosylated Oligopeptides Using Ribosylated Amino Acid Building Blocks Gerbrand J. van der Heden van Noort, Maarten G. van der Horst, Herman S. Overkleeft, Gijsbert A. van der Marel and Dmitri V. Filippov pp 5236–5240 DOI: 10.1021/ja910940q Supporting Info

Cobalt(II) “Scorpionate” Complexes as Models for Cobalt-Substituted Zinc Enzymes: Electronic Structure Investigation by High-Frequency and -Field Electron Paramagnetic Resonance Spectroscopy J. Krzystek, Dale C. Swenson, S. A. Zvyagin, Dmitry Smirnov, Andrew Ozarowski and Joshua Telser pp 5241–5253 DOI: 10.1021/ja910766w Supporting Info

Crystal Engineering of Pharmaceutical Co-crystals: Application of Methyl Paraben as Molecular Hook Mujeeb Khan, Volker Enkelmann and Gunther Brunklaus pp 5254–5263 DOI: 10.1021/ja100146f Supporting Info

Oxygen-Isotope Exchange Rates for Three Isostructural Polyoxometalate Ions Eric M. Villa, C. Andr Ohlin and William H. Casey pp 5264–5272 DOI: 10.1021/ja100490n Supporting Info

Cationic Polymerization and Insertion Chemistry in the Reactions of Vinyl Ethers with (α-Diimine)PdMe+ Species Changle Chen, Shuji Luo and Richard F. Jordan pp 5273–5284 DOI: 10.1021/ja100491y Supporting Info

Enzyme-Amplified Array Sensing of Proteins in Solution and in Biofluids Oscar R. Miranda, Hung-Ting Chen, Chang-Cheng You, David E. Mortenson, Xiao-Chao Yang, Uwe H. F. Bunz and Vincent M. Rotello pp 5285–5289 DOI: 10.1021/ja1006756 Supporting Info

Roles of the Distinct Electronic Structures of the {Fe(NO)2}9 and {Fe(NO)2}10 Dinitrosyliron Complexes in Modulating Nitrite Binding Modes and Nitrite Activation Pathways Fu-Te Tsai, Pei-Lin Chen and Wen-Feng Liaw pp 5290–5299 DOI: 10.1021/ja100849r Supporting Info

Biomimetic Syntheses from Squalene-Like Precursors: Synthesis of ent-Abudinol B and Reassessment of the Structure of Muzitone Matthew A. Boone, Rongbiao Tong, Frank E. McDonald, Sheri Lense, Rui Cao and Kenneth I. Hardcastle pp 5300–5308 DOI: 10.1021/ja1006806 Supporting Info

Diels−Alder Active-Template Synthesis of Rotaxanes and Metal-Ion-Switchable Molecular Shuttles James D. Crowley, Kevin D. Hnni, David A. Leigh and Alexandra M. Z. Slawin pp 5309–5314 DOI: 10.1021/ja101029u Supporting Info

A New Class of Surfactants with Multinuclear, Inorganic Head Groups Steve Landsmann, Carlos Lizandara-Pueyo and Sebastian Polarz pp 5315–5321 DOI: 10.1021/ja1011178 Supporting Info

Instability of Cationic Gold Nanoparticle Bioconjugates: The Role of Citrate Ions Isaac Ojea-Jimenez and Victor Puntes p 5322 DOI: 10.1021/ja101213s

Electrocatalytic Oxidation of Tyrosine by Parallel Rate-Limiting Proton Transfer and Multisite Electron−Proton Transfer Christine J. Fecenko, Thomas J. Meyer and H. Holden Thorp p 5323 DOI: 10.1021/ja1015266

Modern Surface Organometallic Chemistry Manuel P. Soriaga p 5324 DOI: 10.1021/ja101575n

Tomorrow’s Chemistry Today: Concepts in Nanoscience, Organic Materials and Environmental Chemistry, 2nd ed p 5324 DOI: 10.1021/ja102131p

Issue 15

One-Step Seeding Growth of Magnetically Recyclable Au@Co Core−Shell Nanoparticles: Highly Efficient Catalyst for Hydrolytic Dehydrogenation of Ammonia Borane Jun-Min Yan, Xin-Bo Zhang, Tomoki Akita, Masatake Haruta and Qiang Xu pp 5326–5327 DOI: 10.1021/ja910513h Supporting Info

Enantioselective Nitroso Aldol Reaction Catalyzed by QuinoxP*·Silver(I) Complex and Tin Methoxide Akira Yanagisawa, Satoshi Takeshita, Youhei Izumi and Kazuhiro Yoshida pp 5328–5329 DOI: 10.1021/ja910588w Supporting Info

A Thieno[3,4-c]pyrrole-4,6-dione-Based Copolymer for Efficient Solar Cells Yingping Zou, Ahmed Najari, Philippe Berrouard, Serge Beaupr, Badrou Rda Ach, Ye Tao and Mario Leclerc pp 5330–5331 DOI: 10.1021/ja101888b Supporting Info

Copper(I)-Catalyzed Substitution Reactions of Propargylic Amines: Importance of C(sp)−C(sp3) Bond Cleavage in Generation of Iminium Intermediates Tsuyuka Sugiishi, Akifumi Kimura and Hiroyuki Nakamura pp 5332–5333 DOI: 10.1021/ja9109055 Supporting Info

Thermal Reaction of a Columnar Assembled Diacetylene Macrocycle Yuewen Xu, Mark D. Smith, Michael F. Geer, Perry J. Pellechia, Julius C. Brown, Arief C. Wibowo and Linda S. Shimizu pp 5334–5335 DOI: 10.1021/ja9107066 Supporting Info

Functional Hyperbranched Polymers: Toward Targeted in Vivo 19F Magnetic Resonance Imaging Using Designed Macromolecules Kristofer J. Thurecht, Idriss Blakey, Hui Peng, Oliver Squires, Steven Hsu, Cameron Alexander and Andrew K. Whittaker pp 5336–5337 DOI: 10.1021/ja100252y Supporting Info

Chiral Bis(imidazolidine)pyridine−Cu(OTf)2: Catalytic Asymmetric Endo-Selective [3 + 2] Cycloaddition of Imino Esters with Nitroalkenes Takayoshi Arai, Asami Mishiro, Naota Yokoyama, Kuniko Suzuki and Hiroyasu Sato pp 5338–5339 DOI: 10.1021/ja100265j Supporting Info

Rhodium-Catalyzed C−C Bond Cleavage: Construction of Acyclic Methyl Substituted Quaternary Stereogenic Centers Tobias Seiser and Nicolai Cramer pp 5340–5341 DOI: 10.1021/ja101469t Supporting Info

Role of Unsatisfied Hydrogen Bond Acceptors in RNA Energetics and Specificity Nathan A. Siegfried, Ryszard Kierzek and Philip C. Bevilacqua pp 5342–5344 DOI: 10.1021/ja9107726 Supporting Info

Cooperative N-Heterocyclic Carbene/Lewis Acid Catalysis for Highly Stereoselective Annulation Reactions with Homoenolates Benoit Cardinal-David, Dustin E. A. Raup and Karl A. Scheidt pp 5345–5347 DOI: 10.1021/ja910666n Supporting Info

Room Temperature Light Emission from the Low-Dimensional Semiconductors AZrPS6 (A = K, Rb, Cs) Santanu Banerjee, Jodi M. Szarko, Benjamin D. Yuhas, Christos D. Malliakas, Lin X. Chen and Mercouri G. Kanatzidis pp 5348–5350 DOI: 10.1021/ja1004653 Supporting Info

Tripodal exTTF-CTV Hosts for Fullerenes Elisa Huerta, Helena Isla, Emilio M. Prez, Carles Bo, Nazario Martn and Javier de Mendoza pp 5351–5353 DOI: 10.1021/ja1006993 Supporting Info

Super Silyl Stereo-Directing Groups for Complete 1,5-Syn and -Anti Stereoselectivities in the Aldol Reactions of β-Siloxy Methyl Ketones with Aldehydes Yousuke Yamaoka and Hisashi Yamamoto pp 5354–5356 DOI: 10.1021/ja101076q Supporting Info

Sensitivity Enhanced Heteronuclear Correlation Spectroscopy in Multidimensional Solid-State NMR of Oriented Systems via Chemical Shift Coherences T. Gopinath, Nathaniel J. Traaseth, Kaustubh Mote and Gianluigi Veglia pp 5357–5363 DOI: 10.1021/ja905991s

Synthesis, Structure, Spirocyclization Mechanism, and Glutathione Peroxidase-like Antioxidant Activity of Stable Spirodiazaselenurane and Spirodiazatellurane Bani Kanta Sarma, Debasish Manna, Mao Minoura and Govindasamy Mugesh pp 5364–5374 DOI: 10.1021/ja908080u Supporting Info

Formation of Beyerene, Kaurene, Trachylobane, and Atiserene Diterpenes by Rearrangements That Avoid Secondary Carbocations Young J. Hong and Dean J. Tantillo pp 5375–5386 DOI: 10.1021/ja9084786 Supporting Info

Molecular Wheels as Nanoporous Materials: Differing Modes of Gas Diffusion through Ga10 and Ga18 Wheels Probed by Hyperpolarized 129Xe NMR Spectroscopy Chi-Yuan Cheng, Theocharis C. Stamatatos, George Christou and Clifford R. Bowers pp 5387–5393 DOI: 10.1021/ja908327w Supporting Info

Ladder-Type Oligo-p-phenylene-Containing Copolymers with High Open-Circuit Voltages and Ambient Photovoltaic Activity Qingdong Zheng, Byung Jun Jung, Jia Sun and Howard E. Katz pp 5394–5404 DOI: 10.1021/ja909111p Supporting Info

In Situ Misfolding of Human Islet Amyloid Polypeptide at Interfaces Probed by Vibrational Sum Frequency Generation Li Fu, Gang Ma and Elsa C. Y. Yan pp 5405–5412 DOI: 10.1021/ja909546b Supporting Info

Metal Sulfide in a C82 Fullerene Cage: A New Form of Endohedral Clusterfullerenes Lothar Dunsch, Shangfeng Yang, Lin Zhang, Anna Svitova, Steffen Oswald and Alexey A. Popov pp 5413–5421 DOI: 10.1021/ja909580j Supporting Info

Low-Energy Electron-Induced DNA Damage: Effect of Base Sequence in Oligonucleotide Trimers Zejun Li, Pierre Cloutier, Lon Sanche and J. Richard Wagner pp 5422–5427 DOI: 10.1021/ja9099505 Supporting Info

Excited State Distortion in Photochromic Ruthenium Sulfoxide Complexes Beth Anne McClure, Eric R. Abrams and Jeffrey J. Rack pp 5428–5436 DOI: 10.1021/ja9099399 Supporting Info

Unexpected Binding Modes of Nitric Oxide Synthase Inhibitors Effective in the Prevention of a Cerebral Palsy Phenotype in an Animal Model Silvia L Delker, Haitao Ji, Huiying Li, Joumana Jamal, Jianguo Fang, Fengtian Xue, Richard B. Silverman and Thomas L. Poulos pp 5437–5442 DOI: 10.1021/ja910228a Supporting Info

Si═X Multiple Bonding with Four-Coordinate Silicon? Insights into the Nature of the Si═O and Si═S Double Bonds in Stable Silanoic Esters and Related Thioesters: A Combined NMR Spectroscopic and Computational Study Jan. D. Epping, Shenglai Yao, Miriam Karni, Yitzhak Apeloig and Matthias Driess pp 5443–5455 DOI: 10.1021/ja1004812 Supporting Info

Polymetallic Oxalate-Based 2D Magnets: Soluble Molecular Precursors for the Nanostructuration of Magnetic Oxides Eugenio Coronado, Carlos Mart-Gastaldo, Jos R. Galn-Mascars and Massimiliano Cavallini pp 5456–5468 DOI: 10.1021/ja100261z Supporting Info

Chemistry and Biology of Deoxynyboquinone, a Potent Inducer of Cancer Cell Death Joseph S. Bair, Rahul Palchaudhuri and Paul J. Hergenrother pp 5469–5478 DOI: 10.1021/ja100610m Supporting Info

Solid-State 115In and 31P NMR Studies of Triarylphosphine Indium Trihalide Adducts Fu Chen, Guibin Ma, Guy M. Bernard, Ronald G. Cavell, Robert McDonald, Michael J. Ferguson and Roderick E. Wasylishen pp 5479–5493 DOI: 10.1021/ja100625p Supporting Info

Probing the Ternary Complexes of Indoleamine and Tryptophan 2,3-Dioxygenases by Cryoreduction EPR and ENDOR Spectroscopy Roman M. Davydov, Nishma Chauhan, Sarah J. Thackray, J. L. Ross Anderson, Nektaria D. Papadopoulou, Christopher G. Mowat, Stephen K. Chapman, Emma L. Raven and Brian M. Hoffman pp 5494–5500 DOI: 10.1021/ja100518z Supporting Info

Microwave Spectrum, Structural Parameters, and Quadrupole Coupling for 1,2-Dihydro-1,2-azaborine Adam M. Daly, Chakree Tanjaroon, Adam J. V. Marwitz, Shih-Yuan Liu and Stephen G. Kukolich pp 5501–5506 DOI: 10.1021/ja1005338 Supporting Info

Mapping the Distribution of an Individual Chromophore Interacting with Silica-Based Nanomaterials Boiko Cohen, Felix Sanchez and Abderrazzak Douhal pp 5507–5514 DOI: 10.1021/ja100771j Supporting Info

The Distal Effect of Electron-Withdrawing Groups and Hydrogen Bonding on the Stability of Peptide Enolates Junming Ho, Christopher J. Easton and Michelle L. Coote pp 5515–5521 DOI: 10.1021/ja100996z Supporting Info

Direct Catalytic Asymmetric Addition of Allyl Cyanide to Ketones via Soft Lewis Acid/Hard Brønsted Base/Hard Lewis Base Catalysis Ryo Yazaki, Naoya Kumagai and Masakatsu Shibasaki pp 5522–5531 DOI: 10.1021/ja101687p Supporting Info

Indene−C60 Bisadduct: A New Acceptor for High-Performance Polymer Solar Cells Youjun He, Hsiang-Yu Chen, Jianhui Hou and Yongfang Li p 5532 DOI: 10.1021/ja101780s

Hard Proof of the NaYF4/NaGdF4 Nanocrystal Core/Shell Structure Keith A. Abel, John-Christopher Boyer and Frank C. J. M. van Veggel p 5533 DOI: 10.1021/ja101738b

A Practical Guide to Scientific Data Analysis p 5534 DOI: 10.1021/ja102187p

Crystallography of Quasicrystals: Concepts, Methods and Structures p 5534 DOI: 10.1021/ja102189x

Issue 16

Direct Detection of Nitroxyl in Aqueous Solution Using a Tripodal Copper(II) BODIPY Complex Joel Rosenthal and Stephen J. Lippard pp 5536–5537 DOI: 10.1021/ja909148v Supporting Info

Breaking the T1 Constraint for Quantitative Measurement in Magic Angle Spinning Solid-State NMR Spectroscopy Guangjin Hou, Shangwu Ding, Limin Zhang and Feng Deng pp 5538–5539 DOI: 10.1021/ja909550f Supporting Info

Plasmon-Enhanced Fluorescence from Single Fluorophores End-Linked to Gold Nanorods Yi Fu, Jian Zhang and Joseph R. Lakowicz pp 5540–5541 DOI: 10.1021/ja9096237 Supporting Info

A Small-Molecule-Based Ternary Data-Storage Device Hua Li, Qingfeng Xu, Najun Li, Ru Sun, Jianfeng Ge, Jianmei Lu, Hongwei Gu and Feng Yan pp 5542–5543 DOI: 10.1021/ja910243f Supporting Info

Chiral Boronate Derivatives via Catalytic Enantioselective Conjugate Addition of Grignard Reagents on 3-Boronyl Unsaturated Esters and Thioesters Jack Chang Hung Lee and Dennis G. Hall pp 5544–5545 DOI: 10.1021/ja9104057 Supporting Info

Detection of Transient Interchain Interactions in the Intrinsically Disordered Protein α-Synuclein by NMR Paramagnetic Relaxation Enhancement Kuen-Phon Wu and Jean Baum pp 5546–5547 DOI: 10.1021/ja9105495 Supporting Info

Effect of Glycosylation on Cis/Trans Isomerization of Prolines in IgA1-Hinge Peptide Yoshiki Narimatsu, Tomomi Kubota, Sanae Furukawa, Hisayuki Morii, Hisashi Narimatsu and Kazuhiko Yamasaki pp 5548–5549 DOI: 10.1021/ja9106429 Supporting Info

Catalysis of a Flavoenzyme-Mediated Amide Hydrolysis Tathagata Mukherjee, Yang Zhang, Sameh Abdelwahed, Steven E. Ealick and Tadhg P. Begley pp 5550–5551 DOI: 10.1021/ja9107676 Supporting Info

Low-Temperature Pseudomorphic Transformation of Ordered Hierarchical Macro-mesoporous SiO2/C Nanocomposite to SiC via Magnesiothermic Reduction Yifeng Shi, Fan Zhang, Yong-Sheng Hu, Xiaohong Sun, Yichi Zhang, Hyung Ik Lee, Liquan Chen and Galen D. Stucky pp 5552–5553 DOI: 10.1021/ja1001136 Supporting Info

Planar Tetracoordinate Carbon Strips in Edge Decorated Graphene Nanoribbon Menghao Wu, Yong Pei and Xiao Cheng Zeng pp 5554–5555 DOI: 10.1021/ja1002026 Supporting Info

Fibrillar vs Crystalline Full-Length β-2-Microglobulin Studied by High-Resolution Solid-State NMR Spectroscopy Emeline Barbet-Massin, Stefano Ricagno, Józef R. Lewandowski, Sofia Giorgetti, Vittorio Bellotti, Martino Bolognesi, Lyndon Emsley and Guido Pintacuda pp 5556–5557 DOI: 10.1021/ja1002839 Supporting Info

Ultrafast MAS Solid-State NMR Permits Extensive 13C and 1H Detection in Paramagnetic Metalloproteins Ivano Bertini, Lyndon Emsley, Moreno Lelli, Claudio Luchinat, Jiafei Mao and Guido Pintacuda pp 5558–5559 DOI: 10.1021/ja100398q Supporting Info

A Simple Method of Separating Metallic and Semiconducting Single-Walled Carbon Nanotubes Based on Molecular Charge Transfer Rakesh Voggu, K. Venkata Rao, Subi J. George and C. N. R. Rao pp 5560–5561 DOI: 10.1021/ja100190p Supporting Info

Palladium-Catalyzed Asymmetric Addition of Diarylphosphines to Enones toward the Synthesis of Chiral Phosphines Jian-Jun Feng, Xue-Feng Chen, Min Shi and Wei-Liang Duan pp 5562–5563 DOI: 10.1021/ja100606v Supporting Info

Inducing α-Helices in Short Oligopeptides through Binding by an Artificial Hydrophobic Cavity Christel Dolain, Yoshiyuki Hatakeyama, Tomohisa Sawada, Shohei Tashiro and Makoto Fujita pp 5564–5565 DOI: 10.1021/ja100585w Supporting Info

Stereospecific Octahedral Group 4 Bis(phenolate) Ether Complexes for Olefin Polymerization Elizabeth T. Kiesewetter, Sren Randoll, Madalyn Radlauer and Robert M. Waymouth pp 5566–5567 DOI: 10.1021/ja100627x Supporting Info

Iron-Catalyzed C−C Bond Formation at α-Position of Aliphatic Amines via C−H Bond Activation through 1,5-Hydrogen Transfer Naohiko Yoshikai, Adam Mieczkowski, Arimasa Matsumoto, Laurean Ilies and Eiichi Nakamura pp 5568–5569 DOI: 10.1021/ja100651t Supporting Info

A Cu2+(S = 1/2) Kagomé Antiferromagnet: MgxCu4−x(OH)6Cl2 Shaoyan Chu, Tyrel M. McQueen, Robin Chisnell, Danna E. Freedman, Peter Müller, Young S. Lee and Daniel G. Nocera pp 5570–5571 DOI: 10.1021/ja1008322 Supporting Info

PbTiO3 Nanofibers with Edge-Shared TiO6 Octahedra Zhaohui Ren, Gang Xu, Yong Liu, Xiao Wei, Yihan Zhu, Xiaobin Zhang, Guanglie Lv, Youwen Wang, Yuewu Zeng, Piyi Du, Wenjian Weng, Ge Shen, J. Z. Jiang and Gaorong Han pp 5572–5573 DOI: 10.1021/ja1011614 Supporting Info

Dimeric Quinidine-Catalyzed Enantioselective Aminooxygenation of Oxindoles: An Organocatalytic Approach to 3-Hydroxyoxindole Derivatives Tommy Bui, Nuno R. Candeias and Carlos F. Barbas, III pp 5574–5575 DOI: 10.1021/ja101032j Supporting Info

Atomic-Level Pd−Pt Alloying and Largely Enhanced Hydrogen-Storage Capacity in Bimetallic Nanoparticles Reconstructed from Core/Shell Structure by a Process of Hydrogen Absorption/Desorption Hirokazu Kobayashi, Miho Yamauchi, Hiroshi Kitagawa, Yoshiki Kubota, Kenichi Kato and Masaki Takata pp 5576–5577 DOI: 10.1021/ja1013163 Supporting Info

Tuning MOF CO2 Adsorption Properties via Cation Exchange Jihyun An and Nathaniel L. Rosi pp 5578–5579 DOI: 10.1021/ja1012992 Supporting Info

Gold(I)-Mediated C−H Activation of Arenes Pengfei Lu, Tanya C. Boorman, Alexandra M. Z. Slawin and Igor Larrosa pp 5580–5581 DOI: 10.1021/ja101525w Supporting Info

Ru-Porphyrin Protein Scaffolds for Sensing O2 Michael B. Winter, Emily J. McLaurin, Steven Y. Reece, Charles Olea, Jr., Daniel G. Nocera and Michael A. Marletta pp 5582–5583 DOI: 10.1021/ja101527r Supporting Info

Measurement of the Intramolecular Isotope Effect on Aliphatic Hydroxylation by Chromobacterium violaceum Phenylalanine Hydroxylase Aram J. Panay and Paul F. Fitzpatrick pp 5584–5585 DOI: 10.1021/ja101563t

Non-, Micro-, and Mesoporous Metal−Organic Framework Isomers: Reversible Transformation, Fluorescence Sensing, and Large Molecule Separation Hai-Long Jiang, Yoshiro Tatsu, Zhang-Hui Lu and Qiang Xu pp 5586–5587 DOI: 10.1021/ja101541s Supporting Info

Highly Diastereoselective Preparation of Homoallylic Alcohols Containing Two Contiguous Quaternary Stereocenters in Acyclic Systems from Simple Terminal Alkynes Bishnu Dutta, Noga Gilboa and Ilan Marek pp 5588–5589 DOI: 10.1021/ja101371x Supporting Info

Brønsted Acid-Catalyzed Cascade Cycloisomerization of Enynes via Acetylene Cations and sp3-Hybridized C−H Bond Activation Tienan Jin, Masafumi Himuro and Yoshinori Yamamoto pp 5590–5591 DOI: 10.1021/ja101633x Supporting Info

Aqueous Synthesis of Zinc Blende CdTe/CdS Magic-Core/Thick-Shell Tetrahedral-Shaped Nanocrystals with Emission Tunable to Near-Infrared Zhengtao Deng, Olaf Schulz, Su Lin, Baoquan Ding, Xiaowei Liu, XiXi Wei, Robert Ros, Hao Yan and Yan Liu pp 5592–5593 DOI: 10.1021/ja101476b Supporting Info

Ultrafast Dynamics of the Low-Lying 3MLCT States of [Ru(bpy)2(dppp2)]2+ Yujie Sun, Yao Liu and Claudia Turro pp 5594–5595 DOI: 10.1021/ja101703w Supporting Info

Membrane Lipids Influence Protein Complex Assembly−Disassembly Leah Shin, Won Jin Cho, Jeremy D. Cook, Timothy L. Stemmler and Bhanu P. Jena pp 5596–5597 DOI: 10.1021/ja101574d Supporting Info

Chiral Kagome Network from Thiacalix[4]arene Tetrasulfonate at the Interface of Aqueous Solution/Au(111) Surface: An in Situ Electrochemical Scanning Tunneling Microscopy Study Ting Chen, Qing Chen, Xu Zhang, Dong Wang and Li-Jun Wan pp 5598–5599 DOI: 10.1021/ja101598p Supporting Info

Borinium Cations as σ-B−H Ligands in Osmium Complexes Miguel A. Esteruelas, Francisco J. Fernndez-Alvarez, Ana M. Lpez, Malka Mora and Enrique Oate pp 5600–5601 DOI: 10.1021/ja101806x Supporting Info

Ionic Liquids: Nondestructive, Nonvolatile Imaging Fluids for Submicrometer-Scale Monolayer Patterns Atsushi Hozumi, Pei Bien and Thomas J. McCarthy pp 5602–5603 DOI: 10.1021/ja102044x

Visualization of Polymer Chain Conformations in Amorphous Polyisocyanide Langmuir−Blodgett Films by Atomic Force Microscopy Jiro Kumaki, Takashi Kajitani, Kanji Nagai, Kento Okoshi and Eiji Yashima pp 5604–5606 DOI: 10.1021/ja908426u Supporting Info

Toward Flexibility−Activity Relationships by NMR Spectroscopy: Dynamics of Pin1 Ligands Andrew T. Namanja, Xiaodong J. Wang, Bailing Xu, Ana Y. Mercedes-Camacho, Brian D. Wilson, Kimberly A. Wilson, Felicia A. Etzkorn and Jeffrey W. Peng pp 5607–5609 DOI: 10.1021/ja9096779 Supporting Info

Prokaryotic Ubiquitin-like Protein (Pup) Is Coupled to Substrates via the Side Chain of Its C-Terminal Glutamate Markus Sutter, Fred F. Damberger, Frank Imkamp, Frdric H.-T. Allain and Eilika Weber-Ban pp 5610–5612 DOI: 10.1021/ja910546x Supporting Info

Synthesis and Characterization of Cadmium Phosphide Quantum Dots Emitting in the Visible Red to Near-Infrared Shiding Miao, Stephen G. Hickey, Bernd Rellinghaus, Christian Waurisch and Alexander Eychmller pp 5613–5615 DOI: 10.1021/ja9105732 Supporting Info

Infrared Signature and Folding Dynamics of a Helical β-Peptide Geronda Montalvo, Matthias M. Waegele, Scott Shandler, Feng Gai and William F. DeGrado pp 5616–5618 DOI: 10.1021/ja100459a Supporting Info

Design of an Encodable Tyrosine Kinase-Inducible Domain: Detection of Tyrosine Kinase Activity by Terbium Luminescence Susan Carr Zondlo, Feng Gao and Neal J. Zondlo pp 5619–5621 DOI: 10.1021/ja100862u Supporting Info

Imaging Structure Sensitive Catalysis on Different Shape-Controlled Platinum Nanoparticles Carlos M. Snchez-Snchez, Jos Solla-Gulln, Francisco J. Vidal-Iglesias, Antonio Aldaz, Vicente Montiel and Enrique Herrero pp 5622–5624 DOI: 10.1021/ja100922h Supporting Info

Stereoselective Construction of Halogenated Quaternary Stereogenic Centers via Catalytic Asymmetric Diels−Alder Reaction Kazutaka Shibatomi, Kentaro Futatsugi, Fumito Kobayashi, Seiji Iwasa and Hisashi Yamamoto pp 5625–5627 DOI: 10.1021/ja1018628 Supporting Info

Lipid−Protein Nanodiscs as Reference Medium in Detergent Screening for High-Resolution NMR Studies of Integral Membrane Proteins Zakhar O. Shenkarev, Ekaterina N. Lyukmanova, Alexander S. Paramonov, Lyudmila N. Shingarova, Vladimir V. Chupin, Mikhail P. Kirpichnikov, Marcel J. J. Blommers and Alexander S. Arseniev pp 5628–5629 DOI: 10.1021/ja9097498 Supporting Info

NMR Structural and Dynamical Investigation of the Isolated Voltage-Sensing Domain of the Potassium Channel KvAP: Implications for Voltage Gating Zakhar O. Shenkarev, Alexander S. Paramonov, Ekaterina N. Lyukmanova, Lyudmila N. Shingarova, Sergei A. Yakimov, Maxim A. Dubinnyi, Vladimir V. Chupin, Mikhail P. Kirpichnikov, Marcel J. J. Blommers and Alexander S. Arseniev pp 5630–5637 DOI: 10.1021/ja909752r Supporting Info

“Chain-Like” Trimetallic Ruthenium Complexes with C7 Carbon-Rich Bridges: Experimental and Theoretical Investigations of Electronic Communication Tuning in Five Distinct Oxidation States Cline Olivier, Karine Costuas, Sylvie Choua, Vincent Maurel, Philippe Turek, Jean-Yves Saillard, Daniel Touchard and Stphane Rigaut pp 5638–5651 DOI: 10.1021/ja908948g Supporting Info

1H NMR, Mechanism, and Mononuclear Oxidative Activity of the Antibiotic Metallopeptide Bacitracin: The Role of d-Glu-4, Interaction with Pyrophosphate Moiety, DNA Binding and Cleavage, and Bioactivity William M. Tay, Jon D. Epperson, Giordano F. Z. da Silva and Li-June Ming pp 5652–5661 DOI: 10.1021/ja910504t

Multiple Nonstoichiometric Phases with Discrete Composition Ranges in the CaAu5−CaAu4Bi−BiAu2 System. A Case Study of the Chemistry of Spinodal Decomposition Qisheng Lin and John D. Corbett pp 5662–5671 DOI: 10.1021/ja100250d Supporting Info

NMR-Based Structural Modeling of Graphite Oxide Using Multidimensional 13C Solid-State NMR and ab Initio Chemical Shift Calculations Leah B. Casabianca, Medhat A. Shaibat, Weiwei W. Cai, Sungjin Park, Richard Piner, Rodney S. Ruoff and Yoshitaka Ishii pp 5672–5676 DOI: 10.1021/ja9030243 Supporting Info

Uncovering the Design Rules for Peptide Synthesis of Metal Nanoparticles Yen Nee Tan, Jim Yang Lee and Daniel I. C. Wang pp 5677–5686 DOI: 10.1021/ja907454f Supporting Info

Aging of Rubrene Layers in Ni/Rubrene Heterostructures Studied by Magneto-Optical Kerr Effect Spectroscopy Wen Li, Michael Fronk, Hartmut Kupfer, Steffen Schulze, Michael Hietschold, Dietrich R. T. Zahn and Georgeta Salvan pp 5687–5692 DOI: 10.1021/ja907728y Supporting Info

Protein Fluctuations as the Possible Origin of the Thermal Activation of Rod Photoreceptors in the Dark Vctor A. Lrenz-Fonfra, Yuji Furutani, Toru Ota, Kazutomo Ido and Hideki Kandori pp 5693–5703 DOI: 10.1021/ja907756e Supporting Info

Half-Metallic Ferromagnetism and Large Negative Magnetoresistance in the New Lacunar Spinel GaTi3VS8 Eugen Dorolti, Laurent Cario, Benot Corraze, Etienne Janod, Cristian Vaju, Hyun-Joo Koo, Erjun Kan and Myung-Hwan Whangbo pp 5704–5710 DOI: 10.1021/ja908128b Supporting Info

How Active-Site Protonation State Influences the Reactivity and Ligation of the Heme in Chlorite Dismutase Bennett R. Streit, Batrice Blanc, Gudrun S. Lukat-Rodgers, Kenton R. Rodgers and Jennifer L. DuBois pp 5711–5724 DOI: 10.1021/ja9082182 Supporting Info

Surface-Initiated Polymerization of Superhydrophobic Polymethylene Juan C. Tuberquia, Nabijan Nizamidin, Robert R. Harl, Jake Albert, Jason Hunter, Bridget R. Rogers and G. Kane Jennings pp 5725–5734 DOI: 10.1021/ja9086193 Supporting Info

Structure of π−π Interactions in Aromatic Liquids Thomas F. Headen, Christopher A. Howard, Neal T. Skipper, Michael A. Wilkinson, Daniel T. Bowron and Alan K. Soper pp 5735–5742 DOI: 10.1021/ja909084e

Ultrathin n-Type Organic Nanoribbons with High Photoconductivity and Application in Optoelectronic Vapor Sensing of Explosives Yanke Che, Xiaomei Yang, Guilin Liu, Chun Yu, Hongwei Ji, Jianmin Zuo, Jincai Zhao and Ling Zang pp 5743–5750 DOI: 10.1021/ja909797q Supporting Info

FexPb4−xSb4Se10: A New Class of Ferromagnetic Semiconductors with Quasi 1D {Fe2Se10} Ladders Pierre F. P. Poudeu, Nathan Takas, Clarence Anglin, James Eastwood and Arianna Rivera pp 5751–5760 DOI: 10.1021/ja910545e Supporting Info

What the Cell “Sees” in Bionanoscience Dorota Walczyk, Francesca Baldelli Bombelli, Marco P. Monopoli, Iseult Lynch and Kenneth A. Dawson pp 5761–5768 DOI: 10.1021/ja910675v Supporting Info

Molecular Basis of Coupled Protein and Electron Transfer Dynamics of Cytochrome c in Biomimetic Complexes Damin Alvarez-Paggi, Diego F. Martn, Pablo M. DeBiase, Peter Hildebrandt, Marcelo A. Mart and Daniel H. Murgida pp 5769–5778 DOI: 10.1021/ja910707r Supporting Info

Proton-Evolved Local-Field Solid-State NMR Studies of Cytochrome b5 Embedded in Bicelles, Revealing both Structural and Dynamical Information Ronald Soong, Pieter E. S. Smith, Jiadi Xu, Kazutoshi Yamamoto, Sang-Choul Im, Lucy Waskell and Ayyalusamy Ramamoorthy pp 5779–5788 DOI: 10.1021/ja910807e

Oxidation of Titanium-Decorated Single-Walled Carbon Nanotubes and Subsequent Reduction by Lithium Ich C. Tran, Roberto Flix, Marcus Br, Lothar Weinhardt, Yufeng Zhang and Clemens Heske pp 5789–5792 DOI: 10.1021/ja910976k

Decoding Circulating Nucleic Acids in Human Serum Using Microfluidic Single Molecule Spectroscopy Kelvin J. Liu, Malcolm V. Brock, Ie-Ming Shih and Tza-Huei Wang pp 5793–5798 DOI: 10.1021/ja100342q Supporting Info

Automated Chemical Crystallography Amy L. Fuller, Lindesay A. S. Scott-Hayward, Yang Li, Michael Bhl, Alexandra M. Z. Slawin and J. Derek Woollins pp 5799–5802 DOI: 10.1021/ja100247y Supporting Info

Changes in Transmembrane Helix Alignment by Arginine Residues Revealed by Solid-State NMR Experiments and Coarse-Grained MD Simulations Vitaly V. Vostrikov, Benjamin A. Hall, Denise V. Greathouse, Roger E. Koeppe, II and Mark S. P. Sansom pp 5803–5811 DOI: 10.1021/ja100598e Supporting Info

The Influence of Spin Effects on the Gas Phase Reactions of Carbanions with N and O Atoms Zhibo Yang, Brian Eichelberger, Oscar Martinez, Jr., Momir Stepanovic, Theodore P. Snow and Veronica M. Bierbaum pp 5812–5819 DOI: 10.1021/ja100673z Supporting Info

Protein Knockdown Using Methyl Bestatin−Ligand Hybrid Molecules: Design and Synthesis of Inducers of Ubiquitination-Mediated Degradation of Cellular Retinoic Acid-Binding Proteins Yukihiro Itoh, Minoru Ishikawa, Mikihiko Naito and Yuichi Hashimoto pp 5820–5826 DOI: 10.1021/ja100691p Supporting Info

A Calix[4]arene Strapped Calix[4]pyrrole: An Ion-Pair Receptor Displaying Three Different Cesium Cation Recognition Modes Sung Kuk Kim, Jonathan L. Sessler, Dustin E. Gross, Chang-Hee Lee, Jong Seung Kim, Vincent M. Lynch, Lætitia H. Delmau and Benjamin P. Hay pp 5827–5836 DOI: 10.1021/ja100715e Supporting Info

Palladium-Catalyzed Ortho-Arylation of O-Phenylcarbamates with Simple Arenes and Sodium Persulfate Xiaodan Zhao, Charles S. Yeung and Vy M. Dong pp 5837–5844 DOI: 10.1021/ja100783c Supporting Info

Topochemistry and Photomechanical Effects in Crystals of Green Fluorescent Protein-like Chromophores: Effects of Hydrogen Bonding and Crystal Packing Pane Naumov, Janusz Kowalik, Kyril M. Solntsev, Anthony Baldridge, Jong-Seok Moon, Christine Kranz and Laren M. Tolbert pp 5845–5857 DOI: 10.1021/ja100844m Supporting Info

Efficient Nonsacrificial Water Splitting through Two-Step Photoexcitation by Visible Light using a Modified Oxynitride as a Hydrogen Evolution Photocatalyst Kazuhiko Maeda, Masanobu Higashi, Daling Lu, Ryu Abe and Kazunari Domen pp 5858–5868 DOI: 10.1021/ja1009025 Supporting Info

Synthesis, Structural Investigations, Hydrogen−Deuterium Exchange Studies, and Molecular Modeling of Conformationally Stablilized Aromatic Oligoamides Yan Yan, Bo Qin, Changliang Ren, Xiuying Chen, Yeow Kwan Yip, Ruijuan Ye, Dawei Zhang, Haibin Su and Huaqiang Zeng pp 5869–5879 DOI: 10.1021/ja100579z Supporting Info

Effect of Stalling after Mismatches on the Error Catastrophe in Nonenzymatic Nucleic Acid Replication Sudha Rajamani, Justin K. Ichida, Tibor Antal, Douglas A. Treco, Kevin Leu, Martin A. Nowak, Jack W. Szostak and Irene A. Chen pp 5880–5885 DOI: 10.1021/ja100780p Supporting Info

Oxidation Catalysis of Nb(salan) Complexes: Asymmetric Epoxidation of Allylic Alcohols Using Aqueous Hydrogen Peroxide as an Oxidant Hiromichi Egami, Takuya Oguma and Tsutomu Katsuki pp 5886–5895 DOI: 10.1021/ja100795k Supporting Info

Yb@C2n (n = 40, 41, 42): New Fullerene Allotropes with Unexplored Electrochemical Properties Xing Lu, Zdenek Slanina, Takeshi Akasaka, Takahiro Tsuchiya, Naomi Mizorogi and Shigeru Nagase pp 5896–5905 DOI: 10.1021/ja101131e Supporting Info

A Palette of Fluorescent Probes with Varying Emission Colors for Imaging Hydrogen Peroxide Signaling in Living Cells Bryan C. Dickinson, Calvin Huynh and Christopher J. Chang pp 5906–5915 DOI: 10.1021/ja1014103 Supporting Info

Pd(II)-Catalyzed Hydroxyl-Directed C−H Olefination Enabled by Monoprotected Amino Acid Ligands Yi Lu, Dong-Hui Wang, Keary M. Engle and Jin-Quan Yu pp 5916–5921 DOI: 10.1021/ja101909t Supporting Info

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides Takeru Furuya, Diego Benitez, Ekaterina Tkatchouk, Alexandra E. Strom, Pingping Tang, William A. Goddard, III and Tobias Ritter p 5922 DOI: 10.1021/ja102348w

Application of the Lithiation−Borylation Reaction to the Preparation of Enantioenriched Allylic Boron Reagents and Subsequent in Situ Conversion into 1,2,4-Trisubstituted Homoallylic Alcohols with Complete Control over All Elements of Stereochemistry Martin Althaus, Adeem Mahmood, Jos Ramn Surez, Stephen P. Thomas and Varinder K. Aggarwal p 5922 DOI: 10.1021/ja102041s Supporting Info

Issue 17

Synthesis of (+)-Complanadine A, an Inducer of Neurotrophic Factor Excretion Changxia Yuan, Chih-Tsung Chang, Abram Axelrod and Dionicio Siegel pp 5924–5925 DOI: 10.1021/ja101956x Supporting Info

Total Synthesis of (+)-Complanadine A Using an Iridium-Catalyzed Pyridine C−H Functionalization Daniel F. Fischer and Richmond Sarpong pp 5926–5927 DOI: 10.1021/ja101893b Supporting Info

One-Pot Enantioselective Extraction of Chiral Fullerene C76 Using a Cyclic Host Carrying an Asymmetrically Distorted, Highly π-Basic Porphyrin Module Yoshiaki Shoji, Kentaro Tashiro and Takuzo Aida pp 5928–5929 DOI: 10.1021/ja910701q Supporting Info

Use of a Robust Dehydrogenase from an Archael Hyperthermophile in Asymmetric Catalysis−Dynamic Reductive Kinetic Resolution Entry into (S)-Profens Jacob A. Friest, Yukari Maezato, Sylvain Broussy, Paul Blum and David B. Berkowitz pp 5930–5931 DOI: 10.1021/ja910778p Supporting Info

Native Laser Lithography of His-Tagged Proteins by Uncaging of Multivalent Chelators Maniraj Bhagawati, Suman Lata, Robert Tamp and Jacob Piehler pp 5932–5933 DOI: 10.1021/ja1000714 Supporting Info

Modulation of T2 Relaxation Time by Light-Induced, Reversible Aggregation of Magnetic Nanoparticles Elizabeth A. Osborne, Benjamin R. Jarrett, Chuqiao Tu and Angelique Y. Louie pp 5934–5935 DOI: 10.1021/ja100254m Supporting Info

A Xenon-Based Molecular Sensor Assembled on an MS2 Viral Capsid Scaffold Tyler Meldrum, Kristen L. Seim, Vikram S. Bajaj, Krishnan K. Palaniappan, Wesley Wu, Matthew B. Francis, David E. Wemmer and Alexander Pines pp 5936–5937 DOI: 10.1021/ja100319f Supporting Info

Development of Highly Sensitive Fluorescent Probes for Detection of Intracellular Copper(I) in Living Systems Masayasu Taki, Shohei Iyoshi, Akio Ojida, Itaru Hamachi and Yukio Yamamoto pp 5938–5939 DOI: 10.1021/ja100714p Supporting Info

Solid-State NMR Spectroscopy of Oriented Membrane Polypeptides at 100 K with Signal Enhancement by Dynamic Nuclear Polarization Evgeniy Salnikov, Melanie Rosay, Shane Pawsey, Olivier Ouari, Paul Tordo and Burkhard Bechinger pp 5940–5941 DOI: 10.1021/ja1007646 Supporting Info

HYSCORE Evidence That Endogenous Mena- and Ubisemiquinone Bind at the Same Q Site (QD) of Escherichia coli Nitrate Reductase A Rodrigo Arias-Cartin, Sevdalina Lyubenova, Pierre Ceccaldi, Thomas Prisner, Axel Magalon, Bruno Guigliarelli and Stphane Grimaldi pp 5942–5943 DOI: 10.1021/ja1009234 Supporting Info

Synthesis of Large, Stable Colloidal Graphene Quantum Dots with Tunable Size Xin Yan, Xiao Cui and Liang-shi Li pp 5944–5945 DOI: 10.1021/ja1009376 Supporting Info

Synthesis and Optical Properties of Monolayer Organosilicon Nanosheets Yusuke Sugiyama, Hirotaka Okamoto, Takuya Mitsuoka, Takeshi Morikawa, Koji Nakanishi, Toshiaki Ohta and Hideyuki Nakano pp 5946–5947 DOI: 10.1021/ja100919d Supporting Info

Liposomes Remain Intact When Complexed with Polycationic Brushes Alexander A. Yaroslavov, Andrei V. Sybachin, Marc Schrinner, Matthias Ballauff, Larisa Tsarkova, Ellina Kesselman, Judith Schmidt, Yeshayahu Talmon and Fredric M. Menger pp 5948–5949 DOI: 10.1021/ja1012323 Supporting Info

Cationic Silane σ-Complexes of Ruthenium with Relevance to Catalysis Dmitry V. Gutsulyak, Sergei F. Vyboishchikov and Georgii I. Nikonov pp 5950–5951 DOI: 10.1021/ja101583m Supporting Info

Ambient-Processed Colloidal Quantum Dot Solar Cells via Individual Pre-Encapsulation of Nanoparticles Ratan Debnath, Jiang Tang, D. Aaron Barkhouse, Xihua Wang, Andras G. Pattantyus-Abraham, Lukasz Brzozowski, Larissa Levina and Edward H. Sargent pp 5952–5953 DOI: 10.1021/ja1013695

RNA-Binding to Archaeal RNA Polymerase Subunits F/E: A DEER and FRET Study Dina Grohmann, Daniel Klose, Johann P. Klare, Christopher W. M. Kay, Heinz-Jrgen Steinhoff and Finn Werner pp 5954–5955 DOI: 10.1021/ja101663d

Polyoxometalatocyclophanes: Controlled Assembly of Polyoxometalate-Based Chiral Metallamacrocycles from Achiral Building Blocks Fengping Xiao, Jian Hao, Jin Zhang, Chunlin Lv, Panchao Yin, Longsheng Wang and Yongge Wei pp 5956–5957 DOI: 10.1021/ja101671q Supporting Info

An “End-On” Chromium(III)-Superoxo Complex: Crystallographic and Spectroscopic Characterization and Reactivity in C−H Bond Activation of Hydrocarbons Jaeheung Cho, Jaeyoung Woo and Wonwoo Nam pp 5958–5959 DOI: 10.1021/ja1015926 Supporting Info

High-Yield Synthesis of Monodisperse Dumbbell-Shaped Polymer Nanoparticles Jin-Gyu Park, Jason D. Forster and Eric R. Dufresne pp 5960–5961 DOI: 10.1021/ja101760q Supporting Info

Regio- and Stereocontrol in Rhenium-Catalyzed Transposition of Allylic Alcohols Aaron T. Herrmann, Tatsuo Saito, Craig E. Stivala, Janine Tom and Armen Zakarian pp 5962–5963 DOI: 10.1021/ja101673v Supporting Info

Epitaxial CdTe Rods on Au/Si Islands from a Molecular Compound Kibriya Ahmad, Mohammad Afzaal, Jamie S. Ritch, Tristram Chivers and Paul O’Brien pp 5964–5965 DOI: 10.1021/ja1017943 Supporting Info

Total Synthesis of (−)-Anominine Ben Bradshaw, Gorka Etxebarria-Jard and Josep Bonjoch pp 5966–5967 DOI: 10.1021/ja101994q Supporting Info

An Alternative Approach to Aldol Reactions: Gold-Catalyzed Formation of Boron Enolates from Alkynes Cindy Krner, Pavel Starkov and Tom D. Sheppard pp 5968–5969 DOI: 10.1021/ja102129c Supporting Info

N-Heterocyclic Carbene-Catalyzed Cascade Reaction Involving the Hydroacylation of Unactivated Alkynes Akkattu T. Biju, Nathalie E. Wurz and Frank Glorius pp 5970–5971 DOI: 10.1021/ja102130s Supporting Info

Phosphopantetheinyl Transferase-Catalyzed Formation of Bioactive Hydrogels for Tissue Engineering Katarzyna A. Mosiewicz, Kai Johnsson and Matthias P. Lutolf pp 5972–5974 DOI: 10.1021/ja9098164 Supporting Info

Intracellular Bioconjugation of Targeted Proteins with Semiconductor Quantum Dots Kelly Boeneman, James B. Delehanty, Kimihiro Susumu, Michael H. Stewart and Igor L. Medintz pp 5975–5977 DOI: 10.1021/ja100201w Supporting Info

Intramolecular π-Stacking in a Phenylpyrazole-Based Iridium Complex and Its Use in Light-Emitting Electrochemical Cells Rubn D. Costa, Enrique Ort, Henk J. Bolink, Stefan Graber, Catherine E. Housecroft and Edwin C. Constable pp 5978–5980 DOI: 10.1021/ja1010674 Supporting Info

Charge Separation in Type II Tunneling Multilayered Structures of CdTe and CdSe Nanocrystals Directly Proven by Surface Photovoltage Spectroscopy Dieter Gross, Ivn Mora-Ser, Thomas Dittrich, Abdelhak Belaidi, Christian Mauser, Arjan J. Houtepen, Enrico Da Como, Andrey L. Rogach and Jochen Feldmann pp 5981–5983 DOI: 10.1021/ja101629c

The Impact of the Size of Dynamic Combinatorial Libraries on the Detectability of Molecular Recognition Induced Amplification R. Frederick Ludlow and Sijbren Otto pp 5984–5986 DOI: 10.1021/ja1013689 Supporting Info

Direct Use of 15N Relaxation Rates as Experimental Restraints on Molecular Shape and Orientation for Docking of Protein−Protein Complexes Yaroslav Ryabov, G. Marius Clore and Charles D. Schwieters pp 5987–5989 DOI: 10.1021/ja101842n Supporting Info

Stereospecific Synthesis of Cyclobutylboronates through Copper(I)-Catalyzed Reaction of Homoallylic Sulfonates and a Diboron Derivative Hajime Ito, Takashi Toyoda and Masaya Sawamura pp 5990–5992 DOI: 10.1021/ja101793a Supporting Info

Time Averaging of NMR Chemical Shifts in the MLF Peptide in the Solid State Itzam De Gortari, Guillem Portella, Xavier Salvatella, Vikram S. Bajaj, Patrick C. A. van der Wel, Jonathan R. Yates, Matthew D. Segall, Chris J. Pickard, Mike C. Payne and Michele Vendruscolo pp 5993–6000 DOI: 10.1021/ja9062629 Supporting Info

Nature of Intermediates in Organo-SOMO Catalysis of α-Arylation of Aldehydes Joann M. Um, Osvaldo Gutierrez, Franziska Schoenebeck, K. N. Houk and David W. C. MacMillan pp 6001–6005 DOI: 10.1021/ja9063074 Supporting Info

Similar Topological Origin of Chiral Centers in Organic and Nanoscale Inorganic Structures: Effect of Stabilizer Chirality on Optical Isomerism and Growth of CdTe Nanocrystals Yunlong Zhou, Ming Yang, Kai Sun, Zhiyong Tang and Nicholas A. Kotov pp 6006–6013 DOI: 10.1021/ja906894r Supporting Info

Ab Inito Modeling of Ethylbenzene Dehydrogenase Reaction Mechanism Maciej Szaleniec, Tomasz Borowski, Karola Schhle, Malgorzata Witko and Johann Heider pp 6014–6024 DOI: 10.1021/ja907208k Supporting Info

A Synthetic Coiled-Coil Interactome Provides Heterospecific Modules for Molecular Engineering Aaron W. Reinke, Robert A. Grant and Amy E. Keating pp 6025–6031 DOI: 10.1021/ja907617a Supporting Info

Oxidation State, Aggregation, and Heterolytic Dissociation of Allyl Indium Reagents Konrad Koszinowski pp 6032–6040 DOI: 10.1021/ja908101j Supporting Info

Tuning Supramolecular Rigidity of Peptide Fibers through Molecular Structure E. Thomas Pashuck, Honggang Cui and Samuel I. Stupp pp 6041–6046 DOI: 10.1021/ja908560n Supporting Info

Enhanced Ion Anisotropy by Nonconventional Coordination Geometry: Single-Chain Magnet Behavior for a [{FeIIL}2{NbIV(CN)8}] Helical Chain Compound Designed with Heptacoordinate FeII Thengarai S. Venkatakrishnan, Shaon Sahoo, Nicolas Brfuel, Carine Duhayon, Carley Paulsen, Anne-Laure Barra, S. Ramasesha and Jean-Pascal Sutter pp 6047–6056 DOI: 10.1021/ja9089389 Supporting Info

Systematic Perturbation of the Trinuclear Copper Cluster in the Multicopper Oxidases: The Role of Active Site Asymmetry in Its Reduction of O2 to H2O Anthony J. Augustine, Christian Kjaergaard, Munzarin Qayyum, Lynn Ziegler, Daniel J. Kosman, Keith O. Hodgson, Britt Hedman and Edward I. Solomon pp 6057–6067 DOI: 10.1021/ja909143d Supporting Info

Impact of Assembly State on the Defect Tolerance of TMV-Based Light Harvesting Arrays Rebekah A. Miller, Nicholas Stephanopoulos, Jesse M. McFarland, Andrew S. Rosko, Phillip L. Geissler and Matthew B. Francis pp 6068–6074 DOI: 10.1021/ja909566z Supporting Info

Suborganelle Sensing of Mitochondrial cAMP-Dependent Protein Kinase Activity Richard S. Agnes, Finith Jernigan, Jennifer R. Shell, Vyas Sharma and David S. Lawrence pp 6075–6080 DOI: 10.1021/ja909652q Supporting Info

High-Resolution Spectral Analysis of Individual SERS-Active Nanoparticles in Flow Gregory Goddard, Leif O. Brown, Robb Habbersett, Christina I. Brady, John C. Martin, Steven W. Graves, James P. Freyer and Stephen K. Doorn pp 6081–6090 DOI: 10.1021/ja909850s Supporting Info

Effect of Heme Modification on Oxygen Affinity of Myoglobin and Equilibrium of the Acid−Alkaline Transition in Metmyoglobin Tomokazu Shibata, Satoshi Nagao, Masashi Fukaya, Hulin Tai, Shigenori Nagatomo, Kenji Morihashi, Takashi Matsuo, Shun Hirota, Akihiro Suzuki, Kiyohiro Imai and Yasuhiko Yamamoto pp 6091–6098 DOI: 10.1021/ja909891q Supporting Info

Turning on Resonant SERRS Using the Chromophore−Plasmon Coupling Created by Host−Guest Complexation at a Plasmonic Nanoarray Edward H. Witlicki, Sissel S. Andersen, Stinne W. Hansen, Jan O. Jeppesen, Eric W. Wong, Lasse Jensen and Amar H. Flood pp 6099–6107 DOI: 10.1021/ja910155b Supporting Info

Solution-Processable Low-Molecular Weight Extended Arylacetylenes: Versatile p-Type Semiconductors for Field-Effect Transistors and Bulk Heterojunction Solar Cells Fabio Silvestri, Assunta Marrocchi, Mirko Seri, Choongik Kim, Tobin J. Marks, Antonio Facchetti and Aldo Taticchi pp 6108–6123 DOI: 10.1021/ja910420t Supporting Info

Constructing Hierarchical Spheres from Large Ultrathin Anatase TiO2 Nanosheets with Nearly 100% Exposed (001) Facets for Fast Reversible Lithium Storage Jun Song Chen, Yi Ling Tan, Chang Ming Li, Yan Ling Cheah, Deyan Luan, Srinivasan Madhavi, Freddy Yin Chiang Boey, Lynden A. Archer and Xiong Wen Lou pp 6124–6130 DOI: 10.1021/ja100102y

Synthesis, Self-Assembly, Disassembly, and Reassembly of Two Types of Cu2O Nanocrystals Unifaceted with {001} or {110} Planes Ke Xin Yao, Xiao Ming Yin, Tai Hong Wang and Hua Chun Zeng pp 6131–6144 DOI: 10.1021/ja100151f Supporting Info

Quantification of the 2-Deoxyribonolactone and Nucleoside 5′-Aldehyde Products of 2-Deoxyribose Oxidation in DNA and Cells by Isotope-Dilution Gas Chromatography Mass Spectrometry: Differential Effects of γ-Radiation and Fe2+−EDTA Wan Chan, Bingzi Chen, Lianrong Wang, Koli Taghizadeh, Michael S. Demott and Peter C. Dedon pp 6145–6153 DOI: 10.1021/ja910928n Supporting Info

Charge Generation and Recombination Dynamics in Poly(3-hexylthiophene)/Fullerene Blend Films with Different Regioregularities and Morphologies Jiamo Guo, Hideo Ohkita, Hiroaki Benten and Shinzaburo Ito pp 6154–6164 DOI: 10.1021/ja100302p Supporting Info

Photoinitiated Singlet and Triplet Electron Transfer across a Redesigned [Myoglobin, Cytochrome b5] Interface Judith M. Nocek, Amanda K. Knutson, Peng Xiong, Nadia Petlakh Co and Brian M. Hoffman pp 6165–6175 DOI: 10.1021/ja100499j Supporting Info

Solution and Solid-State Studies of Doubly Trimethylene-Bridged Tetraalkyl p-Phenylenediamine Diradical Dication Conformations Almaz S. Jalilov, Gaoquan Li, Stephen F. Nelsen, Ilia A. Guzei and Qin Wu pp 6176–6182 DOI: 10.1021/ja100322k Supporting Info

Activation and Deactivation of DNAzyme and Antisense Function with Light for the Photochemical Regulation of Gene Expression in Mammalian Cells Douglas D. Young, Mark O. Lively and Alexander Deiters pp 6183–6193 DOI: 10.1021/ja100710j Supporting Info

Effect of a Strong Interfacial Electric Field on the Orientation of the Dipole Moment of Thiolated Aib-Oligopeptides Tethered to Mercury on Either the N- or C-Terminus Lucia Becucci, Ivan Guryanov, Flavio Maran and Rolando Guidelli pp 6194–6204 DOI: 10.1021/ja100486y

Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions Gavin O. Jones, Peng Liu, K. N. Houk and Stephen L. Buchwald pp 6205–6213 DOI: 10.1021/ja100739h Supporting Info

Analyzing Protein Folding Cooperativity by Differential Scanning Calorimetry and NMR Spectroscopy Patrick Farber, Hariyanto Darmawan, Tara Sprules and Anthony Mittermaier pp 6214–6222 DOI: 10.1021/ja100815a Supporting Info

Accumulation of Fluorophores into DNA Duplexes To Mimic the Properties of Quantum Dots Hiromu Kashida, Koji Sekiguchi, Xingguo Liang and Hiroyuki Asanuma pp 6223–6230 DOI: 10.1021/ja101007d Supporting Info

Do [all]-S,S′-Dioxide Oligothiophenes Show Electronic and Optical Properties of Oligoenes and/or of Oligothiophenes? Mara Moreno Oliva, Juan Casado, Juan T. Lpez Navarrete, Serguei Patchkovskii, Theodore Goodson, III, Michael R. Harpham, J. Srgio Seixas de Melo, Elizabeta Amir and Shlomo Rozen pp 6231–6242 DOI: 10.1021/ja101015q Supporting Info

An Unusual Nickel−Copper-Mediated Alkyne Homocoupling Reaction for the Active-Template Synthesis of [2]Rotaxanes James D. Crowley, Stephen M. Goldup, Nicholas D. Gowans, David A. Leigh, Vicki E. Ronaldson and Alexandra M. Z. Slawin pp 6243–6248 DOI: 10.1021/ja101121j Supporting Info

Carbene-Metal Hydrides Can Be Much Less Acidic Than Phosphine-Metal Hydrides: Significance in Hydrogenations Ye Zhu, Yubo Fan and Kevin Burgess pp 6249–6253 DOI: 10.1021/ja101233g Supporting Info

Detection of the Sulfhydryl Groups in Proteins with Slow Hydrogen Exchange Rates and Determination of Their Proton/Deuteron Fractionation Factors Using the Deuterium-Induced Effects on the 13Cβ NMR Signals Mitsuhiro Takeda, JunGoo Jee, Tsutomu Terauchi and Masatsune Kainosho pp 6254–6260 DOI: 10.1021/ja101205j Supporting Info

Goldilocks Effect in Magnetic Bistability: Remote Substituent Modulation and Lattice Control of Photoinduced Valence Tautomerism and Light-Induced Thermal Hysteresis R. D. Schmidt, D. A. Shultz, J. D. Martin and P. D. Boyle pp 6261–6273 DOI: 10.1021/ja101957c Supporting Info

Chemically Modified Electrodes. Advances in Electrochemical Science and Engineering, Vol. 11 Waldemar Gorski p 6274 DOI: 10.1021/ja1023578

Nanoscience and Nanotechnology for Chemical and Biological Defense p 6274 DOI: 10.1021/ja1027875

Handbook of Transition Metal Polymerization Catalysts p 6274 DOI: 10.1021/ja102842d

Issue 18

Intramolecular Alkene Aminopalladation Reactions of (dppf)Pd(Ar)[N(Ar1)(CH2)3CH═CH2] Complexes. Insertion of Unactivated Alkenes into Pd−N Bonds Joshua D. Neukom, Nicholas S. Perch and John P. Wolfe pp 6276–6277 DOI: 10.1021/ja9102259 Supporting Info

A Discrete Quadruple-Decker Phthalocyanine Takamitsu Fukuda, Tsuneaki Biyajima and Nagao Kobayashi pp 6278–6279 DOI: 10.1021/ja100125e Supporting Info

One-Pot Protocol for Au-Based Hybrid Magnetic Nanostructures via a Noble-Metal-Induced Reduction Process Dingsheng Wang and Yadong Li pp 6280–6281 DOI: 10.1021/ja100845v Supporting Info

Metallosupramolecular Tetragonal Prisms via Multicomponent Coordination-Driven Template-Free Self-Assembly Ming Wang, Yao-Rong Zheng, Koushik Ghosh and Peter J. Stang pp 6282–6283 DOI: 10.1021/ja100889h Supporting Info

Palladium-Catalyzed Oxime Assisted Intramolecular Dioxygenation of Alkenes with 1 atm of Air as the Sole Oxidant Ming-Kui Zhu, Jun-Feng Zhao and Teck-Peng Loh pp 6284–6285 DOI: 10.1021/ja100716x Supporting Info

Direct Asymmetric Aldol Reaction of 5H-Oxazol-4-ones with Aldehydes Catalyzed by Chiral Guanidines Tomonori Misaki, Gouta Takimoto and Takashi Sugimura pp 6286–6287 DOI: 10.1021/ja101216x Supporting Info

Metabolon Catalyzed Pyruvate/Air Biofuel Cell Michael J. Moehlenbrock, Timothy K. Toby, Abdul Waheed and Shelley D. Minteer pp 6288–6289 DOI: 10.1021/ja101326b Supporting Info

Protein/Solvent Medium Effects on Mg2+−Carboxylate Interactions in Metalloenzymes C. Satheesan Babu and Carmay Lim pp 6290–6291 DOI: 10.1021/ja101494m Supporting Info

Self-Assembled Heterosupramolecular Visible Light Photocatalyst Consisting of Gold Nanoparticle-Loaded Titanium(IV) Dioxide and Surfactant Shin-ichi Naya, Aimi Inoue and Hiroaki Tada pp 6292–6293 DOI: 10.1021/ja101711j Supporting Info

Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation Yuanjian Zhang, Toshiyuki Mori, Jinhua Ye and Markus Antonietti pp 6294–6295 DOI: 10.1021/ja101749y Supporting Info

Synthesis and C−C Coupling Reactivity of a Dinuclear NiI−NiI Complex Supported by a Terphenyl Diphosphine Alexandra Velian, Sibo Lin, Alexander J. M. Miller, Michael W. Day and Theodor Agapie pp 6296–6297 DOI: 10.1021/ja101699a Supporting Info

Surface Plasmons Control the Dynamics of Excited Triplet States in the Presence of Gold Nanoparticles Natalia L. Pacioni, Mara Gonzlez-Bjar, Emilio Alarcn, Katherine L. McGilvray and J. C. Scaiano pp 6298–6299 DOI: 10.1021/ja101925d Supporting Info

Assembly of DNA-Functionalized Nanoparticles in Alcoholic Solvents Reveals Opposite Thermodynamic and Kinetic Trends for DNA Hybridization Brendan D. Smith and Juewen Liu pp 6300–6301 DOI: 10.1021/ja101973g Supporting Info

Intermolecular Insertion of Ethylene and Octene into a Palladium−Amide Bond. Spectroscopic Evidence for an Ethylene Amido Intermediate Patrick S. Hanley, Dean Markovi and John F. Hartwig pp 6302–6303 DOI: 10.1021/ja102172m Supporting Info

A General Strategy for Regiocontrol in Nickel-Catalyzed Reductive Couplings of Aldehydes and Alkynes Hasnain A. Malik, Grant J. Sormunen and John Montgomery pp 6304–6305 DOI: 10.1021/ja102262v Supporting Info

Direct Observation of Nucleation and Growth in Amyloid Self-Assembly Yan Liang, David G. Lynn and Keith M. Berland pp 6306–6308 DOI: 10.1021/ja910964c Supporting Info

Using Isotopic Tools to Dissect and Quantitate Parallel Metabolic Pathways Sushabhan Sadhukhan, Yong Han, Guo-Fang Zhang, Henri Brunengraber and Gregory P Tochtrop pp 6309–6311 DOI: 10.1021/ja100399m Supporting Info

Stabilization of Amine-Containing CO2 Adsorbents: Dramatic Effect of Water Vapor Abdelhamid Sayari and Youssef Belmabkhout pp 6312–6314 DOI: 10.1021/ja1013773 Supporting Info

High-Resolution Excitation and Absorption Spectroscopy of Gas-Phase p-Coumaric Acid: Unveiling an Elusive Chromophore Szymon Smolarek, Alexander Vdovin, Dayinta L. Perrier, Jorrit P. Smit, Marcel Drabbels and Wybren J. Buma pp 6315–6317 DOI: 10.1021/ja101668v Supporting Info

FRET-Enabled Optical Modulation for High Sensitivity Fluorescence Imaging Chris I. Richards, Jung-Cheng Hsiang, Andrew M. Khalil, Nathan P. Hull and Robert M. Dickson pp 6318–6323 DOI: 10.1021/ja100175r

Structural Variations in the Cross-β Core of Amyloid β Fibrils Revealed by Deep UV Resonance Raman Spectroscopy Ludmila A. Popova, Ravindra Kodali, Ronald Wetzel and Igor K. Lednev pp 6324–6328 DOI: 10.1021/ja909074j

Nacre Protein Fragment Templates Lamellar Aragonite Growth Rebecca A. Metzler, John Spencer Evans, Christopher E. Killian, Dong Zhou, Tyler H. Churchill, Narayana P. Appathurai, Susan N. Coppersmith and P. U. P. A. Gilbert pp 6329–6334 DOI: 10.1021/ja909735y Supporting Info

Variability in C3-Plant Cell-Wall Biosynthesis in a High-CO2 Atmosphere by Solid-State NMR Spectroscopy Tsyr-Yan Yu, Manmilan Singh, Shigeru Matsuoka, Gary J. Patti, Gregory S. Potter and Jacob Schaefer pp 6335–6341 DOI: 10.1021/ja909796y

Loading Pentapod Deca(organo)[60]fullerenes with Electron Donors: From Photophysics to Photoelectrochemical Bilayers Yutaka Matsuo, Takahiko Ichiki, Shankara Gayathri Radhakrishnan, Dirk M. Guldi and Eiichi Nakamura pp 6342–6348 DOI: 10.1021/ja909970h Supporting Info

Challenges Posed to Bornyl Diphosphate Synthase: Diverging Reaction Mechanisms in Monoterpenes Michal Weitman and Dan Thomas Major pp 6349–6360 DOI: 10.1021/ja910134x Supporting Info

Mechanism of Lithium Diisopropylamide-Mediated Substitution of 2,6-Difluoropyridine Mihai S. Viciu, Lekha Gupta and David B. Collum pp 6361–6365 DOI: 10.1021/ja910834b Supporting Info

X-ray Snapshot of HIV-1 Protease in Action: Observation of Tetrahedral Intermediate and Short Ionic Hydrogen Bond SIHB with Catalytic Aspartate Amit Das, Smita Mahale, Vishal Prashar, Subhash Bihani, J.-L. Ferrer and M. V. Hosur pp 6366–6373 DOI: 10.1021/ja100002b

Lysine and Arginine Side Chains in Glycosaminoglycan−Protein Complexes Investigated by NMR, Cross-Linking, and Mass Spectrometry: A Case Study of the Factor H−Heparin Interaction Brbel S. Blaum, Jon A. Deakin, Conny M. Johansson, Andrew P. Herbert, Paul N. Barlow, Malcolm Lyon and Duan Uhrn pp 6374–6381 DOI: 10.1021/ja1000517 Supporting Info

“Magnet-in-the-Semiconductor” FePt−PbS and FePt−PbSe Nanostructures: Magnetic Properties, Charge Transport, and Magnetoresistance Jong-Soo Lee, Maryna I. Bodnarchuk, Elena V. Shevchenko and Dmitri V. Talapin pp 6382–6391 DOI: 10.1021/ja100029s Supporting Info

Immobilizing Water-Soluble Dendritic Electron Donors and Electron Acceptors—Phthalocyanines and Perylenediimides—onto Single Wall Carbon Nanotubes Uwe Hahn, Sarah Engmann, Christian Oelsner, Christian Ehli, Dirk M. Guldi and Tomas Torres pp 6392–6401 DOI: 10.1021/ja100065h Supporting Info

A Three Enzyme Pathway for 2-Amino-3-hydroxycyclopent-2-enone Formation and Incorporation in Natural Product Biosynthesis Wenjun Zhang, Megan L. Bolla, Daniel Kahne and Christopher T. Walsh pp 6402–6411 DOI: 10.1021/ja1002845 Supporting Info

Tandem Processes Identified from Reaction Screening: Nucleophilic Addition to Aryl N-Phosphinylimines Employing La(III)-TFAA Activation Hidenori Kinoshita, Oscar J. Ingham, Winnie W. Ong, Aaron B. Beeler and John A. Porco, Jr. pp 6412–6418 DOI: 10.1021/ja100346w Supporting Info

Exploring Peptide Space for Enzyme Modulators Jinglin Fu, Katherine Cai, Stephen Albert Johnston and Neal W. Woodbury pp 6419–6424 DOI: 10.1021/ja100403a Supporting Info

Structural and Conformational Requisites in DNA Quadruplex Groove Binding: Another Piece to the Puzzle Sandro Cosconati, Luciana Marinelli, Roberta Trotta, Ada Virno, Stefano De Tito, Romeo Romagnoli, Bruno Pagano, Vittorio Limongelli, Concetta Giancola, Pier Giovanni Baraldi, Luciano Mayol, Ettore Novellino and Antonio Randazzo pp 6425–6433 DOI: 10.1021/ja1003872 Supporting Info

Vibrational Sum-Frequency Generation Spectroscopy at the Water/Lipid Interface: Molecular Dynamics Simulation Study Yuki Nagata and Shaul Mukamel pp 6434–6442 DOI: 10.1021/ja100508n

Soluble Chlorofullerenes C60Cl2,4,6,8,10. Synthesis, Purification, Compositional Analysis, Stability, and Experimental/Theoretical Structure Elucidation, Including the X-ray Structure of C1-C60Cl10 Igor V. Kuvychko, Alexey V. Streletskii, Natalia B. Shustova, Konrad Seppelt, Thomas Drewello, Alexey A. Popov, Steven H. Strauss and Olga V. Boltalina pp 6443–6462 DOI: 10.1021/ja1005256 Supporting Info

Efficient Bulky Phosphines for the Selective Telomerization of 1,3-Butadiene with Methanol Mathieu J.-L. Tschan, Eduardo J. Garca-Surez, Zoraida Freixa, Hlne Launay, Henk Hagen, Jordi Benet-Buchholz and Piet W. N. M. van Leeuwen pp 6463–6473 DOI: 10.1021/ja100521m Supporting Info

Solvation Response along the Reaction Coordinate in the Active Site of Ketosteroid Isomerase William Childs and Steven G. Boxer pp 6474–6480 DOI: 10.1021/ja1007849

Bright Monomeric Photoactivatable Red Fluorescent Protein for Two-Color Super-Resolution sptPALM of Live Cells Fedor V. Subach, George H. Patterson, Malte Renz, Jennifer Lippincott-Schwartz and Vladislav V. Verkhusha pp 6481–6491 DOI: 10.1021/ja100906g Supporting Info

Scaling Dopant States in a Semiconducting Nanostructure by Chemically Resolved Electron Energy-Loss Spectroscopy: A Case Study on Co-Doped ZnO Xuefeng Wang, Fengqi Song, Qian Chen, Tingyu Wang, Jinlan Wang, Peng Liu, Mingrong Shen, Jianguo Wan, Guanghou Wang and Jian-Bin Xu pp 6492–6497 DOI: 10.1021/ja100912k Supporting Info

Revealing Noncovalent Interactions Erin R. Johnson, Shahar Keinan, Paula Mori-Snchez, Julia Contreras-Garca, Aron J. Cohen and Weitao Yang pp 6498–6506 DOI: 10.1021/ja100936w Supporting Info

Transition State Analogue Structures of Human Phosphoglycerate Kinase Establish the Importance of Charge Balance in Catalysis Matthew J. Cliff, Matthew W. Bowler, Andrea Varga, James P. Marston, Judit Szab, Andrea M. Hounslow, Nicola J. Baxter, G. Michael Blackburn, Mria Vas and Jonathan P. Waltho pp 6507–6516 DOI: 10.1021/ja100974t Supporting Info

Ethoxycarbonyl-Based Organic Electrode for Li-Batteries Wesley Walker, Sylvie Grugeon, Olivier Mentre, Stphane Laruelle, Jean-Marie Tarascon and Fred Wudl pp 6517–6523 DOI: 10.1021/ja1012849 Supporting Info

Rational Synthesis of Heterostructured Nanoparticles with Morphology Control Chao Wang, Wende Tian, Yong Ding, Yu-qiang Ma, Zhong Lin Wang, Nenad M. Markovic, Vojislav R. Stamenkovic, Hideo Daimon and Shouheng Sun pp 6524–6529 DOI: 10.1021/ja101305x Supporting Info

Interfacial Free Energy Governs Single Polystyrene Chain Collapse in Water and Aqueous Solutions Isaac T. S. Li and Gilbert C. Walker pp 6530–6540 DOI: 10.1021/ja101155h Supporting Info

Ruthenium(0) Nanoclusters Stabilized by a Nanozeolite Framework: Isolable, Reusable, and Green Catalyst for the Hydrogenation of Neat Aromatics under Mild Conditions with the Unprecedented Catalytic Activity and Lifetime Mehmet Zahmakıran, Yalın Tonbul and Saim zkar pp 6541–6549 DOI: 10.1021/ja101602d Supporting Info

Electrical Contacting of an Assembly of Pseudoazurin and Nitrite Reductase Using DNA-Directed Immobilization Armand W. J. W. Tepper pp 6550–6557 DOI: 10.1021/ja101515y Supporting Info

Effects of Primary and Secondary Surface Groups in Enantioselective Catalysis Using Nanoporous Materials with Chiral Walls Andreas Kuschel and Sebastian Polarz pp 6558–6565 DOI: 10.1021/ja1017706 Supporting Info

A Thin Film Detection/Response System for Pathogenic Bacteria Jin Zhou, Andrew L. Loftus, Geraldine Mulley and A. Toby A. Jenkins pp 6566–6570 DOI: 10.1021/ja101554a Supporting Info

Asymmetric Partitioning of Anions in Lysozyme Dispersions Pierandrea Lo Nostro, Niccol Peruzzi, Mirko Severi, Barry W. Ninham and Piero Baglioni pp 6571–6577 DOI: 10.1021/ja101603n Supporting Info

Synthesis and Properties of Carborane-Appended C3-Symmetrical Extended π Systems Barada Prasanna Dash, Rashmirekha Satapathy, Elizabeth R. Gaillard, John A. Maguire and Narayan S. Hosmane pp 6578–6587 DOI: 10.1021/ja101845m Supporting Info

Photochemical “Triode” Molecular Signal Transducer Amy E. Keirstead, James W. Bridgewater, Yuichi Terazono, Gerdenis Kodis, Stephen Straight, Paul A. Liddell, Ana L. Moore, Thomas A. Moore and Devens Gust pp 6588–6595 DOI: 10.1021/ja1019595 Supporting Info

Probing the Structural Evolution of Medium-Sized Gold Clusters: Aun− (n = 27−35) Nan Shao, Wei Huang, Yi Gao, Lei-Ming Wang, Xi Li, Lai-Sheng Wang and Xiao Cheng Zeng pp 6596–6605 DOI: 10.1021/ja102145g Supporting Info

Smart Microgel Capsules from Macromolecular Precursors Sebastian Seiffert, Julian Thiele, Adam R. Abate and David A. Weitz pp 6606–6609 DOI: 10.1021/ja102156h Supporting Info

The Structural Basis of Cryptosporidium-Specific IMP Dehydrogenase Inhibitor Selectivity Iain S. MacPherson, Sivapriya Kirubakaran, Suresh Kumar Gorla, Thomas V. Riera, J. Alejandro D’Aquino, Minjia Zhang, Gregory D. Cuny and Lizbeth Hedstrom p 6610 DOI: 10.1021/ja102628e

Cellular and Biomolecular Recognition: Synthetic and Non-Biological Molecules Jin Wang p 6611 DOI: 10.1021/ja102523m

Click Chemistry for Biotechnology and Materials Science Ronald Kluger pp 6611–6612 DOI: 10.1021/ja102850q

Issue 19

Femtosecond Diffuse Reflectance Transient Absorption for Dye-Sensitized Solar Cells under Operational Conditions: Effect of Electrolyte on Electron Injection Akihiro Furube, Zhong-Sheng Wang, Kenji Sunahara, Kohjiro Hara, Ryuzi Katoh and Masanori Tachiya pp 6614–6615 DOI: 10.1021/ja910934y Supporting Info

Hydrogenation of Nanocrystalline Mg at Room Temperature in the Presence of TiH2 Jun Lu, Young Joon Choi, Zhigang Zak Fang, Hong Yong Sohn and Ewa Rnnebro pp 6616–6617 DOI: 10.1021/ja910944w Supporting Info

The Big Red Shift of Photoluminescence of Mn Dopants in Strained CdS: A Case Study of Mn-Doped MnS−CdS Heteronanostructures Taisen Zuo, Zhipeng Sun, Yuliang Zhao, Xiaoming Jiang and Xueyun Gao pp 6618–6619 DOI: 10.1021/ja100136a Supporting Info

High Proton Conductivity in Prussian Blue Analogues and the Interference Effect by Magnetic Ordering Shin-ichi Ohkoshi, Kosuke Nakagawa, Keisuke Tomono, Kenta Imoto, Yoshihide Tsunobuchi and Hiroko Tokoro pp 6620–6621 DOI: 10.1021/ja100385f Supporting Info

Protonated Titanate Nanotubes as Solid Acid Catalyst Masaaki Kitano, Kiyotaka Nakajima, Junko N. Kondo, Shigenobu Hayashi and Michikazu Hara pp 6622–6623 DOI: 10.1021/ja100435w Supporting Info

Tandem β-Alkylation−α-Arylation of Amines by Carbolithiation and Rearrangement of N-Carbamoyl Enamines (Vinyl Ureas) Jonathan Clayden, Morgan Donnard, Julien Lefranc, Alberto Minassi and Daniel J. Tetlow pp 6624–6625 DOI: 10.1021/ja1007992 Supporting Info

UDP-(5F)-GlcNAc Acts as a Slow-Binding Inhibitor of MshA, a Retaining Glycosyltransferase Patrick A. Frantom, James K. Coward and John S. Blanchard pp 6626–6627 DOI: 10.1021/ja101231a Supporting Info

Chiroselective Assembly of a Chiral Porphyrin−Fullerene Dyad: Photoconductive Nanofiber with a Top-Class Ambipolar Charge-Carrier Mobility Yumi Hizume, Kentaro Tashiro, Richard Charvet, Yohei Yamamoto, Akinori Saeki, Shu Seki and Takuzo Aida pp 6628–6629 DOI: 10.1021/ja1014713 Supporting Info

Localization of p-Nitroaniline Chains Inside Zeolite ZSM-5 with Second-Harmonic Generation Microscopy Monique A. van der Veen, Bert F. Sels, Dirk E. De Vos and Thierry Verbiest pp 6630–6631 DOI: 10.1021/ja101614w Supporting Info

In Vitro Reconstitution of Mycobacterial Ergothioneine Biosynthesis Florian P. Seebeck pp 6632–6633 DOI: 10.1021/ja101721e Supporting Info

Resistive-Switching Memory Effects of NiO Nanowire/Metal Junctions Keisuke Oka, Takeshi Yanagida, Kazuki Nagashima, Tomoji Kawai, Jin-Soo Kim and Bae Ho Park pp 6634–6635 DOI: 10.1021/ja101742f Supporting Info

Evidence for Copper-dioxygen Reactivity during α-Synuclein Fibril Formation Heather R. Lucas, Serena DeBeer, Myoung-Soon Hong and Jennifer C. Lee pp 6636–6637 DOI: 10.1021/ja101756m Supporting Info

Identification of Modular Chiral Bisphosphines Effective for Cu(I)-Catalyzed Asymmetric Allylation and Propargylation of Ketones Shi-Liang Shi, Li-Wen Xu, Kounosuke Oisaki, Motomu Kanai and Masakatsu Shibasaki pp 6638–6639 DOI: 10.1021/ja101948s Supporting Info

Cyclopropenation of Alkylidene Carbenes Derived from α-Silyl Ketones Jingwei Li, Chunrui Sun and Daesung Lee pp 6640–6641 DOI: 10.1021/ja101998w Supporting Info

CuInS2 Solar Cells by Air-Stable Ink Rolling Benjamin D. Weil, Stephen T. Connor and Yi Cui pp 6642–6643 DOI: 10.1021/ja1020475 Supporting Info

Recognition, Neutralization, and Clearance of Target Peptides in the Bloodstream of Living Mice by Molecularly Imprinted Polymer Nanoparticles: A Plastic Antibody Yu Hoshino, Hiroyuki Koide, Takeo Urakami, Hiroaki Kanazawa, Takashi Kodama, Naoto Oku and Kenneth J. Shea pp 6644–6645 DOI: 10.1021/ja102148f Supporting Info

Separating Ion and Electron Transport: The Bilayer Light-Emitting Electrochemical Cell Andreas Sandstrm, Piotr Matyba, Olle Ingans and Ludvig Edman pp 6646–6647 DOI: 10.1021/ja102038e

Synthesis of a Glycosylphosphatidylinositol Anchor Bearing Unsaturated Lipid Chains Benjamin M. Swarts and Zhongwu Guo pp 6648–6650 DOI: 10.1021/ja1009037 Supporting Info

n → π* Interaction and n)(π Pauli Repulsion Are Antagonistic for Protein Stability Charles E. Jakobsche, Amit Choudhary, Scott J. Miller and Ronald T. Raines pp 6651–6653 DOI: 10.1021/ja100931y Supporting Info

Nonclassical Active Site for Enhanced Gas Sorption in Porous Coordination Polymer Jian-Bin Lin, Jie-Peng Zhang and Xiao-Ming Chen pp 6654–6656 DOI: 10.1021/ja1009635 Supporting Info

1D Cu(OH)2 Nanomaterial Synthesis Templated in Water Microdroplets Gilles R. Bourret and R. Bruce Lennox pp 6657–6659 DOI: 10.1021/ja101579v Supporting Info

Structure-Selective Modification of Aromatic Side Chains with Dirhodium Metallopeptide Catalysts Brian V. Popp and Zachary T. Ball pp 6660–6662 DOI: 10.1021/ja101456c Supporting Info

Functional Characterization of TtnD and TtnF, Unveiling New Insights into Tautomycetin Biosynthesis Yinggang Luo, Wenli Li, Jianhua Ju, Qiuping Yuan, Noel R. Peters, F. Michael Hoffmann, Sheng-Xiong Huang, Tim S. Bugni, Scott Rajski, Hiroyuki Osada and Ben Shen pp 6663–6671 DOI: 10.1021/ja9082446 Supporting Info

Hydrogenation-Induced Surface Polarity Recognition and Proton Memory Behavior at Protic-Ionic-Liquid/Oxide Electric-Double-Layer Interfaces Hongtao Yuan, Hidekazu Shimotani, Atsushi Tsukazaki, Akira Ohtomo, Masashi Kawasaki and Yoshihiro Iwasa pp 6672–6678 DOI: 10.1021/ja909110s

Shape-Enhanced Photocatalytic Activity of Single-Crystalline Anatase TiO2 (101) Nanobelts Nianqiang Wu, Jin Wang, De Nyago Tafen, Hong Wang, Jian-Guo Zheng, James P. Lewis, Xiaogang Liu, Stephen S. Leonard and Ayyakkannu Manivannan pp 6679–6685 DOI: 10.1021/ja909456f Supporting Info

Semiconductor Nanocrystals Functionalized with Antimony Telluride Zintl Ions for Nanostructured Thermoelectrics Maksym V. Kovalenko, Boris Spokoyny, Jong-Soo Lee, Marcus Scheele, Andrew Weber, Susanthri Perera, Daniel Landry and Dmitri V. Talapin pp 6686–6695 DOI: 10.1021/ja909591x Supporting Info

Stark Effects after Excited-State Interfacial Electron Transfer at Sensitized TiO2 Nanocrystallites Shane Ardo, Yali Sun, Aaron Staniszewski, Felix N. Castellano and Gerald J. Meyer pp 6696–6709 DOI: 10.1021/ja909781g Supporting Info

Solvent-Exposed Tails as Prestalk Transition States for Membrane Fusion at Low Hydration Yuliya G. Smirnova, Siewert-Jan Marrink, Reinhard Lipowsky and Volker Knecht pp 6710–6718 DOI: 10.1021/ja910050x Supporting Info

Inhibition of the Fe4S4-Cluster-Containing Protein IspH (LytB): Electron Paramagnetic Resonance, Metallacycles, and Mechanisms Ke Wang, Weixue Wang, Joo-Hwan No, Yonghui Zhang, Yong Zhang and Eric Oldfield pp 6719–6727 DOI: 10.1021/ja909664j Supporting Info

Metal Inorganic Frameworks: Dynamic Flexible Architecture with Extended Pore Order Built from [Se3]2− Linkers and [Re6Se6Br8]2− Clusters Nan Ding, Gerasimos S. Armatas and Mercouri G. Kanatzidis pp 6728–6734 DOI: 10.1021/ja910506b Supporting Info

On the Origin of the Hydrophobic Water Gap: An X-ray Reflectivity and MD Simulation Study Markus Mezger, Felix Sedlmeier, Dominik Horinek, Harald Reichert, Diego Pontoni and Helmut Dosch pp 6735–6741 DOI: 10.1021/ja910624j Supporting Info

Light-Harvesting Conjugated Microporous Polymers: Rapid and Highly Efficient Flow of Light Energy with a Porous Polyphenylene Framework as Antenna Long Chen, Yoshihito Honsho, Shu Seki and Donglin Jiang pp 6742–6748 DOI: 10.1021/ja100327h Supporting Info

Altered Binding of a Multimeric Protein by Changing the Self-Assembling Properties of its Substrate Brooke A. Rosenzweig, Nathan T. Ross, Marc J. Adler and Andrew D. Hamilton pp 6749–6754 DOI: 10.1021/ja100485n Supporting Info

An Adsorption-Based Model for Pulse Duration in Resistive-Pulse Protein Sensing Lindsay T. Sexton, Hitomi Mukaibo, Parag Katira, Henry Hess, Stefanie A. Sherrill, Lloyd P. Horne and Charles R. Martin pp 6755–6763 DOI: 10.1021/ja100693x Supporting Info

Evidence of Dynamic Pentagon−Heptagon Pairs in Single-Wall Carbon Nanotubes using Surface-Enhanced Raman Scattering Toshihiko Fujimori, Koki Urita, Tomonori Ohba, Hirofumi Kanoh and Katsumi Kaneko pp 6764–6767 DOI: 10.1021/ja100760m Supporting Info

NMR Analyses of the Interaction between CCR5 and Its Ligand Using Functional Reconstitution of CCR5 in Lipid Bilayers Chie Yoshiura, Yutaka Kofuku, Takumi Ueda, Yoko Mase, Mariko Yokogawa, Masanori Osawa, Yuya Terashima, Kouji Matsushima and Ichio Shimada pp 6768–6777 DOI: 10.1021/ja100830f Supporting Info

Room-Temperature Synthesis Leading to Nanocrystalline Ag2V4O11 Frdric Sauvage, Vincent Bodenez, Jean-Marie Tarascon and Kenneth R. Poeppelmeier pp 6778–6782 DOI: 10.1021/ja1009713 Supporting Info

Self-Assembly of Flexible One-Dimensional Coordination Polymers on Metal Surfaces Daniel Heim, David cija, Knud Seufert, Willi Auwrter, Claudia Aurisicchio, Chiara Fabbro, Davide Bonifazi and Johannes V. Barth pp 6783–6790 DOI: 10.1021/ja1010527 Supporting Info

Regioselectively Controlled Synthesis of Colloidal Mushroom Nanostructures and Their Hollow Derivatives Mathias Feyen, Claudia Weidenthaler, Ferdi Schth and An-Hui Lu pp 6791–6799 DOI: 10.1021/ja101270r Supporting Info

Synthesis of Multivalent Glycoconjugates Containing the Immunoactive LELTE Peptide: Effect of Glycosylation on Cellular Activation and Natural Killing by Human Peripheral Blood Mononuclear Cells Olivier Renaudet, Karel Kenek, Isabelle Bossu, Pascal Dumy, Alan Kdek, David Admek, Ondej Vank, Daniel Kavan, Radek Gak, Miroslav ulc, Karel Bezouka and Vladimr Ken pp 6800–6808 DOI: 10.1021/ja101296t Supporting Info

Photo-Induced Spin-State Conversion in Solvated Transition Metal Complexes Probed via Time-Resolved Soft X-ray Spectroscopy Nils Huse, Tae Kyu Kim, Lindsey Jamula, James K. McCusker, Frank M. F. de Groot and Robert W. Schoenlein pp 6809–6816 DOI: 10.1021/ja101381a

Conductance and Geometry of Pyridine-Linked Single-Molecule Junctions M. Kamenetska, Su Ying Quek, A. C. Whalley, M. L. Steigerwald, H. J. Choi, Steven G. Louie, C. Nuckolls, M. S. Hybertsen, J. B. Neaton and L. Venkataraman pp 6817–6821 DOI: 10.1021/ja1015348 Supporting Info

Accessing Ultrashort Reaction Times in Particle Formation with SAXS Experiments: ZnS Precipitation on the Microsecond Time Scale Wolfgang Schmidt, Patrick Bussian, Mika Lindn, Heinz Amenitsch, Patrik Agren, Michael Tiemann and Ferdi Schth pp 6822–6826 DOI: 10.1021/ja101519z Supporting Info

Biochemical, Structural, and Biological Evaluation of Tranylcypromine Derivatives as Inhibitors of Histone Demethylases LSD1 and LSD2 Claudia Binda, Sergio Valente, Mauro Romanenghi, Simona Pilotto, Roberto Cirilli, Aristotele Karytinos, Giuseppe Ciossani, Oronza A. Botrugno, Federico Forneris, Maria Tardugno, Dale E. Edmondson, Saverio Minucci, Andrea Mattevi and Antonello Mai pp 6827–6833 DOI: 10.1021/ja101557k Supporting Info

Design of Injection and Recombination in Quantum Dot Sensitized Solar Cells Eva M. Barea, Menny Shalom, Sixto Gimnez, Idan Hod, Ivn Mora-Ser, Arie Zaban and Juan Bisquert pp 6834–6839 DOI: 10.1021/ja101752d

Templated Synthesis of Cyclic [4]Rotaxanes Consisting of Two Stiff Rods Threaded through Two Bis-macrocycles with a Large and Rigid Central Plate as Spacer Jean-Paul Collin, Fabien Durola, Julien Frey, Valrie Heitz, Felipe Reviriego, Jean-Pierre Sauvage, Yann Trolez and Kari Rissanen pp 6840–6850 DOI: 10.1021/ja101759w Supporting Info

Predictions of the Pt8Ti Phase in Unexpected Systems Richard H. Taylor, Stefano Curtarolo and Gus L. W. Hart pp 6851–6854 DOI: 10.1021/ja101890k

Synthesis of the ABCDEFG Ring System of Maitotoxin K. C. Nicolaou, Robert J. Aversa, Jian Jin and Fatima Rivas pp 6855–6861 DOI: 10.1021/ja102260q Supporting Info

Conjugated Diene-Assisted Allylic C−H Bond Activation: Cationic Rh(I)-Catalyzed Syntheses of Polysubstituted Tetrahydropyrroles, Tetrahydrofurans, and Cyclopentanes from Ene-2-Dienes Qian Li and Zhi-Xiang Yu p 6862 DOI: 10.1021/ja102776s

A Solid-State NMR Study of Lead and Vanadium Substitution into Hydroxyapatite Hlne Pizzala, Stefano Caldarelli, Jean-Guillaume Eon, Alexandre Malta Rossi, Rosane A. S. San Gil, Danielle Laurencin and Mark E. Smith p 6862 DOI: 10.1021/ja102908g

Hydrogen Bonding in Organic Synthesis Igor Alabugin pp 6863–6864 DOI: 10.1021/ja103155b

Miniaturization of Analytical Systems: Principles, Designs and Applications Daniel E. Austin p 6864 DOI: 10.1021/ja102715s

Recoverable and Recyclable Catalysts Francesca M. Kerton p 6865 DOI: 10.1021/ja103058k

Handbook of Cyclization Reactions, Vols. 1−2 Paul E. Floreancig pp 6865–6866 DOI: 10.1021/ja103004f

Macromolecules Containing Metal and Metal-Like Elements, Volume 9: Supramolecular and Self-Assembled Metal-Containing Materials Louis Messerle p 6866 DOI: 10.1021/ja103005b

Quantum Tunnelling in Enzyme-Catalysed Reactions Jan Florin p 6866 DOI: 10.1021/ja103114z

Issue 20

Water Hydrogen Bond Structure near Highly Charged Interfaces Is Not Like Ice Satoshi Nihonyanagi, Shoichi Yamaguchi and Tahei Tahara pp 6867–6869 DOI: 10.1021/ja910914g Supporting Info

Rotational Libration of a Double-Decker Porphyrin Visualized Joe Otsuki, Yuji Komatsu, Daiya Kobayashi, Masumi Asakawa and Koji Miyake pp 6870–6871 DOI: 10.1021/ja907077e Supporting Info

High-Performance Silicon Nanohole Solar Cells Kui-Qing Peng, Xin Wang, Li Li, Xiao-Ling Wu and Shuit-Tong Lee pp 6872–6873 DOI: 10.1021/ja910082y Supporting Info

Mononuclear Copper Complex-Catalyzed Four-Electron Reduction of Oxygen Shunichi Fukuzumi, Hiroaki Kotani, Heather R. Lucas, Kaoru Doi, Tomoyoshi Suenobu, Ryan L. Peterson and Kenneth D. Karlin pp 6874–6875 DOI: 10.1021/ja100538x Supporting Info

An In Silico Design Tool for Fe(II) Spin Crossover and Light-Induced Excited Spin State-Trapped Complexes Robert J. Deeth, Anna E. Anastasi and Martin J. Wilcockson pp 6876–6877 DOI: 10.1021/ja1007323 Supporting Info

Nanoengineered Electrically Contacted Enzymes on DNA Scaffolds: Functional Assemblies for the Selective Analysis of Hg2+ Ions Gilad Mor-Piperberg, Ran Tel-Vered, Johann Elbaz and Itamar Willner pp 6878–6879 DOI: 10.1021/ja1006355 Supporting Info

Nickel-Catalyzed Allylic Substitution of Simple Alkenes Ryosuke Matsubara and Timothy F. Jamison pp 6880–6881 DOI: 10.1021/ja101186p Supporting Info

EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH J. Gregory McAlpin, Yogesh Surendranath, Mircea Dinc, Troy A. Stich, Sebastian A. Stoian, William H. Casey, Daniel G. Nocera and R. David Britt pp 6882–6883 DOI: 10.1021/ja1013344 Supporting Info

Near-Infrared Light Emitting Luciferase via Biomineralization Nan Ma, Ann F. Marshall and Jianghong Rao pp 6884–6885 DOI: 10.1021/ja101378g Supporting Info

Face-on Oriented Bilayer of Two Discotic Columnar Liquid Crystals for Organic Donor−Acceptor Heterojunction Olivier Thiebaut, Harald Bock and Eric Grelet pp 6886–6887 DOI: 10.1021/ja1012596 Supporting Info

Synthesis of a Nitrido-Substituted Analogue of the Uranyl Ion, [N═U═O]+ Skye Fortier, Guang Wu and Trevor W. Hayton pp 6888–6889 DOI: 10.1021/ja101567h Supporting Info

Bifunctional Patterning of Mixed Monolayer Surfaces Using Scanning Probe Lithography for Multiplexed Directed Assembly David A. Unruh, Clayton Mauldin, Stefan J. Pastine, Marco Rolandi and Jean M. J. Frchet pp 6890–6891 DOI: 10.1021/ja101627e Supporting Info

Remnant Polarization in Thin Films from a Columnar Liquid Crystal Carel F. C. Fiti, W. S. Christian Roelofs, Martijn Kemerink and Rint P. Sijbesma pp 6892–6893 DOI: 10.1021/ja101734g Supporting Info

Conformational Gating of Electron Transfer from the Nitrogenase Fe Protein to MoFe Protein Karamatullah Danyal, Diana Mayweather, Dennis R. Dean, Lance C. Seefeldt and Brian M. Hoffman pp 6894–6895 DOI: 10.1021/ja101737f

Isotope Effect, Mechanism, and Origin of Catalysis in the Decarboxylation of Mandelylthiamin Ollie M. Gonzalez-James and Daniel A. Singleton pp 6896–6897 DOI: 10.1021/ja101775s Supporting Info

Conduction Band Energy Level Control of Titanium Dioxide: Toward an Efficient Visible-Light-Sensitive Photocatalyst Huogen Yu, Hiroshi Irie and Kazuhito Hashimoto pp 6898–6899 DOI: 10.1021/ja101714s Supporting Info

A New Entry of Amination Reagents for Heteroaromatic C−H Bonds: Copper-Catalyzed Direct Amination of Azoles with Chloroamines at Room Temperature Tsuyoshi Kawano, Koji Hirano, Tetsuya Satoh and Masahiro Miura pp 6900–6901 DOI: 10.1021/ja101939r Supporting Info

Preparation of Unique 1-D Nanoparticle Superstructures and Tailoring their Structural Features Chun-Long Chen and Nathaniel L. Rosi pp 6902–6903 DOI: 10.1021/ja102000g Supporting Info

“Weighing” Photon Energies with Mass Spectrometry: Effects of Water on Ion Fluorescence William A. Donald, Ryan D. Leib, Maria Demireva, Bogdan Negru, Daniel M. Neumark and Evan R. Williams pp 6904–6905 DOI: 10.1021/ja1022656 Supporting Info

Local Release of Highly Loaded Antibodies from Functionalized Nanoporous Support for Cancer Immunotherapy Chenghong Lei, Pu Liu, Baowei Chen, Yumeng Mao, Heather Engelmann, Yongsoon Shin, Jade Jaffar, Ingegerd Hellstrom, Jun Liu and Karl Erik Hellstrom pp 6906–6907 DOI: 10.1021/ja102414t Supporting Info

Rhodium(III)-Catalyzed Isoquinolone Synthesis: The N−O Bond as a Handle for C−N Bond Formation and Catalyst Turnover Nicolas Guimond, Christina Gouliaras and Keith Fagnou pp 6908–6909 DOI: 10.1021/ja102571b Supporting Info

Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes Derek J. Schipper, Marieke Hutchinson and Keith Fagnou pp 6910–6911 DOI: 10.1021/ja103080d Supporting Info

Activation of Ammonia by a Si═O Double Bond and Formation of a Unique Pair of Sila-Hemiaminal and Silanoic Amide Tautomers Yun Xiong, Shenglai Yao, Robert Mller, Martin Kaupp and Matthias Driess pp 6912–6913 DOI: 10.1021/ja1031024 Supporting Info

Identification of Protein-Bound Dinitrosyl Iron Complexes by Nuclear Resonance Vibrational Spectroscopy Zachary J. Tonzetich, Hongxin Wang, Devrani Mitra, Christine E. Tinberg, Loi H. Do, Francis E. Jenney, Jr., Michael W. W. Adams, Stephen P. Cramer and Stephen J. Lippard pp 6914–6916 DOI: 10.1021/ja101002f Supporting Info

Hydrated Electrons at the Water/Air Interface D. M. Sagar, Colin. D. Bain and Jan R. R. Verlet pp 6917–6919 DOI: 10.1021/ja101176r Supporting Info

Metalloradical-Catalyzed Aliphatic Carbon−Carbon Activation of Cyclooctane Yun Wai Chan and Kin Shing Chan pp 6920–6922 DOI: 10.1021/ja101586w Supporting Info

Supramolecular n/p-Heterojunction Photosystems with Antiparallel Redox Gradients in Electron- and Hole-Transporting Pathways Naomi Sakai, Rajesh Bhosale, Daniel Emery, Jiri Mareda and Stefan Matile pp 6923–6925 DOI: 10.1021/ja101944r Supporting Info

Postchemistry of Organic Particles: When TTF Microparticles Meet TCNQ Microstructures in Aqueous Solution Jinchong Xiao, Zongyou Yin, Hong Li, Qing Zhang, Freddy Boey, Hua Zhang and Qichun Zhang pp 6926–6928 DOI: 10.1021/ja102154b Supporting Info

Use of a Copper-Chelated Lipid Speeds Up NMR Measurements from Membrane Proteins Kazutoshi Yamamoto, Jiadi Xu, Karen E. Kawulka, John C. Vederas and Ayyalusamy Ramamoorthy pp 6929–6931 DOI: 10.1021/ja102103n Supporting Info

Biomineralization-Assisted Ultrasensitive Detection of DNA Xin Zhou, Sijing Xia, Zhiqiang Lu, Yuan Tian, Yishu Yan and Jin Zhu pp 6932–6934 DOI: 10.1021/ja102271r Supporting Info

Rh(I)-Catalyzed Olefin Hydroarylation with Electron-Deficient Perfluoroarenes Zhong-Ming Sun, Jing Zhang, Rajith S. Manan and Pinjing Zhao pp 6935–6937 DOI: 10.1021/ja102575d Supporting Info

Enzymelike Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation Courtney J. Hastings, Michael D. Pluth, Robert G. Bergman and Kenneth N. Raymond pp 6938–6940 DOI: 10.1021/ja102633e Supporting Info

Stereoretentive Suzuki−Miyaura Coupling of Haloallenes Enables Fully Stereocontrolled Access to (−)-Peridinin Eric M. Woerly, Alan H. Cherney, Erin K. Davis and Martin D. Burke pp 6941–6943 DOI: 10.1021/ja102721p Supporting Info

Triple-Stranded Metallo-Helicates Addressable as Lloyd’s Electron Spin Qubits Yasushi Morita, Yumi Yakiyama, Shigeaki Nakazawa, Tsuyoshi Murata, Tomoaki Ise, Daisuke Hashizume, Daisuke Shiomi, Kazunobu Sato, Masahiro Kitagawa, Kazuhiro Nakasuji and Takeji Takui pp 6944–6946 DOI: 10.1021/ja102030w Supporting Info

Silver Sub-nanoclusters Electrocatalyze Ethanol Oxidation and Provide Protection against Ethanol Toxicity in Cultured Mammalian Cells Javier Selva, Susana E. Martnez, David Buceta, Mara J. Rodrguez-Vzquez, M. Carmen Blanco, M. Arturo Lpez-Quintela and Gustavo Egea pp 6947–6954 DOI: 10.1021/ja907988s Supporting Info

Theoretical Study of Phosphodiester Hydrolysis in Nucleotide Pyrophosphatase/Phosphodiesterase. Environmental Effects on the Reaction Mechanism Violeta Lpez-Canut, Maite Roca, Juan Bertrn, Vicent Moliner and Iaki Tun pp 6955–6963 DOI: 10.1021/ja908391v Supporting Info

Showdomycin as a Versatile Chemical Tool for the Detection of Pathogenesis-Associated Enzymes in Bacteria Thomas Bttcher and Stephan A. Sieber pp 6964–6972 DOI: 10.1021/ja909150y Supporting Info

Molecular Determinants of Microbial Resistance to Thiopeptide Antibiotics Sascha Baumann, Sebastian Schoof, Marcel Bolten, Claudia Haering, Motoki Takagi, Kazuo Shin-ya and Hans-Dieter Arndt pp 6973–6981 DOI: 10.1021/ja909317n Supporting Info

Pseudocapacitive Contributions to Charge Storage in Highly Ordered Mesoporous Group V Transition Metal Oxides with Iso-Oriented Layered Nanocrystalline Domains Kirstin Brezesinski, John Wang, Jan Haetge, Christian Reitz, Sven O. Steinmueller, Sarah H. Tolbert, Bernd M. Smarsly, Bruce Dunn and Torsten Brezesinski pp 6982–6990 DOI: 10.1021/ja9106385 Supporting Info

Membrane-Bound Hydrogenase I from the Hyperthermophilic Bacterium Aquifex aeolicus: Enzyme Activation, Redox Intermediates and Oxygen Tolerance Maria-Eirini Pandelia, Vincent Fourmond, Pascale Tron-Infossi, Elisabeth Lojou, Patrick Bertrand, Christophe Lger, Marie-Thrse Giudici-Orticoni and Wolfgang Lubitz pp 6991–7004 DOI: 10.1021/ja910838d Supporting Info

Adsorption and Separation of Reactive Aromatic Isomers and Generation and Stabilization of Their Radicals within Cadmium(II)−Triazole Metal−Organic Confined Space in a Single-Crystal-to-Single-Crystal Fashion Qi-Kui Liu, Jian-Ping Ma and Yu-Bin Dong pp 7005–7017 DOI: 10.1021/ja101807c Supporting Info

Product Deuterium Isotope Effects for Orotidine 5′-Monophosphate Decarboxylase: Effect of Changing Substrate and Enzyme Structure on the Partitioning of the Vinyl Carbanion Reaction Intermediate Krisztina Toth, Tina L. Amyes, Bryant M. Wood, Kui Chan, John A. Gerlt and John P. Richard pp 7018–7024 DOI: 10.1021/ja102408k Supporting Info

Structural Responses of DNA-DDAB Films to Varying Hydration and Temperature Thorsten Neumann, Surekha Gajria, Nathan F. Bouxsein, Luc Jaeger and Matthew Tirrell pp 7025–7037 DOI: 10.1021/ja909514j Supporting Info

Directed Evolution of an Enantioselective Lipase with Broad Substrate Scope for Hydrolysis of α-Substituted Esters Karin Engstrm, Jonas Nyhln, Anders G. Sandstrm and Jan-E. Bckvall pp 7038–7042 DOI: 10.1021/ja100593j Supporting Info

Binding or Bending: Distinction of Allosteric Abl Kinase Agonists from Antagonists by an NMR-Based Conformational Assay Wolfgang Jahnke, Robert M. Grotzfeld, Xavier Pell, Andr Strauss, Gabriele Fendrich, Sandra W. Cowan-Jacob, Simona Cotesta, Doriano Fabbro, Pascal Furet, Jrgen Mestan and Andreas L. Marzinzik pp 7043–7048 DOI: 10.1021/ja101837n Supporting Info

The Divalent Metal Ion in the Active Site of Uteroferrin Modulates Substrate Binding and Catalysis Nataa Miti, Kieran S. Hadler, Lawrence R. Gahan, Alvan C. Hengge and Gerhard Schenk pp 7049–7054 DOI: 10.1021/ja910583y

Low-Dimensional Structure and Magnetism of the Quantum Antiferromagnet Rb4Cu(MoO4)3 and the Structure of Rb4Zn(MoO4)3 Rieko Ishii, Dixie Gautreaux, Keisuke Onuma, Yo Machida, Yoshiteru Maeno, Satoru Nakatsuji and Julia Y. Chan pp 7055–7061 DOI: 10.1021/ja100077v Supporting Info

MASKE: Macroscopic Approach to Studying Kinetics at Equilibrium Victor Okhonin, Maxim V. Berezovski and Sergey N. Krylov pp 7062–7068 DOI: 10.1021/ja100104m Supporting Info

La2Co2Se2O3: A Quasi-Two-Dimensional Mott Insulator with Unusual Cobalt Spin State and Possible Orbital Ordering Cao Wang, Ming-qiu Tan, Chun-mu Feng, Zhi-feng Ma, Shuai Jiang, Zhu-an Xu, Guang-han Cao, Kazuyuki Matsubayashi and Yoshiya Uwatoko pp 7069–7073 DOI: 10.1021/ja1001295 Supporting Info

Analytical Model for Rates of Electron Attachment and Intramolecular Electron Transfer in Electron Transfer Dissociation Mass Spectrometry Jack Simons pp 7074–7085 DOI: 10.1021/ja100240f

Fractional Polymerization of a Suspended Planar Bilayer Creates a Fluid, Highly Stable Membrane for Ion Channel Recordings Benjamin A. Heitz, Ian W. Jones, Henry K. Hall, Jr., Craig A. Aspinwall and S. Scott Saavedra pp 7086–7093 DOI: 10.1021/ja100245d Supporting Info

Unprecedented Near-Infrared (NIR) Emission in Diplatinum(III) (d7−d7) Complexes at Room Temperature Martin A. Bennett, Suresh K. Bhargava, Eddie Chung-Chin Cheng, Wai Han Lam, Terence Kwok-Ming Lee, Steven H. Privr, Jrg Wagler, Anthony C. Willis and Vivian Wing-Wah Yam pp 7094–7103 DOI: 10.1021/ja1002313 Supporting Info

Effects of Point Mutation on Enzymatic Activity: Correlation between Protein Electronic Structure and Motion in Chorismate Mutase Reaction Toyokazu Ishida pp 7104–7118 DOI: 10.1021/ja100744h

Scalable Total Syntheses of N-Linked Tryptamine Dimers by Direct Indole−Aniline Coupling: Psychotrimine and Kapakahines B and F Timothy Newhouse, Chad A. Lewis, Kyle J. Eastman and Phil S. Baran pp 7119–7137 DOI: 10.1021/ja1009458 Supporting Info

Total Synthesis and Structural Revision of Vannusals A and B: Synthesis of the Originally Assigned Structure of Vannusal B K. C. Nicolaou, Adrian Ortiz, Hongjun Zhang, Philippe Dagneau, Andreas Lanver, Michael P. Jennings, Stellios Arseniyadis, Raffaella Faraoni and Dimitrios E. Lizos pp 7138–7152 DOI: 10.1021/ja100740t Supporting Info

Total Synthesis and Structural Revision of Vannusals A and B: Synthesis of the True Structures of Vannusals A and B K. C. Nicolaou, Adrian Ortiz, Hongjun Zhang and Graziano Guella pp 7153–7176 DOI: 10.1021/ja100742b Supporting Info

Selectivity Principles in Anion Separation by Crystallization of Hydrogen-Bonding Capsules Radu Custelcean, Aurelien Bock and Bruce A. Moyer pp 7177–7185 DOI: 10.1021/ja101354r Supporting Info

Para-hydrogenated Glucose Derivatives as Potential 13C-Hyperpolarized Probes for Magnetic Resonance Imaging Francesca Reineri, Daniela Santelia, Alessandra Viale, Erika Cerutti, Luisa Poggi, Tomas Tichy, Samuel S. D. Premkumar, Roberto Gobetto and Silvio Aime pp 7186–7193 DOI: 10.1021/ja101399q Supporting Info

A Single Watson−Crick G·C Base Pair in Water: Aqueous Hydrogen Bonds in Hydrophobic Cavities Tomohisa Sawada and Makoto Fujita pp 7194–7201 DOI: 10.1021/ja101718c Supporting Info

Reversible Anion Exchange and Catalytic Properties of Two Cationic Metal−Organic Frameworks Based on Cu(I) and Ag(I) Honghan Fei, David L. Rogow and Scott R. J. Oliver pp 7202–7209 DOI: 10.1021/ja102134c Supporting Info

On the Origin of Siphonariid Polypropionates: Total Synthesis of Baconipyrone A, Baconipyrone C, and Siphonarin B via their Putative Common Precursor Garrison E. Beye and Dale E. Ward pp 7210–7215 DOI: 10.1021/ja102356j Supporting Info

Asymmetric Supramolecular Primary Amine Catalysis in Aqueous Buffer: Connections of Selective Recognition and Asymmetric Catalysis Shenshen Hu, Jiuyuan Li, Junfeng Xiang, Jie Pan, Sanzhong Luo and Jin-Pei Cheng pp 7216–7228 DOI: 10.1021/ja102819g Supporting Info

β-Directing Effect of Electron-Withdrawing Groups at O-3, O-4, and O-6 Positions and α-Directing Effect by Remote Participation of 3-O-Acyl and 6-O-Acetyl Groups of Donors in Mannopyranosylations Ju Yuel Baek, Bo-Young Lee, Myung Gi Jo and Kwan Soo Kim p 7229 DOI: 10.1021/ja103131s Supporting Info

Differential Ion Mobility Spectrometry: Nonlinear Ion Transport and Fundamentals of FAIMS Peter de Boves Harrington p 7230 DOI: 10.1021/ja103200q

Issue 21

A U-Tetrad Stabilizes Human Telomeric RNA G-Quadruplex Structure Yan Xu, Takumi Ishizuka, Takashi Kimura and Makoto Komiyama pp 7231–7233 DOI: 10.1021/ja909708a Supporting Info

Nanocomposites with Spatially Separated Functionalities for Combined Imaging and Magnetolytic Therapy Shang-Hsiu Hu and Xiaohu Gao pp 7234–7237 DOI: 10.1021/ja102489q Supporting Info

Synthesis and Solution-Phase Conformation of the RG-I Fragment of the Plant Polysaccharide Pectin Reveals a Modification-Modulated Assembly Mechanism Eoin M. Scanlan, Mukram M. Mackeen, Mark R. Wormald and Benjamin G. Davis pp 7238–7239 DOI: 10.1021/ja9090963 Supporting Info

Oxathiirane Peter R. Schreiner, Hans Peter Reisenauer, Jaroslaw Romanski and Grzegorz Mloston pp 7240–7241 DOI: 10.1021/ja100670q Supporting Info

Targeting SDF-1/CXCL12 with a Ligand That Prevents Activation of CXCR4 through Structure-Based Drug Design Christopher T. Veldkamp, Joshua J. Ziarek, Francis C. Peterson, Yu Chen and Brian F. Volkman pp 7242–7243 DOI: 10.1021/ja1002263 Supporting Info

Mechanisms of Quenching of Alexa Fluorophores by Natural Amino Acids Huimin Chen, Syed S. Ahsan, Mitk’El B. Santiago-Berrios, Hector D. Abrua and Watt W. Webb pp 7244–7245 DOI: 10.1021/ja100500k Supporting Info

A Stable Non-Kekul Singlet Biradicaloid from meso-Free 5,10,20,25-Tetrakis(Pentafluorophenyl)-Substituted [26]Hexaphyrin(1.1.1.1.1.1) Taro Koide, Ko Furukawa, Hiroshi Shinokubo, Jae-Yoon Shin, Kil Suk Kim, Dongho Kim and Atsuhiro Osuka pp 7246–7247 DOI: 10.1021/ja101040s Supporting Info

Oxo Ligand Silylation in a Uranyl β-Ketoiminate Complex Jessie L. Brown, Guang Wu and Trevor W. Hayton pp 7248–7249 DOI: 10.1021/ja1013739 Supporting Info

Plasmonic Field Enhancement of the Bacteriorhodopsin Photocurrent during Its Proton Pump Photocycle Chun-Wan Yen, Li-Kang Chu and Mostafa A El-Sayed pp 7250–7251 DOI: 10.1021/ja101301u Supporting Info

Sampling Long Time Scale Protein Motions: OSRW Simulation of Active Site Loop Conformational Free Energies in Formyl-CoA:Oxalate CoA Transferase Sangbae Lee, Mengen Chen, Wei Yang and Nigel G. J. Richards pp 7252–7253 DOI: 10.1021/ja101446u Supporting Info

Synthesis of the Long-Sought Unsubstituted Aminodiboranate Na(H3B−NH2−BH3) and Its N-Alkyl Analogs Scott R. Daly, Brian J. Bellott, Do Young Kim and Gregory S. Girolami pp 7254–7255 DOI: 10.1021/ja1016427 Supporting Info

Gold-Catalyzed Three-Component Tandem Process: An Efficient and Facile Assembly of Complex Butenolides from Alkynes, Amines, and Glyoxylic Acid Qiang Zhang, Ming Cheng, Xiaoyu Hu, Bo-Gang Li and Jian-Xin Ji pp 7256–7257 DOI: 10.1021/ja101804p Supporting Info

A Method To Determine Residue-Specific Unfolded-State pKa Values from Analysis of Stability Changes in Single Mutant Cycles Jana K. Shen pp 7258–7259 DOI: 10.1021/ja101761m

Asymmetric Deprotonation of N-Boc Piperidine: React IR Monitoring and Mechanistic Aspects Darren Stead, Giorgio Carbone, Peter O’Brien, Kevin R. Campos, Iain Coldham and Adam Sanderson pp 7260–7261 DOI: 10.1021/ja102043e Supporting Info

Copper-Mediated Aerobic Oxidative Trifluoromethylation of Terminal Alkynes with Me3SiCF3 Lingling Chu and Feng-Ling Qing pp 7262–7263 DOI: 10.1021/ja102175w Supporting Info

Synthesis of 4- and 4,5-Functionalized Imidazol-2-ylidenes from a Single 4,5-Unsubstituted Imidazol-2-ylidene Daniel Mendoza-Espinosa, Bruno Donnadieu and Guy Bertrand pp 7264–7265 DOI: 10.1021/ja102639a Supporting Info

Copper-Catalyzed Synthesis of Azaspirocyclohexadienones from α-Azido-N-arylamides under an Oxygen Atmosphere Shunsuke Chiba, Line Zhang and Jian-Yuan Lee pp 7266–7267 DOI: 10.1021/ja1027327 Supporting Info

Transition-Metal-Catalyzed Immobilization of Organic Functional Groups onto Solid Supports through Vinylsilane Coupling Reactions Jung-Woo Park and Chul-Ho Jun pp 7268–7269 DOI: 10.1021/ja102741k Supporting Info

Sulfur Modification of Au via Treatment with Piranha Solution Provides Low-Pd Releasing and Recyclable Pd Material, SAPd Naoyuki Hoshiya, Masahiko Shimoda, Hideki Yoshikawa, Yoshiyuki Yamashita, Satoshi Shuto and Mitsuhiro Arisawa pp 7270–7272 DOI: 10.1021/ja9100084 Supporting Info

Phenylhydroxycarbene Dennis Gerbig, Hans Peter Reisenauer, Chia-Hua Wu, David Ley, Wesley D. Allen and Peter R. Schreiner pp 7273–7275 DOI: 10.1021/ja9107885 Supporting Info

Prediction of Folding Equilibria of Differently Substituted Peptides Using One-Step Perturbation Zhixiong Lin, Jrgen Kornfeld, Markus Mchler and Wilfred F. van Gunsteren pp 7276–7278 DOI: 10.1021/ja100879k Supporting Info

Toward a Universal “Adhesive Nanosheet” for the Assembly of Multiple Nanoparticles Based on a Protein-Induced Reduction/Decoration of Graphene Oxide Jinbin Liu, Songhe Fu, Bin Yuan, Yulin Li and Zhaoxiang Deng pp 7279–7281 DOI: 10.1021/ja100938r Supporting Info

Water Exchange on Manganese(III) Porphyrins. Mechanistic Insights Relevant for Oxygen Evolving Complex and Superoxide Dismutation Catalysis Dominik Lieb, Achim Zahl, Tatyana E. Shubina and Ivana Ivanovi-Burmazovi pp 7282–7284 DOI: 10.1021/ja1014585 Supporting Info

Structural Analysis of Protein Interfaces from 13C Direct-Detected Paramagnetic Relaxation Enhancements Tobias Madl, Isabella C. Felli, Ivano Bertini and Michael Sattler pp 7285–7287 DOI: 10.1021/ja1014508 Supporting Info

Rationally Simplified Bistramide Analog Reversibly Targets Actin Polymerization and Inhibits Cancer Progression in Vitro and in Vivo Syed Alipayam Rizvi, Song Liu, Zhonglei Chen, Colleen Skau, Matthew Pytynia, David R. Kovar, Steven J. Chmura and Sergey A. Kozmin pp 7288–7290 DOI: 10.1021/ja101811x Supporting Info

Disassembly-Driven Turn-On Fluorescent Nanoprobes for Selective Protein Detection Keigo Mizusawa, Yoshiyuki Ishida, Yousuke Takaoka, Masayoshi Miyagawa, Shinya Tsukiji and Itaru Hamachi pp 7291–7293 DOI: 10.1021/ja101879g Supporting Info

Gold(I)-Catalyzed Rearrangement of Propargyl Benzyl Ethers: A Practical Method for the Generation and in Situ Transformation of Substituted Allenes Benoit Bolte, Yann Odabachian and Fabien Gagosz pp 7294–7296 DOI: 10.1021/ja1020469 Supporting Info

Enantioselective Gel Collapsing: A New Means of Visual Chiral Sensing Xi Chen, Zeng Huang, Shan-Yong Chen, Kun Li, Xiao-Qi Yu and Lin Pu pp 7297–7299 DOI: 10.1021/ja102480t Supporting Info

Discovery of New Ferroelectrics: [H2dbco]2·[Cl3]·[CuCl3(H2O)2]·H2O (dbco = 1,4-Diaza-bicyclo[2.2.2]octane) Wen Zhang, Heng-Yun Ye, Hong-Ling Cai, Jia-Zhen Ge, Ren-Gen Xiong and Songping D. Huang pp 7300–7302 DOI: 10.1021/ja102573h Supporting Info

Stable Mononuclear Organometallic Pd(III) Complexes and Their C−C Bond Formation Reactivity Julia R. Khusnutdinova, Nigam P. Rath and Liviu M. Mirica pp 7303–7305 DOI: 10.1021/ja103001g Supporting Info

Two-Dimensional Phase Behavior of a Bimolecular Porphyrin System at the Solid−Vacuum Interface Nikolai Wintjes, Jorge Lobo-Checa, Jens Hornung, Tom Samuely, Franois Diederich and Thomas A. Jung pp 7306–7311 DOI: 10.1021/ja909674e Supporting Info

Development of a Rotamer Library for Use in β-Peptide Foldamer Computational Design Scott J. Shandler, Maxim V. Shapovalov, Roland L. Dunbrack, Jr. and William F. DeGrado pp 7312–7320 DOI: 10.1021/ja906700x Supporting Info

Molecular Silicate and Aluminate Species in Anhydrous and Hydrated Cements Aditya Rawal, Benjamin J. Smith, George L. Athens, Christopher L. Edwards, Lawrence Roberts, Vijay Gupta and Bradley F. Chmelka pp 7321–7337 DOI: 10.1021/ja908146m Supporting Info

Using Intramolecular Energy Transfer to Transform non-Photoactive, Visible-Light-Absorbing Chromophores into Sensitizers for Photoredox Reactions Jing Gu, Jin Chen and Russell H. Schmehl pp 7338–7346 DOI: 10.1021/ja909785b Supporting Info

Nanoscale Structure, Composition, and Charge Transport Analysis of Transparent Conducting Oxide Nanowires Written by Focused Ion Beam Implantation Norma E. Sosa, Christopher Chen, Jun Liu, Sujing Xie, Tobin J. Marks and Mark C. Hersam pp 7347–7354 DOI: 10.1021/ja9092242 Supporting Info

Structures of [Ag7(SR)4]− and [Ag7(DMSA)4]− Hongjun Xiang, Su-Huai Wei and Xingao Gong pp 7355–7360 DOI: 10.1021/ja9108374 Supporting Info

Single-Molecule Pulling Simulations Can Discern Active from Inactive Enzyme Inhibitors Francesco Colizzi, Remo Perozzo, Leonardo Scapozza, Maurizio Recanatini and Andrea Cavalli pp 7361–7371 DOI: 10.1021/ja100259r Supporting Info

Recognition of the Ring-Opened State of Proliferating Cell Nuclear Antigen by Replication Factor C Promotes Eukaryotic Clamp-Loading John A. Tainer, J. Andrew McCammon and Ivaylo Ivanov pp 7372–7378 DOI: 10.1021/ja100365x Supporting Info

Bridged Photochromic Diarylethenes Investigated by Ultrafast Absorption Spectroscopy: Evidence for Two Distinct Photocyclization Pathways Stphane Alose, Michel Sliwa, Zuzanna Pawlowska, Julien Rhault, Julien Dubois, Olivier Poizat, Guy Buntinx, Aurlie Perrier, Franois Maurel, Shouhei Yamaguchi and Michinori Takeshita pp 7379–7390 DOI: 10.1021/ja910813x Supporting Info

Ruthenium-Catalyzed Synthesis of Functional Conjugated Dienes via Addition of Two Carbene Units to Alkynes Jacques Le Paih, Chlo Vovard-Le Bray, Sylvie Drien and Pierre H. Dixneuf pp 7391–7397 DOI: 10.1021/ja101064b Supporting Info

Gas-Phase Vibrational Spectroscopy of Microhydrated Magnesium Nitrate Ions [MgNO3(H2O)1−4]+ Ling Jiang, Torsten Wende, Risshu Bergmann, Gerard Meijer and Knut R. Asmis pp 7398–7404 DOI: 10.1021/ja1011806 Supporting Info

A Biosynthetic Pathway for BE-7585A, a 2-Thiosugar-Containing Angucycline-Type Natural Product Eita Sasaki, Yasushi Ogasawara and Hung-wen Liu pp 7405–7417 DOI: 10.1021/ja1014037 Supporting Info

Preferential CO Oxidation in Hydrogen: Reactivity of Core−Shell Nanoparticles Anand Udaykumar Nilekar, Selim Alayoglu, Bryan Eichhorn and Manos Mavrikakis pp 7418–7428 DOI: 10.1021/ja101108w Supporting Info

Transcription Inhibition by Platinum−DNA Cross-Links in Live Mammalian Cells Wee Han Ang, MyatNoeZin Myint and Stephen J. Lippard pp 7429–7435 DOI: 10.1021/ja101495v Supporting Info

Photoelectrochemical Water Splitting with Mesoporous Hematite Prepared by a Solution-Based Colloidal Approach Kevin Sivula, Radek Zboril, Florian Le Formal, Rosa Robert, Anke Weidenkaff, Jiri Tucek, Jiri Frydrych and Michael Grtzel pp 7436–7444 DOI: 10.1021/ja101564f Supporting Info

An Electrochemical Scanning Tunneling Microscopy Study of 2-(6-Mercaptoalkyl)hydroquinone Molecules on Au(111) Paolo Petrangolini, Andrea Alessandrini, Lorenzo Berti and Paolo Facci pp 7445–7453 DOI: 10.1021/ja101666q

Circular Dichroism Tensor of a Triarylmethyl Propeller in Sodium Chlorate Crystals Yonghong Bing, David Selassie, Ruthanne H. Paradise, Christine Isborn, Nicholas Kramer, Martin Sadilek, Werner Kaminsky and Bart Kahr pp 7454–7465 DOI: 10.1021/ja1018892 Supporting Info

Oligopyrenotides: Abiotic, Polyanionic Oligomers with Nucleic Acid-like Structural Properties Robert Hner, Florian Garo, Daniel Wenger and Vladimir L. Malinovskii pp 7466–7471 DOI: 10.1021/ja102042p Supporting Info

Ni(OH)2 Nanoplates Grown on Graphene as Advanced Electrochemical Pseudocapacitor Materials Hailiang Wang, Hernan Sanchez Casalongue, Yongye Liang and Hongjie Dai pp 7472–7477 DOI: 10.1021/ja102267j Supporting Info

Self-Assembly, Dynamics, and Phase Transformation Kinetics of Donor−Acceptor Substituted Perylene Derivatives Nikos Tasios, Christos Grigoriadis, Michael Ryan Hansen, Henrike Wonneberger, Chen Li, Hans W. Spiess, Klaus Mllen and George Floudas pp 7478–7487 DOI: 10.1021/ja102150g Supporting Info

Mechanistic Insights into Alkene Epoxidation with H2O2 by Ti- and other TM-Containing Polyoxometalates: Role of the Metal Nature and Coordination Environment Nadya S. Antonova, Jorge J. Carb, Ulrich Kortz, Oxana A. Kholdeeva and Josep M. Poblet pp 7488–7497 DOI: 10.1021/ja1023157 Supporting Info

Metal-Catalyzed Simultaneous Chain- and Step-Growth Radical Polymerization: Marriage of Vinyl Polymers and Polyesters Masato Mizutani, Kotaro Satoh and Masami Kamigaito pp 7498–7507 DOI: 10.1021/ja1023892 Supporting Info

Mechanistic Investigation of the Palladium-Catalyzed Decarboxylative Cyclization of γ-Methylidene-δ-valerolactones with Isocyanates: Kinetic Studies and Origin of the Site Selectivity in the Nucleophilic Attack at a (π-Allyl)palladium Ryo Shintani, Takaoki Tsuji, Soyoung Park and Tamio Hayashi pp 7508–7513 DOI: 10.1021/ja1023223 Supporting Info

Silver Nanoparticle-Catalyzed Diels−Alder Cycloadditions of 2′-Hydroxychalcones Huan Cong, Clinton F. Becker, Sean J. Elliott, Mark W. Grinstaff and John A. Porco, Jr. pp 7514–7518 DOI: 10.1021/ja102482b Supporting Info

Manipulation of Thiocillin Variants by Prepeptide Gene Replacement: Structure, Conformation, and Activity of Heterocycle Substitution Mutants Albert A. Bowers, Michael G. Acker, Alexander Koglin and Christopher T. Walsh pp 7519–7527 DOI: 10.1021/ja102339q Supporting Info

Efficient Calculation of Diffusion Limitations in Metal Organic Framework Materials: A Tool for Identifying Materials for Kinetic Separations Emmanuel Haldoupis, Sankar Nair and David S. Sholl pp 7528–7539 DOI: 10.1021/ja1023699 Supporting Info

Total Synthesis and Biological Evaluation of the Resveratrol-Derived Polyphenol Natural Products Hopeanol and Hopeahainol A K. C. Nicolaou, Qiang Kang, T. Robert Wu, Chek Shik Lim and David Y.-K. Chen pp 7540–7548 DOI: 10.1021/ja102623j Supporting Info

Impact of Mutation on Proton Transfer Reactions in Ketosteroid Isomerase: Insights from Molecular Dynamics Simulations Dhruva K. Chakravorty and Sharon Hammes-Schiffer pp 7549–7555 DOI: 10.1021/ja102714u Supporting Info

Base-Promoted Ammonia Borane Hydrogen-Release Daniel W. Himmelberger, Chang Won Yoon, Martin E. Bluhm, Patrick J. Carroll and Larry G. Sneddon p 7556 DOI: 10.1021/ja103189e Supporting Info

Computational Inorganic and Bioinorganic Chemistry Thomas R. Cundari p 7557 DOI: 10.1021/ja103254n

Chemical Reactivity Theory: A Density Functional View John C Hackett p 7558 DOI: 10.1021/ja1030744

Issue 22

Inner-Sphere Heterogeneous Electrode Reactions. Electrocatalysis and Photocatalysis: The Challenge Allen J. Bard pp 7559–7567 DOI: 10.1021/ja101578m

Synthesis and Electrocatalytic Properties of Cubic Mn−Pt Nanocrystals (Nanocubes) Yijin Kang and Christopher B. Murray pp 7568–7569 DOI: 10.1021/ja100705j Supporting Info

Supramolecular Protein Structure Determination by Site-Specific Long-Range Intermolecular Solid State NMR Spectroscopy Andrew J. Nieuwkoop and Chad M. Rienstra pp 7570–7571 DOI: 10.1021/ja100992y Supporting Info

Observation of a Secondary Slow Relaxation Process for the Field-Induced Single-Molecule Magnet U(H2BPz2)3 Jeffrey D. Rinehart, Katie R. Meihaus and Jeffrey R. Long pp 7572–7573 DOI: 10.1021/ja1009019 Supporting Info

Membrane Proteins Diffuse as Dynamic Complexes with Lipids Perttu S. Niemel, Markus S. Miettinen, Luca Monticelli, Henrik Hammaren, Pr Bjelkmar, Teemu Murtola, Erik Lindahl and Ilpo Vattulainen pp 7574–7575 DOI: 10.1021/ja101481b Supporting Info

Ni-Catalyzed Borylative Diene−Aldehyde Coupling: The Remarkable Effect of P(SiMe3)3 Hee Yeon Cho and James P. Morken pp 7576–7577 DOI: 10.1021/ja101513d Supporting Info

Modulation of the Peptide Backbone Conformation by the Selenoxo Photoswitch Yun Huang, Gnther Jahreis, Christian Lcke, Dirk Wildemann and Gunter Fischer pp 7578–7579 DOI: 10.1021/ja1019386 Supporting Info

Direct Electrodeposition of Tetrahexahedral Pd Nanocrystals with High-Index Facets and High Catalytic Activity for Ethanol Electrooxidation Na Tian, Zhi-You Zhou, Neng-Fei Yu, Li-Yang Wang and Shi-Gang Sun pp 7580–7581 DOI: 10.1021/ja102177r Supporting Info

Conversion of a Zinc Disilazide to a Zinc Hydride Mediated by LiCl Debabrata Mukherjee, Arkady Ellern and Aaron D. Sadow pp 7582–7583 DOI: 10.1021/ja102323g Supporting Info

An Iron-Capped Metal−Organic Polyyne: {[Fe](C≡C)2[W]≡CC≡CC≡[W](C≡C)2[Fe]} Sergey N. Semenov, Shiva F. Taghipourian, Olivier Blacque, Thomas Fox, Koushik Venkatesan and Heinz Berke pp 7584–7585 DOI: 10.1021/ja102570f Supporting Info

Side-Chain Pairing Preferences in the Parallel Coiled-Coil Dimer Motif: Insight on Ion Pairing between Core and Flanking Sites Jay D. Steinkruger, Derek N. Woolfson and Samuel H. Gellman pp 7586–7588 DOI: 10.1021/ja100080q Supporting Info

Determination of Isoleucine Side-Chain Conformations in Ground and Excited States of Proteins from Chemical Shifts D. Flemming Hansen, Philipp Neudecker and Lewis E. Kay pp 7589–7591 DOI: 10.1021/ja102090z Supporting Info

The Transition between Conformal Atomic Layer Epitaxy and Nanowire Growth Ren Bin Yang, Nikolai Zakharov, Oussama Moutanabbir, Kurt Scheerschmidt, Li-Ming Wu, Ulrich Gsele, Julien Bachmann and Kornelius Nielsch pp 7592–7594 DOI: 10.1021/ja102590v Supporting Info

Synthetic Control of Structural Order in N-Alkylthieno[3,4-c]pyrrole-4,6-dione-Based Polymers for Efficient Solar Cells Claudia Piliego, Thomas W. Holcombe, Jessica D. Douglas, Claire H. Woo, Pierre M. Beaujuge and Jean M. J. Frchet pp 7595–7597 DOI: 10.1021/ja103275u Supporting Info

Unusual Reversal of Enantioselectivity in the Proline-Mediated α-Amination of Aldehydes Induced by Tertiary Amine Additives Donna G. Blackmond, Antonio Moran, Matthew Hughes and Alan Armstrong pp 7598–7599 DOI: 10.1021/ja102718x Supporting Info

Copper Catalyzed Asymmetric Propargylation of Aldehydes Daniel R. Fandrick, Keith R. Fandrick, Jonathan T. Reeves, Zhulin Tan, Wenjun Tang, Andrew G. Capacci, Sonia Rodriguez, Jinhua J. Song, Heewon Lee, Nathan K. Yee and Chris H. Senanayake pp 7600–7601 DOI: 10.1021/ja103312x Supporting Info

Polyketide Assembly by Alkene−Alkyne Reductive Cross-Coupling: Spiroketals through the Union of Homoallylic Alcohols Daniel P. Canterbury and Glenn C. Micalizio pp 7602–7604 DOI: 10.1021/ja102888f Supporting Info

Manganese Catalysts for C−H Activation: An Experimental/Theoretical Study Identifies the Stereoelectronic Factor That Controls the Switch between Hydroxylation and Desaturation Pathways Jonathan F. Hull, David Balcells, Effiette L. O. Sauer, Christophe Raynaud, Gary W. Brudvig, Robert H. Crabtree and Odile Eisenstein pp 7605–7616 DOI: 10.1021/ja908744w Supporting Info

Halogenated β,γ-Methylene- and Ethylidene-dGTP-DNA Ternary Complexes with DNA Polymerase β: Structural Evidence for Stereospecific Binding of the Fluoromethylene Analogues Vinod K. Batra, Lars C. Pedersen, William A. Beard, Samuel H. Wilson, Boris A. Kashemirov, Thomas G. Upton, Myron F. Goodman and Charles E. McKenna pp 7617–7625 DOI: 10.1021/ja909370k Supporting Info

On the Mechanism of Ylide-Mediated Cyclopropanations: Evidence for a Proton-Transfer Step and Its Effect on Stereoselectivity Samantha L. Riches, Chandreyee Saha, Noelia Fontn Filgueira, Emma Grange, Eoghan M. McGarrigle and Varinder K. Aggarwal pp 7626–7630 DOI: 10.1021/ja910631u Supporting Info

A Clear Correlation between the Diradical Character of 1,3-Dipoles and Their Reactivity toward Ethylene or Acetylene Benoit Braida, Christof Walter, Bernd Engels and Philippe C. Hiberty pp 7631–7637 DOI: 10.1021/ja100512d Supporting Info

Redox Potential and C−H Bond Cleaving Properties of a Nonheme FeIV═O Complex in Aqueous Solution Dong Wang, Mo Zhang, Philippe Bhlmann and Lawrence Que, Jr. pp 7638–7644 DOI: 10.1021/ja909923w Supporting Info

Computation-Guided Development of Au-Catalyzed Cycloisomerizations Proceeding via 1,2-Si or 1,2-H Migrations: Regiodivergent Synthesis of Silylfurans Alexander S. Dudnik, Yuanzhi Xia, Yahong Li and Vladimir Gevorgyan pp 7645–7655 DOI: 10.1021/ja910290c Supporting Info

What Factors Influence the Rate Constant of Substrate Epoxidation by Compound I of Cytochrome P450 and Analogous Iron(IV)-Oxo Oxidants? Devesh Kumar, Baharan Karamzadeh, G. Narahari Sastry and Sam P. de Visser pp 7656–7667 DOI: 10.1021/ja9106176 Supporting Info

Columnar Organization of Head-to-Tail Self-Assembled Pt4 Rings Peter D. Frischmann, Samuel Guieu, Raymond Tabeshi and Mark J. MacLachlan pp 7668–7675 DOI: 10.1021/ja910886g Supporting Info

Reversible C−C Coupling in a Uranium Biheterocyclic Complex Marisa J. Monreal and Paula L. Diaconescu pp 7676–7683 DOI: 10.1021/ja9109715 Supporting Info

Structural Properties and Dynamic Behavior of Nonfibrillar Oligomers Formed by PrP(106−126) Patrick Walsh, Philipp Neudecker and Simon Sharpe pp 7684–7695 DOI: 10.1021/ja100431q Supporting Info

Insights into Initial Kinetic Nucleation of Gold Nanocrystals Tao Yao, Zhihu Sun, Yuanyuan Li, Zhiyun Pan, He Wei, Yi Xie, Masaharu Nomura, Yasuhiro Niwa, Wensheng Yan, Ziyu Wu, Yong Jiang, Qinghua Liu and Shiqiang Wei pp 7696–7701 DOI: 10.1021/ja101101d Supporting Info

Nanostructured Liquid Crystals Combining Ionic and Electronic Functions Sanami Yazaki, Masahiro Funahashi, Junko Kagimoto, Hiroyuki Ohno and Takashi Kato pp 7702–7708 DOI: 10.1021/ja101366x Supporting Info

Variation in Quadrupole Couplings of α Deuterons in Ubiquitin Suggests the Presence of Cα−Hα···O═C Hydrogen Bonds Devon Sheppard, Da-Wei Li, Raquel Godoy-Ruiz, Rafael Brschweiler and Vitali Tugarinov pp 7709–7719 DOI: 10.1021/ja101691s Supporting Info

Size-Dependent Hydrogen Sorption in Ultrasmall Pd Clusters Embedded in a Mesoporous Carbon Template Claudia Zlotea, Fermin Cuevas, Valrie Paul-Boncour, Eric Leroy, Philippe Dibandjo, Roger Gadiou, Cathie Vix-Guterl and Michel Latroche pp 7720–7729 DOI: 10.1021/ja101795g Supporting Info

Intramolecular Charge Transfer with 1-tert-Butyl-6-cyano-1,2,3,4-tetrahydroquinoline (NTC6) and Other Aminobenzonitriles. A Comparison of Experimental Vapor Phase Spectra and Crystal Structures with Calculations Sergey I. Druzhinin, Peter Mayer, Dietmar Stalke, Rixa von Blow, Mathias Noltemeyer and Klaas A. Zachariasse pp 7730–7744 DOI: 10.1021/ja101336n Supporting Info

Charge-Mediated Adsorption Behavior of CO on MgO-Supported Au Clusters Xiao Lin, Bing Yang, Hadj-Mohamed Benia, Philipp Myrach, Maxim Yulikov, Andreas Aumer, Matthew A. Brown, Martin Sterrer, Oleksander Bondarchuk, Esther Kieseritzky, Jan Rocker, Thomas Risse, Hong-Jun Gao, Niklas Nilius and Hans-Joachim Freund pp 7745–7749 DOI: 10.1021/ja101188x

Shutting Down Secondary Reaction Pathways: The Essential Role of the Pyrrolyl Ligand in Improving Silica Supported d0-ML4 Alkene Metathesis Catalysts from DFT Calculations Xavier Solans-Monfort, Christophe Copret and Odile Eisenstein pp 7750–7757 DOI: 10.1021/ja101597s Supporting Info

Conjugated Polymers That Respond to Oxidation with Increased Emission Eric L. Dane, Sarah B. King and Timothy M. Swager pp 7758–7768 DOI: 10.1021/ja1019063 Supporting Info

Simulation Study of Chiral Two-Dimensional Ultraviolet Spectroscopy of the Protein Backbone Darius Abramavicius, Jun Jiang, Benjamin M. Bulheller, Jonathan D. Hirst and Shaul Mukamel pp 7769–7775 DOI: 10.1021/ja101968g

Total Synthesis of Complestatin: Development of a Pd(0)-Mediated Indole Annulation for Macrocyclization Hiroyuki Shimamura, Steven P. Breazzano, Joie Garfunkle, F. Scott Kimball, John D. Trzupek and Dale L. Boger pp 7776–7783 DOI: 10.1021/ja102304p Supporting Info

Tuning of the Thermochemical and Kinetic Properties of Ascorbate by Its Local Environment: Solution Chemistry and Biochemical Implications Jeffrey J. Warren and James M. Mayer pp 7784–7793 DOI: 10.1021/ja102337n Supporting Info

Molecular Order in a Chromonic Liquid Crystal: A Molecular Simulation Study of the Anionic Azo Dye Sunset Yellow Fatima Chami and Mark R. Wilson pp 7794–7802 DOI: 10.1021/ja102468g Supporting Info

Random Catalyst Walking along Polymerized Poly(3-hexylthiophene) Chains in Kumada Catalyst-Transfer Polycondensation Roman Tkachov, Volodymyr Senkovskyy, Hartmut Komber, Jens-Uwe Sommer and Anton Kiriy pp 7803–7810 DOI: 10.1021/ja102210r Supporting Info

Hydration Isomers of Protonated Phenylalanine and Derivatives: Relative Stabilities from Infrared Photodissociation James S. Prell, Terrence M. Chang, Jeremy T. O’Brien and Evan R. Williams pp 7811–7819 DOI: 10.1021/ja102765w Supporting Info

Molecular Basis of Coupled Protein and Electron Transfer Dynamics of Cytochrome c in Biomimetic Complexes Damin Alvarez-Paggi, Diego F. Martn, Pablo M. DeBiase, Peter Hildebrandt, Marcelo A. Mart and Daniel H. Murgida p 7820 DOI: 10.1021/ja1034045

Design and Construction of Coordination Polymers Michael J. Zaworotko p 7821 DOI: 10.1021/ja103305p

Advances in Friedel−Crafts Acylation Reactions: Catalytic and Green Processes Marco Bandini pp 7821–7822 DOI: 10.1021/ja103390g

Issue 23

Dual-Reactive Surfactant Used for Synthesis of Functional Nanocapsules in Miniemulsion Wenwen Li, Jeong Ae Yoon and Krzysztof Matyjaszewski pp 7823–7825 DOI: 10.1021/ja100685s Supporting Info

Chromium-Catalyzed Homoaldol Equivalent Reaction Employing a Nucleophilic Propenyl Acetate Jun Yong Kang and Brian T. Connell pp 7826–7827 DOI: 10.1021/ja910057g Supporting Info

Intramolecular Halogen Stabilization of Silylium Ions Directs Gearing Dynamics Paola Romanato, Simon Duttwyler, Anthony Linden, Kim K. Baldridge and Jay S. Siegel pp 7828–7829 DOI: 10.1021/ja9109665 Supporting Info

Noninnocent Dithiolene Ligands: A New Oxomolybdenum Complex Possessing a Donor−Acceptor Dithiolene Ligand Kelly G. Matz, Regina P. Mtei, Belinda Leung, Sharon J. Nieter Burgmayer and Martin L. Kirk pp 7830–7831 DOI: 10.1021/ja100220x Supporting Info

Metal−Organic Frameworks as Sensors: A ZIF-8 Based Fabry−Prot Device as a Selective Sensor for Chemical Vapors and Gases Guang Lu and Joseph T. Hupp pp 7832–7833 DOI: 10.1021/ja101415b Supporting Info

Virus-like Particles Templated by DNA Micelles: A General Method for Loading Virus Nanocarriers Minseok Kwak, Inge J. Minten, Diana-Milena Anaya, Andrew J. Musser, Melanie Brasch, Roeland J. M. Nolte, Klaus Mllen, Jeroen J. L. M. Cornelissen and Andreas Herrmann pp 7834–7835 DOI: 10.1021/ja101444j Supporting Info

Large Relaxivity Enhancement of Paramagnetic Lipid Nanoparticles by Restricting the Local Motions of the GdIII Chelates Filip Kielar, Lorenzo Tei, Enzo Terreno and Mauro Botta pp 7836–7837 DOI: 10.1021/ja101518v Supporting Info

Development of a Bioorthogonal and Highly Efficient Conjugation Method for Quantum Dots Using Tetrazine−Norbornene Cycloaddition Hee-Sun Han, Neal K. Devaraj, Jungmin Lee, Scott A. Hilderbrand, Ralph Weissleder and Moungi G. Bawendi pp 7838–7839 DOI: 10.1021/ja101677r Supporting Info

Spatial Control of Entangled Two-Photon Absorption with Organic Chromophores Alica R. Guzman, Michael R. Harpham, zgn Szer, Michael M. Haley and Theodore G. Goodson, III pp 7840–7841 DOI: 10.1021/ja1016816 Supporting Info

Coexisting Hydrophobic Compartments through Self-Sorting in Rod-like Micelles of Bisurea Bolaamphiphiles Asish Pal, S. Karthikeyan and Rint P. Sijbesma pp 7842–7843 DOI: 10.1021/ja101872x Supporting Info

Azulenocyanine: A New Family of Phthalocyanines with Intense Near-IR Absorption Atsuya Muranaka, Mitsuhiro Yonehara and Masanobu Uchiyama pp 7844–7845 DOI: 10.1021/ja101818g Supporting Info

Reduction of Copper(II) Complexes of Tripodal Ligands by Nitric Oxide and Trinitrosation of the Ligands Moushumi Sarma, Apurba Kalita, Pankaj Kumar, Amardeep Singh and Biplab Mondal pp 7846–7847 DOI: 10.1021/ja102279c Supporting Info

Core/Shell Pd/FePt Nanoparticles as an Active and Durable Catalyst for the Oxygen Reduction Reaction Vismadeb Mazumder, Miaofang Chi, Karren L. More and Shouheng Sun pp 7848–7849 DOI: 10.1021/ja1024436 Supporting Info

In Situ Liquid Phase Synthesis of Hydrogen Peroxide from Molecular Oxygen Using Gold Nanoparticle-Loaded Titanium(IV) Dioxide Photocatalyst Miwako Teranishi, Shin-ichi Naya and Hiroaki Tada pp 7850–7851 DOI: 10.1021/ja102651g Supporting Info

CuH-Catalyzed Enantioselective 1,2-Reductions of α,β-Unsaturated Ketones Ralph Moser, arko V. Bokovi, Christopher S. Crowe and Bruce H. Lipshutz pp 7852–7853 DOI: 10.1021/ja102689e Supporting Info

Ruthenium-Catalyzed Hydrogenation of Nitriles: Insights into the Mechanism Rebeca Reguillo, Mary Grellier, Nicolas Vautravers, Laure Vendier and Sylviane Sabo-Etienne pp 7854–7855 DOI: 10.1021/ja102759z Supporting Info

Highly-Selective and Reversible O2 Binding in Cr3(1,3,5-benzenetricarboxylate)2 Leslie J. Murray, Mircea Dinca, Junko Yano, Sachin Chavan, Silvia Bordiga, Craig M. Brown and Jeffrey R. Long pp 7856–7857 DOI: 10.1021/ja1027925 Supporting Info

Diastereoselective Encapsulation of Tartaric Acid by a Helical Aromatic Oligoamide Yann Ferrand, Amol M. Kendhale, Brice Kauffmann, Axelle Grlard, Ccile Marie, Virginie Blot, Muriel Pipelier, Didier Dubreuil and Ivan Huc pp 7858–7859 DOI: 10.1021/ja102794a Supporting Info

Fluorescent Ratiometric MFC Probe Sensitive to Early Stages of α-Synuclein Aggregation Dmytro A. Yushchenko, Jonathan A. Fauerbach, Shyamala Thirunavukkuarasu, Elizabeth A. Jares-Erijman and Thomas M. Jovin pp 7860–7861 DOI: 10.1021/ja102838n Supporting Info

Crystallization of an Achiral Cyclohexanone Ethylene Ketal in Enantiomorphs and Determination of the Absolute Structure Sara Graus, Rosa M. Tejedor, Santiago Uriel, Jos Luis Serrano, Ibon Alkorta and Jos Elguero pp 7862–7863 DOI: 10.1021/ja1025062 Supporting Info

Pairwise Selective Formation of Aromatic Stacks in a Coordination Cage Takashi Murase, Kosuke Otsuka and Makoto Fujita pp 7864–7865 DOI: 10.1021/ja103109z Supporting Info

Metal-Triggered Collagen Peptide Disk Formation David E. Przybyla and Jean Chmielewski pp 7866–7867 DOI: 10.1021/ja103148t Supporting Info

Helix Formation in Preorganized β/γ-Peptide Foldamers: Hydrogen-Bond Analogy to the α-Helix without α-Amino Acid Residues Li Guo, Aaron M. Almeida, Weicheng Zhang, Andrew G. Reidenbach, Soo Hyuk Choi, Ilia A. Guzei and Samuel H. Gellman pp 7868–7869 DOI: 10.1021/ja103233a Supporting Info

Synthesis and Preliminary Biological Studies of 3-Substituted Indoles Accessed by a Palladium-Catalyzed Enantioselective Alkene Difunctionalization Reaction Tejas P. Pathak, Keith M. Gligorich, Bryan E. Welm and Matthew S. Sigman pp 7870–7871 DOI: 10.1021/ja103472a Supporting Info

Iridium/Chiral Diene-Catalyzed Asymmetric 1,6-Addition of Arylboroxines to α,β,γ,δ-Unsaturated Carbonyl Compounds Takahiro Nishimura, Yuichi Yasuhara, Takahiro Sawano and Tamio Hayashi pp 7872–7873 DOI: 10.1021/ja1034842 Supporting Info

Reversible Addition of Alkynes to Gallium Complex of Chelating Diamide Ligand Igor L. Fedushkin, Alexander S. Nikipelov and Konstantin A. Lyssenko pp 7874–7875 DOI: 10.1021/ja103467a Supporting Info

Total Synthesis of (+)-Sieboldine A Stephen M. Canham, David J. France and Larry E. Overman pp 7876–7877 DOI: 10.1021/ja103666n Supporting Info

Zirconium(IV)- and Hafnium(IV)-Catalyzed Highly Enantioselective Epoxidation of Homoallylic and Bishomoallylic Alcohols Zhi Li and Hisashi Yamamoto pp 7878–7880 DOI: 10.1021/ja100951u Supporting Info

Enantioselective Synthesis of (E)-δ-Stannyl Homoallylic Alcohols via Aldehyde Allylboration Using α-Stannylallylboranes Generated by Allene Hydroboration Followed by a Highly Diastereoselective 1,3-Boratropic Shift Ming Chen, Daniel H. Ess and William R. Roush pp 7881–7883 DOI: 10.1021/ja103041u Supporting Info

Copper-Catalyzed Tandem [2,3]-Rearrangement and 6π-3-Azatriene Electrocyclization in (E)-O-Propargylic α,β-Unsaturated Oximes Itaru Nakamura, Dong Zhang and Masahiro Terada pp 7884–7886 DOI: 10.1021/ja102436z Supporting Info

The Chameleonic Nature of Electron Transport through π-Stacked Systems Gemma C. Solomon, Carmen Herrmann, Josh Vura-Weis, Michael R. Wasielewski and Mark A. Ratner pp 7887–7889 DOI: 10.1021/ja102434m Supporting Info

Catalytic Asymmetric Protonation of Chiral Calcium Enolates via 1,4-Addition of Malonates Thomas Poisson, Yasuhiro Yamashita and Sh Kobayashi pp 7890–7892 DOI: 10.1021/ja102555a Supporting Info

Size-Selective Separation of Macromolecules by Nanochannel Titania Membrane with Self-Cleaning (Declogging) Ability Poulomi Roy, Tuli Dey, Kiyoung Lee, Doohun Kim, Ben Fabry and Patrik Schmuki pp 7893–7895 DOI: 10.1021/ja102712j Supporting Info

Cationic Rhodium(I) Complex-Catalyzed [3 + 2] and [2 + 1] Cycloadditions of Propargyl Esters with Electron-Deficient Alkynes and Alkenes Yu Shibata, Keiichi Noguchi and Ken Tanaka pp 7896–7898 DOI: 10.1021/ja102418h Supporting Info

High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata and Michinori Suginome pp 7899–7901 DOI: 10.1021/ja102428q Supporting Info

Cubic Octanuclear Ni(II) Clusters in Highly Porous Polypyrazolyl-Based Materials Norberto Masciocchi, Simona Galli, Valentina Colombo, Angelo Maspero, Giovanni Palmisano, Behnam Seyyedi, Carlo Lamberti and Silvia Bordiga pp 7902–7904 DOI: 10.1021/ja102862j Supporting Info

Catalytic Asymmetric Synthesis of R207910 Yutaka Saga, Rie Motoki, Sae Makino, Yohei Shimizu, Motomu Kanai and Masakatsu Shibasaki pp 7905–7907 DOI: 10.1021/ja103183r Supporting Info

NMR Investigations of the Rieske Protein from Thermus thermophilus Support a Coupled Proton and Electron Transfer Mechanism Kuang-Lung Hsueh, William M. Westler and John L. Markley pp 7908–7918 DOI: 10.1021/ja1026387 Supporting Info

Multimodal Study of Secondary Interactions in Cp*Ir Complexes of Imidazolylphosphines Bearing an NH Group Douglas B. Grotjahn, John E. Kraus, Hani Amouri, Marie-Noelle Rager, Andrew L. Cooksy, Amy J. Arita, Sara A. Cortes-Llamas, Arthur A. Mallari, Antonio G. DiPasquale, Curtis E. Moore, Louise M. Liable-Sands, James D. Golen, Lev N. Zakharov and Arnold L. Rheingold pp 7919–7934 DOI: 10.1021/ja906712g Supporting Info

Conformations of End-Tethered DNA Molecules on Gold Surfaces: Influences of Applied Electric Potential, Electrolyte Screening, and Temperature Wolfgang Kaiser and Ulrich Rant pp 7935–7945 DOI: 10.1021/ja908727d Supporting Info

Optimizing Single-Molecule Conductivity of Conjugated Organic Oligomers with Carbodithioate Linkers Yangjun Xing, Tae-Hong Park, Ravindra Venkatramani, Shahar Keinan, David N. Beratan, Michael J. Therien and Eric Borguet pp 7946–7956 DOI: 10.1021/ja909559m Supporting Info

Biophysical Mimicry of Lung Surfactant Protein B by Random Nylon-3 Copolymers Michelle T. Dohm, Brendan P. Mowery, Ann M. Czyzewski, Shannon S. Stahl, Samuel H. Gellman and Annelise E. Barron pp 7957–7967 DOI: 10.1021/ja909734n Supporting Info

Direct Observations of Oxygen-induced Platinum Nanoparticle Ripening Studied by In Situ TEM Søren B. Simonsen, Ib Chorkendorff, Søren Dahl, Magnus Skoglundh, Jens Sehested and Stig Helveg pp 7968–7975 DOI: 10.1021/ja910094r Supporting Info

Small Molecule Modifiers of MicroRNA miR-122 Function for the Treatment of Hepatitis C Virus Infection and Hepatocellular Carcinoma Douglas D. Young, Colleen M. Connelly, Christoph Grohmann and Alexander Deiters pp 7976–7981 DOI: 10.1021/ja910275u Supporting Info

Direct Observation of Adsorption-Induced Inactivation of Antibody Fragments Surrounded by Mixed-PEG Layer on a Gold Surface Keitaro Yoshimoto, Motohiko Nishio, Hiroaki Sugasawa and Yukio Nagasaki pp 7982–7989 DOI: 10.1021/ja910372e Supporting Info

Membrane-Mediated Effect on Ion Channels Induced by the Anesthetic Drug Ketamine Hansjrg Jerabek, Georg Pabst, Michael Rappolt and Thomas Stockner pp 7990–7997 DOI: 10.1021/ja910843d

In Situ Generated Bulky Palladium Hydride Complexes as Catalysts for the Efficient Isomerization of Olefins. Selective Transformation of Terminal Alkenes to 2-Alkenes Delphine Gauthier, Anders T. Lindhardt, Esben P. K. Olsen, Jacob Overgaard and Troels Skrydstrup pp 7998–8009 DOI: 10.1021/ja9108424 Supporting Info

Detection of Native-State Nonadditivity in Double Mutant Cycles via Hydrogen Exchange Joshua A. Boyer, Cristina J. Clay, K. Scott Luce, Marshall H. Edgell and Andrew L. Lee pp 8010–8019 DOI: 10.1021/ja1003922 Supporting Info

Molecular Recognition at the Membrane−Water Interface: Controlling Integral Peptide Helices by Off-Membrane Nucleobase Pairing Philipp Erik Schneggenburger, Stefan Mllar, Brigitte Worbs, Claudia Steinem and Ulf Diederichsen pp 8020–8028 DOI: 10.1021/ja1006349 Supporting Info

Selective Manipulation of ICT and PET Processes in Styryl-Bodipy Derivatives: Applications in Molecular Logic and Fluorescence Sensing of Metal Ions O. Altan Bozdemir, Ruslan Guliyev, Onur Buyukcakir, Sencer Selcuk, Safacan Kolemen, Gulcihan Gulseren, Tugrul Nalbantoglu, Hande Boyaci and Engin U. Akkaya pp 8029–8036 DOI: 10.1021/ja1008163 Supporting Info

Molecular Restructuring of Water and Lipids upon the Interaction of DNA with Lipid Monolayers R. Kramer Campen, Thuy T. M. Ngo, Maria Sovago, Jean-Marie Ruysschaert and Mischa Bonn pp 8037–8047 DOI: 10.1021/ja100838q Supporting Info

Donor−Acceptor Conjugates of Lanthanum Endohedral Metallofullerene and π-Extended Tetrathiafulvalene Yuta Takano, M. ngeles Herranz, Nazario Martn, Shankara Gayathri Radhakrishnan, Dirk M. Guldi, Takahiro Tsuchiya, Shigeru Nagase and Takeshi Akasaka pp 8048–8055 DOI: 10.1021/ja100665q Supporting Info

Hydrogen Generation from Alcohols Catalyzed by Ruthenium−Triphenylphosphine Complexes: Multiple Reaction Pathways Nicolas Sieffert and Michael Bhl pp 8056–8070 DOI: 10.1021/ja101044c Supporting Info

Hierarchical Supramolecular Ordering with Biaxial Orientation of a Combined Main-Chain/Side-Chain Liquid-Crystalline Polymer Obtained from Radical Polymerization of 2-Vinylterephthalate He-Lou Xie, Chang-Kai Jie, Zhen-Qiang Yu, Xuan-Bo Liu, Hai-Liang Zhang, Zhihao Shen, Er-Qiang Chen and Qi-Feng Zhou pp 8071–8080 DOI: 10.1021/ja101184u Supporting Info

Sonogashira Coupling on an Extended Gold Surface in Vacuo: Reaction of Phenylacetylene with Iodobenzene on Au(111) Vijay K. Kanuru, Georgios Kyriakou, Simon K. Beaumont, Anthoula C. Papageorgiou, David J. Watson and Richard M. Lambert pp 8081–8086 DOI: 10.1021/ja1011542 Supporting Info

Solid-State NMR Reveals the Hydrophobic-Core Location of Poly(amidoamine) Dendrimers in Biomembranes Pieter E. S. Smith, Jeffrey R. Brender, Ulrich H. N. Drr, Jiadi Xu, Douglas G. Mullen, Mark M. Banaszak Holl and Ayyalusamy Ramamoorthy pp 8087–8097 DOI: 10.1021/ja101524z Supporting Info

Temperature Effects on the Solvent-Dependent Deactivation of Singlet Oxygen Rasmus Lybech Jensen, Jacob Arnbjerg and Peter R. Ogilby pp 8098–8105 DOI: 10.1021/ja101753n Supporting Info

Molecular Spintronics in Mixed-Valence Magnetic Dimers: The Double-Exchange Blockade Mechanism Alessandro Soncini, Talal Mallah and Liviu F. Chibotaru pp 8106–8114 DOI: 10.1021/ja101887f Supporting Info

Multiple N-Methylation of MT-II Backbone Amide Bonds Leads to Melanocortin Receptor Subtype hMC1R Selectivity: Pharmacological and Conformational Studies Lucas Doedens, Florian Opperer, Minying Cai, Johannes G. Beck, Matt Dedek, Erin Palmer, Victor J. Hruby and Horst Kessler pp 8115–8128 DOI: 10.1021/ja101428m Supporting Info

Confinement Effect and Synergistic Function of H-ZSM-5/Cu-ZnO-Al2O3 Capsule Catalyst for One-Step Controlled Synthesis Guohui Yang, Noritatsu Tsubaki, Jun Shamoto, Yoshiharu Yoneyama and Yi Zhang pp 8129–8136 DOI: 10.1021/ja101882a Supporting Info

Crystal and Magnetic Structures and Properties of BiMnO3+δ Alexei A. Belik, Katsuaki Kodama, Naoki Igawa, Shin-ichi Shamoto, Kosuke Kosuda and Eiji Takayama-Muromachi pp 8137–8144 DOI: 10.1021/ja102014n Supporting Info

The Membrane-Bound State of K2P Potassium Channels Werner Treptow and Michael L. Klein pp 8145–8151 DOI: 10.1021/ja102191s Supporting Info

Growth and Shape-Ordering of Iron Nanostructures on Au Single Crystalline Electrodes in an Ionic Liquid: A Paradigm of Magnetostatic Coupling Yi-Min Wei, Yong-Chun Fu, Jia-Wei Yan, Chun-Feng Sun, Zhan Shi, Zhao-Xiong Xie, De-Yin Wu and Bing-Wei Mao pp 8152–8157 DOI: 10.1021/ja1021816 Supporting Info

Sensitive Efficiency of Photoinduced Electron Transfer to Band Gaps of Semiconductive Single-Walled Carbon Nanotubes with Supramolecularly Attached Zinc Porphyrin Bearing Pyrene Glues Eranda Maligaspe, Atula S. D. Sandanayaka, Taku Hasobe, Osamu Ito and Francis D’Souza pp 8158–8164 DOI: 10.1021/ja101776p Supporting Info

Nanoscale Morphology in Precisely Sequenced Poly(ethylene-co-acrylic acid) Zinc Ionomers Michelle E. Seitz, Christopher D. Chan, Kathleen L. Opper, Travis W. Baughman, Kenneth B. Wagener and Karen I. Winey pp 8165–8174 DOI: 10.1021/ja101991d Supporting Info

Chemistry under Cover: Tuning Metal−Graphene Interaction by Reactive Intercalation Peter Sutter, Jerzy T. Sadowski and Eli A. Sutter pp 8175–8179 DOI: 10.1021/ja102398n Supporting Info

Graphene Oxide Sheets at Interfaces Jaemyung Kim, Laura J. Cote, Franklin Kim, Wa Yuan, Kenneth R. Shull and Jiaxing Huang pp 8180–8186 DOI: 10.1021/ja102777p Supporting Info

From Redox Gating to Quantized Charging Zhihai Li, Yaqing Liu, Stijn F. L. Mertens, Ilya V. Pobelov and Thomas Wandlowski pp 8187–8193 DOI: 10.1021/ja102754n Supporting Info

Donor−Acceptor Biomorphs from the Ionic Self-Assembly of Porphyrins Kathleen E. Martin, Zhongchun Wang, Tito Busani, Robert M. Garcia, Zhu Chen, Yingbing Jiang, Yujiang Song, John L. Jacobsen, Tony T. Vu, Neil E. Schore, Brian S. Swartzentruber, Craig J. Medforth and John A. Shelnutt pp 8194–8201 DOI: 10.1021/ja102194x Supporting Info

Twisted Metal−Amino Acid Nanobelts: Chirality Transcription from Molecules to Frameworks Chao Li, Ke Deng, Zhiyong Tang and Lei Jiang pp 8202–8209 DOI: 10.1021/ja102827f Supporting Info

Chirality and Electronic Structure of the Thiolate-Protected Au38 Nanocluster Olga Lopez-Acevedo, Hironori Tsunoyama, Tatsuya Tsukuda, Hannu Hkkinen and Christine M. Aikens pp 8210–8218 DOI: 10.1021/ja102934q Supporting Info

Total Synthesis of Englerin A K. C. Nicolaou, Qiang Kang, Sin Yee Ng and David Y.-K. Chen pp 8219–8222 DOI: 10.1021/ja102927n Supporting Info

A Concise Total Synthesis of Saliniketal B Jun Liu and Jef K. De Brabander p 8223 DOI: 10.1021/ja1037116

A Concise Synthesis of Berkelic Acid Inspired by Combining the Natural Products Spicifernin and Pulvilloric Acid Christopher F. Bender, Francis K. Yoshimoto, Christopher L. Paradise and Jef K. De Brabander p 8223 DOI: 10.1021/ja103712r

Tandem Nucleophilic Addition/Fragmentation Reactions and Synthetic Versatility of Vinylogous Acyl Triflates Shin Kamijo and Gregory B. Dudley p 8223 DOI: 10.1021/ja103806p

Cinchona Alkaloids in Synthesis & Catalysis: Ligands, Immobilization and Organocatalysis Daniel Seidel p 8224 DOI: 10.1021/ja103586v

Issue 24

Determination of Molecular Torsion Angles Using Nuclear Singlet Relaxation Michael C. D. Tayler, Sabrina Marie, A. Ganesan and Malcolm H. Levitt pp 8225–8227 DOI: 10.1021/ja1012917 Supporting Info

Distance Determination in Proteins inside Xenopus laevis Oocytes by Double Electron−Electron Resonance Experiments Ryuji Igarashi, Tomomi Sakai, Hideyuki Hara, Takeshi Tenno, Toshiaki Tanaka, Hidehito Tochio and Masahiro Shirakawa pp 8228–8229 DOI: 10.1021/ja906104e Supporting Info

Nanoporous Linear Polyethylene from a Block Polymer Precursor Louis M. Pitet, Mark A. Amendt and Marc A. Hillmyer pp 8230–8231 DOI: 10.1021/ja100985d Supporting Info

From Sensors to Silencers: Quinoline- and Benzimidazole-Sulfonamides as Inhibitors for Zinc Proteases Matthieu Rouffet, Csar Augusto F. de Oliveira, Yael Udi, Arpita Agrawal, Irit Sagi, J. Andrew McCammon and Seth M. Cohen pp 8232–8233 DOI: 10.1021/ja101088j Supporting Info

Ozone Formation from Illuminated Titanium Dioxide Surfaces Mara Eugenia Monge, Christian George, Barbara D’Anna, Jean-Franois Doussin, Adla Jammoul, Junnan Wang, Grgory Eyglunent, Graldine Solignac, Vronique Dale and Abdelwahid Mellouki pp 8234–8235 DOI: 10.1021/ja1018755 Supporting Info

Nanotube Formation through the Continuous One-Dimensional Fusion of Hollow Nanocapsules Composed of Layer-by-Layer Poly(lactic acid) Stereocomplex Films Kenta Kondo, Toshiyuki Kida, Yuji Ogawa, Yuuya Arikawa and Mitsuru Akashi pp 8236–8237 DOI: 10.1021/ja1020537 Supporting Info

Enantioselective Construction of Highly Substituted Pyrrolidines by Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Ketimines Barry M. Trost and Steven M. Silverman pp 8238–8240 DOI: 10.1021/ja102102d Supporting Info

Effect of Nanoparticle Conjugation on Gene Silencing by RNA Interference Neetu Singh, Amit Agrawal, Anthony K. L. Leung, Phillip A. Sharp and Sangeeta N. Bhatia pp 8241–8243 DOI: 10.1021/ja102132e Supporting Info

Visible Fluorescence Detection of Type III Protein Secretion from Bacterial Pathogens Jacob S. Yount, Lun K. Tsou, Paul D. Dossa, Amy L. Kullas, Adrianus W. M. van der Velden and Howard C. Hang pp 8244–8245 DOI: 10.1021/ja102257v Supporting Info

Surface-Functionalizable Polymer Nanogels with Facile Hydrophobic Guest Encapsulation Capabilities Ja-Hyoung Ryu, Siriporn Jiwpanich, Reuben Chacko, Sean Bickerton and S. Thayumanavan pp 8246–8247 DOI: 10.1021/ja102316a Supporting Info

Sulfate Ion Patterns Water at Long Distance Jeremy T. O’Brien, James S. Prell, Matthew F. Bush and Evan R. Williams pp 8248–8249 DOI: 10.1021/ja1024113

Photoinduced Metal-to-Metal Charge Transfer toward Single-Chain Magnet Tao Liu, Yan-Juan Zhang, Shinji Kanegawa and Osamu Sato pp 8250–8251 DOI: 10.1021/ja1027953 Supporting Info

Measurement of Site-Specific 13C Spin−Lattice Relaxation in a Crystalline Protein Jzef R. Lewandowski, Julien Sein, Hans Jrgen Sass, Stephan Grzesiek, Martin Blackledge and Lyndon Emsley pp 8252–8254 DOI: 10.1021/ja102744b Supporting Info

A Resonance Assignment Method for Oriented-Sample Solid-State NMR of Proteins Robert W. Knox, George J. Lu, Stanley J. Opella and Alexander A. Nevzorov pp 8255–8257 DOI: 10.1021/ja102932n

A Stable Doubly Hydrogen-Bridged Butterfly-Shaped Diborane(4) Compound Yoshiaki Shoji, Tsukasa Matsuo, Daisuke Hashizume, Hiroyuki Fueno, Kazuyoshi Tanaka and Kohei Tamao pp 8258–8260 DOI: 10.1021/ja102913g Supporting Info

Does Stacking Restrain the Photodynamics of Individual Nucleobases? Dana Nachtigallov, Tom Zelen, Matthias Ruckenbauer, Thomas Mller, Mario Barbatti, Pavel Hobza and Hans Lischka pp 8261–8263 DOI: 10.1021/ja1029705 Supporting Info

Step-by-Step Assembly of Self-Patterning Polyelectrolyte Films Violating (Almost) All Rules of Layer-by-Layer Deposition Nejla Cini, Tlay Tulun, Gero Decher and Vincent Ball pp 8264–8265 DOI: 10.1021/ja102611q Supporting Info

An Organocatalytic Asymmetric Nazarov Cyclization Ashok K. Basak, Naoyuki Shimada, William F. Bow, David A. Vicic and Marcus A. Tius pp 8266–8267 DOI: 10.1021/ja103028r Supporting Info

A Radical on the Met-Tyr-Trp Modification Required for Catalase Activity in Catalase-Peroxidase Is Established by Isotopic Labeling and Site-Directed Mutagenesis Xiangbo Zhao, Javier Suarez, Abdelahad Khajo, Shengwei Yu, Leonid Metlitsky and Richard S. Magliozzo pp 8268–8269 DOI: 10.1021/ja103311e Supporting Info

PyDipSi: A General and Easily Modifiable/Traceless Si-Tethered Directing Group for C−H Acyloxylation of Arenes Natalia Chernyak, Alexander S. Dudnik, Chunhui Huang and Vladimir Gevorgyan pp 8270–8272 DOI: 10.1021/ja1033167 Supporting Info

Copper Catalyzed Arylation/C−C Bond Activation: An Approach toward α-Aryl Ketones Chuan He, Sheng Guo, Li Huang and Aiwen Lei pp 8273–8275 DOI: 10.1021/ja1033777 Supporting Info

Gold(I)-Catalyzed Enantioselective Polycyclization Reactions Steven G. Sethofer, Timo Mayer and F. Dean Toste pp 8276–8277 DOI: 10.1021/ja103544p Supporting Info

Autohydration of Nanosized Cubic Zirconium Tungstate Nathan A. Banek, Hassan I. Baiz, Akena Latigo and Cora Lind pp 8278–8279 DOI: 10.1021/ja101475f

Total Structure Determination of Thiolate-Protected Au38 Nanoparticles Huifeng Qian, William T. Eckenhoff, Yan Zhu, Tomislav Pintauer and Rongchao Jin pp 8280–8281 DOI: 10.1021/ja103592z Supporting Info

Cyclopropylazetoindolines as Precursors to C(3)-Quaternary-Substituted Indolines Vinson R. Espejo, Xi-Bo Li and Jon D. Rainier pp 8282–8284 DOI: 10.1021/ja103428y Supporting Info

Gated Ion Transport through Dense Carbon Nanotube Membranes Miao Yu, Hans H. Funke, John L. Falconer and Richard D. Noble pp 8285–8290 DOI: 10.1021/ja9091769 Supporting Info

Molecular Mechanism of the Glycosylation Step Catalyzed by Golgi α-Mannosidase II: A QM/MM Metadynamics Investigation Luis Petersen, Albert Ardvol, Carme Rovira and Peter J. Reilly pp 8291–8300 DOI: 10.1021/ja909249u Supporting Info

Static and Dynamic Electrowetting of an Ionic Liquid in a Solid/Liquid/Liquid System Mani Paneru, Craig Priest, Rossen Sedev and John Ralston pp 8301–8308 DOI: 10.1021/ja9106397

The Protease-Mediated Nucleus Shuttles of Subnanometer Gold Quantum Dots for Real-Time Monitoring of Apoptotic Cell Death Shu-Yi Lin, Nai-Tzu Chen, Shu-Pin Sun, Jerry C. Chang, Yu-Chao Wang, Chung-Shi Yang and Leu-Wei Lo pp 8309–8315 DOI: 10.1021/ja100561k

Combined Multimodal Optical Imaging and Targeted Gene Silencing Using Stimuli-Transforming Nanotheragnostics Min Suk Shim, Chang Soo Kim, Yeh-Chan Ahn, Zhongping Chen and Young Jik Kwon pp 8316–8324 DOI: 10.1021/ja100580y Supporting Info

Can π6+π4 = 10? Exploring Cycloaddition Routes to Highly Unsaturated 10-Membered Rings Roger W. Alder, Jeremy N. Harvey, Guy C. Lloyd-Jones and Josep M. Oliva pp 8325–8337 DOI: 10.1021/ja1008135 Supporting Info

Layer-by-Layer Assembly of Polyelectrolytes into Ionic Current Rectifying Solid-State Nanopores: Insights from Theory and Experiment Mubarak Ali, Basit Yameen, Javier Cervera, Patricio Ramrez, Reinhard Neumann, Wolfgang Ensinger, Wolfgang Knoll and Omar Azzaroni pp 8338–8348 DOI: 10.1021/ja101014y

Synthesis of [(DPPNCH2CH2)3N]3− Molybdenum Complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and Studies Relevant to Catalytic Reduction of Dinitrogen Michael R. Reithofer, Richard R. Schrock and Peter Mller pp 8349–8358 DOI: 10.1021/ja1008213 Supporting Info

Sulfur K-Edge X-ray Absorption Spectroscopy and Density Functional Calculations on Mo(IV) and Mo(VI)═O Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in DMSO Reductase and Related Functional Analogues Adam L. Tenderholt, Jun-Jieh Wang, Robert K. Szilagyi, Richard H. Holm, Keith O. Hodgson, Britt Hedman and Edward I. Solomon pp 8359–8371 DOI: 10.1021/ja910369c Supporting Info

Reversibly Photoswitchable Nucleosides: Synthesis and Photochromic Properties of Diarylethene-Functionalized 7-Deazaadenosine Derivatives Marco Singer and Andres Jschke pp 8372–8377 DOI: 10.1021/ja1024782 Supporting Info

Chemical Analysis of the Superatom Model for Sulfur-Stabilized Gold Nanoparticles Jeffrey R. Reimers, Yun Wang, Burak O. Cankurtaran and Michael J. Ford pp 8378–8384 DOI: 10.1021/ja101083v Supporting Info

Site-Specific Incorporation of 3-Nitrotyrosine as a Probe of pKa Perturbation of Redox-Active Tyrosines in Ribonucleotide Reductase Kenichi Yokoyama, Ulla Uhlin and JoAnne Stubbe pp 8385–8397 DOI: 10.1021/ja101097p Supporting Info

Artificial Photosynthesis over Crystalline TiO2-Based Catalysts: Fact or Fiction? Chieh-Chao Yang, Yi-Hui Yu, Bart van der Linden, Jeffrey C. S. Wu and Guido Mul pp 8398–8406 DOI: 10.1021/ja101318k Supporting Info

NMR Characterization of Long-Range Order in Intrinsically Disordered Proteins Loc Salmon, Gabrielle Nodet, Valry Ozenne, Guowei Yin, Malene Ringkjøbing Jensen, Markus Zweckstetter and Martin Blackledge pp 8407–8418 DOI: 10.1021/ja101645g Supporting Info

Palladium-Catalyzed Oxidative Arylhalogenation of Alkenes: Synthetic Scope and Mechanistic Insights Dipannita Kalyani, Andrew D. Satterfield and Melanie S. Sanford pp 8419–8427 DOI: 10.1021/ja101851v Supporting Info

On the Distinction between Nitroxyl and Nitric Oxide Using Nitronyl Nitroxides Uri Samuni, Yuval Samuni and Sara Goldstein pp 8428–8432 DOI: 10.1021/ja101945j

Label-Free Imaging of Lipophilic Bioactive Molecules during Lipid Digestion by Multiplex Coherent Anti-Stokes Raman Scattering Microspectroscopy James P. R. Day, Gianluca Rago, Katrin F. Domke, Krassimir P. Velikov and Mischa Bonn pp 8433–8439 DOI: 10.1021/ja102069d

Organic n-Channel Field-Effect Transistors Based on Arylenediimide-Thiophene Derivatives Roco Ponce Ortiz, Helena Herrera, Ral Blanco, Hui Huang, Antonio Facchetti, Tobin J. Marks, Yan Zheng and Jos L. Segura pp 8440–8452 DOI: 10.1021/ja1018783 Supporting Info

Determination of Oxygen Sources for Oxidation of Benzene on TiO2 Photocatalysts in Aqueous Solutions Containing Molecular Oxygen Thuan Duc Bui, Akira Kimura, Shigeru Ikeda and Michio Matsumura pp 8453–8458 DOI: 10.1021/ja102305e Supporting Info

On the Molecular and Electronic Structures of AsP3 and P4 Brandi M. Cossairt, Christopher C. Cummins, Ashley R. Head, Dennis L. Lichtenberger, Raphael J. F. Berger, Stuart A. Hayes, Norbert W. Mitzel and Gang Wu pp 8459–8465 DOI: 10.1021/ja102580d Supporting Info

Multifunctional Mesoporous Composite Microspheres with Well-Designed Nanostructure: A Highly Integrated Catalyst System Yonghui Deng, Yue Cai, Zhenkun Sun, Jia Liu, Chong Liu, Jing Wei, Wei Li, Chang Liu, Yao Wang and Dongyuan Zhao pp 8466–8473 DOI: 10.1021/ja1025744 Supporting Info

Crystal Growth and Structure and Magnetic Properties of the 5d Oxide Ca3LiOsO6: Extended Superexchange Magnetic Interaction in Oxide Youguo Shi, Yanfeng Guo, Shan Yu, Masao Arai, Akira Sato, Alexei A. Belik, Kazunari Yamaura and Eiji Takayama-Muromachi pp 8474–8483 DOI: 10.1021/ja102606q Supporting Info

Infrared Spectra and Quantum Chemical Calculations of the Uranium Carbide Molecules UC and CUC with Triple Bonds Xuefeng Wang, Lester Andrews, Per-Åke Malmqvist, Bjrn O. Roos, Antnio P. Gonalves, Cludia C. L. Pereira, Joaquim Maralo, Claude Godart and Benjamin Villeroy pp 8484–8488 DOI: 10.1021/ja102475t Supporting Info

Total Synthesis and Evaluation of a Key Series of C5-Substituted Vinblastine Derivatives Porino Va, Erica L. Campbell, William M. Robertson and Dale L. Boger pp 8489–8495 DOI: 10.1021/ja1027748 Supporting Info

Chromophore Formation in DsRed Occurs by a Branched Pathway Rita L. Strack, Daniel E. Strongin, Laurens Mets, Benjamin S. Glick and Robert J. Keenan pp 8496–8505 DOI: 10.1021/ja1030084 Supporting Info

Total Synthesis of Enantiopure Phalarine via a Stereospecific Pictet−Spengler Reaction: Traceless Transfer of Chirality from l-Tryptophan John D. Trzupek, Dongjoo Lee, Brendan M. Crowley, Vasilios M. Marathias and Samuel J. Danishefsky pp 8506–8512 DOI: 10.1021/ja1030968 Supporting Info

Intramolecular Catalysis of Phosphodiester Hydrolysis by Two Imidazoles Elisa S. Orth, Tiago A. S. Brando, Bruno S. Souza, Josefredo R. Pliego, Boniek G. Vaz, Marcos N. Eberlin, Anthony J. Kirby and Faruk Nome pp 8513–8523 DOI: 10.1021/ja1034733 Supporting Info

Modern Molecular Photochemistry of Organic Molecules Mark G. Steinmetz p 8524 DOI: 10.1021/ja1036176

Organotransition Metal Chemistry: From Bonding to Catalysis Shannon S. Stahl pp 8524–8525 DOI: 10.1021/ja103695e

Chiral Separations by Capillary Electrophoresis Apryll M. Stalcup pp 8525–8526 DOI: 10.1021/ja104079q

Single Particle Tracking and Single Molecule Energy Transfer Linda Peteanu p 8526 DOI: 10.1021/ja1037758

Issue 25

Intramolecular [1 + 2] and [3 + 2] Cycloaddition Reactions of Cyclopropenone Ketals Paresma R. Patel and Dale L. Boger pp 8527–8529 DOI: 10.1021/ja103933n Supporting Info

Columnar Liquid Crystal with a Spontaneous Polarization along the Columnar Axis Daigo Miyajima, Fumito Araoka, Hideo Takezoe, Jungeun Kim, Kenichi Kato, Masaki Takata and Takuzo Aida pp 8530–8531 DOI: 10.1021/ja101866e Supporting Info

Catalytic Asymmetric Roskamp Reaction of α-Alkyl-α-diazoesters with Aromatic Aldehydes: Highly Enantioselective Synthesis of α-Alkyl-β-keto Esters Wei Li, Jun Wang, Xiaolei Hu, Ke Shen, Wentao Wang, Yangyang Chu, Lili Lin, Xiaohua Liu and Xiaoming Feng pp 8532–8533 DOI: 10.1021/ja102832f Supporting Info

Nonproductive Events in Ring-Closing Metathesis Using Ruthenium Catalysts Ian C. Stewart, Benjamin K. Keitz, Kevin M. Kuhn, Renee M. Thomas and Robert H. Grubbs pp 8534–8535 DOI: 10.1021/ja1029045 Supporting Info

Catalytic Asymmetric Transacetalization Ilija ori, Sreekumar Vellalath and Benjamin List pp 8536–8537 DOI: 10.1021/ja102753d Supporting Info

Two-Step Relaxation in a Linear Tetranuclear Dysprosium(III) Aggregate Showing Single-Molecule Magnet Behavior Yun-Nan Guo, Gong-Feng Xu, Patrick Gamez, Lang Zhao, Shuang-Yan Lin, Ruiping Deng, Jinkui Tang and Hong-Jie Zhang pp 8538–8539 DOI: 10.1021/ja103018m Supporting Info

Direct Evidence of Water-Assisted Sintering of Cobalt on Carbon Nanofiber Catalysts during Simulated Fischer−Tropsch Conditions Revealed with in Situ Mssbauer Spectroscopy G. Leendert Bezemer, Tom J. Remans, Alexander P. van Bavel and A. Iulian Dugulan pp 8540–8541 DOI: 10.1021/ja103002k Supporting Info

N−H Activation of Amines and Ammonia by Ru via Metal−Ligand Cooperation Eugene Khaskin, Mark A. Iron, Linda J. W. Shimon, Jing Zhang and David Milstein pp 8542–8543 DOI: 10.1021/ja103130u Supporting Info

pH-Responsive Molecular Tweezers Jeanne Leblond, Hui Gao, Anne Petitjean and Jean-Christophe Leroux pp 8544–8545 DOI: 10.1021/ja103153t Supporting Info

Controlling Phase Separation and Optical Properties in Conjugated Polymers through Selenophene−Thiophene Copolymerization Jon Hollinger, Ashlee A. Jahnke, Neil Coombs and Dwight S. Seferos pp 8546–8547 DOI: 10.1021/ja103191u Supporting Info

Deformations in Si−Li Anodes Upon Electrochemical Alloying in Nano-Confined Space Benjamin Hertzberg, Alexander Alexeev and Gleb Yushin pp 8548–8549 DOI: 10.1021/ja1031997 Supporting Info

Gold-Catalyzed One-Step Practical Synthesis of Oxetan-3-ones from Readily Available Propargylic Alcohols Longwu Ye, Weimin He and Liming Zhang pp 8550–8551 DOI: 10.1021/ja1033952 Supporting Info

Controlling the Shapes of Silver Nanocrystals with Different Capping Agents Jie Zeng, Yiqun Zheng, Matthew Rycenga, Jing Tao, Zhi-Yuan Li, Qiang Zhang, Yimei Zhu and Younan Xia pp 8552–8553 DOI: 10.1021/ja103655f Supporting Info

Differing HOMO and LUMO Mediated Conduction in a Porphyrin Nanorod Benjamin A. Friesen, Bryan Wiggins, Jeanne L. McHale, Ursula Mazur and K. W. Hipps pp 8554–8556 DOI: 10.1021/ja103078q

Label-Free, Dual-Analyte Electrochemical Biosensors: A New Class of Molecular-Electronic Logic Gates Fan Xia, Xiaolei Zuo, Renqiang Yang, Ryan J. White, Yi Xiao, Di Kang, Xiong Gong, Arica A. Lubin, Alexis Valle-Blisle, Jonathan D. Yuen, Ben Y. B. Hsu and Kevin W. Plaxco pp 8557–8559 DOI: 10.1021/ja101379k Supporting Info

Characterization of RNA Invasion by 19F NMR Spectroscopy Anu Kiviniemi and Pasi Virta pp 8560–8562 DOI: 10.1021/ja1014629 Supporting Info

Real-Time Bioluminescence Imaging of Glycans on Live Cells Allison S. Cohen, Elena A. Dubikovskaya, Jason S. Rush and Carolyn R. Bertozzi pp 8563–8565 DOI: 10.1021/ja101766r Supporting Info

Assembly of Fullerene-Carbon Nanotubes: Temperature Indicator for Photothermal Conversion Yanfei Shen, Andre G. Skirtach, Tomohiro Seki, Shiki Yagai, Hongguang Li, Helmuth Mhwald and Takashi Nakanishi pp 8566–8568 DOI: 10.1021/ja1026024 Supporting Info

Synthesis of Phenanthrone Derivatives from sec-Alkyl Aryl Ketones and Aryl Halides via a Palladium-Catalyzed Dual C−H Bond Activation and Enolate Cyclization Parthasarathy Gandeepan, Kanniyappan Parthasarathy and Chien-Hong Cheng pp 8569–8571 DOI: 10.1021/ja1026248 Supporting Info

[2+2] Cycloadditions by Oxidative Visible Light Photocatalysis Michael A. Ischay, Zhan Lu and Tehshik P. Yoon pp 8572–8574 DOI: 10.1021/ja103934y Supporting Info

Enantioselective Separation on Chiral Au Nanoparticles Nisha Shukla, Melissa A. Bartel and Andrew J. Gellman pp 8575–8580 DOI: 10.1021/ja908219h

Intramolecular Electronic Interactions between Nonconjugated Arene and Quinone Chromophores Georg Jansen, Bjrn Kahlert, Frank-Gerrit Klrner, Roland Boese and Dieter Blser pp 8581–8592 DOI: 10.1021/ja910362j Supporting Info

Simulation of Electrocatalytic Hydrogen Production by a Bioinspired Catalyst Anchored to a Pyrite Electrode Federico Zipoli, Roberto Car, Morrel H. Cohen and Annabella Selloni pp 8593–8601 DOI: 10.1021/ja910694p Supporting Info

Elucidating the Tertiary Structure of Protein Ions in Vacuo with Site Specific Photoinitiated Radical Reactions Tony Ly and Ryan R. Julian pp 8602–8609 DOI: 10.1021/ja910665d Supporting Info

Evolution of Metal Selectivity in Templated Protein Interfaces Jeffrey D. Brodin, Annette Medina-Morales, Thomas Ni, Eric N. Salgado, Xavier I. Ambroggio and F. Akif Tezcan pp 8610–8617 DOI: 10.1021/ja910844n Supporting Info

NMR Methods for Characterizing the Pore Structures and Hydrogen Storage Properties of Microporous Carbons Robert J. Anderson, Thomas P. McNicholas, Alfred Kleinhammes, Anmiao Wang, Jie Liu and Yue Wu pp 8618–8626 DOI: 10.1021/ja9109924 Supporting Info

Multifunctional Conjugates To Prepare Nucleolar-Targeting CdS Quantum Dots Ran Shen, Xiaoqin Shen, Zengming Zhang, Yuesheng Li, Shiyong Liu and Hewen Liu pp 8627–8634 DOI: 10.1021/ja1002668 Supporting Info

The Crystal Structure of a High-Spin Oxoiron(IV) Complex and Characterization of Its Self-Decay Pathway Jason England, Yisong Guo, Erik R. Farquhar, Victor G. Young Jr., Eckard Mnck and Lawrence Que Jr. pp 8635–8644 DOI: 10.1021/ja100366c Supporting Info

Experimental and Theoretical EPR Study of Jahn−Teller-Active [HIPTN3N]MoL Complexes (L = N2, CO, NH3) Rebecca L. McNaughton, Michael Roemelt, Jia Min Chin, Richard R. Schrock, Frank Neese and Brian M. Hoffman pp 8645–8656 DOI: 10.1021/ja1004619 Supporting Info

A Combinatorial NMR and EPR Approach for Evaluating the Structural Ensemble of Partially Folded Proteins Jampani Nageswara Rao, Christine C. Jao, Balachandra G. Hegde, Ralf Langen and Tobias S. Ulmer pp 8657–8668 DOI: 10.1021/ja100646t Supporting Info

On the Origin of Increased Phonon Scattering in Nanostructured PbTe Based Thermoelectric Materials Jiaqing He, Joseph R. Sootsman, Steven N. Girard, Jin-Cheng Zheng, Jianguo Wen, Yimei Zhu, Mercouri G. Kanatzidis and Vinayak P. Dravid pp 8669–8675 DOI: 10.1021/ja1010948 Supporting Info

Short Peptide Nucleic Acids Bind Strongly to Homopurine Tract of Double Helical RNA at pH 5.5 Ming Li, Thomas Zengeya and Eriks Rozners pp 8676–8681 DOI: 10.1021/ja101384k Supporting Info

Comparison of Entropic Contributions to Binding in a “Hydrophilic” versus “Hydrophobic” Ligand−Protein Interaction Neil R. Syme, Caitriona Dennis, Agnieszka Bronowska, Guido C. Paesen and Steve W. Homans pp 8682–8689 DOI: 10.1021/ja101362u Supporting Info

Molecular Crowding Stabilizes Folded RNA Structure by the Excluded Volume Effect Duncan Kilburn, Joon Ho Roh, Liang Guo, Robert M. Briber and Sarah A. Woodson pp 8690–8696 DOI: 10.1021/ja101500g Supporting Info

Evolution of Structure and Chemistry of Bimetallic Nanoparticle Catalysts under Reaction Conditions Feng Tao, Michael E. Grass, Yawen Zhang, Derek R. Butcher, Funda Aksoy, Shaul Aloni, Virginia Altoe, Selim Alayoglu, James R. Renzas, Chia-Kuang Tsung, Zhongwei Zhu, Zhi Liu, Miquel Salmeron and Gabor A. Somorjai pp 8697–8703 DOI: 10.1021/ja101502t

Structural Basis of Multivalent Binding to Wheat Germ Agglutinin David Schwefel, Caroline Maierhofer, Johannes G. Beck, Sonja Seeberger, Kay Diederichs, Heiko M. Mller, Wolfram Welte and Valentin Wittmann pp 8704–8719 DOI: 10.1021/ja101646k Supporting Info

Formation and Reactivity of Chromium(V)−Thiolato Complexes: A Model for the Intracellular Reactions of Carcinogenic Chromium(VI) with Biological Thiols Aviva Levina, Lianbo Zhang and Peter A. Lay pp 8720–8731 DOI: 10.1021/ja101675w Supporting Info

The Polar Phase of NaNbO3: A Combined Study by Powder Diffraction, Solid-State NMR, and First-Principles Calculations Karen E. Johnston, Chiu C. Tang, Julia E. Parker, Kevin S. Knight, Philip Lightfoot and Sharon E. Ashbrook pp 8732–8746 DOI: 10.1021/ja101860r Supporting Info

Solving the Structure of Size-Selected Pt Nanocatalysts Synthesized by Inverse Micelle Encapsulation Beatriz Roldan Cuenya, Jason R. Croy, Simon Mostafa, Farzad Behafarid, Long Li, Zhongfan Zhang, Judith C. Yang, Qi Wang and Anatoly I. Frenkel pp 8747–8756 DOI: 10.1021/ja101997z Supporting Info

Universal Polymer Analysis by 1H NMR Using Complementary Trimethylsilyl End Groups Michael Pch, Daniel Zehm, Maik Lange, Ina Dambowsky, Jan Weiss and Andr Laschewsky pp 8757–8765 DOI: 10.1021/ja102096u Supporting Info

Thorpe−Ingold Acceleration of Oxirane Formation Is Mostly a Solvent Effect Jakub Kostal and William L. Jorgensen pp 8766–8773 DOI: 10.1021/ja1023755 Supporting Info

Probing Electronic Superexchange Coupling at Isolated Poly-p-phenylene Molecules Weihua Wang, Shiyong Wang, Xiuyuan Li, Jean-Paul Collin, Jun Liu, Pei Nian Liu and Nian Lin pp 8774–8778 DOI: 10.1021/ja102415f Supporting Info

Alkaline Beryllium Borate NaBeB3O6 and ABe2B3O7 (A = K, Rb) as UV Nonlinear Optical Crystals Shichao Wang, Ning Ye, Wei Li and Dan Zhao pp 8779–8786 DOI: 10.1021/ja102737t Supporting Info

Pyrophosphate Interactions at the Transition States of Plasmodium falciparum and Human Orotate Phosphoribosyltransferases Yong Zhang and Vern L. Schramm pp 8787–8794 DOI: 10.1021/ja102849w Supporting Info

Synthesis, Crystal and Electronic Structures of New Narrow-Band-Gap Semiconducting Antimonide Oxides RE3SbO3 and RE8Sb3−δO8, with RE = La, Sm, Gd, and Ho Peng Wang, Scott Forbes, Taras Kolodiazhnyi, Kosuke Kosuda and Yurij Mozharivskyj pp 8795–8803 DOI: 10.1021/ja1027698 Supporting Info

Radical and Radical Ion Reactivity in Nucleic Acid Chemistry Norman P. Schepp p 8804 DOI: 10.1021/ja1038769

MALDI Mass Spectrometry for Synthetic Polymer Analysis Franco Basile pp 8805–8806 DOI: 10.1021/ja104286c

Issue 26

Controllable Growth and Field-Effect Property of Monolayer to Multilayer Microstripes of an Organic Semiconductor Liqiang Li, Peng Gao, Klaus C. Schuermann, Stefan Ostendorp, Wenchong Wang, Chuan Du, Yong Lei, Harald Fuchs, Luisa De Cola, Klaus Mllen and Lifeng Chi pp 8807–8809 DOI: 10.1021/ja1017267 Supporting Info

An Enantioselective Claisen Rearrangement Catalyzed by N-Heterocyclic Carbenes Juthanat Kaeobamrung, Jessada Mahatthananchai, Pinguan Zheng and Jeffrey W. Bode pp 8810–8812 DOI: 10.1021/ja103631u Supporting Info

Ultrafast Photodriven Intramolecular Electron Transfer from a Zinc Porphyrin to a Readily Reduced Diiron Hydrogenase Model Complex Amanda P. S. Samuel, Dick T. Co, Charlotte L. Stern and Michael R. Wasielewski pp 8813–8815 DOI: 10.1021/ja100016v Supporting Info

Conformational Stability of Syrian Hamster Prion Protein PrP(90−231) Megan Grabenauer, Thomas Wyttenbach, Narinder Sanghera, Susan E. Slade, Teresa J. T. Pinheiro, James H. Scrivens and Michael T. Bowers pp 8816–8818 DOI: 10.1021/ja100243h Supporting Info

Direct Observation of Morphological Tranformation from Twisted Ribbons into Helical Ribbons E. Thomas Pashuck and Samuel I. Stupp pp 8819–8821 DOI: 10.1021/ja100613w Supporting Info

19F NMR Analysis of the Antimicrobial Peptide PGLa Bound to Native Cell Membranes from Bacterial Protoplasts and Human Erythrocytes Marco Ieronimo, Sergii Afonin, Katja Koch, Marina Berditsch, Parvesh Wadhwani and Anne S. Ulrich pp 8822–8824 DOI: 10.1021/ja101608z Supporting Info

Solvent Effects on the Coexistence of Localized and Delocalized 4,4′-Dinitrotolane Radical Anion by Resonance Raman Spectroscopy Ryan M. Hoekstra, Joo P. Telo, Qin Wu, Rachel M. Stephenson, Stephen F. Nelsen and Jeffrey I. Zink pp 8825–8827 DOI: 10.1021/ja1017859 Supporting Info

Development of pH-Responsive Fluorescent False Neurotransmitters Minhee Lee, Niko G. Gubernator, David Sulzer and Dalibor Sames pp 8828–8830 DOI: 10.1021/ja101740k Supporting Info

Mechanism and Engineering of Polyketide Chain Initiation in Fredericamycin Biosynthesis Abhirup Das, Ping-Hui Szu, Jay T. Fitzgerald and Chaitan Khosla pp 8831–8833 DOI: 10.1021/ja102517q Supporting Info

Nonhydrolyzable Ubiquitin−Isopeptide Isosteres as Deubiquitinating Enzyme Probes. Anitha Shanmugham, Alexander Fish, Mark P. A. Luna-Vargas, Alex C. Faesen, Farid El Oualid, Titia K. Sixma and Huib Ovaa pp 8834–8835 DOI: 10.1021/ja101803s Supporting Info

Structural Characterization of N-Protonated Amides: Regioselective N-Activation of Medium-Bridged Twisted Lactams Michal Szostak, Lei Yao, Victor W. Day, Douglas R. Powell and Jeffrey Aub pp 8836–8837 DOI: 10.1021/ja101690u Supporting Info

When Is the Helix Conformation Restored after the Reverse Reaction of Phototropin? Yuki Kawaguchi, Yusuke Nakasone, Kazunori Zikihara, Satoru Tokutomi and Masahide Terazima pp 8838–8839 DOI: 10.1021/ja1020519 Supporting Info

Initiation and Termination Mode of Enyne Cross-Metathesis and Metallotropic [1,3]-Shift Controlled by Remote Substituents Sang Young Yun, Kung-Pern Wang, Mansuk Kim and Daesung Lee pp 8840–8841 DOI: 10.1021/ja1020525 Supporting Info

Enantioselective Preparation of 8-Oxabicyclo[3.2.1]octane Derivatives via Asymmetric [3+2]-Cycloaddition of Platinum-Containing Carbonyl Ylides with Vinyl Ethers Kento Ishida, Hiroyuki Kusama and Nobuharu Iwasawa pp 8842–8843 DOI: 10.1021/ja102391t Supporting Info

Unexpected Enhancement in Biological Activity of a GPCR Ligand Induced by an Oligoethylene Glycol Substituent Chutima Jiarpinitnun and Laura L. Kiessling pp 8844–8845 DOI: 10.1021/ja102640c Supporting Info

Post-Synthetic Modification of DNA by Inverse-Electron-Demand Diels−Alder Reaction Juliane Schoch, Manfred Wiessler and Andres Jschke pp 8846–8847 DOI: 10.1021/ja102871p Supporting Info

Targeted Intracellular Delivery of Antisense Oligonucleotides via Conjugation with Small-Molecule Ligands Osamu Nakagawa, Xin Ming, Leaf Huang and Rudolph L. Juliano pp 8848–8849 DOI: 10.1021/ja102635c Supporting Info

Genome Mining in Streptomyces avermitilis: Cloning and Characterization of SAV_76, the Synthase for a New Sesquiterpene, Avermitilol Wayne K. W. Chou, Immacolata Fanizza, Takuma Uchiyama, Mamoru Komatsu, Haruo Ikeda and David E. Cane pp 8850–8851 DOI: 10.1021/ja103087w Supporting Info

Use of a 1H-Benzoimidazole Derivative as an n-Type Dopant and To Enable Air-Stable Solution-Processed n-Channel Organic Thin-Film Transistors Peng Wei, Joon Hak Oh, Guifang Dong and Zhenan Bao pp 8852–8853 DOI: 10.1021/ja103173m Supporting Info

Length-Dependent Conductance of Conjugated Molecular Wires Synthesized by Stepwise “Click” Chemistry Liang Luo and C. Daniel Frisbie pp 8854–8855 DOI: 10.1021/ja103239b Supporting Info

Narrowing of Protein NMR Spectral Lines Broadened by Chemical Exchange Ying Li and Arthur G. Palmer, III pp 8856–8857 DOI: 10.1021/ja103251h Supporting Info

Carboxylation of C−H Bonds Using N-Heterocyclic Carbene Gold(I) Complexes Ine I. F. Boogaerts and Steven P. Nolan pp 8858–8859 DOI: 10.1021/ja103429q Supporting Info

Deactivation of Pressure-Induced Amorphization in Silicalite SiO2 by Insertion of Guest Species Julien Haines, Olivier Cambon, Claire Levelut, Mario Santoro, Federico Gorelli and Gaston Garbarino pp 8860–8861 DOI: 10.1021/ja1034599

Catalytic Enantioselective Construction of β-Quaternary Carbons via a Conjugate Addition of Cyanide to β,β-Disubstituted α,β-Unsaturated Carbonyl Compounds Yuta Tanaka, Motomu Kanai and Masakatsu Shibasaki pp 8862–8863 DOI: 10.1021/ja1035286 Supporting Info

Borylated Methylenephosphonium Salts: Precursors of Elusive Boryl(phosphino)carbenes Florie Lavigne, Eddy Maerten, Gilles Alcaraz, Nathalie Saffon-Merceron, Carles Acosta-Silva, Vicen Branchadell and Antoine Baceiredo pp 8864–8865 DOI: 10.1021/ja103422b Supporting Info

Solution Phase Epitaxial Self-Assembly and High Charge-Carrier Mobility Nanofibers of Semiconducting Molecular Gelators Seelam Prasanthkumar, Akinori Saeki, Shu Seki and Ayyappanpillai Ajayaghosh pp 8866–8867 DOI: 10.1021/ja103685j Supporting Info

Near-IR Photoresponse in New Up-Converting CdSe/NaYF4:Yb,Er Nanoheterostructures Chenglin Yan, Afshin Dadvand, Federico Rosei and Dmitrii F. Perepichka pp 8868–8869 DOI: 10.1021/ja103743t Supporting Info

A Cyclodextrin Host/Guest Approach to a Hydrogenase Active Site Biomimetic Cavity Michael L. Singleton, Joseph H. Reibenspies and Marcetta Y. Darensbourg pp 8870–8871 DOI: 10.1021/ja103774j Supporting Info

An Efficient Nickel Catalyst for the Reduction of Carbon Dioxide with a Borane Sumit Chakraborty, Jie Zhang, Jeanette A. Krause and Hairong Guan pp 8872–8873 DOI: 10.1021/ja103982t Supporting Info

Synthesis and Solution Self-Assembly of Side-Chain Cobaltocenium-Containing Block Copolymers Lixia Ren, Christopher G. Hardy and Chuanbing Tang pp 8874–8875 DOI: 10.1021/ja1037726 Supporting Info

Tandem 6π-Electrocyclization and Cycloaddition of Nitrodienes to Yield Multicyclic Nitroso Acetals Gardner S. Creech and Ohyun Kwon pp 8876–8877 DOI: 10.1021/ja1038819 Supporting Info

Rhodium-Catalyzed Arylzincation of Terminal Allenes Providing Allylzinc Reagents and Its Application to Versatile Three-component Coupling Reaction Yuji Yoshida, Kei Murakami, Hideki Yorimitsu and Koichiro Oshima pp 8878–8879 DOI: 10.1021/ja102303s Supporting Info

Highly Flexible Synthesis of Chiral Azacycles via Iridium-Catalyzed Hydrogenation J. Johan Verendel, Taigang Zhou, Jia-Qi Li, Alexander Paptchikhine, Oleg Lebedev and Pher G. Andersson pp 8880–8881 DOI: 10.1021/ja103901e Supporting Info

Precise Mapping of RNA Tertiary Structure via Nanometer Distance Measurements with Double Electron−Electron Resonance Spectroscopy Nak-Kyoon Kim, Michael K. Bowman and Victoria J. DeRose pp 8882–8884 DOI: 10.1021/ja101317g Supporting Info

Gold-Catalyzed Three-Component Coupling: Oxidative Oxyarylation of Alkenes Asa D. Melhado, William E. Brenzovich, Jr., Aaron D. Lackner and F. Dean Toste pp 8885–8887 DOI: 10.1021/ja1034123 Supporting Info

Taming of the Silver FOX Sonali Garg, Haixiang Gao, Young-Hyuk Joo, Damon A. Parrish, Yangen Huang and Jean’ne M. Shreeve pp 8888–8890 DOI: 10.1021/ja103935q Supporting Info

Assignment of Dynamic Regions in Biological Solids Enabled by Spin-State Selective NMR Experiments Rasmus Linser, Uwe Fink and Bernd Reif pp 8891–8893 DOI: 10.1021/ja102612m Supporting Info

Protein Core Packing by Dynamic Combinatorial Chemistry Liton Roy and Martin A. Case pp 8894–8896 DOI: 10.1021/ja1029717 Supporting Info

Radioactive Iodine Capture in Silver-Containing Mordenites through Nanoscale Silver Iodide Formation Karena W. Chapman, Peter J. Chupas and Tina M. Nenoff pp 8897–8899 DOI: 10.1021/ja103110y Supporting Info

Copper-Catalyzed Intramolecular C−H Oxidation/Acylation of Formyl-N-arylformamides Leading to Indoline-2,3-diones Bo-Xiao Tang, Ren-Jie Song, Cui-Yan Wu, Yu Liu, Ming-Bo Zhou, Wen-Ting Wei, Guo-Bo Deng, Du-Lin Yin and Jin-Heng Li pp 8900–8902 DOI: 10.1021/ja103426d Supporting Info

Electrochemical Method for the Determination of Enantiomeric Excess of Binol Using Redox-Active Boronic Acids as Chiral Sensors Giorgio Mirri, Steven D. Bull, Peter N. Horton, Tony D. James, Louise Male and James H. R. Tucker pp 8903–8905 DOI: 10.1021/ja103462x Supporting Info

Controlled Alignment of Multiple Proteins and Nanoparticles with Nanometer Resolution via Backbone-Modified Phosphorothioate DNA and Bifunctional Linkers Jung Heon Lee, Ngo Yin Wong, Li Huey Tan, Zidong Wang and Yi Lu pp 8906–8908 DOI: 10.1021/ja103739f Supporting Info

Pd-Catalyzed Asymmetric Hydrogenation of Unprotected Indoles Activated by Brønsted Acids Duo-Sheng Wang, Qing-An Chen, Wei Li, Chang-Bin Yu, Yong-Gui Zhou and Xumu Zhang pp 8909–8911 DOI: 10.1021/ja103668q Supporting Info

Phosphine-Free Synthesis of p-Type Copper(I) Selenide Nanocrystals in Hot Coordinating Solvents Sasanka Deka, Alessandro Genovese, Yang Zhang, Karol Miszta, Giovanni Bertoni, Roman Krahne, Cinzia Giannini and Liberato Manna pp 8912–8914 DOI: 10.1021/ja103223x Supporting Info

Palladium-Catalyzed Asymmetric Allylic Alkylation of 2-Acylimidazoles as Ester Enolate Equivalents Barry M. Trost, Konrad Lehr, David J. Michaelis, Jiayi Xu and Andreas K. Buckl pp 8915–8917 DOI: 10.1021/ja103771w Supporting Info

Iridium-Catalyzed Kinetic Asymmetric Transformations of Racemic Allylic Benzoates Levi M. Stanley, Chen Bai, Mitsuhiro Ueda and John F. Hartwig pp 8918–8920 DOI: 10.1021/ja103779e Supporting Info

Four-Coordinate Iridium(I) Monohydrides: Reversible Dinitrogen Binding, Bond Activations, and Deprotonations Matthew D. Millard, Curtis E. Moore, Arnold L. Rheingold and Joshua S. Figueroa pp 8921–8923 DOI: 10.1021/ja1037808 Supporting Info

Iron-Catalyzed Hydrogen Production from Formic Acid Albert Boddien, Bjrn Loges, Felix Grtner, Christian Torborg, Koichi Fumino, Henrik Junge, Ralf Ludwig and Matthias Beller pp 8924–8934 DOI: 10.1021/ja100925n Supporting Info

Hindered Rotation of a Cofactor Methyl Group as a Probe for Protein−Cofactor Interaction Richard Brosi, Boris Illarionov, Tilo Mathes, Markus Fischer, Monika Joshi, Adelbert Bacher, Peter Hegemann, Robert Bittl, Stefan Weber and Erik Schleicher pp 8935–8944 DOI: 10.1021/ja910681z Supporting Info

Mesostructured Assemblies of Ultrathin Superlong Tellurium Nanowires and Their Photoconductivity Jian-Wei Liu, Jian-Hua Zhu, Chuan-Ling Zhang, Hai-Wei Liang and Shu-Hong Yu pp 8945–8952 DOI: 10.1021/ja910871s Supporting Info

The Role of Order, Nanocrystal Size, and Capping Ligands in the Collective Mechanical Response of Three-Dimensional Nanocrystal Solids Paul Podsiadlo, Galyna Krylova, Byeongdu Lee, Kevin Critchley, David J. Gosztola, Dmitri V. Talapin, Paul D. Ashby and Elena V. Shevchenko pp 8953–8960 DOI: 10.1021/ja100464a Supporting Info

Structural Assembly of Molecular Complexes Based on Residual Dipolar Couplings Konstantin Berlin, Dianne P. O’Leary and David Fushman pp 8961–8972 DOI: 10.1021/ja100447p Supporting Info

Role of Zinc in Human Islet Amyloid Polypeptide Aggregation Jeffrey R. Brender, Kevin Hartman, Ravi Prakash Reddy Nanga, Nataliya Popovych, Roberto de la Salud Bea, Subramanian Vivekanandan, E. Neil G. Marsh and Ayyalusamy Ramamoorthy pp 8973–8983 DOI: 10.1021/ja1007867 Supporting Info

PNAzymes That Are Artificial RNA Restriction Enzymes Merita Murtola, Malgorzata Wenska and Roger Strmberg pp 8984–8990 DOI: 10.1021/ja1008739 Supporting Info

Coexistence of an ILPR i-Motif and a Partially Folded Structure with Comparable Mechanical Stability Revealed at the Single-Molecule Level Soma Dhakal, Joseph D. Schonhoft, Deepak Koirala, Zhongbo Yu, Soumitra Basu and Hanbin Mao pp 8991–8997 DOI: 10.1021/ja100944j Supporting Info

Development and Loss of Ferromagnetism Controlled by the Interplay of Ge Concentration and Mn Vacancies in Structurally Modulated Y4Mn1−xGa12−yGey Melanie C. Francisco, Christos D. Malliakas, Paula M. B. Piccoli, Matthias J. Gutmann, Arthur J. Schultz and Mercouri G. Kanatzidis pp 8998–9006 DOI: 10.1021/ja1009986 Supporting Info

Dueling Post-Translational Modifications Trigger Folding and Unfolding of a β-Hairpin Peptide Alexander J. Riemen and Marcey L. Waters pp 9007–9013 DOI: 10.1021/ja101079z Supporting Info

STM Tip Catalyzed Adsorption of Thiol Molecules at the Nanometer Scale Young Hwan Min, Soon Jung Jung, Young -Sang Youn, Do Hwan Kim and Sehun Kim pp 9014–9019 DOI: 10.1021/ja101166m Supporting Info

Characterization of Single-Walled Carbon Nanotubes by Scanning Transmission X-ray Spectromicroscopy: Purification, Order and Dodecyl Functionalization Ebrahim Najafi, Jian Wang, Adam P. Hitchcock, Jingwen Guan, Stephane Dnomme and Benoit Simard pp 9020–9029 DOI: 10.1021/ja101001t Supporting Info

Spectroscopic Comparison of Photogenerated Tryptophan Radicals in Azurin: Effects of Local Environment and Structure Hannah S. Shafaat, Brian S. Leigh, Michael J. Tauber and Judy E. Kim pp 9030–9039 DOI: 10.1021/ja101322g Supporting Info

Nanometer-Scale Distance Measurements in Proteins Using Gd3+ Spin Labeling Alexey Potapov, Hiromasa Yagi, Thomas Huber, Slobodan Jergic, Nicholas E. Dixon, Gottfried Otting and Daniella Goldfarb pp 9040–9048 DOI: 10.1021/ja1015662 Supporting Info

Structure of a GPCR Ligand in Its Receptor-Bound State: Leukotriene B4 Adopts a Highly Constrained Conformation When Associated to Human BLT2 Laurent J. Catoire, Marjorie Damian, Fabrice Giusti, Aime Martin, Carine van Heijenoort, Jean-Luc Popot, ric Guittet and Jean-Louis Banres pp 9049–9057 DOI: 10.1021/ja101868c Supporting Info

Ultrathin Bi2S3 Nanowires: Surface and Core Structure at the Cluster-Nanocrystal Transition Jordan W. Thomson, Ludovico Cademartiri, Mark MacDonald, Srebri Petrov, Gianluca Calestani, Peng Zhang and Geoffrey A. Ozin pp 9058–9068 DOI: 10.1021/ja101908k Supporting Info

Chrysophaentins A−H, Antibacterial Bisdiarylbutene Macrocycles That Inhibit the Bacterial Cell Division Protein FtsZ Alberto Plaza, Jessica L. Keffer, Giuseppe Bifulco, John R. Lloyd and Carole A. Bewley pp 9069–9077 DOI: 10.1021/ja102100h Supporting Info

A Molecular Ce2@Ih-C80 Switch—Unprecedented Oxidative Pathway in Photoinduced Charge Transfer Reactivity Dirk M. Guldi, Lai Feng, Shankara Gayathri Radhakrishnan, Hidefumi Nikawa, Michio Yamada, Naomi Mizorogi, Takahiro Tsuchiya, Takeshi Akasaka, Shigeru Nagase, M. ngeles Herranz and Nazario Martn pp 9078–9086 DOI: 10.1021/ja101856j Supporting Info

In Silico Prediction of the 3D Structure of Trimeric Asialoglycoprotein Receptor Bound to Triantennary Oligosaccharide Sai Kumar Ramadugu, Ying-Hua Chung, Ernesto J. Fuentes, Kevin G. Rice and Claudio J. Margulis pp 9087–9095 DOI: 10.1021/ja1021766

The Influence of Local Electric Fields on Photoinduced Absorption in Dye-Sensitized Solar Cells Ute B. Cappel, Sandra M. Feldt, Jan Schneboom, Anders Hagfeldt and Gerrit Boschloo pp 9096–9101 DOI: 10.1021/ja102334h Supporting Info

Probing the Surface of Transition-Metal Nanocrystals by Chemiluminesence Galyna Krylova, Nada M. Dimitrijevic, Dmitri V. Talapin, Jeffrey R. Guest, Holger Borchert, Arun Lobo, Tijana Rajh and Elena V. Shevchenko pp 9102–9110 DOI: 10.1021/ja102413k Supporting Info

Iridium Compounds with κ-P,P,Si (biPSi) Pincer Ligands: Favoring Reactive Structures in Unsaturated Complexes Eduardo Sola, Alba Garca-Camprub, Jos L. Andrs, Marta Martn and Pablo Plou pp 9111–9121 DOI: 10.1021/ja102479h Supporting Info

Cloning, Sequencing, Heterologous Expression, and Mechanistic Analysis of A-74528 Biosynthesis Kathia Zaleta-Rivera, Louise K. Charkoudian, Christian P. Ridley and Chaitan Khosla pp 9122–9128 DOI: 10.1021/ja102519v Supporting Info

Mercaptosilane-Assisted Synthesis of Metal Clusters within Zeolites and Catalytic Consequences of Encapsulation Minkee Choi, Zhijie Wu and Enrique Iglesia pp 9129–9137 DOI: 10.1021/ja102778e Supporting Info

CMPs as Scaffolds for Constructing Porous Catalytic Frameworks: A Built-in Heterogeneous Catalyst with High Activity and Selectivity Based on Nanoporous Metalloporphyrin Polymers Long Chen, Yong Yang and Donglin Jiang pp 9138–9143 DOI: 10.1021/ja1028556 Supporting Info

Iterative Saturation Mutagenesis Accelerates Laboratory Evolution of Enzyme Stereoselectivity: Rigorous Comparison with Traditional Methods Manfred T. Reetz, Shreenath Prasad, Jos D. Carballeira, Yosephine Gumulya and Marco Bocola pp 9144–9152 DOI: 10.1021/ja1030479 Supporting Info

Iridium-Catalyzed anti-Diastereo- and Enantioselective Carbonyl (Trimethylsilyl)allylation from the Alcohol or Aldehyde Oxidation Level Soo Bong Han, Xin Gao and Michael J. Krische pp 9153–9156 DOI: 10.1021/ja103299f Supporting Info

Identifying Diversity in Nanoscale Electrical Break Junctions Santiago Martn, Iain Grace, Martin R. Bryce, Changsheng Wang, Rukkiat Jitchati, Andrei S. Batsanov, Simon J. Higgins, Colin J. Lambert and Richard J. Nichols pp 9157–9164 DOI: 10.1021/ja103327f Supporting Info

Arylethynyl Derivatives of the Dihydroazulene/Vinylheptafulvene Photo/Thermoswitch: Tuning the Switching Event Søren Lindbæk Broman, Michael Åxman Petersen, Christian G. Tortzen, Anders Kadziola, Kristine Kilså and Mogens Brøndsted Nielsen pp 9165–9174 DOI: 10.1021/ja103235g Supporting Info

Streamlined Syntheses of (−)-Dictyostatin, 16-Desmethyl-25,26-dihydrodictyostatin, and 6-epi-16-Desmethyl-25,26-dihydrodictyostatin Wei Zhu, Mara Jimnez, Won-Hyuk Jung, Daniel P. Camarco, Raghavan Balachandran, Andreas Vogt, Billy W. Day and Dennis P. Curran pp 9175–9187 DOI: 10.1021/ja103537u Supporting Info

Asymmetric Formal trans-Dihydroxylation and trans-Aminohydroxylation of α,β-Unsaturated Aldehydes via an Organocatalytic Reaction Cascade Łukasz Albrecht, Hao Jiang, Gustav Dickmeiss, Bjrn Gschwend, Signe Grann Hansen and Karl Anker Jørgensen pp 9188–9196 DOI: 10.1021/ja103538s Supporting Info

Orientation, Dynamics, and Lipid Interaction of an Antimicrobial Arylamide Investigated by 19F and 31P Solid-State NMR Spectroscopy Yongchao Su, William F. DeGrado and Mei Hong pp 9197–9205 DOI: 10.1021/ja103658h

Differential Reactivities of Enyne Substrates in Ruthenium- and Palladium-Catalyzed Cycloisomerizations Barry M. Trost, Alicia C. Gutierrez and Eric M. Ferreira pp 9206–9218 DOI: 10.1021/ja103663h Supporting Info

A C2-Symmetric Chiral Bis-Sulfoxide Ligand in a Rhodium-Catalyzed Reaction: Asymmetric 1,4-Addition of Sodium Tetraarylborates to Chromenones Jun Chen, Junmin Chen, Feng Lang, Xiangyang Zhang, Linfeng Cun, Jin Zhu, Jingen Deng and Jian Liao p 9219 DOI: 10.1021/ja103812e

Phytochrome as Molecular Machine: Revealing Chromophore Action during the Pfr → Pr Photoconversion by Magic-Angle Spinning NMR Spectroscopy Thierry Rohmer, Christina Lang, Christian Bongards, Karthick Babu Sai Sankar Gupta, Johannes Neugebauer, Jon Hughes, Wolfgang Grtner and Jrg Matysik p 9219 DOI: 10.1021/ja104192u

Polysaccharide Materials: Performance by Design p 9220 DOI: 10.1021/ja104088w

Introduction to Modern Liquid Chromatography, 3rd ed John G. Dorsey p 9220 DOI: 10.1021/ja104156b

Solid State Electrochemistry I: Fundamentals, Materials and their Applications David W. Hatchett pp 9220–9221 DOI: 10.1021/ja1042885

Esterification: Methods, Reactions, and Applications: Completely Revised and Enlarged 2nd ed p 9221 DOI: 10.1021/ja104341h

Dictionary of Mass Spectrometry p 9221 DOI: 10.1021/ja105115v

Stilbenes: Applications in Chemistry, Life Sciences and Materials Science Jack Saltiel pp 9221–9222 DOI: 10.1021/ja104338d

Issue 27

Molten Globule Precursor States Are Conformationally Correlated to Amyloid Fibrils of Human β-2-Microglobulin Lukasz Skora, Stefan Becker and Markus Zweckstetter pp 9223–9225 DOI: 10.1021/ja100453e Supporting Info

Two-Dimensional Bipolar Electrochemistry Stephen E. Fosdick, John A. Crooks, Byoung-Yong Chang and Richard M. Crooks pp 9226–9227 DOI: 10.1021/ja103667y Supporting Info

A Sensing Platform Based on Electrodissolution of a Ag Bipolar Electrode Kwok-Fan Chow, Byoung-Yong Chang, Brian A. Zaccheo, Franois Mavr and Richard M. Crooks pp 9228–9229 DOI: 10.1021/ja103715u Supporting Info

Near-IR Phosphorescence of Iridium(III) Corroles at Ambient Temperature Joshua H. Palmer, Alec C. Durrell, Zeev Gross, Jay R. Winkler and Harry B. Gray pp 9230–9231 DOI: 10.1021/ja101647t Supporting Info

Enantioselective Synthesis of Planar Chiral Organonitrogen Cycles Katsuhiko Tomooka, Kazuhiro Uehara, Rie Nishikawa, Masaki Suzuki and Kazunobu Igawa pp 9232–9233 DOI: 10.1021/ja1024657 Supporting Info

Patterned Plastics That Change Physical Structure in Response to Applied Chemical Signals Wanji Seo and Scott T. Phillips pp 9234–9235 DOI: 10.1021/ja104420k Supporting Info

Hypervalent λ3-Bromane Strategy for Baeyer−Villiger Oxidation: Selective Transformation of Primary Aliphatic and Aromatic Aldehydes to Formates, Which is Missing in the Classical Baeyer−Villiger Oxidation Masahito Ochiai, Akira Yoshimura, Kazunori Miyamoto, Satoko Hayashi and Waro Nakanishi pp 9236–9239 DOI: 10.1021/ja104330g Supporting Info

Formation of Cysteine Sulfenic Acid by Oxygen Atom Transfer from Nitrite Julie Heinecke and Peter C. Ford pp 9240–9243 DOI: 10.1021/ja102221e Supporting Info

When the Signal Is Not from the Original Molecule To Be Detected: Chemical Transformation of para-Aminothiophenol on Ag during the SERS Measurement Yi-Fan Huang, Hong-Ping Zhu, Guo-Kun Liu, De-Yin Wu, Bin Ren and Zhong-Qun Tian pp 9244–9246 DOI: 10.1021/ja101107z Supporting Info

[FeFe]-Hydrogenase Maturation: HydG-Catalyzed Synthesis of Carbon Monoxide Eric M. Shepard, Benjamin R. Duffus, Simon J. George, Shawn E. McGlynn, Martin R. Challand, Kevin D. Swanson, Peter L. Roach, Stephen P. Cramer, John W. Peters and Joan B. Broderick pp 9247–9249 DOI: 10.1021/ja1012273 Supporting Info

Size-Tunable Phosphorescence in Colloidal Metastable γ-Ga2O3 Nanocrystals Ting Wang, Shokouh S. Farvid, Mutalifu Abulikemu and Pavle V. Radovanovic pp 9250–9252 DOI: 10.1021/ja101333h Supporting Info

Pt Monolayer on Porous Pd−Cu Alloys as Oxygen Reduction Electrocatalysts Minhua Shao, Krista Shoemaker, Amra Peles, Keiichi Kaneko and Lesia Protsailo pp 9253–9255 DOI: 10.1021/ja101966a Supporting Info

Mononuclear NiIII−Alkyl Complexes (Alkyl = Me and Et): Relevance to the Acetyl-CoA Synthase and Methyl-CoM Reductase Chien-Ming Lee, Chien-Hong Chen, Fu-Xing Liao, Ching-Han Hu and Gene-Hsiang Lee pp 9256–9258 DOI: 10.1021/ja102430d Supporting Info

Distinct Biological Network Properties between the Targets of Natural Products and Disease Genes Vlado Dank, Kathleen Petri Seiler, Damian W. Young, Stuart L. Schreiber and Paul A. Clemons pp 9259–9261 DOI: 10.1021/ja102798t Supporting Info

A Metal−Organic Framework with Covalently Bound Organometallic Complexes Kounosuke Oisaki, Qiaowei Li, Hiroyasu Furukawa, Alexander U. Czaja and Omar M. Yaghi pp 9262–9264 DOI: 10.1021/ja103016y Supporting Info

Attomole Detection of Mesophilic DNA Polymerase Products by Nanoparticle-Enhanced Surface Plasmon Resonance Imaging on Glassified Gold Surfaces Lida K. Gifford, Iuliana E. Sendroiu, Robert M. Corn and Andrej Luptk pp 9265–9267 DOI: 10.1021/ja103043p Supporting Info

Voltage-Responsive Vesicles Based on Orthogonal Assembly of Two Homopolymers Qiang Yan, Jinying Yuan, Zhinan Cai, Yan Xin, Yan Kang and Yingwu Yin pp 9268–9270 DOI: 10.1021/ja1027502 Supporting Info

A Chiral Ferromagnetic Molecular Metal Jos R. Galn-Mascars, Eugenio Coronado, Paul A. Goddard, John Singleton, Amalia I. Coldea, John D. Wallis, Simon J. Coles and Antonio Alberola pp 9271–9273 DOI: 10.1021/ja103147k Supporting Info

Aptamer/Graphene Oxide Nanocomplex for in Situ Molecular Probing in Living Cells Ying Wang, Zhaohui Li, Dehong Hu, Chiann-Tso Lin, Jinghong Li and Yuehe Lin pp 9274–9276 DOI: 10.1021/ja103169v Supporting Info

Probe Position Dependence of DNA Dynamics: Comparison of the Time-Resolved Stokes Shift of Groove-Bound to Base-Stacked Probes Nibedita Pal, Sachin Dev Verma and Sobhan Sen pp 9277–9279 DOI: 10.1021/ja103387t Supporting Info

Decarboxylative Benzylations of Alkynes and Ketones Robert R. P. Torregrosa, Yamuna Ariyarathna, Kalicharan Chattopadhyay and Jon A. Tunge pp 9280–9282 DOI: 10.1021/ja1035557 Supporting Info

Direct Observation of Photodriven Intermolecular Hole Transfer across TiO2 Nanocrystallites: Lateral Self-Exchange Reactions and Catalyst Oxidation Shane Ardo and Gerald J. Meyer pp 9283–9285 DOI: 10.1021/ja1035946

Enantioselective Catalytic α-Alkylation of Aldehydes via an SN1 Pathway Adam R. Brown, Wen-Hsin Kuo and Eric N. Jacobsen pp 9286–9288 DOI: 10.1021/ja103618r Supporting Info

Metallopeptides for Asymmetric Dirhodium Catalysis Ramya Sambasivan and Zachary T. Ball pp 9289–9291 DOI: 10.1021/ja103747h Supporting Info

Gold(I)-Catalyzed Intermolecular [2+2] Cycloaddition of Alkynes with Alkenes Vernica Lpez-Carrillo and Antonio M. Echavarren pp 9292–9294 DOI: 10.1021/ja104177w Supporting Info

Linear vs Exponential Formation of Molecular-Based Assemblies Joyanta Choudhury, Revital Kaminker, Leila Motiei, Graham de Ruiter, Michael Morozov, Fabio Lupo, Antonino Gulino and Milko E. van der Boom pp 9295–9297 DOI: 10.1021/ja104203v Supporting Info

Gold-Catalyzed Stereocontrolled Oxacyclization/[4+2]-Cycloaddition Cascade of Ketone-Allene Substrates Tse-Min Teng and Rai-Shung Liu pp 9298–9300 DOI: 10.1021/ja1043837 Supporting Info

Selective Covalent Labeling of Tag-Fused GPCR Proteins on Live Cell Surface with a Synthetic Probe for Their Functional Analysis Hiroshi Nonaka, Sho-hei Fujishima, Sho-hei Uchinomiya, Akio Ojida and Itaru Hamachi pp 9301–9309 DOI: 10.1021/ja910703v Supporting Info

Modeling, Preparation, and Characterization of a Dipole Moment Switch Driven by Z/E Photoisomerization Alfonso Melloni, Riccardo Rossi Paccani, Donato Donati, Vinicio Zanirato, Adalgisa Sinicropi, Maria Laura Parisi, Elena Martin, Mikhail Ryazantsev, Wan Jian Ding, Luis Manuel Frutos, Riccardo Basosi, Stefania Fusi, Loredana Latterini, Nicolas Ferr and Massimo Olivucci pp 9310–9319 DOI: 10.1021/ja906733q Supporting Info

Order at the Edge of the Bilayer: Membrane Remodeling at the Edge of a Planar Supported Bilayer Is Accompanied by a Localized Phase Change Andreia M. Smith, Madhuri Vinchurkar, Niels Gronbech-Jensen and Atul N. Parikh pp 9320–9327 DOI: 10.1021/ja100294k Supporting Info

Electrospray Mass Spectrometry of Telomeric RNA (TERRA) Reveals the Formation of Stable Multimeric G-Quadruplex Structures Gavin W. Collie, Gary N. Parkinson, Stephen Neidle, Frdric Rosu, Edwin De Pauw and Valrie Gabelica pp 9328–9334 DOI: 10.1021/ja100345z Supporting Info

Origins of Stereoselectivity in the trans Diels−Alder Paradigm Robert S. Paton, Joel L. Mackey, Woo Han Kim, Jun Hee Lee, Samuel J. Danishefsky and K. N. Houk pp 9335–9340 DOI: 10.1021/ja1009162 Supporting Info

Reversible Twisting during Helical Hippuric Acid Crystal Growth Alexander G. Shtukenberg, John Freudenthal and Bart Kahr pp 9341–9349 DOI: 10.1021/ja101491n Supporting Info

Tuning the Supramolecular Chirality of One- and Two-Dimensional Aggregates with the Number of Stereogenic Centers in the Component Porphyrins Patrizia Iavicoli, Hong Xu, Lise N. Feldborg, Mathieu Linares, Markos Paradinas, Sven Stafstrm, Carmen Ocal, Belen Nieto-Ortega, Juan Casado, Juan T. López Navarrete, Roberto Lazzaroni, Steven De Feyter and David B. Amabilino pp 9350–9362 DOI: 10.1021/ja101533j Supporting Info

Clickable NAD Analogues for Labeling Substrate Proteins of Poly(ADP-ribose) Polymerases Hong Jiang, Jun Hyun Kim, Kristine M. Frizzell, W. Lee Kraus and Hening Lin pp 9363–9372 DOI: 10.1021/ja101588r Supporting Info

Electrified Selective “Sponges” Made of Au Nanoparticles Marco Frasconi, Ran Tel-Vered, Michael Riskin and Itamar Willner pp 9373–9382 DOI: 10.1021/ja102153f Supporting Info

Involvement of the LSPR Spectral Overlap for Energy Transfer between a Dye and Au Nanoparticle Mani Prabha Singh and Geoffrey F. Strouse pp 9383–9391 DOI: 10.1021/ja1022128 Supporting Info

Effects of Proteins on Protein Diffusion Yaqiang Wang, Conggang Li and Gary J. Pielak pp 9392–9397 DOI: 10.1021/ja102296k Supporting Info

Size-Dependent Passivation Shell and Magnetic Properties in Antiferromagnetic/Ferrimagnetic Core/Shell MnO Nanoparticles Alberto Lpez-Ortega, Dina Tobia, Elin Winkler, Igor V. Golosovsky, German Salazar-Alvarez, Snia Estrad, Marta Estrader, Jordi Sort, Miguel Angel Gonzlez, Santiago Suriach, Jordi Arbiol, Francesca Peir, Roberto D. Zysler, Maria Dolors Bar and Josep Nogus pp 9398–9407 DOI: 10.1021/ja1021798 Supporting Info

Protein Structure-Sensitive Electrocatalysis at Dithiothreitol-Modified Electrodes Veronika Ostatn, Hana ernock and Emil Paleek pp 9408–9413 DOI: 10.1021/ja102427y Supporting Info

Epitaxial-like Growth of Anisotropic Mesostructure on an Anisotropic Surface of an Oblique Nanocolumnar Structure Hirokatsu Miyata, Wataru Kubo, Akira Sakai, Yohei Ishida, Takashi Noma, Masatoshi Watanabe, Avi Bendavid and Philip J. Martin pp 9414–9419 DOI: 10.1021/ja102537s Supporting Info

Arrested Catalysis: Controlling Kumada Coupling Activity via a Redox-Active N-Heterocyclic Carbene Andrew G. Tennyson, Vincent M. Lynch and Christopher W. Bielawski pp 9420–9429 DOI: 10.1021/ja102686u Supporting Info

Chemoenzymatic Synthesis and Enzymatic Analysis of 8-Modified Cytidine Monophosphate-Sialic Acid and Sialyl Lactose Derivatives Thomas J. Morley and Stephen G. Withers pp 9430–9437 DOI: 10.1021/ja102644a Supporting Info

Pressure-Induced Spin-State Transition in BiCoO3 Kengo Oka, Masaki Azuma, Wei-tin Chen, Hitoshi Yusa, Alexei A. Belik, Eiji Takayama-Muromachi, Masaichiro Mizumaki, Naoki Ishimatsu, Nozomu Hiraoka, Masahiko Tsujimoto, Matthew G. Tucker, J. Paul Attfield and Yuichi Shimakawa pp 9438–9443 DOI: 10.1021/ja102987d

Evidence, from Simulations, of a Single State with Residual Native Structure at the Thermal Denaturation Midpoint of a Small Globular Protein Gia G. Maisuradze, Adam Liwo, Stanisław Ołdziej and Harold A. Scheraga pp 9444–9452 DOI: 10.1021/ja1031503

Enhanced Functional Potential of Nucleic Acid Aptamer Libraries Patterned to Increase Secondary Structure Karen M. Ruff, Thomas M. Snyder and David R. Liu pp 9453–9464 DOI: 10.1021/ja103023m Supporting Info

Nitrone [2]Rotaxanes: Simultaneous Chemical Protection and Electrochemical Activation of a Functional Group Daniel M. D’Souza, David A. Leigh, Loc Mottier, Kathleen M. Mullen, Francesco Paolucci, Simon J. Teat and Songwei Zhang pp 9465–9470 DOI: 10.1021/ja1034683 Supporting Info

A Proton-Shuttle Reaction Mechanism for Histone Deacetylase 8 and the Catalytic Role of Metal Ions Ruibo Wu, Shenglong Wang, Nengjie Zhou, Zexing Cao and Yingkai Zhang pp 9471–9479 DOI: 10.1021/ja103932d Supporting Info

Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates David R. Armstrong, Victoria L. Blair, William Clegg, Sophie H. Dale, Joaquin Garcia-Alvarez, Gordon W. Honeyman, Eva Hevia, Robert E. Mulvey and Luca Russo pp 9480–9487 DOI: 10.1021/ja1038598 Supporting Info

Explanation of the Adsorption of Polar Vapors in the Highly Flexible Metal Organic Framework MIL-53(Cr) Sandrine Bourrelly, Batrice Moulin, Angel Rivera, Guillaume Maurin, Sabine Devautour-Vinot, Christian Serre, Thomas Devic, Patricia Horcajada, Alexandre Vimont, Guillaume Clet, Marco Daturi, Jean-Claude Lavalley, Sandra Loera-Serna, Renaud Denoyel, Philip L. Llewellyn and Grard Frey pp 9488–9498 DOI: 10.1021/ja1023282 Supporting Info

E-Type Delayed Fluorescence of a Phosphine-Supported Cu2(μ-NAr2)2 Diamond Core: Harvesting Singlet and Triplet Excitons in OLEDs Joseph C. Deaton, Steven C. Switalski, Denis Y. Kondakov, Ralph H. Young, Thomas D. Pawlik, David J. Giesen, Seth B. Harkins, Alex J. M. Miller, Seth F. Mickenberg and Jonas C. Peters pp 9499–9508 DOI: 10.1021/ja1004575 Supporting Info

Ultrasensitive Detection of Enzymatic Activity with Nanowire Electrodes Marcel A. Roberts and Shana O. Kelley p 9509 DOI: 10.1021/ja1018805

Biochemistry and Molecular Genetics of the Biosynthesis of the Earthy Odorant Methylisoborneol in Streptomyces coelicolor Chieh-Mei Wang and David E. Cane p 9509 DOI: 10.1021/ja104306p

Insights into the Recognition and Association of Transmembrane α-Helices. The Free Energy of α-Helix Dimerization in Glycophorin A Jrme Hnin, Andrew Pohorille and Christophe Chipot p 9510 DOI: 10.1021/ja104328f

Electrochemistry of Functional Supramolecular Systems John D. Tovar p 9511 DOI: 10.1021/ja104428n

Non-Covalent Interactions: Theory and Experiment Gregory S. Tschumper and Nathan I. Hammer p 9512 DOI: 10.1021/ja104759m

Issue 28

Functional Reconstitution of an ABC Transporter in Nanodiscs for Use in Electron Paramagnetic Resonance Spectroscopy Frances Joan D. Alvarez, Cdric Orelle and Amy L. Davidson pp 9513–9515 DOI: 10.1021/ja104047c Supporting Info

A Strategy for the Selective Imaging of Glycans Using Caged Metabolic Precursors Pamela V. Chang, Danielle H. Dube, Ellen M. Sletten and Carolyn R. Bertozzi pp 9516–9518 DOI: 10.1021/ja101080y Supporting Info

SnSe Nanocrystals: Synthesis, Structure, Optical Properties, and Surface Chemistry William J. Baumgardner, Joshua J. Choi, Yee-Fun Lim and Tobias Hanrath pp 9519–9521 DOI: 10.1021/ja1013745 Supporting Info

A Heteronuclear Zero Quantum Coherence Nz-Exchange Experiment That Resolves Resonance Overlap and Its Application To Measure the Rates of Heme Binding to the IsdC Protein Scott A. Robson, Robert Peterson, Louis-S Bouchard, Valerie A. Villareal and Robert T. Clubb pp 9522–9523 DOI: 10.1021/ja1017865 Supporting Info

Photocontrolled Compound Release System Using Caged Antimicrobial Peptide Shin Mizukami, Mariko Hosoda, Takafumi Satake, Satoshi Okada, Yuichiro Hori, Toshiaki Furuta and Kazuya Kikuchi pp 9524–9525 DOI: 10.1021/ja102167m Supporting Info

A Reductive Trigger for Peptide Self-Assembly and Hydrogelation Charles J. Bowerman and Bradley L. Nilsson pp 9526–9527 DOI: 10.1021/ja1025535 Supporting Info

Correlation between the Photoluminescence and Oriented Attachment Growth Mechanism of CdS Quantum Dots Jinsheng Zheng, Feng Huang, Shungao Yin, Yongjing Wang, Zhang Lin, Xiaoli Wu and Yibing Zhao pp 9528–9530 DOI: 10.1021/ja101848w Supporting Info

Fermentanomics: Monitoring Mammalian Cell Cultures with NMR Spectroscopy Scott A. Bradley, Anli Ouyang, Jennifer Purdie, Tim A. Smitka, Tongtong Wang and Andreas Kaerner pp 9531–9533 DOI: 10.1021/ja101962c Supporting Info

In Situ Identification of Intermediates of Benzyl Chloride Reduction at a Silver Electrode by SERS Coupled with DFT Calculations An Wang, Yi-Fan Huang, Ujjal Kumar Sur, De-Yin Wu, Bin Ren, Sandra Rondinini, Christian Amatore and Zhong-Qun Tian pp 9534–9536 DOI: 10.1021/ja1024639 Supporting Info

Reducing the Symmetry of Bimetallic Au@Ag Nanoparticles by Exploiting Eccentric Polymer Shells Shuangxi Xing, Yuhua Feng, Yee Yan Tay, Tao Chen, Jun Xu, Ming Pan, Jiating He, Huey Hoon Hng, Qingyu Yan and Hongyu Chen pp 9537–9539 DOI: 10.1021/ja102591z Supporting Info

UV and Near-IR Triggered Release from Polymeric Nanoparticles Nadezda Fomina, Cathryn McFearin, Marleen Sermsakdi, Osayimwense Edigin and Adah Almutairi pp 9540–9542 DOI: 10.1021/ja102595j Supporting Info

Microsecond Dye Regeneration Kinetics in Efficient Solid State Dye-Sensitized Solar Cells Using a Photoelectrochemically Deposited PEDOT Hole Conductor Attila J. Mozer, Dillip K. Panda, Sanjeev Gambhir, Bjorn Winther-Jensen and Gordon G. Wallace pp 9543–9545 DOI: 10.1021/ja1026453 Supporting Info

Functionalization of Peptides and Proteins by Mukaiyama Aldol Reaction Jenefer Alam, Thomas H. Keller and Teck-Peng Loh pp 9546–9548 DOI: 10.1021/ja102733a Supporting Info

Complexes of Gilman Reagents with C−S and C−N Double Bonds: σ or π Bonding? Steven H. Bertz, Yasamin Moazami, Michael D. Murphy, Craig A. Ogle, Joshua D. Richter and Andy A. Thomas pp 9549–9551 DOI: 10.1021/ja103068h Supporting Info

π-Extended Dipyrrins Capable of Highly Fluorogenic Complexation with Metal Ions Mikhail A. Filatov, Artem Y. Lebedev, Sergei N. Mukhin, Sergei A. Vinogradov and Andrei V. Cheprakov pp 9552–9554 DOI: 10.1021/ja102852v Supporting Info

m × n Stacks of Discrete Aromatic Stacks in Solution Yoshihiro Yamauchi, Yuya Hanaoka, Michito Yoshizawa, Munetaka Akita, Takahiro Ichikawa, Masafumi Yoshio, Takashi Kato and Makoto Fujita pp 9555–9557 DOI: 10.1021/ja103180z Supporting Info

Asymmetric Vinylogous Aldol Reaction of Silyloxy Furans with a Chiral Organic Salt Ravi P. Singh, Bruce M. Foxman and Li Deng pp 9558–9560 DOI: 10.1021/ja103331t Supporting Info

Rapid Acquisition of Multidimensional Solid-State NMR Spectra of Proteins Facilitated by Covalently Bound Paramagnetic Tags Philippe S. Nadaud, Jonathan J. Helmus, Ishita Sengupta and Christopher P. Jaroniec pp 9561–9563 DOI: 10.1021/ja103545e Supporting Info

Persistently Folded Circular Aromatic Amide Pentamers Containing Modularly Tunable Cation-Binding Cavities with High Ion Selectivity Bo Qin, Changliang Ren, Ruijuan Ye, Chang Sun, Khalid Chiad, Xiuying Chen, Zhao Li, Feng Xue, Haibin Su, Gregory A. Chass and Huaqiang Zeng pp 9564–9566 DOI: 10.1021/ja1035804 Supporting Info

Total Synthesis of (±)-Aplykurodinone-1: Traceless Stereochemical Guidance Yandong Zhang and Samuel J. Danishefsky pp 9567–9569 DOI: 10.1021/ja1035495 Supporting Info

Narrow-Chirality Distributed Single-Walled Carbon Nanotube Growth from Nonmagnetic Catalyst Zohreh Ghorannevis, Toshiaki Kato, Toshiro Kaneko and Rikizo Hatakeyama pp 9570–9572 DOI: 10.1021/ja103362j Supporting Info

Fullerene-like Colloidal Nanocrystal of Nickel Hydroxychloride Shi Hu and Xun Wang pp 9573–9575 DOI: 10.1021/ja103607q Supporting Info

Chemoselective Reductive Cross-Coupling of 1,5-Diene-3-ols with Alkynes: A Facile Entry to Stereodefined Skipped Trienes Peter S. Diez and Glenn C. Micalizio pp 9576–9578 DOI: 10.1021/ja103836h Supporting Info

Dual Emission Caused by Ring Inversion Isomerization of a 4-Methyl-2-pyridyl-pyrimidine Copper(I) Complex Michihiro Nishikawa, Kuniharu Nomoto, Shoko Kume, Keiichi Inoue, Makoto Sakai, Masaaki Fujii and Hiroshi Nishihara pp 9579–9581 DOI: 10.1021/ja103718e Supporting Info

New Insights into Brust−Schiffrin Metal Nanoparticle Synthesis Paul J. G. Goulet and R. Bruce Lennox pp 9582–9584 DOI: 10.1021/ja104011b Supporting Info

Pyrrole Synthesis via Allylic sp3 C−H Activation of Enamines Followed by Intermolecular Coupling with Unactivated Alkynes Souvik Rakshit, Frederic W. Patureau and Frank Glorius pp 9585–9587 DOI: 10.1021/ja104305s Supporting Info

Disorder−Order Ferroelectric Transition in the Metal Formate Framework of [NH4][Zn(HCOO)3] Guan-Cheng Xu, Xiao-Ming Ma, Li Zhang, Zhe-Ming Wang and Song Gao pp 9588–9590 DOI: 10.1021/ja104263m Supporting Info

Fully Substituted Carbon Centers by Diastereoselective Spirocyclization: Stereoselective Synthesis of (+)-Lepadiformine C Matthew A. Perry, Matthew D. Morin, Brian W. Slafer, Scott A. Wolckenhauer and Scott D. Rychnovsky pp 9591–9593 DOI: 10.1021/ja104250b Supporting Info

Total Synthesis of (+)-Fastigiatine Brian B. Liau and Matthew D. Shair pp 9594–9595 DOI: 10.1021/ja104575h Supporting Info

Ordered Nanoporous Silica with Periodic 30−60 nm Pores as an Effective Support for Gold Nanoparticle Catalysts with Enhanced Lifetime Guicen Ma, Xiaoqing Yan, Yunlong Li, Liping Xiao, Zhangjun Huang, Yanping Lu and Jie Fan pp 9596–9597 DOI: 10.1021/ja1027524 Supporting Info

Organic Two-Step Spin-Transition-Like Behavior in a Linear S = 1 Array: 3′-Methylbiphenyl-3,5-diyl Bis(tert-butylnitroxide) and Related Compounds Hirokazu Nishimaki and Takayuki Ishida pp 9598–9599 DOI: 10.1021/ja102890g Supporting Info

Plasmonic Nanoparticle Dimers for Optical Sensing of DNA in Complex Media Jennifer I. L. Chen, Yeechi Chen and David S. Ginger pp 9600–9601 DOI: 10.1021/ja103240g Supporting Info

Iridium-Catalyzed Annulation of N-Arylcarbamoyl Chlorides with Internal Alkynes Tomohiro Iwai, Tetsuaki Fujihara, Jun Terao and Yasushi Tsuji pp 9602–9603 DOI: 10.1021/ja104153k Supporting Info

Dihydrogen Activation by Antiaromatic Pentaarylboroles Cheng Fan, Lauren G. Mercier, Warren E. Piers, Heikki M. Tuononen and Masood Parvez pp 9604–9606 DOI: 10.1021/ja105075h Supporting Info

Transmetalation is the Rate-Limiting Step: Quantitative Kinetic Investigation of Nickel-Catalyzed Oxidative Coupling of Arylzinc Reagents Liqun Jin, Jie Xin, Zhiliang Huang, Jun He and Aiwen Lei pp 9607–9609 DOI: 10.1021/ja1045296 Supporting Info

Kinetic Isolation and Characterization of the Radical Rearrangement Step in Coenzyme B12-Dependent Ethanolamine Ammonia-lyase Chen Zhu and Kurt Warncke pp 9610–9615 DOI: 10.1021/ja907769g

Tuning the Acid/Base Properties of Nanocarbons by Functionalization via Amination Rosa Arrigo, Michael Hvecker, Sabine Wrabetz, Raoul Blume, Martin Lerch, James McGregor, Edward P. J. Parrott, J. Axel Zeitler, Lynn F. Gladden, Axel Knop-Gericke, Robert Schlgl and Dang Sheng Su pp 9616–9630 DOI: 10.1021/ja910169v Supporting Info

Bimodal Polarons and Hole Transport in Poly(3-hexylthiophene):Fullerene Blend Films Jiamo Guo, Hideo Ohkita, Seiichirou Yokoya, Hiroaki Benten and Shinzaburo Ito pp 9631–9637 DOI: 10.1021/ja9108787 Supporting Info

Design of Single-Stranded Nucleic Acid Binding Peptides Based on Nucleocapsid CCHC-Box Zinc-Binding Domains Anthony L. Guerrerio and Jeremy M. Berg pp 9638–9643 DOI: 10.1021/ja910942v

Evolution of Various Porphyrin Nanostructures via an Oil/Aqueous Medium: Controlled Self-Assembly, Further Organization, and Supramolecular Chirality Yunfeng Qiu, Penglei Chen and Minghua Liu pp 9644–9652 DOI: 10.1021/ja1001967 Supporting Info

An Array-Based Method To Identify Multivalent Inhibitors Yalong Zhang, Qian Li, Luis G. Rodriguez and Jeffrey C. Gildersleeve pp 9653–9662 DOI: 10.1021/ja100608w Supporting Info

Molecular Mechanisms in Morpholino−DNA Surface Hybridization Ping Gong, Kang Wang, Yatao Liu, Kenneth Shepard and Rastislav Levicky pp 9663–9671 DOI: 10.1021/ja100881a Supporting Info

Controlled Assembly of Hydrogenase-CdTe Nanocrystal Hybrids for Solar Hydrogen Production Katherine A. Brown, Smita Dayal, Xin Ai, Garry Rumbles and Paul W. King pp 9672–9680 DOI: 10.1021/ja101031r Supporting Info

Mechanical Distortion of Protein Receptor Decreases the Lifetime of a Receptor−Ligand Bond Senli Guo, Nan Li, Nimit Lad, Chad Ray and Boris B. Akhremitchev pp 9681–9687 DOI: 10.1021/ja1011756 Supporting Info

Dynamic Kinetic Asymmetric Synthesis of Substituted Pyrrolidines from Racemic Cyclopropanes and Aldimines: Reaction Development and Mechanistic Insights Andrew T. Parsons, Austin G. Smith, Andrew J. Neel and Jeffrey S. Johnson pp 9688–9692 DOI: 10.1021/ja1032277 Supporting Info

Control of the Orientational Order and Nonlinear Optical Response of the “Push−Pull” Chromophore RuPZn via Specific Incorporation into Densely Packed Monolayer Ensembles of an Amphiphilic 4-Helix Bundle Peptide: Second Harmonic Generation at High Chromophore Densities Grazia Gonella, Hai-Lung Dai, H. Christopher Fry, Michael J. Therien, Venkata Krishnan, Andrey Tronin and J. Kent Blasie pp 9693–9700 DOI: 10.1021/ja1010724 Supporting Info

Development Plus Kinetic and Mechanistic Studies of a Prototype Supported-Nanoparticle Heterogeneous Catalyst Formation System in Contact with Solution: Ir(1,5-COD)Cl/γ-Al2O3 and Its Reduction by H2 to Ir(0)n/γ-Al2O3 Joseph E. Mondloch, Qi Wang, Anatoly I. Frenkel and Richard G. Finke pp 9701–9714 DOI: 10.1021/ja1030062 Supporting Info

Probing Valence Orbital Composition with Iron Kβ X-ray Emission Spectroscopy Nicole Lee, Taras Petrenko, Uwe Bergmann, Frank Neese and Serena DeBeer pp 9715–9727 DOI: 10.1021/ja101281e Supporting Info

Linear dsDNA Partitions Spontaneously into the Inverse Hexagonal Lyotropic Liquid Crystalline Phases of Phospholipids Camilla F. Black, Richard J. Wilson, Tommy Nylander, Marcus K. Dymond and George S. Attard pp 9728–9732 DOI: 10.1021/ja101550c Supporting Info

Cell Adhesion to Unnatural Ligands Mediated by a Bifunctional Protein Juan Snchez-Corts, Katinka Bhr and Milan Mrksich pp 9733–9737 DOI: 10.1021/ja1016188

Nature of the Energy Landscape for Gated Electron Transfer in a Dynamic Redox Protein Sam Hay, Sibylle Brenner, Basile Khara, Anne Marie Quinn, Stephen E. J. Rigby and Nigel S. Scrutton pp 9738–9745 DOI: 10.1021/ja1016206 Supporting Info

Anisotropic and Inhomogeneous Magnetic Interactions Observed in All-Organic Nitroxide Radical Liquid Crystals Yoshiaki Uchida, Katsuaki Suzuki, Rui Tamura, Naohiko Ikuma, Satoshi Shimono, Yohei Noda and Jun Yamauchi pp 9746–9752 DOI: 10.1021/ja101930d Supporting Info

NMR and DFT Investigation of Heme Ruffling: Functional Implications for Cytochrome c Matthew D. Liptak, Xin Wen and Kara L. Bren pp 9753–9763 DOI: 10.1021/ja102098p Supporting Info

Nonhumidified Intermediate Temperature Fuel Cells Using Protic Ionic Liquids Seung-Yul Lee, Atsushi Ogawa, Michihiro Kanno, Hirofumi Nakamoto, Tomohiro Yasuda and Masayoshi Watanabe pp 9764–9773 DOI: 10.1021/ja102367x Supporting Info

Designing Green Oxidation Catalysts for Purifying Environmental Waters W. Chadwick Ellis, Camly T. Tran, Riddhi Roy, Marte Rusten, Andreas Fischer, Alexander D. Ryabov, Bruce Blumberg and Terrence J. Collins pp 9774–9781 DOI: 10.1021/ja102524v Supporting Info

Proton Transport through the Influenza A M2 Channel: Three-Dimensional Reference Interaction Site Model Study Saree Phongphanphanee, Thanyada Rungrotmongkol, Norio Yoshida, Supot Hannongbua and Fumio Hirata pp 9782–9788 DOI: 10.1021/ja1027293 Supporting Info

Hairpin DNA-Functionalized Gold Colloids for the Imaging of mRNA in Live Cells Ashwath Jayagopal, Kristin C. Halfpenny, Jonas W. Perez and David W. Wright pp 9789–9796 DOI: 10.1021/ja102585v Supporting Info

In Vitro Formation of Amyloid from α-Synuclein Is Dominated by Reactions at Hydrophobic Interfaces Jeremy Pronchik, Xianglan He, Jason T. Giurleo and David S. Talaga pp 9797–9803 DOI: 10.1021/ja102896h Supporting Info

Multidentate Poly(ethylene glycol) Ligands Provide Colloidal Stability to Semiconductor and Metallic Nanocrystals in Extreme Conditions Michael H. Stewart, Kimihiro Susumu, Bing C. Mei, Igor L. Medintz, James B. Delehanty, Juan B. Blanco-Canosa, Philip E. Dawson and Hedi Mattoussi pp 9804–9813 DOI: 10.1021/ja102898d Supporting Info

Morphology Control of Nanostructures via Surface Reaction of Metal Nanodroplets K.Y. Niu, J. Yang, S. A. Kulinich, J. Sun, H. Li and X. W. Du pp 9814–9819 DOI: 10.1021/ja102967a Supporting Info

Thymidylate Synthase Catalyzed H-Transfers: Two Chapters in One Tale Zhen Wang and Amnon Kohen pp 9820–9825 DOI: 10.1021/ja103010b Supporting Info

Hydrogen Molecules inside Fullerene C70: Quantum Dynamics, Energetics, Maximum Occupancy, And Comparison with C60 Francesco Sebastianelli, Minzhong Xu, Zlatko Bai, Ronald Lawler and Nicholas J. Turro pp 9826–9832 DOI: 10.1021/ja103062g Supporting Info

Magnetic Conjugated Polymer Nanoparticles as Bimodal Imaging Agents Philip Howes, Mark Green, Alex Bowers, David Parker, Gopal Varma, Mathew Kallumadil, Mary Hughes, Alice Warley, Anthony Brain and Rene Botnar pp 9833–9842 DOI: 10.1021/ja1031634 Supporting Info

Transmission Electron Microscopy Evidence of Spontaneous B-Cation Layered Distribution in NaNb1−xTaxO3 Almudena Torres-Pardo, Frank Krumeich, Jos M. Gonzlez-Calbet and Ester Garca-Gonzlez pp 9843–9849 DOI: 10.1021/ja1031858 Supporting Info

Reversible Biological Birch Reduction at an Extremely Low Redox Potential Johannes W. Kung, Sven Baumann, Martin von Bergen, Michael Mller, Peter-Leon Hagedoorn, Wilfred R. Hagen and Matthias Boll pp 9850–9856 DOI: 10.1021/ja103448u Supporting Info

Structural, NMR Spectroscopic, and Computational Investigation of Hemin Loading in the Hemophore HasAp from Pseudomonas aeruginosa Grace Jepkorir, Juan Carlos Rodrguez, Huan Rui, Wonpil Im, Scott Lovell, Kevin P. Battaile, Aileen Y. Alontaga, Erik T. Yukl, Pierre Monne-Loccoz and Mario Rivera pp 9857–9872 DOI: 10.1021/ja103498z Supporting Info

In Situ EPR Study of Chemical Reactions in Q-Band at Higher Temperatures: A Challenge for Elucidating Structure−Reactivity Relationships in Catalysis Reinhard Stsser, Ulrich Marx, Werner Herrmann, Jabor K. Jabor and Angelika Brckner pp 9873–9880 DOI: 10.1021/ja1035418 Supporting Info

Solution Synthesis of a New Thermoelectric Zn1+xSb Nanophase and Its Structure Determination Using Automated Electron Diffraction Tomography Christina S. Birkel, Enrico Mugnaioli, Tatiana Gorelik, Ute Kolb, Martin Panthfer and Wolfgang Tremel pp 9881–9889 DOI: 10.1021/ja1035122 Supporting Info

Environmental Effects Dominate the Folding of Oligocholates in Solution, Surfactant Micelles, and Lipid Membranes Hongkwan Cho and Yan Zhao pp 9890–9899 DOI: 10.1021/ja103694p Supporting Info

Synthesis of the QRSTU Domain of Maitotoxin and Its 85-epi- and 86-epi-Diastereoisomers K. C. Nicolaou, Christine F. Gelin, Jae Hong Seo, Zhihong Huang and Taiki Umezawa pp 9900–9907 DOI: 10.1021/ja103708j Supporting Info

Direct Synthesis of Polymer Nanocapsules: Self-Assembly of Polymer Hollow Spheres through Irreversible Covalent Bond Formation Dongwoo Kim, Eunju Kim, Jiyeong Lee, Soonsang Hong, Wokyung Sung, Namseok Lim, Chan Gyung Park and Kimoon Kim pp 9908–9919 DOI: 10.1021/ja1039242 Supporting Info

Crystalline Domain Structure and Cholesterol Crystal Nucleation in Single Hydrated DPPC:Cholesterol:POPC Bilayers Roy Ziblat, Leslie Leiserowitz and Lia Addadi pp 9920–9927 DOI: 10.1021/ja103975g Supporting Info

Total Synthesis of (±)-Aplykurodinone-1: Traceless Stereochemical Guidance Yandong Zhang and Samuel J. Danishefsky p 9928 DOI: 10.1021/ja105280j Supporting Info

Ionic and Organometallic-Catalyzed Organosilane Reductions Paul F. Hudrlik p 9929 DOI: 10.1021/ja104621z

Comprehensive Natural Products II: Chemistry and Biology, Volumes 1−10 p 9929 DOI: 10.1021/ja105512f

Fullerene Polymers: Synthesis, Properties and Applications Harry W. Gibson pp 9929–9930 DOI: 10.1021/ja1047347

Issue 29

Highly Tunable Photoluminescent Properties of Amphiphilic Conjugated Block Copolymers Sang-Jae Park, Seung-Gu Kang, Michael Fryd, Jeffery G. Saven and So-Jung Park pp 9931–9933 DOI: 10.1021/ja1004569 Supporting Info

Electronic Structure of Four-Coordinate Iron(I) Complex Supported by a Bis(phosphaethenyl)pyridine Ligand Yumiko Nakajima, Yoshihide Nakao, Shigeyoshi Sakaki, Yoshinori Tamada, Teruo Ono and Fumiyuki Ozawa pp 9934–9936 DOI: 10.1021/ja102009n Supporting Info

Discrete and Active Enzyme Nanoarrays on DNA Origami Scaffolds Purified by Affinity Tag Separation Kentaro Numajiri, Takahiro Yamazaki, Mayumi Kimura, Akinori Kuzuya and Makoto Komiyama pp 9937–9939 DOI: 10.1021/ja104702q Supporting Info

Selective 2′-Hydroxyl Acylation Analyzed by Protection from Exoribonuclease Kady-Ann Steen, Arun Malhotra and Kevin M. Weeks pp 9940–9943 DOI: 10.1021/ja103781u Supporting Info

INEPT-Based Separated-Local-Field NMR Spectroscopy: A Unique Approach To Elucidate Side-Chain Dynamics of Membrane-Associated Proteins Jiadi Xu, Ronald Soong, Sang-Choul Im, Lucy Waskell and Ayyalusamy Ramamoorthy pp 9944–9947 DOI: 10.1021/ja103983f Supporting Info

Kinetics of Amyloid β Monomer-to-Oligomer Exchange by NMR Relaxation Nicolas L. Fawzi, Jinfa Ying, Dennis A. Torchia and G. Marius Clore pp 9948–9951 DOI: 10.1021/ja1048253 Supporting Info

Validation of a Lanthanide Tag for the Analysis of Protein Dynamics by Paramagnetic NMR Spectroscopy Mathias A. S. Hass, Peter H. J. Keizers, Anneloes Blok, Yoshitaka Hiruma and Marcellus Ubbink pp 9952–9953 DOI: 10.1021/ja909508r Supporting Info

Palladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B−H Activation Sung-Kwan Kim, Won-Sik Han, Tae-Jin Kim, Tae-Young Kim, Suk Woo Nam, Mariusz Mitoraj, Łukasz Pieko, Artur Michalak, Son-Jong Hwang and Sang Ook Kang pp 9954–9955 DOI: 10.1021/ja101685u Supporting Info

Solid-State 13C NMR Assignment of Carbon Resonances on Metallic and Semiconducting Single-Walled Carbon Nanotubes Chaiwat Engtrakul, Mark F. Davis, Kevin Mistry, Brian A. Larsen, Anne C. Dillon, Michael J. Heben and Jeffrey L. Blackburn pp 9956–9957 DOI: 10.1021/ja101955e Supporting Info

Holographically Defined Nanoparticle Placement in 3D Colloidal Crystals Yoonho Jun, Dongguk Yu, Matthew C. George and Paul V. Braun pp 9958–9959 DOI: 10.1021/ja1023628 Supporting Info

Infrared-Active Heterostructured Nanocrystals with Ultralong Carrier Lifetimes Doh C. Lee, Istvn Robel, Jeffrey M. Pietryga and Victor I. Klimov pp 9960–9962 DOI: 10.1021/ja102716p Supporting Info

Synthesis of Glycopolymers for Microarray Applications via Ligation of Reducing Sugars to a Poly(acryloyl hydrazide) Scaffold Kamil Godula and Carolyn R. Bertozzi pp 9963–9965 DOI: 10.1021/ja103009d Supporting Info

Straightforward Self-Assembly of Porphyrin Nanowires in Water: Harnessing Adamantane/β-Cyclodextrin Interactions Maher Fathalla, Amelia Neuberger, Shao-Chun Li, Russell Schmehl, Ulrike Diebold and Janarthanan Jayawickramarajah pp 9966–9967 DOI: 10.1021/ja1030722 Supporting Info

A Biomimetic Approach to C-nor-D-homo-Steroids Philipp Heretsch, Sebastian Rabe and Athanassios Giannis pp 9968–9969 DOI: 10.1021/ja103152k Supporting Info

Introducing a 2-His-1-Glu Nonheme Iron Center into Myoglobin Confers Nitric Oxide Reductase Activity Ying-Wu Lin, Natasha Yeung, Yi-Gui Gao, Kyle D. Miner, Lanyu Lei, Howard Robinson and Yi Lu pp 9970–9972 DOI: 10.1021/ja103516n Supporting Info

Light-Triggered Crystallization of a Molecular Host−Guest Complex Guido H. Clever, Shohei Tashiro and Mitsuhiko Shionoya pp 9973–9975 DOI: 10.1021/ja103620z Supporting Info

Modifying the Size and Shape of Monodisperse Bifunctional Alkaline-Earth Fluoride Nanocrystals through Lanthanide Doping Daqin Chen, Yunlong Yu, Feng Huang, Ping Huang, Anping Yang and Yuansheng Wang pp 9976–9978 DOI: 10.1021/ja1036429 Supporting Info

Probing Slow Protein Dynamics by Adiabatic R1ρ and R2ρ NMR Experiments Silvia Mangia, Nathaniel J. Traaseth, Gianluigi Veglia, Michael Garwood and Shalom Michaeli pp 9979–9981 DOI: 10.1021/ja1038787 Supporting Info

Rh Catalyzed Olefination and Vinylation of Unactivated Acetanilides Frederic W. Patureau and Frank Glorius pp 9982–9983 DOI: 10.1021/ja103834b Supporting Info

Supramolecular Control of Fluorescence through Reversible Encapsulation Henry Dube, Mark R. Ams and Julius Rebek, Jr. pp 9984–9985 DOI: 10.1021/ja103912a Supporting Info

Site-Specific Introduction of an Acetyl-Lysine Mimic into Peptides and Proteins by Cysteine Alkylation Rong Huang, Marc A. Holbert, Mary Katherine Tarrant, Sandrine Curtet, David R. Colquhoun, Beverley M. Dancy, Blair C. Dancy, Yousang Hwang, Yong Tang, Katrina Meeth, Ronen Marmorstein, Robert N. Cole, Saadi Khochbin and Philip A. Cole pp 9986–9987 DOI: 10.1021/ja103954u Supporting Info

Insertion of Carboryne into Aromatic Rings: Formation of Cyclooctatetraenocarboranes Sunewang R. Wang, Zaozao Qiu and Zuowei Xie pp 9988–9989 DOI: 10.1021/ja1044488 Supporting Info

Pd-Catalyzed O-Arylation of Ethyl Acetohydroximate: Synthesis of O-Arylhydroxylamines and Substituted Benzofurans Thomas J. Maimone and Stephen L. Buchwald pp 9990–9991 DOI: 10.1021/ja1044874 Supporting Info

η2-Porphyrin Ru(II) π Complexes Shigeru Yamaguchi, Hiroshi Shinokubo and Atsuhiro Osuka pp 9992–9993 DOI: 10.1021/ja104842h Supporting Info

Linear Free Energy Relationships Demonstrate a Catalytic Role for the Flavin Mononucleotide Coenzyme of the Type II Isopentenyl Diphosphate:Dimethylallyl Diphosphate Isomerase Christopher J. Thibodeaux, Wei-chen Chang and Hung-wen Liu pp 9994–9996 DOI: 10.1021/ja104090m Supporting Info

Nanoheterostructure Cation Exchange: Anionic Framework Conservation Prashant K. Jain, Lilac Amirav, Shaul Aloni and A. Paul Alivisatos pp 9997–9999 DOI: 10.1021/ja104126u Supporting Info

Polarization-Bound Quasi-Continuum States Are Responsible for the “Blue Tail” in the Optical Absorption Spectrum of the Aqueous Electron Leif D. Jacobson and John M. Herbert pp 10000–10002 DOI: 10.1021/ja1042484 Supporting Info

AAB-Sequence Living Radical Chain Copolymerization of Naturally Occurring Limonene with Maleimide: An End-to-End Sequence-Regulated Copolymer Kotaro Satoh, Masaru Matsuda, Kanji Nagai and Masami Kamigaito pp 10003–10005 DOI: 10.1021/ja1042353 Supporting Info

Iodine as an Oxidant in the Topotactic Deintercalation of Interstitial Iron in Fe1+xTe Efrain E. Rodriguez, Peter Zavalij, Ping-Yen Hsieh and Mark A. Green pp 10006–10008 DOI: 10.1021/ja104004t Supporting Info

“On−Off” Au(I)···Cu(I) Interactions in a Au(NHC)2 Luminescent Vapochromic Sensor Christoph E. Strasser and Vincent J. Catalano pp 10009–10011 DOI: 10.1021/ja104585q Supporting Info

Concerning the Mechanism of the FeCl3-Catalyzed α-Oxyamination of Aldehydes: Evidence for a Non-SOMO Activation Pathway Jeffrey F. Van Humbeck, Scott P. Simonovich, Robert R. Knowles and David W. C. MacMillan pp 10012–10014 DOI: 10.1021/ja1043006 Supporting Info

Enantioselective Organo-SOMO Cascade Cycloadditions: A Rapid Approach to Molecular Complexity from Simple Aldehydes and Olefins Nathan T. Jui, Esther C. Y. Lee and David W. C. MacMillan pp 10015–10017 DOI: 10.1021/ja104313x Supporting Info

A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene Rajendra S. Ghadwal, Herbert W. Roesky, Markus Granitzka and Dietmar Stalke pp 10018–10020 DOI: 10.1021/ja104386g Supporting Info

Carbon Dioxide Reduction by Terminal Tantalum Hydrides: Formation and Isolation of Bridging Methylene Diolate Complexes Matthew A. Rankin and Christopher C. Cummins pp 10021–10023 DOI: 10.1021/ja104761n Supporting Info

Heteroatom-Directed Alkylcyanation of Alkynes Yoshiaki Nakao, Akira Yada and Tamejiro Hiyama pp 10024–10026 DOI: 10.1021/ja1017078 Supporting Info

Rapid Covalent Ligation of Fluorescent Peptides to Water Solubilized Quantum Dots Juan B. Blanco-Canosa, Igor L. Medintz, Dorothy Farrell, Hedi Mattoussi and Philip E. Dawson pp 10027–10033 DOI: 10.1021/ja910988d Supporting Info

Cutting of Oxidized Graphene into Nanosized Pieces Shintaro Fujii and Toshiaki Enoki pp 10034–10041 DOI: 10.1021/ja101265r

Modification of the Optoelectronic Properties of Membranes via Insertion of Amphiphilic Phenylenevinylene Oligoelectrolytes Logan E. Garner, Juhyun Park, Scott M. Dyar, Arkadiusz Chworos, James J. Sumner and Guillermo C. Bazan pp 10042–10052 DOI: 10.1021/ja1016156 Supporting Info

Highly Selective and Sensitive DNA Assay Based on Electrocatalytic Oxidation of Ferrocene Bearing Zinc(II)−Cyclen Complexes with Diethylamine Muhammad J. A. Shiddiky, Angel A. J. Torriero, Zhanghua Zeng, Leone Spiccia and Alan M. Bond pp 10053–10063 DOI: 10.1021/ja1021365 Supporting Info

Hydrogels with Cylindrically Symmetric Structure at Macroscopic Scale by Self-Assembly of Semi-rigid Polyion Complex Zi Liang Wu, Takayuki Kurokawa, Songmiao Liang, Hidemitsu Furukawa and Jian Ping Gong pp 10064–10069 DOI: 10.1021/ja101969k Supporting Info

Nickel/Lewis Acid-Catalyzed Cyanoesterification and Cyanocarbamoylation of Alkynes Yasuhiro Hirata, Akira Yada, Eiji Morita, Yoshiaki Nakao, Tamejiro Hiyama, Masato Ohashi and Sensuke Ogoshi pp 10070–10077 DOI: 10.1021/ja102346v Supporting Info

Controlled Incorporation of Particles into the Central Portion of Vesicle Walls Yiyong Mai and Adi Eisenberg pp 10078–10084 DOI: 10.1021/ja1024063 Supporting Info

Expanding the Chemical Versatility of Colloidal Nanocrystals Capped with Molecular Metal Chalcogenide Ligands Maksym V. Kovalenko, Maryna I. Bodnarchuk, Jana Zaumseil, Jong-Soo Lee and Dmitri V. Talapin pp 10085–10092 DOI: 10.1021/ja1024832 Supporting Info

Transforming a Blue Copper into a Red Copper Protein: Engineering Cysteine and Homocysteine into the Axial Position of Azurin Using Site-Directed Mutagenesis and Expressed Protein Ligation Kevin M. Clark, Yang Yu, Nicholas M. Marshall, Nathan A. Sieracki, Mark J. Nilges, Ninian J. Blackburn, Wilfred A. van der Donk and Yi Lu pp 10093–10101 DOI: 10.1021/ja102632p Supporting Info

Dual-Channel Microreactor for Gas−Liquid Syntheses Chan Pil Park and Dong-Pyo Kim pp 10102–10106 DOI: 10.1021/ja102666y Supporting Info

Flexibility of Shape-Persistent Molecular Building Blocks Composed of p-Phenylene and Ethynylene Units Gunnar Jeschke, Muhammad Sajid, Miriam Schulte, Navid Ramezanian, Aleksei Volkov, Herbert Zimmermann and Adelheid Godt pp 10107–10117 DOI: 10.1021/ja102983b Supporting Info

Simultaneous Noncontact Topography and Electrochemical Imaging by SECM/SICM Featuring Ion Current Feedback Regulation Yasufumi Takahashi, Andrew I. Shevchuk, Pavel Novak, Yumi Murakami, Hitoshi Shiku, Yuri E. Korchev and Tomokazu Matsue pp 10118–10126 DOI: 10.1021/ja1029478 Supporting Info

Electronic and Steric Control of Regioselectivities in Rh(I)-Catalyzed (5 + 2) Cycloadditions: Experiment and Theory Peng Liu, Lauren E. Sirois, Paul Ha-Yeon Cheong, Zhi-Xiang Yu, Ingo V. Hartung, Heiko Rieck, Paul A. Wender and K. N. Houk pp 10127–10135 DOI: 10.1021/ja103253d Supporting Info

Transannular Disulfide Formation in Gliotoxin Biosynthesis and Its Role in Self-Resistance of the Human Pathogen Aspergillus fumigatus Daniel H. Scharf, Nicole Remme, Thorsten Heinekamp, Peter Hortschansky, Axel A. Brakhage and Christian Hertweck pp 10136–10141 DOI: 10.1021/ja103262m Supporting Info

Effect of Base Pairing on the Electrochemical Oxidation of Guanine Cyrille Costentin, Viviane Hajj, Marc Robert, Jean-Michel Savant and Cdric Tard pp 10142–10147 DOI: 10.1021/ja103421f Supporting Info

Multistage Collapse of a Bacterial Ribozyme Observed by Time-Resolved Small-Angle X-ray Scattering Joon Ho Roh, Liang Guo, J. Duncan Kilburn, Robert M. Briber, Thomas Irving and Sarah A. Woodson pp 10148–10154 DOI: 10.1021/ja103867p Supporting Info

Structure and Photoinduced Electron Transfer Dynamics of a Series of Hydrogen-Bonded Supramolecular Complexes Composed of Electron Donors and a Saddle-Distorted Diprotonated Porphyrin Tatsuhiko Honda, Tatsuaki Nakanishi, Kei Ohkubo, Takahiko Kojima and Shunichi Fukuzumi pp 10155–10163 DOI: 10.1021/ja103889f Supporting Info

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon Anukul Jana, Prinson P. Samuel, Gaper Tavar, Herbert W. Roesky and Carola Schulzke pp 10164–10170 DOI: 10.1021/ja103988d Supporting Info

Nano Building Blocks via Iodination of [PhSiO1.5]n, Forming [p-I-C6H4SiO1.5]n (n = 8, 10, 12), and a New Route to High-Surface-Area, Thermally Stable, Microporous Materials via Thermal Elimination of I2 M. F. Roll, J. W. Kampf, Y. Kim, E. Yi and R. M. Laine pp 10171–10183 DOI: 10.1021/ja102453s Supporting Info

Design, Synthesis, and Study of Main Chain Poly(N-Heterocyclic Carbene) Complexes: Applications in Electrochromic Devices Adam B. Powell, Christopher W. Bielawski and Alan H. Cowley pp 10184–10194 DOI: 10.1021/ja104051x Supporting Info

Utilizing Self-Exchange To Address the Binding of Carboxylic Acid Ligands to CdSe Quantum Dots Bernd Fritzinger, Richard K. Capek, Karel Lambert, Jos C. Martins and Zeger Hens pp 10195–10201 DOI: 10.1021/ja104351q Supporting Info

Ruthenium-Catalyzed Hydroxylation of Unactivated Tertiary C−H Bonds Eric McNeill and J. Du Bois pp 10202–10204 DOI: 10.1021/ja1046999 Supporting Info

Ruthenium(0) Nanoclusters Stabilized by Nanozeolite Framework: Isolable, Reusable, and Green Catalyst for the Hydrogenation of Neat Aromatics under Mild Conditions with the Unprecedented Catalytic Activity and Lifetime Mehmet Zahmakıran, Yalın Tonbul and Saim zkar p 10205 DOI: 10.1021/ja103871s Supporting Info

A New Mechanism for Chemically Induced Dynamic Nuclear Polarization in the Solid State Gunnar Jeschke p 10205 DOI: 10.1021/ja104063g

Chiral Ferrocenes in Asymmetric Catalysis: Synthesis and Applications Kevin Burgess p 10206 DOI: 10.1021/ja105679w

Controlled and Living Polymerizations: From Mechanisms to Applications Jennifer O’Donnell pp 10206–10207 DOI: 10.1021/ja105230x

Molecular Nano Dynamics, Volume 1: Spectroscopy Methods and Nanostructures, and Volume 2: Active Surfaces, Single Crystals and Single Biocells Wei David Wei pp 10207–10208 DOI: 10.1021/ja1048175

Practical Methods for Biocatalysis and Biotransformations p 10208 DOI: 10.1021/ja105554c

Issue 30

Palladium-Catalyzed Hydroarylation of 1,3-Dienes with Boronic Esters via Reductive Formation of π-Allyl Palladium Intermediates under Oxidative Conditions Longyan Liao and Matthew S. Sigman pp 10209–10211 DOI: 10.1021/ja105010t Supporting Info

Templated Synthesis of DNA Nanotubes with Controlled, Predetermined Lengths Pik Kwan Lo, Florian Altvater and Hanadi F. Sleiman pp 10212–10214 DOI: 10.1021/ja1017442 Supporting Info

Carrier-Tunable Magnetic Ordering in Vanadium−Naphthalene Sandwich Nanowires Zhuhua Zhang, Xiaojun Wu, Wanlin Guo and Xiao Cheng Zeng pp 10215–10217 DOI: 10.1021/ja1029057 Supporting Info

Highly Stable and CO-Tolerant Pt/Ti0.7W0.3O2 Electrocatalyst for Proton-Exchange Membrane Fuel Cells Deli Wang, Chinmayee V. Subban, Hongsen Wang, Eric Rus, Francis J. DiSalvo and Hector D. Abrua pp 10218–10220 DOI: 10.1021/ja102931d Supporting Info

A Zeolitic Material with a Three-Dimensional Pore System Formed by Straight 12- and 10-Ring Channels Synthesized with an Imidazolium Derivative as Structure-Directing Agent Mathias Dodin, Jean-Louis Paillaud, Yannnick Lorgouilloux, Philippe Caullet, Erik Elkam and Nicolas Bats pp 10221–10223 DOI: 10.1021/ja103648k Supporting Info

Giant Plasmon Resonance Shift Using Poly(3,4-ethylenedioxythiophene) Electrochemical Switching Verena Stockhausen, Pascal Martin, Jalal Ghilane, Yann Leroux, Hyacinthe Randriamahazaka, Johan Grand, Nordin Felidj and Jean Christophe Lacroix pp 10224–10226 DOI: 10.1021/ja103337d Supporting Info

Catalytic Asymmetric Epoxidation of α-Branched Enals Olga Lifchits, Corinna M. Reisinger and Benjamin List pp 10227–10229 DOI: 10.1021/ja1037935 Supporting Info

Lectin Biosensing Using Digital Analysis of Ru(II)-Glycodendrimers Raghavendra Kikkeri, Dan Grnstein and Peter H. Seeberger pp 10230–10232 DOI: 10.1021/ja103688s Supporting Info

Total Synthesis of (+)-Manzamine A Tatsuya Toma, Yoichi Kita and Tohru Fukuyama pp 10233–10235 DOI: 10.1021/ja103721s Supporting Info

Nanoscale Positioning of Individual DNA Molecules by an Atomic Force Microscope Eric A. Josephs and Tao Ye pp 10236–10238 DOI: 10.1021/ja1039677 Supporting Info

Molecular Analysis of Carbohydrate−Antibody Interactions: Case Study Using a Bacillus anthracis Tetrasaccharide Matthias A. Oberli, Marco Tamborrini, Yu-Hsuan Tsai, Daniel B. Werz, Tim Horlacher, Alexander Adibekian, Dominik Gauss, Heiko M. Mller, Gerd Pluschke and Peter H. Seeberger pp 10239–10241 DOI: 10.1021/ja104027w Supporting Info

Enantioselective Cationic Polyene Cyclization vs Enantioselective Intramolecular Carbonyl−Ene Reaction Yu-Jun Zhao, Bin Li, Li-Jun Serena Tan, Zhi-Liang Shen and Teck-Peng Loh pp 10242–10244 DOI: 10.1021/ja104119j Supporting Info

Facile, Efficient, and Catalyst-Free Electrophilic Aminoalkoxylation of Olefins: Scope and Application Ling Zhou, Chong Kiat Tan, Jing Zhou and Ying-Yeung Yeung pp 10245–10247 DOI: 10.1021/ja104168q Supporting Info

Enantioselective (Formal) Aza-Diels−Alder Reactions with Non-Danishefsky-Type Dienes Uttam K. Tambar, Sharon K. Lee and James L. Leighton pp 10248–10250 DOI: 10.1021/ja104480g Supporting Info

Topology-Directed Control on Thermal Stability: Micelles Formed from Linear and Cyclized Amphiphilic Block Copolymers Satoshi Honda, Takuya Yamamoto and Yasuyuki Tezuka pp 10251–10253 DOI: 10.1021/ja104691j Supporting Info

Palladium-Catalyzed Dimerization of Vinyl Ethers to Acetals Changle Chen and Richard F. Jordan pp 10254–10255 DOI: 10.1021/ja104523y Supporting Info

Temperature-Responsive Nanospheres with Bicontinuous Internal Structures from a Semicrystalline Amphiphilic Block Copolymer Beulah E. McKenzie, Fabio Nudelman, Paul H. H. Bomans, Simon J. Holder and Nico A. J. M. Sommerdijk pp 10256–10259 DOI: 10.1021/ja102040u Supporting Info

UV-Induced TA Photoproducts: Formation and Hydrolysis in Double-Stranded DNA Sadia Asgatay, Agathe Martinez, Stphanie Coantic-Castex, Dominique Harakat, Coralie Philippe, Thierry Douki and Pascale Clivio pp 10260–10261 DOI: 10.1021/ja1023173 Supporting Info

A Crystalline Phosphinyl Radical Cation Olivier Back, Mehmet Ali Celik, Gernot Frenking, Mohand Melaimi, Bruno Donnadieu and Guy Bertrand pp 10262–10263 DOI: 10.1021/ja1046846 Supporting Info

Synthesis of a Pentasilapropellane. Exploring the Nature of a Stretched Silicon−Silicon Bond in a Nonclassical Molecule Dominik Nied, Ralf Kppe, Wim Klopper, Hansgeorg Schnckel and Frank Breher pp 10264–10265 DOI: 10.1021/ja104810u Supporting Info

Programmable Microcapsules from Self-Immolative Polymers Aaron P. Esser-Kahn, Nancy R. Sottos, Scott R. White and Jeffrey S. Moore pp 10266–10268 DOI: 10.1021/ja104812p Supporting Info

Rotational and Core Level Spectroscopies As Complementary Techniques in Tautomeric/Conformational Studies: The Case of 2-Mercaptopyridine Sonia Melandri, Luca Evangelisti, Assimo Maris, Walther Caminati, Barbara M. Giuliano, Vitaliy Feyer, Kevin C. Prince and Marcello Coreno pp 10269–10271 DOI: 10.1021/ja104484b Supporting Info

A New Combined Source of “CN” from N,N-Dimethylformamide and Ammonia in the Palladium-Catalyzed Cyanation of Aryl C−H Bonds Jinho Kim and Sukbok Chang pp 10272–10274 DOI: 10.1021/ja104917t Supporting Info

Direct Catalytic Asymmetric Conjugate Addition of Terminal Alkynes to α,β-Unsaturated Thioamides Ryo Yazaki, Naoya Kumagai and Masakatsu Shibasaki pp 10275–10277 DOI: 10.1021/ja105141x Supporting Info

Isolation, Structural Elucidation, and Absolute Stereochemistry of Enigmazole A, a Cytotoxic Phosphomacrolide from the Papua New Guinea Marine Sponge Cinachyrella enigmatica Naoya Oku, Kentaro Takada, Richard W. Fuller, Jennifer A. Wilson, Megan L. Peach, Lewis K. Pannell, James B. McMahon and Kirk R. Gustafson pp 10278–10285 DOI: 10.1021/ja1016766 Supporting Info

Total Synthesis of Enigmazole A from Cinachyrella enigmatica. Bidirectional Bond Constructions with an Ambident 2,4-Disubstituted Oxazole Synthon Colin K. Skepper, Tim Quach and Tadeusz F. Molinski pp 10286–10292 DOI: 10.1021/ja1016975 Supporting Info

Peroxo−Iron Mediated Deformylation in Sterol 14α-Demethylase Catalysis Kakali Sen and John C Hackett pp 10293–10305 DOI: 10.1021/ja906192b Supporting Info

Origin of Pressure Effects on Regioselectivity and Enantioselectivity in the Rhodium-Catalyzed Hydroformylation of Styrene with (S,S,S)-BisDiazaphos Avery L. Watkins and Clark R. Landis pp 10306–10317 DOI: 10.1021/ja909619a Supporting Info

Quantitative 2D and 3D Γ-HCP Experiments for the Determination of the Angles α and ζ in the Phosphodiester Backbone of Oligonucleotides Senada Nozinovic, Christian Richter, Jrg Rinnenthal, Boris Frtig, Elke Duchardt-Ferner, Julia E. Weigand and Harald Schwalbe pp 10318–10329 DOI: 10.1021/ja910015n Supporting Info

Backbone Flexibility Controls the Activity and Specificity of a Protein−Protein Interface: Specificity in Snake Venom Metalloproteases Hannes G. Wallnoefer, Torsten Lingott, Jos Mara Gutirrez, Irmgard Merfort and Klaus R. Liedl pp 10330–10337 DOI: 10.1021/ja909908y Supporting Info

Communication between the Zinc and Nickel Sites in Dimeric HypA: Metal Recognition and pH Sensing Robert W. Herbst, Iva Perovic, Vlad Martin-Diaconescu, Kerrie O’Brien, Peter T. Chivers, Susan Sondej Pochapsky, Thomas C. Pochapsky and Michael J. Maroney pp 10338–10351 DOI: 10.1021/ja1005724 Supporting Info

High-Performance Solution-Processed Amorphous Zinc−Indium−Tin Oxide Thin-Film Transistors Myung-Gil Kim, Hyun Sung Kim, Young-Geun Ha, Jiaqing He, Mercouri G. Kanatzidis, Antonio Facchetti and Tobin J. Marks pp 10352–10364 DOI: 10.1021/ja100615r Supporting Info

Nanoscale Morphology, Dimensional Control, and Electrical Properties of Oligoanilines Yue Wang, Henry D. Tran, Lei Liao, Xiangfeng Duan and Richard B. Kaner pp 10365–10373 DOI: 10.1021/ja1014184 Supporting Info

Diferrocenyl Molecular Wires. The Role of Heteroatom Linkers Yu Li, Mira Josowicz and Laren M. Tolbert pp 10374–10382 DOI: 10.1021/ja101585z Supporting Info

Protein and Small Molecule Recognition Properties of Deep Cavitands in a Supported Lipid Membrane Determined by Calcination-Enhanced SPR Spectroscopy Ying Liu, Puhong Liao, Quan Cheng and Richard J. Hooley pp 10383–10390 DOI: 10.1021/ja102252d Supporting Info

Nanoscale Ln(III)-Carboxylate Coordination Polymers (Ln = Gd, Eu, Yb): Temperature-Controlled Guest Encapsulation and Light Harvesting Xuanjun Zhang, Mohamed Ali Ballem, Maria Ahrn, Anke Suska, Peder Bergman and Kajsa Uvdal pp 10391–10397 DOI: 10.1021/ja102299b Supporting Info

Biphasic Pd−Au Alloy Catalyst for Low-Temperature CO Oxidation Jing Xu, Tim White, Ping Li, Chongheng He, Jianguo Yu, Weikang Yuan and Yi-Fan Han pp 10398–10406 DOI: 10.1021/ja102617r

Exploiting Enzymatic Promiscuity to Engineer a Focused Library of Highly Selective Antifungal and Antiproliferative Aureothin Analogues Martina Werneburg, Benjamin Busch, Jing He, Martin E.A. Richter, Longkuan Xiang, Bradley S. Moore, Martin Roth, Hans-Martin Dahse and Christian Hertweck pp 10407–10413 DOI: 10.1021/ja102751h Supporting Info

Magic Angle Spinning NMR Analysis of β2-Microglobulin Amyloid Fibrils in Two Distinct Morphologies Galia T. Debelouchina, Geoffrey W. Platt, Marvin J. Bayro, Sheena E. Radford and Robert G. Griffin pp 10414–10423 DOI: 10.1021/ja102775u Supporting Info

Site-Directed Spin-Labeling of Nucleic Acids by Click Chemistry: Detection of Abasic Sites in Duplex DNA by EPR Spectroscopy Ulla Jakobsen, Sandip A. Shelke, Stefan Vogel and Snorri Th. Sigurdsson pp 10424–10428 DOI: 10.1021/ja102797k Supporting Info

Chemical Imaging of Catalyst Deactivation during the Conversion of Renewables at the Single Particle Level: Etherification of Biomass-Based Polyols with Alkenes over H-Beta Zeolites Andrei N. Parvulescu, Davide Mores, Eli Stavitski, Cristian M. Teodorescu, Pieter C. A. Bruijnincx, Robertus J. M. Klein Gebbink and Bert M. Weckhuysen pp 10429–10439 DOI: 10.1021/ja102566b Supporting Info

Direct Observation of Enantiospecific Substitution in a Two-Dimensional Chiral Phase Transition Bing Yang, Yeliang Wang, Huanyao Cun, Shixuan Du, Mingchun Xu, Yue Wang, Karl-Heinz Ernst and Hong-Jun Gao pp 10440–10444 DOI: 10.1021/ja102989y Supporting Info

Macromolecular Crowding Remodels the Energy Landscape of a Protein by Favoring a More Compact Unfolded State Jiang Hong and Lila M. Gierasch pp 10445–10452 DOI: 10.1021/ja103166y Supporting Info

((Alkyloxy)carbonyl)cyanomethylene-Substituted Thienoquinoidal Compounds: a New Class of Soluble n-Channel Organic Semiconductors for Air-Stable Organic Field-Effect Transistors Yuki Suzuki, Eigo Miyazaki and Kazuo Takimiya pp 10453–10466 DOI: 10.1021/ja103171y Supporting Info

Compositional Control of the Superconducting Properties of LiFeAs Michael J. Pitcher, Tom Lancaster, Jack D. Wright, Isabel Franke, Andrew J. Steele, Peter J. Baker, Francis L. Pratt, William Trevelyan Thomas, Dinah R. Parker, Stephen J. Blundell and Simon J. Clarke pp 10467–10476 DOI: 10.1021/ja103196c Supporting Info

Ridge-Tile-like Chiral Topology: Synthesis, Resolution, and Complete Chiroptical Characterization of Enantiomers of Edge-Sharing Binuclear Square Planar Complexes of Ni(II) Bearing Achiral Ligands Vadim A. Soloshonok, Taizo Ono, Hisanori Ueki, Nicolas Vanthuyne, Teodor Silviu Balaban, Jochen Brck, Heike Fliegl, Wim Klopper, Jean-Valre Naubron, Tam T. T. Bui, Alex F. Drake and Christian Roussel pp 10477–10483 DOI: 10.1021/ja103296g Supporting Info

M═Nα Cycloaddition and Nα−Nβ Insertion in the Reactions of Titanium Hydrazido Compounds with Alkynes: A Combined Experimental and Computational Study A. Daniel Schofield, Ainara Nova, Jonathan D. Selby, Catherine D. Manley, Andrew D. Schwarz, Eric Clot and Philip Mountford pp 10484–10497 DOI: 10.1021/ja1036513 Supporting Info

Diquat Derivatives: Highly Active, Two-Dimensional Nonlinear Optical Chromophores with Potential Redox Switchability Benjamin J. Coe, John Fielden, Simon P. Foxon, James A. Harris, Madeleine Helliwell, Bruce S. Brunschwig, Inge Asselberghs, Koen Clays, Javier Garn and Jess Orduna pp 10498–10512 DOI: 10.1021/ja103289a Supporting Info

Scope of the Ring-Opening Metathesis Polymerization (ROMP) Reaction of 1-Substituted Cyclobutenes Airong Song, Jae Chul Lee, Kathlyn A. Parker and Nicole S. Sampson pp 10513–10520 DOI: 10.1021/ja1037098 Supporting Info

G-Quadruplex Hinders Translocation of BLM Helicase on DNA: A Real-Time Fluorescence Spectroscopic Unwinding Study and Comparison with Duplex Substrates Jia-quan Liu, Chang-yue Chen, Yong Xue, Yu-hua Hao and Zheng Tan pp 10521–10527 DOI: 10.1021/ja1038165 Supporting Info

Membrane Disk and Sphere: Controllable Mesoscopic Structures for the Capture and Release of a Targeted Object Tsutomu Hamada, Ryoko Sugimoto, Mun’delanji C. Vestergaard, Takeshi Nagasaki and Masahiro Takagi pp 10528–10532 DOI: 10.1021/ja103895b Supporting Info

Organozirconium Complexes as Catalysts for Markovnikov-Selective Intermolecular Hydrothiolation of Terminal Alkynes: Scope and Mechanism Charles J. Weiss and Tobin J. Marks pp 10533–10546 DOI: 10.1021/ja103979b Supporting Info

Development of an Efficient and Durable Photocatalytic System for Hydride Reduction of an NAD(P)+ Model Compound Using a Ruthenium(II) Complex Based on Mechanistic Studies Yasuo Matsubara, Kichitaro Koga, Atsuo Kobayashi, Hideo Konno, Kazuhiko Sakamoto, Tatsuki Morimoto and Osamu Ishitani pp 10547–10552 DOI: 10.1021/ja1040122 Supporting Info

Carbon Monoxide-Induced Dinitrogen Cleavage with Group 4 Metallocenes: Reaction Scope and Coupling to N−H Bond Formation and CO Deoxygenation Donald J. Knobloch, Emil Lobkovsky and Paul J. Chirik pp 10553–10564 DOI: 10.1021/ja104025v Supporting Info

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C−H/N−H Activation Todd K. Hyster and Tomislav Rovis pp 10565–10569 DOI: 10.1021/ja103776u Supporting Info

Fluorescence Activated Cell Sorting as a General Ultra-High-Throughput Screening Method for Directed Evolution of Glycosyltransferases Guangyu Yang, Jamie R. Rich, Michel Gilbert, Warren W. Wakarchuk, Yan Feng and Stephen G. Withers pp 10570–10577 DOI: 10.1021/ja104167y Supporting Info

Dehydrogenation of Saturated CC and BN Bonds at Cationic N-Heterocyclic Carbene Stabilized M(III) Centers (M = Rh, Ir) Christina Y. Tang, Amber L. Thompson and Simon Aldridge pp 10578–10591 DOI: 10.1021/ja1043787 Supporting Info

Copper-Catalyzed Enantioselective Propargylic Amination of Propargylic Esters with Amines: Copper−Allenylidene Complexes as Key Intermediates Gaku Hattori, Ken Sakata, Hiroshi Matsuzawa, Yoshiaki Tanabe, Yoshihiro Miyake and Yoshiaki Nishibayashi pp 10592–10608 DOI: 10.1021/ja1047494 Supporting Info

Mechanochemical Transduction of Externally Applied Forces to Mechanophores Jordi Ribas-Arino, Motoyuki Shiga and Dominik Marx pp 10609–10614 DOI: 10.1021/ja104958e Supporting Info

Linker Strategies in Solid-Phase Organic Synthesis Mark J. Kurth p 10615 DOI: 10.1021/ja104455s

Electrochemistry in Nonaqueous Solutions: Revised and Enlarged 2nd ed Wesley A. Henderson pp 10615–10616 DOI: 10.1021/ja104941q

Issue 31

Potentially Deadly Carcinogenic Chromium Redox Cycle Involving Peroxochromium(IV) and Glutathione Roberto Marin, Yachna Ahuja and Rathindra N. Bose pp 10617–10619 DOI: 10.1021/ja102173v

Detection of the Photosystem I:Ferredoxin Complex by Backscattering Interferometry Pierre Stif, Nathan Harris, Bernard Lagoutte, Stephen Dotson and Scot. R Weinberger pp 10620–10622 DOI: 10.1021/ja102208u Supporting Info

Noninvasive Remote-Controlled Release of Drug Molecules in Vitro Using Magnetic Actuation of Mechanized Nanoparticles Courtney R. Thomas, Daniel P. Ferris, Jae-Hyun Lee, Eunjoo Choi, Mi Hyeon Cho, Eun Sook Kim, J. Fraser Stoddart, Jeon-Soo Shin, Jinwoo Cheon and Jeffrey I. Zink pp 10623–10625 DOI: 10.1021/ja1022267 Supporting Info

Reagent-Dependent Formation of C−C and C−F Bonds in Pt Complexes: An Unexpected Twist in the Electrophilic Fluorination Chemistry Ariela W. Kaspi, Israel Goldberg and Arkadi Vigalok pp 10626–10627 DOI: 10.1021/ja101436w Supporting Info

Rapid Visualization and Large-Scale Profiling of Bacterial Lipoproteins with Chemical Reporters Kavita J. Rangan, Yu-Ying Yang, Guillaume Charron and Howard C. Hang pp 10628–10629 DOI: 10.1021/ja101387b Supporting Info

Enantioselective Synthesis of Boron-Substituted Quaternary Carbons by NHC−Cu-Catalyzed Boronate Conjugate Additions to Unsaturated Carboxylic Esters, Ketones, or Thioesters Jeannette M. O’Brien, Kang-sang Lee and Amir H. Hoveyda pp 10630–10633 DOI: 10.1021/ja104777u Supporting Info

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions Aikomari Guzman-Martinez and Amir H. Hoveyda pp 10634–10637 DOI: 10.1021/ja104254d Supporting Info

Tailoring DNA Structure To Increase Target Hybridization Kinetics on Surfaces Andrew E. Prigodich, One-Sun Lee, Weston L. Daniel, Dwight S. Seferos, George C. Schatz and Chad A. Mirkin pp 10638–10641 DOI: 10.1021/ja104859j Supporting Info

Rapid Release of Entrapped Contents from Multi-Functionalizable, Surface Cross-Linked Micelles upon Different Stimulation Shiyong Zhang and Yan Zhao pp 10642–10644 DOI: 10.1021/ja103391k Supporting Info

Anticancer Drug Release from a Mesoporous Silica Based Nanophotocage Regulated by Either a One- or Two-Photon Process Qiuning Lin, Qi Huang, Chunyan Li, Chunyan Bao, Zhenzhen Liu, Fuyou Li and Linyong Zhu pp 10645–10647 DOI: 10.1021/ja103415t Supporting Info

Is There a Lower Limit to the CC Bonding Distances in Neutral Radical π-Dimers? The Case of Phenalenyl Derivatives Yong-Hui Tian and Miklos Kertesz pp 10648–10649 DOI: 10.1021/ja103396h Supporting Info

Chiral Bisguanidine-Catalyzed Inverse-Electron-Demand Hetero-Diels−Alder Reaction of Chalcones with Azlactones Shunxi Dong, Xiaohua Liu, Xiaohong Chen, Fang Mei, Yulong Zhang, Bo Gao, Lili Lin and Xiaoming Feng pp 10650–10651 DOI: 10.1021/ja1046928 Supporting Info

Characterization of a Six-Coordinate Ferrous High-Spin Heme with Both Intramolecular Axial Carboxylic Acid and Pyridine Ismail Hijazi, Thierry Roisnel, Pascale Even-Hernandez, Eric Furet, Jean-Franois Halet, Olivier Cador and Bernard Boitrel pp 10652–10653 DOI: 10.1021/ja103825g Supporting Info

A New Route to Carbohydrate Secondary and Tertiary Structure Using Raman Spectroscopy and Raman Optical Activity Nicola R. Yaffe, Andrew Almond and Ewan W. Blanch pp 10654–10655 DOI: 10.1021/ja104077n

Structure and Orientation of Water at Charged Lipid Monolayer/Water Interfaces Probed by Heterodyne-Detected Vibrational Sum Frequency Generation Spectroscopy Jahur A. Mondal, Satoshi Nihonyanagi, Shoichi Yamaguchi and Tahei Tahara pp 10656–10657 DOI: 10.1021/ja104327t Supporting Info

Facile Synthesis of Aminodiborane and Inorganic Butane Analogue NH3BH2NH2BH3 Xuenian Chen, Ji-Cheng Zhao and Sheldon G. Shore pp 10658–10659 DOI: 10.1021/ja104938v Supporting Info

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide Andreas Berkefeld, Warren E. Piers and Masood Parvez pp 10660–10661 DOI: 10.1021/ja105320c Supporting Info

1,4,7-Trimethyloxatriquinane: SN2 Reaction at Tertiary Carbon Mark Mascal, Nema Hafezi and Michael D. Toney pp 10662–10664 DOI: 10.1021/ja103880c Supporting Info

Synthesis and Characterization of a Coupled Binuclear CuI/CuIII Complex Jess Garca-Lpez, Vctor Yaez-Rodrguez, Laura Roces, Santiago Garca-Granda, Ana Martnez, Alfredo Guevara-Garca, German R. Castro, Flix Jimnez-Villacorta, Mara J. Iglesias and Fernando Lpez Ortiz pp 10665–10667 DOI: 10.1021/ja1034667 Supporting Info

Dioxygen Activation by a Non-Heme Iron(II) Complex: Formation of an Iron(IV)−Oxo Complex via C−H Activation by a Putative Iron(III)−Superoxo Species Yong-Min Lee, Seungwoo Hong, Yuma Morimoto, Woonsup Shin, Shunichi Fukuzumi and Wonwoo Nam pp 10668–10670 DOI: 10.1021/ja103903c Supporting Info

Expanding Micelle Nanolithography to the Self-Assembly of Multicomponent Core−Shell Nanoparticles Beri N. Mbenkum, Alejandro Daz-Ortiz, Lin Gu, Peter A. van Aken and Gisela Schtz pp 10671–10673 DOI: 10.1021/ja104098u Supporting Info

Iron-Catalyzed Suzuki−Miyaura Coupling of Alkyl Halides Takuji Hatakeyama, Toru Hashimoto, Yoshiyuki Kondo, Yuichi Fujiwara, Hirofumi Seike, Hikaru Takaya, Yoshinori Tamada, Teruo Ono and Masaharu Nakamura pp 10674–10676 DOI: 10.1021/ja103973a Supporting Info

A Carbene−Carbene Complex Equilibrium Robert A. Moss, Lei Wang, Christina M. Odorisio and Karsten Krogh-Jespersen pp 10677–10679 DOI: 10.1021/ja104514h Supporting Info

Synthesis of a pH-Sensitive Nitrilotriacetic Linker to Peptide Transduction Domains To Enable Intracellular Delivery of Histidine Imidazole Ring-Containing Macromolecules Ronald K. June, Khirud Gogoi, Akiko Eguchi, Xian-Shu Cui and Steven F. Dowdy pp 10680–10682 DOI: 10.1021/ja1040418 Supporting Info

Noncovalent Encapsulation Stabilities in Supramolecular Nanoassemblies Siriporn Jiwpanich, Ja-Hyoung Ryu, Sean Bickerton and S. Thayumanavan pp 10683–10685 DOI: 10.1021/ja105059g Supporting Info

Pd-Catalyzed Enantioselective Allyl−Allyl Cross-Coupling Ping Zhang, Laura A. Brozek and James P. Morken pp 10686–10688 DOI: 10.1021/ja105161f Supporting Info

Oxidation of Organoplatinum(II) by Coordinated Dimethylsulfoxide: Metal−Metal Bonded, Dinuclear, Liquid-Crystalline Complexes of Platinum(III) Amedeo Santoro, Marcin Wegrzyn, Adrian C. Whitwood, Bertrand Donnio and Duncan W. Bruce pp 10689–10691 DOI: 10.1021/ja105469a Supporting Info

Investigation of the Mechanism of C(sp3)−H Bond Cleavage in Pd(0)-Catalyzed Intramolecular Alkane Arylation Adjacent to Amides and Sulfonamides Sophie Rousseaux, Serge I. Gorelsky, Benjamin K. W. Chung and Keith Fagnou pp 10692–10705 DOI: 10.1021/ja103081n Supporting Info

Intramolecular Palladium-Catalyzed Alkane C−H Arylation from Aryl Chlorides Sophie Rousseaux, Michal Davi, Julien Sofack-Kreutzer, Cathleen Pierre, Christos E. Kefalidis, Eric Clot, Keith Fagnou and Olivier Baudoin pp 10706–10716 DOI: 10.1021/ja1048847 Supporting Info

Crystal Structure of Chiral γPNA with Complementary DNA Strand: Insights into the Stability and Specificity of Recognition and Conformational Preorganization Joanne I. Yeh, Boris Shivachev, Srinivas Rapireddy, Matthew J. Crawford, Roberto R. Gil, Shoucheng Du, Marcela Madrid and Danith H. Ly pp 10717–10727 DOI: 10.1021/ja907225d Supporting Info

The Histidine Effect. Electron Transfer and Capture Cause Different Dissociations and Rearrangements of Histidine Peptide Cation-Radicals Frantiek Tureek, Thomas W. Chung, Christopher L. Moss, Jean A. Wyer, Anneli Ehlerding, Anne I. S. Holm, Henning Zettergren, Steen Brøndsted Nielsen, Preben Hvelplund, Julia Chamot-Rooke, Benjamin Bythell and Bla Paizs pp 10728–10740 DOI: 10.1021/ja907808h Supporting Info

Azodicarboxamides as Template Binding Motifs for the Building of Hydrogen-Bonded Molecular Shuttles Jos Bern, Mateo Alajarn and Ral-Angel Orenes pp 10741–10747 DOI: 10.1021/ja101151t Supporting Info

CO2 Triggering and Controlling Orthogonally Multiresponsive Photochromic Systems Tamim A. Darwish, Richard A. Evans, Michael James, Nino Malic, Gerry Triani and Tracey L. Hanley pp 10748–10755 DOI: 10.1021/ja1013322 Supporting Info

Structural and Chemical Control in Assembly of Multicomponent Metal−Organic Coordination Networks on a Surface Ziliang Shi and Nian Lin pp 10756–10761 DOI: 10.1021/ja1018578

Engineering ESPT Pathways Based on Structural Analysis of LSSmKate Red Fluorescent Proteins with Large Stokes Shift Kiryl D. Piatkevich, Vladimir N. Malashkevich, Steven C. Almo and Vladislav V. Verkhusha pp 10762–10770 DOI: 10.1021/ja101974k Supporting Info

Synthesis, Morphological Control, and Antibacterial Properties of Hollow/Solid Ag2S/Ag Heterodimers Maolin Pang, Jiangyong Hu and Hua Chun Zeng pp 10771–10785 DOI: 10.1021/ja102105q Supporting Info

Pairing Fullerenes and Porphyrins: Supramolecular Wires That Exhibit Charge Transfer Activity Florian Wessendorf, Bruno Grimm, Dirk M. Guldi and Andreas Hirsch pp 10786–10795 DOI: 10.1021/ja101937w Supporting Info

Tetrathiafulvalene End-Functionalized Poly(N-isopropylacrylamide): A New Class of Amphiphilic Polymer for the Creation of Multistimuli Responsive Micelles Julien Bigot, Bernadette Charleux, Graeme Cooke, Franois Delattre, David Fournier, Jol Lyskawa, Lna Sambe, Franois Stoffelbach and Patrice Woisel pp 10796–10801 DOI: 10.1021/ja1027452 Supporting Info

Oxygen-17 Appears Only in Protein in Water-Stressed Soybean Leaves Labeled by 17O2 Terry Gullion, Tsyr-Yan Yu, Manmilan Singh, Gary J. Patti, Gregory S. Potter and Jacob Schaefer pp 10802–10807 DOI: 10.1021/ja102264w

Molecular Impact of the Membrane Potential on the Regulatory Mechanism of Proton Transfer in Sensory Rhodopsin II Xiue Jiang, Martin Engelhard, Kenichi Ataka and Joachim Heberle pp 10808–10815 DOI: 10.1021/ja102295g Supporting Info

Single-Molecule Observation of Protein Adsorption onto an Inorganic Surface David J. Niedzwiecki, John Grazul and Liviu Movileanu pp 10816–10822 DOI: 10.1021/ja1026858 Supporting Info

Largest Molecular Clusters in the Supertetrahedral Tn Series Tao Wu, Le Wang, Xianhui Bu, Victoria Chau and Pingyun Feng pp 10823–10831 DOI: 10.1021/ja102688p Supporting Info

Investigation of Methanol Oxidation over Au/Catalysts Using Operando IR Spectroscopy: Determination of the Active Sites, Intermediate/Spectator Species, and Reaction Mechanism Sverine Rousseau, Olivier Marie, Philippe Bazin, Marco Daturi, Stphane Verdier and Virginie Harl pp 10832–10841 DOI: 10.1021/ja1028809 Supporting Info

Rational Design and Simple Chemistry Yield a Superior, Neuroprotective HDAC6 Inhibitor, Tubastatin A Kyle V. Butler, Jay Kalin, Camille Brochier, Guilio Vistoli, Brett Langley and Alan P. Kozikowski pp 10842–10846 DOI: 10.1021/ja102758v Supporting Info

A Combined Experimental and Theoretical Study of Ion Solvation in Liquid N-Methylacetamide Haibo Yu, Christopher L. Mazzanti, Troy W. Whitfield, Roger E. Koeppe, II, Olaf S. Andersen and Benoît Roux pp 10847–10856 DOI: 10.1021/ja103270w Supporting Info

The Aberrance of the 4S Diastereomer of 4-Hydroxyproline Matthew D. Shoulders, Frank W. Kotch, Amit Choudhary, Ilia A. Guzei and Ronald T. Raines pp 10857–10865 DOI: 10.1021/ja103082y Supporting Info

The Impact of Hydrogen Bonding on Amide 1H Chemical Shift Anisotropy Studied by Cross-Correlated Relaxation and Liquid Crystal NMR Spectroscopy Lishan Yao, Alexander Grishaev, Gabriel Cornilescu and Ad Bax pp 10866–10875 DOI: 10.1021/ja103629e Supporting Info

Simultaneous Discrimination of Handedness and Diameter of Single-Walled Carbon Nanotubes (SWNTs) with Chiral Diporphyrin Nanotweezers Leading to Enrichment of a Single Enantiomer of (6,5)-SWNTs Feng Wang, Kazunari Matsuda, A. F. M. Mustafizur Rahman, Xiaobin Peng, Takahide Kimura and Naoki Komatsu pp 10876–10881 DOI: 10.1021/ja1044677 Supporting Info

Self-Assembly and Induced Circular Dichroism in Dendritic Supramolecules with Cholesteric Pendant Groups Antti J. Soininen, Edis Kasmi, A. Dieter Schlter, Olli Ikkala, Janne Ruokolainen and Raffaele Mezzenga pp 10882–10890 DOI: 10.1021/ja103754d Supporting Info

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation Wojciech I. Dzik, Xue Xu, X. Peter Zhang, Joost N. H. Reek and Bas de Bruin pp 10891–10902 DOI: 10.1021/ja103768r Supporting Info

Structure−Activity Relationships in Gold Nanoparticle Dimers and Trimers for Surface-Enhanced Raman Spectroscopy Kristin L. Wustholz, Anne-Isabelle Henry, Jeffrey M. McMahon, R. Griffith Freeman, Nicholas Valley, Marcelo E. Piotti, Michael J. Natan, George C. Schatz and Richard P. Van Duyne pp 10903–10910 DOI: 10.1021/ja104174m

Dynamics Characterization of Fully Hydrated Bacterial Cell Walls by Solid-State NMR: Evidence for Cooperative Binding of Metal Ions Thomas Kern, Mathilde Giffard, Sabine Hediger, Ana Amoroso, Ccile Giustini, Nhat Khai Bui, Bernard Joris, Catherine Bougault, Waldemar Vollmer and Jean-Pierre Simorre pp 10911–10919 DOI: 10.1021/ja104533w Supporting Info

New Insights into Poly(lactic-co-glycolic acid) Microstructure: Using Repeating Sequence Copolymers To Decipher Complex NMR and Thermal Behavior Ryan M. Stayshich and Tara Y. Meyer pp 10920–10934 DOI: 10.1021/ja102670n Supporting Info

XeOF3−, an Example of an AX3YE2 Valence Shell Electron Pair Repulsion Arrangement; Syntheses and Structural Characterizations of [M][XeOF3] (M = Cs, N(CH3)4) David S. Brock, Hlne P. A. Mercier and Gary J. Schrobilgen pp 10935–10943 DOI: 10.1021/ja103730c Supporting Info

Electrochemical Behavior and Electrogenerated Chemiluminescence of Star-Shaped D−A Compounds with a 1,3,5-Triazine Core and Substituted Fluorene Arms Khalid M. Omer, Sung-Yu Ku, Yu-Chen Chen, Ken-Tsung Wong and Allen J. Bard pp 10944–10952 DOI: 10.1021/ja104160f Supporting Info

Edaxadiene: A New Bioactive Diterpene from Mycobacterium tuberculosis Francis M. Mann, Meimei Xu, Xiaoming Chen, D. Bruce Fulton, David G. Russell and Reuben J. Peters p 10953 DOI: 10.1021/ja1001696

Highly Enantioselective Organocatalytic Biginelli and Biginelli-Like Condensations: Reversal of the Stereochemistry by Tuning the 3,3′-Disubstituents of Phosphoric Acids Nan Li, Xiao-Hua Chen, Jin Song, Shi-Wei Luo, Wu Fan and Liu-Zhu Gong p 10953 DOI: 10.1021/ja105157b

The Supramolecular Chemistry of Organic-Inorganic Hybrid Materials Paul S. Weiss p 10954 DOI: 10.1021/ja1059312

Quantitation and Mass Spectrometric Data of Drugs and Isotopically Labeled Analogs p 10954 DOI: 10.1021/ja105922k

Issue 32

Enantioselective Nickel-Catalyzed Reductive Coupling of Alkynes and Imines Chang-Yue Zhou, Shou-Fei Zhu, Li-Xin Wang and Qi-Lin Zhou pp 10955–10957 DOI: 10.1021/ja104505t Supporting Info

Magic Angle Spinning NMR Investigation of Influenza A M218−60: Support for an Allosteric Mechanism of Inhibition Loren B. Andreas, Matthew T. Eddy, Rafal M. Pielak, James Chou and Robert G. Griffin pp 10958–10960 DOI: 10.1021/ja101537p Supporting Info

α-Selective Ni-Catalyzed Hydroalumination of Aryl- and Alkyl-Substituted Terminal Alkynes: Practical Syntheses of Internal Vinyl Aluminums, Halides, or Boronates Fang Gao and Amir H. Hoveyda pp 10961–10963 DOI: 10.1021/ja104896b Supporting Info

Dissociation of Single-Strand DNA: Single-Walled Carbon Nanotube Hybrids by Watson−Crick Base-Pairing Seungwon Jung, Misun Cha, Jiyong Park, Namjo Jeong, Gunn Kim, Changwon Park, Jisoon Ihm and Junghoon Lee pp 10964–10966 DOI: 10.1021/ja102673m Supporting Info

Mechanochromic and Thermochromic Luminescence of a Copper Iodide Cluster Sandrine Perruchas, Xavier F. Le Goff, Sbastien Maron, Isabelle Maurin, Franois Guillen, Alain Garcia, Thierry Gacoin and Jean-Pierre Boilot pp 10967–10969 DOI: 10.1021/ja103431d Supporting Info

Size Selection and Concentration of Silver Nanoparticles by Tangential Flow Ultrafiltration for SERS-Based Biosensors John C. Trefry, Jennifer L. Monahan, Kent M. Weaver, Allie J. Meyerhoefer, Marjorie M. Markopolous, Zachary S. Arnold, Dawn P. Wooley and Ioana E. Pavel pp 10970–10972 DOI: 10.1021/ja103809c Supporting Info

Mysteries of TOPSe Revealed: Insights into Quantum Dot Nucleation Christopher M. Evans, Meagan E. Evans and Todd D. Krauss pp 10973–10975 DOI: 10.1021/ja103805s Supporting Info

Graphene-Based SELDI Probe with Ultrahigh Extraction and Sensitivity for DNA Oligomer Lena Ai Ling Tang, Junzhong Wang and Kian Ping Loh pp 10976–10977 DOI: 10.1021/ja104017y Supporting Info

Main-Group and Transition-Element IRMOF Homologues Steffen Hausdorf, Felix Baitalow, Tony Bhle, David Rafaja and Florian O. R. L. Mertens pp 10978–10981 DOI: 10.1021/ja1028777 Supporting Info

A Potential Site for Trapping Photogenerated Holes on Rutile TiO2 Surface as Revealed by EPR Spectroscopy: An Avenue for Enhancing Photocatalytic Activity Neeruganti O. Gopal, Hsin-Hsi Lo, Shiann-Cherng Sheu and Shyue-Chu Ke pp 10982–10983 DOI: 10.1021/ja909901f Supporting Info

BaGe5: A New Type of Intermetallic Clathrate Umut Aydemir, Lev Akselrud, Wilder Carrillo-Cabrera, Christophe Candolfi, Niels Oeschler, Michael Baitinger, Frank Steglich and Yuri Grin pp 10984–10985 DOI: 10.1021/ja104197c Supporting Info

Chemoselective Peptidomimetic Ligation Using Thioacid Peptides and Aziridine Templates Naila Assem, Aditya Natarajan and Andrei K. Yudin pp 10986–10987 DOI: 10.1021/ja104488d Supporting Info

Electrochemical Synthesis and Electrocatalytic Properties of Au@Pt Dendrimer-Encapsulated Nanoparticles David F. Yancey, Emily V. Carino and Richard M. Crooks pp 10988–10989 DOI: 10.1021/ja104677z Supporting Info

Fast Water Oxidation Using Iron W. Chadwick Ellis, Neal D. McDaniel, Stefan Bernhard and Terrence J. Collins pp 10990–10991 DOI: 10.1021/ja104766z

13CHD2 Methyl Group Probes of Millisecond Time Scale Exchange in Proteins by 1H Relaxation Dispersion: An Application to Proteasome Gating Residue Dynamics Andrew J. Baldwin, Tomasz L. Religa, D. Flemming Hansen, Guillaume Bouvignies and Lewis E. Kay pp 10992–10995 DOI: 10.1021/ja104578n Supporting Info

Energetics of Intercavity Diffusion in a Simple Model of a Low-Density p-tert-Butylcalix[4]arene Crystal Matthew D. Breite, Jack R. Cox and John E. Adams pp 10996–10997 DOI: 10.1021/ja105006f Supporting Info

Access to B═S and B═Se Double Bonds via Sulfur and Selenium Insertion into a B−H Bond and Hydrogen Migration Hao Wang, Jianying Zhang, Hongfan Hu and Chunming Cui pp 10998–10999 DOI: 10.1021/ja105021d Supporting Info

Hyperbranched Polymers with Controlled Degree of Branching from 0 to 100% Yukari Segawa, Tomoya Higashihara and Mitsuru Ueda pp 11000–11001 DOI: 10.1021/ja105213r Supporting Info

Synthesis and Photodynamics of 9-Mesitylacridinium Ion-Modified Gold Nanoclusters Shunichi Fukuzumi, Ryo Hanazaki, Hiroaki Kotani and Kei Ohkubo pp 11002–11003 DOI: 10.1021/ja105314x Supporting Info

Cyclobutenone as a Highly Reactive Dienophile: Expanding Upon Diels−Alder Paradigms Xiaohua Li and Samuel J. Danishefsky pp 11004–11005 DOI: 10.1021/ja1056888 Supporting Info

A Combined Experimental−Computational Investigation of Carbon Dioxide Capture in a Series of Isoreticular Zeolitic Imidazolate Frameworks William Morris, Belinda Leung, Hiroyasu Furukawa, Omar K. Yaghi, Ning He, Hideki Hayashi, Yao Houndonougbo, Mark Asta, Brian B. Laird and Omar M. Yaghi pp 11006–11008 DOI: 10.1021/ja104035j Supporting Info

Cu(I)-Catalyzed Regioselective Diamination of Conjugated Dienes via Dual Mechanistic Pathways Baoguo Zhao, Xingao Peng, Sunliang Cui and Yian Shi pp 11009–11011 DOI: 10.1021/ja103838d Supporting Info

Synthesis and Electronic Properties of Extended, Fused-Ring Aromatic Systems Containing Multiple Pentalene Units Zerubba U. Levi and T. Don Tilley pp 11012–11014 DOI: 10.1021/ja1043159 Supporting Info

Self-Confirming “AND” Logic Nanoparticles for Fault-Free MRI Jin-sil Choi, Jae-Hyun Lee, Tae-Hyun Shin, Ho-Taek Song, Eung Yeop Kim and Jinwoo Cheon pp 11015–11017 DOI: 10.1021/ja104503g Supporting Info

Photoswitchable Catalysis Mediated by Dynamic Aggregation of Nanoparticles Yanhu Wei, Shuangbing Han, Jiwon Kim, Siowling Soh and Bartosz A. Grzybowski pp 11018–11020 DOI: 10.1021/ja104260n Supporting Info

Synthesis and Characterization of Teranthene: A Singlet Biradical Polycyclic Aromatic Hydrocarbon Having Kekul Structures Akihito Konishi, Yasukazu Hirao, Masayoshi Nakano, Akihiro Shimizu, Edith Botek, Benot Champagne, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Kouzou Matsumoto, Hiroyuki Kurata and Takashi Kubo pp 11021–11023 DOI: 10.1021/ja1049737 Supporting Info

High Density Orthogonal Surface Immobilization via Photoactivated Copper-Free Click Chemistry Sara V. Orski, Andrei A. Poloukhtine, Selvanathan Arumugam, Leidong Mao, Vladimir V. Popik and Jason Locklin pp 11024–11026 DOI: 10.1021/ja105066t Supporting Info

Asymmetric Suzuki Cross-Couplings of Activated Secondary Alkyl Electrophiles: Arylations of Racemic α-Chloroamides Pamela M. Lundin and Gregory C. Fu pp 11027–11029 DOI: 10.1021/ja105148g Supporting Info

A Photochemical Metallocene Route to Anionic Enediynes: Synthesis, Solid-State Structures, and ab Initio Computations on Cyclopentadienidoenediynes Joseph M. O’Connor, Kim K. Baldridge, Betsy L. Rodgers, Marissa Aubrey, Ryan L. Holland, W. Scott Kassel and Arnold L. Rheingold pp 11030–11032 DOI: 10.1021/ja105149k Supporting Info

Chemoselective and Regiospecific Suzuki Coupling on a Multisubstituted sp3-Carbon in 1,1-Diborylalkanes at Room Temperature Kohei Endo, Takahiro Ohkubo, Munenao Hirokami and Takanori Shibata pp 11033–11035 DOI: 10.1021/ja105176v Supporting Info

Pulling Genetic RNA out of Tobacco Mosaic Virus Using Single-Molecule Force Spectroscopy Ningning Liu, Bo Peng, Yuan Lin, Zhaohui Su, Zhongwei Niu, Qian Wang, Wenke Zhang, Hongbin Li and Jiacong Shen pp 11036–11038 DOI: 10.1021/ja1052544 Supporting Info

Formal [2 + 2 + 2] Cycloaddition Strategy Based on an Intramolecular Propargylic Ene Reaction/Diels−Alder Cycloaddition Cascade Julia M. Robinson, Takeo Sakai, Katsuhiko Okano, Takafumi Kitawaki and Rick L. Danheiser pp 11039–11041 DOI: 10.1021/ja1053829 Supporting Info

Protecting-Group-Free and Catalysis-Based Total Synthesis of the Ecklonialactones Volker Hickmann, Manuel Alcarazo and Alois Frstner pp 11042–11044 DOI: 10.1021/ja104796a Supporting Info

Practical New Silyloxy-Based Alkyne Metathesis Catalysts with Optimized Activity and Selectivity Profiles Johannes Heppekausen, Robert Stade, Richard Goddard and Alois Frstner pp 11045–11057 DOI: 10.1021/ja104800w Supporting Info

Constraining Binding Hot Spots: NMR and Molecular Dynamics Simulations Provide a Structural Explanation for Enthalpy−Entropy Compensation in SH2−Ligand Binding Joshua M. Ward, Nina M. Gorenstein, Jianhua Tian, Stephen F. Martin and Carol Beth Post pp 11058–11070 DOI: 10.1021/ja910535j Supporting Info

Free-Energy Surfaces for Liquid-Phase Reactions and Their Use To Study the Border Between Concerted and Nonconcerted α,β-Elimination Reactions of Esters and Thioesters Yongho Kim, Jerry R. Mohrig and Donald G. Truhlar pp 11071–11082 DOI: 10.1021/ja101104q Supporting Info

Control of the Orientational Order and Nonlinear Optical Response of the “Push-Pull” Chromophore RuPZn via Specific Incorporation into Densely Packed Monolayer Ensembles of an Amphiphilic Four-Helix Bundle Peptide: Characterization of the Peptide−Chromophore Complexes Venkata Krishnan, Andrey Tronin, Joseph Strzalka, H. Christopher Fry, Michael J. Therien and J. Kent Blasie pp 11083–11092 DOI: 10.1021/ja1010702 Supporting Info

Visualizing Proton Antenna in a High-Resolution Green Fluorescent Protein Structure Ai Shinobu, Gottfried J. Palm, Abraham J. Schierbeek and Noam Agmon pp 11093–11102 DOI: 10.1021/ja1010652 Supporting Info

Fluorogenic Dendrons with Multiple Donor Chromophores as Bright Genetically Targeted and Activated Probes Christopher Szent-Gyorgyi, Brigitte F. Schmidt, James A. J. Fitzpatrick and Marcel P. Bruchez pp 11103–11109 DOI: 10.1021/ja9099328 Supporting Info

Automated Fmoc-Based Solid-Phase Synthesis of Peptide Thioesters with Self-Purification Effect and Application in the Construction of Immobilized SH3 Domains Franziska Mende, Michael Beisswenger and Oliver Seitz pp 11110–11118 DOI: 10.1021/ja101732a Supporting Info

A New Family of Nonionic Dendritic Amphiphiles Displaying Unexpected Packing Parameters in Micellar Assemblies Britta Trappmann, Kai Ludwig, Michał R. Radowski, Anuj Shukla, Andreas Mohr, Heinz Rehage, Christoph Bttcher and Rainer Haag pp 11119–11124 DOI: 10.1021/ja101523v Supporting Info

Selective Synthesis of Subnanometer Diameter Semiconducting Single-Walled Carbon Nanotubes Codruta Zoican Loebick, Ramakrishna Podila, Jason Reppert, Joel Chudow, Fang Ren, Gary L. Haller, Apparao M. Rao and Lisa D. Pfefferle pp 11125–11131 DOI: 10.1021/ja102011h Supporting Info

Layer-by-Layer Self-Assembled Osmium Polymer-Mediated Laccase Oxygen Cathodes for Biofuel Cells: The Role of Hydrogen Peroxide Pablo Scodeller, Romina Carballo, Rafael Szamocki, Laura Levin, Flavia Forchiassin and Ernesto J. Calvo pp 11132–11140 DOI: 10.1021/ja1020487 Supporting Info

Synthetic Analogs Tailor Native AI-2 Signaling Across Bacterial Species Varnika Roy, Jacqueline A. I. Smith, Jingxin Wang, Jessica E. Stewart, William E. Bentley and Herman O. Sintim pp 11141–11150 DOI: 10.1021/ja102587w Supporting Info

Synthesis, Structure, and Density Functional Theory Analysis of a Scandium Dinitrogen Complex, [(C5Me4H)2Sc]2(μ-η2:η2-N2) Selvan Demir, Sara E. Lorenz, Ming Fang, Filipp Furche, Gerd Meyer, Joseph W. Ziller and William J. Evans pp 11151–11158 DOI: 10.1021/ja102681w Supporting Info

Folding of a Helix at Room Temperature Is Critically Aided by Electrostatic Polarization of Intraprotein Hydrogen Bonds Li L. Duan, Ye Mei, Dawei Zhang, Qing G. Zhang and John Z. H. Zhang pp 11159–11164 DOI: 10.1021/ja102735g

Mechanism of the Enantioselective Oxidation of Racemic Secondary Alcohols Catalyzed by Chiral Mn(III)−Salen Complexes M. Kevin Brown, Megan M. Blewett, James R. Colombe and E. J. Corey pp 11165–11170 DOI: 10.1021/ja103103d Supporting Info

Antisense-Induced Guanine Quadruplexes Inhibit Reverse Transcription by HIV-1 Reverse Transcriptase Masaki Hagihara, Lisa Yamauchi, Akiko Seo, Keisuke Yoneda, Mayo Senda and Kazuhiko Nakatani pp 11171–11178 DOI: 10.1021/ja1032088

Intramolecular [1 + 4 + 1] Cycloaddition: Establishment of the Method Douglass F. Taber, Pengfei Guo and Na Guo pp 11179–11182 DOI: 10.1021/ja103551x Supporting Info

Navigating the Downhill Protein Folding Regime via Structural Homologues Athi N. Naganathan, Peng Li, Ral Perez-Jimenez, Jose M. Sanchez-Ruiz and Victor Muoz pp 11183–11190 DOI: 10.1021/ja103612q Supporting Info

NMR Study of the Exchange Coupling in the Trinuclear Cluster of the Multicopper Oxidase Fet3p Mara-Eugenia Zaballa, Lynn Ziegler, Daniel J. Kosman and Alejandro J. Vila pp 11191–11196 DOI: 10.1021/ja1037148 Supporting Info

A Tyrosyl−Dimanganese Coupled Spin System is the Native Metalloradical Cofactor of the R2F Subunit of the Ribonucleotide Reductase of Corynebacterium ammoniagenes Nicholas Cox, Hideaki Ogata, Patrick Stolle, Edward Reijerse, Georg Auling and Wolfgang Lubitz pp 11197–11213 DOI: 10.1021/ja1036995 Supporting Info

Hollow V2O5 Nanoparticles (Fullerene-Like Analogues) Prepared by Laser Ablation Roi Levi, Maya Bar-Sadan, Ana Albu-Yaron, Ronit Popovitz-Biro, Lothar Houben, Chen Shahar, Andrey Enyashin, Gotthard Seifert, Yehiam Prior and Reshef Tenne pp 11214–11222 DOI: 10.1021/ja103719x Supporting Info

Conformations, Conformational Preferences, and Conformational Exchange of N′-Substituted N-Acylguanidines: Intermolecular Interactions Hold the Key Roland Kleinmaier, Max Keller, Patrick Igel, Armin Buschauer and Ruth M. Gschwind pp 11223–11233 DOI: 10.1021/ja103756y Supporting Info

Neutral Transition Metal Hydrides as Acids in Hydrogen Bonding and Proton Transfer: Media Polarity and Specific Solvation Effects Vladislava A. Levina, Oleg A. Filippov, Evgenii I. Gutsul, Natalia V. Belkova, Lina M. Epstein, Agusti Lledos and Elena S. Shubina pp 11234–11246 DOI: 10.1021/ja103862r Supporting Info

Mechanism for Recognition of Polyubiquitin Chains: Balancing Affinity through Interplay between Multivalent Binding and Dynamics Craig J. Markin, Wei Xiao and Leo Spyracopoulos pp 11247–11258 DOI: 10.1021/ja103869x Supporting Info

Layer-by-Layer Assembly of Three-Dimensional Colloidal Supercrystals with Tunable Plasmonic Properties Meng-Hsien Lin, Hung-Ying Chen and Shangjr Gwo pp 11259–11263 DOI: 10.1021/ja103722p Supporting Info

Design, Synthesis, and Imaging of an Activatable Photoacoustic Probe Jelena Levi, Sri Rajasekhar Kothapalli, Te-Jen Ma, Keith Hartman, Butrus T. Khuri-Yakub and Sanjiv Sam Gambhir pp 11264–11269 DOI: 10.1021/ja104000a Supporting Info

Surface Charge of Electrosprayed Water Nanodroplets: A Molecular Dynamics Study Elias Ahadi and Lars Konermann pp 11270–11277 DOI: 10.1021/ja1041989

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd-Catalyzed Suzuki−Miyaura Reaction: Substrate Scope and Quantum Mechanical Investigations Xiaoqiang Shen, Gavin O. Jones, Donald A. Watson, Brijesh Bhayana and Stephen L. Buchwald pp 11278–11287 DOI: 10.1021/ja104297g Supporting Info

Self-Assembly of Hybrid Dendrons into Doubly Segregated Supramolecular Polyhedral Columns and Vesicles Mihai Peterca, Mohammad R. Imam, Pawaret Leowanawat, Brad M. Rosen, Daniela A. Wilson, Christopher J. Wilson, Xiangbing Zeng, Goran Ungar, Paul A. Heiney and Virgil Percec pp 11288–11305 DOI: 10.1021/ja104432d Supporting Info

The Complex Role of Multivalency in Nanoparticles Targeting the Transferrin Receptor for Cancer Therapies Jin Wang, Shaomin Tian, Robby A. Petros, Mary E. Napier and Joseph M. DeSimone pp 11306–11313 DOI: 10.1021/ja1043177 Supporting Info

Theoretical Study of Substituted PBPB Dimers: Structural Analysis, Tetraradical Character, and Excited States Franziska Bell, David Casanova and Martin Head-Gordon pp 11314–11322 DOI: 10.1021/ja104772w Supporting Info

Synthesis of Complex Allylic Esters via C−H Oxidation vs C−C Bond Formation Nicolaas A. Vermeulen, Jared H. Delcamp and M. Christina White pp 11323–11328 DOI: 10.1021/ja104826g Supporting Info

Direct Analysis of Donor−Acceptor Distance and Relationship to Isotope Effects and the Force Constant for Barrier Compression in Enzymatic H-Tunneling Reactions Christopher R. Pudney, Linus O. Johannissen, Michael J. Sutcliffe, Sam Hay and Nigel S. Scrutton pp 11329–11335 DOI: 10.1021/ja1048048 Supporting Info

Interfacial Water Structure Associated with Phospholipid Membranes Studied by Phase-Sensitive Vibrational Sum Frequency Generation Spectroscopy Xiangke Chen, Wei Hua, Zishuai Huang and Heather C. Allen pp 11336–11342 DOI: 10.1021/ja1048237 Supporting Info

Reactivity of [1],[1]Disilamolybdenocenophane toward Zerovalent Platinum Complexes Holger Braunschweig, Peter Brenner, Manuela Gross and Krzysztof Radacki pp 11343–11349 DOI: 10.1021/ja1049548 Supporting Info

Total Synthesis of Sporolide B and 9-epi-Sporolide B K. C. Nicolaou, Jianhua Wang, Yefeng Tang and Lorenzo Botta pp 11350–11363 DOI: 10.1021/ja1048994 Supporting Info

Six Different Assemblies from One Building Block: Two-Dimensional Crystallization of an Amide Amphiphile Seokhoon Ahn and Adam J. Matzger pp 11364–11371 DOI: 10.1021/ja105039s Supporting Info

Seed-Mediated Synthesis of Ag Nanocubes with Controllable Edge Lengths in the Range of 30−200 nm and Comparison of Their Optical Properties Qiang Zhang, Weiyang Li, Christine Moran, Jie Zeng, Jingyi Chen, Long-Ping Wen and Younan Xia pp 11372–11378 DOI: 10.1021/ja104931h Supporting Info

Enantiomerically Pure trans-β-Lactams from α-Amino Acids via Compact Fluorescent Light (CFL) Continuous-Flow Photolysis Yvette S. Mimieux Vaske, Maximillian E. Mahoney, Joseph P. Konopelski, David L. Rogow and William J. McDonald pp 11379–11385 DOI: 10.1021/ja1050023 Supporting Info

Chiral Boronate Derivatives via Catalytic Enantioselective Conjugate Addition of Grignard Reagents on 3-Boronyl Unsaturated Esters and Thioesters Jack Chang Hung Lee and Dennis G. Hall p 11386 DOI: 10.1021/ja105083n

Scanning Tunneling Microscopy in Surface Science, Nanoscience and Catalysis Heather L. Tierney and E. Charles H. Sykes p 11387 DOI: 10.1021/ja106375e

Quantal Density Functional Theory II. Approximation Methods and Applications Steven M. Valone pp 11387–11388 DOI: 10.1021/ja105861z

Issue 33

Cyanation of Arenes via Iridium-Catalyzed Borylation Carl W. Liskey, Xuebin Liao and John F. Hartwig pp 11389–11391 DOI: 10.1021/ja104442v Supporting Info

Gold Nanoparticle Enrichment Method for Identifying S-Nitrosylation and S-Glutathionylation Sites in Proteins Adam Faccenda, Christopher A. Bonham, Panayiotis O. Vacratsis, Xueji Zhang and Bulent Mutus pp 11392–11394 DOI: 10.1021/ja103591v Supporting Info

Mechanism of Fast Proton Transport along One-Dimensional Water Chains Confined in Carbon Nanotubes Zhen Cao, Yuxing Peng, Tianying Yan, Shu Li, Ailin Li and Gregory A. Voth pp 11395–11397 DOI: 10.1021/ja1046704 Supporting Info

Visualization of a Discrete Solid-State Process with Steady-State X-ray Diffraction: Observation of Hopping of Sulfur Atoms in Single Crystals of Realgar Pane Naumov, Petre Makreski, Gjorgji Petruevski, Tome Runevski and Gligor Jovanovski pp 11398–11401 DOI: 10.1021/ja1030672 Supporting Info

Diffusion of Metal in a Confined Nanospace of Carbon Nanotubes Induced by Air Oxidation Jisheng Zhou, Huaihe Song, Xiaohong Chen and Junping Huo pp 11402–11405 DOI: 10.1021/ja105712w Supporting Info

Thermal Stabilization of DMPC/DHPC Bicelles by Addition of Cholesterol Sulfate Rebecca A. Shapiro, Amanda J. Brindley and Rachel W. Martin pp 11406–11407 DOI: 10.1021/ja1041012 Supporting Info

Rhenium-Catalyzed Didehydroxylation of Vicinal Diols to Alkenes Using a Simple Alcohol as a Reducing Agent Elena Arceo, Jonathan A. Ellman and Robert G. Bergman pp 11408–11409 DOI: 10.1021/ja103436v Supporting Info

Self-Assembly of a Nanosized, Saddle-Shaped, Solution-Stable Polyoxometalate Anion Built from Pentagonal Building Blocks: [H34W119Se8Fe2O420]54− Jun Yan, Jing Gao, De-Liang Long, Haralampos N. Miras and Leroy Cronin pp 11410–11411 DOI: 10.1021/ja104043s Supporting Info

Carbonylative Polymerization of Propylene Oxide: A Multicatalytic Approach to the Synthesis of Poly(3-Hydroxybutyrate) Erin W. Dunn and Geoffrey W. Coates pp 11412–11413 DOI: 10.1021/ja1049862 Supporting Info

Highly Enantioselective Hydrogenative Desymmetrization of Bicyclic Imides Leading to Multiply Functionalized Chiral Cyclic Compounds Masato Ito, Chika Kobayashi, Akio Himizu and Takao Ikariya pp 11414–11415 DOI: 10.1021/ja105048c Supporting Info

The Role of Reversible Oxidative Addition in Selective Palladium(0)-Catalyzed Intramolecular Cross-Couplings of Polyhalogenated Substrates: Synthesis of Brominated Indoles Stephen G. Newman and Mark Lautens pp 11416–11417 DOI: 10.1021/ja1052335 Supporting Info

Enantioselective Construction of Spiroindolenines by Ir-Catalyzed Allylic Alkylation Reactions Qing-Feng Wu, Hu He, Wen-Bo Liu and Shu-Li You pp 11418–11419 DOI: 10.1021/ja105111n Supporting Info

Palladium-Catalyzed Dehydrohalogenative Polycondensation of 2-Bromo-3-hexylthiophene: An Efficient Approach to Head-to-Tail Poly(3-hexylthiophene) Qifeng Wang, Ryo Takita, Yuuta Kikuzaki and Fumiyuki Ozawa pp 11420–11421 DOI: 10.1021/ja105767z Supporting Info

Total Synthesis of Lehualide B by Allylic Alcohol−Alkyne Reductive Cross-Coupling Valer Jeso and Glenn C. Micalizio pp 11422–11424 DOI: 10.1021/ja104782u Supporting Info

Synthesis of High-Curie-Temperature Fe0.02Ge0.98 Quantum Dots Faxian Xiu, Yong Wang, Xufeng Kou, Pramey Upadhyaya, Yi Zhou, Jin Zou and Kang L. Wang pp 11425–11427 DOI: 10.1021/ja105036j Supporting Info

Synthesis of Multivalent Tuberculosis and Leishmania-Associated Capping Carbohydrates Reveals Structure-Dependent Responses Allowing Immune Evasion Eun-Ho Song, Alex O. Osanya, Christine A. Petersen and Nicola L. B. Pohl pp 11428–11430 DOI: 10.1021/ja103351m Supporting Info

Orthogonal Photocleavage of a Monochromophoric Linker Laxminarayana Kammari, Tom olomek, Bokolombe Pitchou Ngoy, Dominik Heger and Petr Kln pp 11431–11433 DOI: 10.1021/ja1047736 Supporting Info

Orthogonal Covalent and Noncovalent Functionalization of Cyclodextrin-Alkyne Patterned Surfaces Arntzazu Gonzlez-Campo, Shu-Han Hsu, Laura Puig, Jurriaan Huskens, David N. Reinhoudt and Aldrik H. Velders pp 11434–11436 DOI: 10.1021/ja1048658 Supporting Info

Indacenodithiophene Semiconducting Polymers for High-Performance, Air-Stable Transistors Weimin Zhang, Jeremy Smith, Scott E. Watkins, Roman Gysel, Michael McGehee, Alberto Salleo, James Kirkpatrick, Shahid Ashraf, Thomas Anthopoulos, Martin Heeney and Iain McCulloch pp 11437–11439 DOI: 10.1021/ja1049324 Supporting Info

Enantioselective Synthesis of trans-Aryl- and -Heteroaryl-Substituted Cyclopropylboronates by Copper(I)-Catalyzed Reactions of Allylic Phosphates with a Diboron Derivative Chongmin Zhong, Shun Kunii, Yuki Kosaka, Masaya Sawamura and Hajime Ito pp 11440–11442 DOI: 10.1021/ja103783p Supporting Info

Conserved Binding Mode of Human β2 Adrenergic Receptor Inverse Agonists and Antagonist Revealed by X-ray Crystallography Daniel Wacker, Gustavo Fenalti, Monica A. Brown, Vsevolod Katritch, Ruben Abagyan, Vadim Cherezov and Raymond C. Stevens pp 11443–11445 DOI: 10.1021/ja105108q Supporting Info

Electron Transfer−Oxygen Transfer Oxygenation of Sulfides Catalyzed by the H5PV2Mo10O40 Polyoxometalate Alexander M. Khenkin, Gregory Leitus and Ronny Neumann pp 11446–11448 DOI: 10.1021/ja105183w Supporting Info

Boryltrihydroborate: Synthesis, Structure, and Reactivity as a Reductant in Ionic, Organometallic, and Radical Reactions Kyoko Nozaki, Yoshitaka Aramaki, Makoto Yamashita, Shau-Hua Ueng, Max Malacria, Emmanuel Lacte and Dennis P. Curran pp 11449–11451 DOI: 10.1021/ja105277u Supporting Info

Memory of Axial Chirality in Aryl Radical Phosphanylations Achim Bruch, Andrea Ambrosius, Roland Frhlich, Armido Studer, David B. Guthrie, Hanmo Zhang and Dennis P. Curran pp 11452–11454 DOI: 10.1021/ja105070k Supporting Info

A Covalent Succinylcysteine-like Intermediate in the Enzyme-Catalyzed Transformation of Maleate to Fumarate by Maleate Isomerase Florian Fisch, Carlos Martinez Fleites, Marie Delenne, Nina Baudendistel, Bernhard Hauer, Johan P. Turkenburg, Sam Hart, Neil C. Bruce and Gideon Grogan pp 11455–11457 DOI: 10.1021/ja1053576 Supporting Info

N−H Activation of Hydrazines by Iridium(I). Double N−H Activation To Form Iridium Aminonitrene Complexes Zheng Huang, Jianrong (Steve) Zhou and John F. Hartwig pp 11458–11460 DOI: 10.1021/ja1053835 Supporting Info

Stopped-Flow NMR: Determining the Kinetics of [rac-(C2H4(1-indenyl)2)ZrMe][MeB(C6F5)3]-Catalyzed Polymerization of 1-Hexene by Direct Observation Matthew D. Christianson, Emily H. P. Tan and Clark R. Landis pp 11461–11463 DOI: 10.1021/ja105107y Supporting Info

Exploiting Conformational Dynamics To Facilitate Formation and Trapping of Electron-Transfer Photoproducts in Metal Complexes Heather A. Meylemans, Joshua T. Hewitt, Mirvat Abdelhaq, Paul J. Vallett and Niels H. Damrauer pp 11464–11466 DOI: 10.1021/ja1055559 Supporting Info

Water Oxidation by λ-MnO2: Catalysis by the Cubical Mn4O4 Subcluster Obtained by Delithiation of Spinel LiMn2O4 David M. Robinson, Yong Bok Go, Martha Greenblatt and G. Charles Dismukes pp 11467–11469 DOI: 10.1021/ja1055615 Supporting Info

Multicompartment Core/Shell Microgels Xiaobo Hu, Zhen Tong and L. Andrew Lyon pp 11470–11472 DOI: 10.1021/ja105616v Supporting Info

Atom-Economical Synthesis of N-Heterocycles via Cascade Inter-/Intramolecular C−N Bond-Forming Reactions Catalyzed by Ti Amides Hao Shen and Zuowei Xie pp 11473–11480 DOI: 10.1021/ja101796k Supporting Info

Electron Transport Properties of Atomic Carbon Nanowires between Graphene Electrodes Lei Shen, Minggang Zeng, Shuo-Wang Yang, Chun Zhang, Xuefeng Wang and Yuanping Feng pp 11481–11486 DOI: 10.1021/ja909531c Supporting Info

Shifting the Equilibrium between the Encounter State and the Specific Form of a Protein Complex by Interfacial Point Mutations Alexander N. Volkov, Qamar Bashir, Jonathan A. R. Worrall, G. Matthias Ullmann and Marcellus Ubbink pp 11487–11495 DOI: 10.1021/ja100867c Supporting Info

Engineering of the Heme Pocket of an H-NOX Domain for Direct Cyanide Detection and Quantification Zhou Dai and Elizabeth M. Boon pp 11496–11503 DOI: 10.1021/ja101674z Supporting Info

Natural-Abundance 43Ca Solid-State NMR Spectroscopy of Bone Jiadi Xu, Peizhi Zhu, Zhehong Gan, Nadder Sahar, Mary Tecklenburg, Michael D. Morris, David H. Kohn and Ayyalusamy Ramamoorthy pp 11504–11509 DOI: 10.1021/ja101961x Supporting Info

Enol Tautomers of Watson−Crick Base Pair Models Are Metastable Because of Nuclear Quantum Effects Alejandro Prez, Mark E. Tuckerman, Harold P. Hjalmarson and O. Anatole von Lilienfeld pp 11510–11515 DOI: 10.1021/ja102004b Supporting Info

Ferro- and Antiferromagnetic Coupling Switch Accompanied by Twist Deformation around the Copper(II) and Nitroxide Coordination Bond Atsushi Okazawa, Daisuke Hashizume and Takayuki Ishida pp 11516–11524 DOI: 10.1021/ja102163d Supporting Info

Quantum Chemical Modeling of Benzene Ethylation over H-ZSM-5 Approaching Chemical Accuracy: A Hybrid MP2:DFT Study Niels Hansen, Torsten Kerber, Joachim Sauer, Alexis T. Bell and Frerich J. Keil pp 11525–11538 DOI: 10.1021/ja102261m Supporting Info

Using a One-Electron Shuttle for the Multielectron Reduction of CO2 to Methanol: Kinetic, Mechanistic, and Structural Insights Emily Barton Cole, Prasad S. Lakkaraju, David M. Rampulla, Amanda J. Morris, Esta Abelev and Andrew B. Bocarsly pp 11539–11551 DOI: 10.1021/ja1023496 Supporting Info

Photomagnetic CoFe Prussian Blue Analogues: Role of the Cyanide Ions as Active Electron Transfer Bridges Modulated by Cyanide−Alkali Metal Ion Interactions Jean-Daniel Cafun, Guillaume Champion, Marie-Anne Arrio, Christophe Cartier dit Moulin and Anne Bleuzen pp 11552–11559 DOI: 10.1021/ja102660b Supporting Info

The Development of Morphology and Structure in Hexagonal Vaterite Emilie M. Pouget, Paul H. H. Bomans, Archan Dey, Peter M. Frederik, Gijsbertus de With and Nico A. J. M. Sommerdijk pp 11560–11565 DOI: 10.1021/ja102439r Supporting Info

Spectral−Structural Effects of the Keto−Enol−Enolate and Phenol−Phenolate Equilibria of Oxyluciferin Pane Naumov and Manoj Kochunnoonny pp 11566–11579 DOI: 10.1021/ja102885g Supporting Info

Organic Single-Crystalline p−n Junction Nanoribbons Yajie Zhang, Huanli Dong, Qingxin Tang, Sunzida Ferdous, Feng Liu, Stefan C. B. Mannsfeld, Wenping Hu and Alejandro L. Briseno pp 11580–11584 DOI: 10.1021/ja102779x Supporting Info

Asprich Peptides Are Occluded in Calcite and Permanently Disorder Biomineral Crystals Rebecca A. Metzler, Gareth A. Tribello, Michele Parrinello and P. U. P. A. Gilbert pp 11585–11591 DOI: 10.1021/ja103089r Supporting Info

A General and Efficient Catalyst for Palladium-Catalyzed C−O Coupling Reactions of Aryl Halides with Primary Alcohols Saravanan Gowrisankar, Alexey G. Sergeev, Pazhamalai Anbarasan, Anke Spannenberg, Helfried Neumann and Matthias Beller pp 11592–11598 DOI: 10.1021/ja103248d Supporting Info

129Xe NMR Study of the Framework Flexibility of the Porous Hybrid MIL-53(Al) Marie-Anne Springuel-Huet, Andrei Nossov, Ziad Adem, Flavien Guenneau, Christophe Volkringer, Thierry Loiseau, Grard Frey and Antoine Gdon pp 11599–11607 DOI: 10.1021/ja103105y Supporting Info

Reagent for the Detection of Protein Thiocarboxylates in the Bacterial Proteome: Lissamine Rhodamine B Sulfonyl Azide Kalyanaraman Krishnamoorthy and Tadhg P. Begley pp 11608–11612 DOI: 10.1021/ja1034107 Supporting Info

Kinetic Isotope Effects for RNA Cleavage by 2′-O- Transphosphorylation: Nucleophilic Activation by Specific Base Michael E. Harris, Qing Dai, Hong Gu, Daniel L. Kellerman, Joseph A. Piccirilli and Vernon E. Anderson pp 11613–11621 DOI: 10.1021/ja103550e Supporting Info

X-ray Crystallographic Structure of an Artificial β-Sheet Dimer Omid Khakshoor, Aaron J. Lin, Tyler P. Korman, Michael R. Sawaya, Shiou-Chuan Tsai, David Eisenberg, and James S. Nowick pp 11622–11628 DOI: 10.1021/ja103438w Supporting Info

Kinetic Resolution of Racemic α-Arylalkanoic Acids with Achiral Alcohols via the Asymmetric Esterification Using Carboxylic Anhydrides and Acyl-Transfer Catalysts Isamu Shiina, Kenya Nakata, Keisuke Ono, Yu-suke Onda and Makoto Itagaki pp 11629–11641 DOI: 10.1021/ja103490h Supporting Info

Unique Electronic Structure Induced High Photoreactivity of Sulfur-Doped Graphitic C3N4 Gang Liu, Ping Niu, Chenghua Sun, Sean C. Smith, Zhigang Chen, Gao Qing (Max) Lu and Hui-Ming Cheng pp 11642–11648 DOI: 10.1021/ja103798k Supporting Info

Mechanistic Study of the Stereoselective Polymerization of d,l-Lactide Using Indium(III) Halides Agostino Pietrangelo, Spencer C. Knight, Aalo K. Gupta, Letitia J. Yao, Marc A. Hillmyer and William B. Tolman pp 11649–11657 DOI: 10.1021/ja103841h Supporting Info

Transition from Tunneling to Hopping in Single Molecular Junctions by Measuring Length and Temperature Dependence Thomas Hines, Ismael Diez-Perez, Joshua Hihath, Hongmei Liu, Zhong-Sheng Wang, Jianwei Zhao, Gang Zhou, Klaus Mllen and Nongjian Tao pp 11658–11664 DOI: 10.1021/ja1040946 Supporting Info

Assessing Molecular Transport Properties of Nanoporous Materials by Interference Microscopy: Remarkable Effects of Composition and Microstructure on Diffusion in the Silicoaluminophosphate Zeotype STA-7 Despina Tzoulaki, Lars Heinke, Maria Castro, Pablo Cubillas, Michael W. Anderson, Wuzong Zhou, Paul A. Wright and Jrg Krger pp 11665–11670 DOI: 10.1021/ja104016n Supporting Info

Hydrogen Bonds between Nitrogen Donors and the Semiquinone in the QB Site of Bacterial Reaction Centers Erik Martin, Rimma I. Samoilova, Kupala V. Narasimhulu, Colin A. Wraight and Sergei A. Dikanov pp 11671–11677 DOI: 10.1021/ja104134e

Concerted Proton−Electron Transfer to Dioxygen in Water Ophir Snir, Yifeng Wang, Mark E. Tuckerman, Yurii V. Geletii and Ira A. Weinstock pp 11678–11691 DOI: 10.1021/ja104392k Supporting Info

Toward a General Approach for RNA-Templated Hierarchical Assembly of Split-Proteins Jennifer L. Furman, Ahmed H. Badran, Oluyomi Ajulo, Jason R. Porter, Cliff I. Stains, David J. Segal and Indraneel Ghosh pp 11692–11701 DOI: 10.1021/ja104395b Supporting Info

Charge Transport in Organic Crystals: Role of Disorder and Topological Connectivity Thorsten Vehoff, Bjrn Baumeier, Alessandro Troisi and Denis Andrienko pp 11702–11708 DOI: 10.1021/ja104380c Supporting Info

Unraveling the Electron Spin Resonance Pattern of Nonsymmetric Radicals with 30 Fluorine Atoms: Electron Spin Resonance and Vis−Near-Infrared Spectroelectrochemistry of the Anion Radicals and Dianions of C60(CF3)2n (2n = 2−10) Derivatives and Density Functional Theory-Assisted Assignment Alexey A. Popov, Ivan E. Kareev, Natalia B. Shustova, Steven H. Strauss, Olga V. Boltalina and Lothar Dunsch pp 11709–11721 DOI: 10.1021/ja1043775 Supporting Info

Electrochemical Stability of Elemental Metal Nanoparticles Lei Tang, Xiaoqian Li, Robert C. Cammarata, Cody Friesen and Karl Sieradzki pp 11722–11726 DOI: 10.1021/ja104421t Supporting Info

A Coiled-Coil Enabled Split-Luciferase Three-Hybrid System: Applied Toward Profiling Inhibitors of Protein Kinases Benjamin W. Jester, Kurt J. Cox, Alicia Gaj, Carolyn D. Shomin, Jason R. Porter and Indraneel Ghosh pp 11727–11735 DOI: 10.1021/ja104491h Supporting Info

A Biomimetic Asymmetric Responsive Single Nanochannel Xu Hou, Fu Yang, Lin Li, Yanlin Song, Lei Jiang and Daoben Zhu pp 11736–11742 DOI: 10.1021/ja1045082 Supporting Info

New Light-Harvesting Molecular Systems Constructed with a Ru(II) Complex and a Linear-Shaped Re(I) Oligomer Youhei Yamamoto, Yusuke Tamaki, Tatsuto Yui, Kazuhide Koike and Osamu Ishitani pp 11743–11752 DOI: 10.1021/ja104601b Supporting Info

Structurally Informed Site-Directed Mutagenesis of a Stereochemically Promiscuous Aldolase To Afford Stereochemically Complementary Biocatalysts Sylvain F. Royer, Luke Haslett, Susan J. Crennell, David W. Hough, Michael J. Danson and Steven D. Bull pp 11753–11758 DOI: 10.1021/ja104412a Supporting Info

Hydrido-Ruthenium Cluster Complexes as Models for Reactive Surface Hydrogen Species of Ruthenium Nanoparticles. Solid-State 2H NMR and Quantum Chemical Calculations Torsten Gutmann, Bernadeta Walaszek, Xu Yeping, Maria Wchtler, Iker del Rosal, Anna Grnberg, Romuald Poteau, Rosa Axet, Guy Lavigne, Bruno Chaudret, Hans-Heinrich Limbach and Gerd Buntkowsky pp 11759–11767 DOI: 10.1021/ja104229a

Development of a General, Sequential, Ring-Closing Metathesis/Intramolecular Cross-Coupling Reaction for the Synthesis of Polyunsaturated Macrolactones Scott E. Denmark and Joseck M. Muhuhi pp 11768–11778 DOI: 10.1021/ja1047363 Supporting Info

In Vitro Selection of a DNA-Templated Small-Molecule Library Reveals a Class of Macrocyclic Kinase Inhibitors Ralph E. Kleiner, Christoph E. Dumelin, Gerald C. Tiu, Kaori Sakurai and David R. Liu pp 11779–11791 DOI: 10.1021/ja104903x Supporting Info

Design and Synthesis of Vanadium Hydrazide Gels for Kubas-Type Hydrogen Adsorption: A New Class of Hydrogen Storage Materials Tuan K. A. Hoang, Michael I. Webb, Hung V. Mai, Ahmad Hamaed, Charles J. Walsby, Michel Trudeau and David M. Antonelli pp 11792–11798 DOI: 10.1021/ja104926h Supporting Info

Difluorobenzocyclooctyne: Synthesis, Reactivity, and Stabilization by β-Cyclodextrin Ellen M. Sletten, Hitomi Nakamura, John C. Jewett and Carolyn R. Bertozzi pp 11799–11805 DOI: 10.1021/ja105005t Supporting Info

Amorphous Precursors in the Nucleation of Clathrate Hydrates Liam C. Jacobson, Waldemar Hujo and Valeria Molinero pp 11806–11811 DOI: 10.1021/ja1051445 Supporting Info

Nitric Oxide Synthase Stabilizes the Tetrahydrobiopterin Cofactor Radical by Controlling Its Protonation State Stefan Stoll, Yaser NejatyJahromy, Joshua J. Woodward, Andrew Ozarowski, Michael A. Marletta and R. David Britt pp 11812–11823 DOI: 10.1021/ja105372s Supporting Info

Catalytic Dicyanative [4+2] Cycloaddition Triggered by Cyanopalladation of Conjugated Enynes under Aerobic Conditions Shigeru Arai, Yuka Koike, Hirohiko Hada and Atsushi Nishida p 11824 DOI: 10.1021/ja1052939 Supporting Info

Catalytic Enantioselective 1,3-Dipolar Cycloaddition of C,N-Cyclic Azomethine Imines with α,β-Unsaturated Aldehydes Takuya Hashimoto, Yuko Maeda, Masato Omote, Hiroki Nakatsu and Keiji Maruoka p 11824 DOI: 10.1021/ja105302r

Synthesis and Surface Modification of Highly Monodispersed, Spherical Gold Nanoparticles of 50−200 nm Steven D. Perrault and Warren C. W. Chan p 11824 DOI: 10.1021/ja105675q

Issue 34

An Opportunity for Mg-Catalyzed Grignard-Type Reactions: Direct Coupling of Benzylic Halides with Pinacolborane with 10 mol % of Magnesium Christine Pintaric, Sandra Olivero, Yves Gimbert, Pierre Y. Chavant and Elisabet Duach pp 11825–11827 DOI: 10.1021/ja1052973 Supporting Info

Facile Fabrication of an Efficient Oxynitride TaON Photoanode for Overall Water Splitting into H2 and O2 under Visible Light Irradiation Ryu Abe, Masanobu Higashi and Kazunari Domen pp 11828–11829 DOI: 10.1021/ja1016552 Supporting Info

Slow Reductive Elimination from Arylpalladium Parent Amido Complexes Jessica L. Klinkenberg and John F. Hartwig pp 11830–11833 DOI: 10.1021/ja1023404 Supporting Info

Fluorescence of Natural DNA: From the Femtosecond to the Nanosecond Time Scales Ignacio Vay, Thomas Gustavsson, Franois-Alexandre Miannay, Thierry Douki and Dimitra Markovitsi pp 11834–11835 DOI: 10.1021/ja102800r Supporting Info

Potassium(I) Amidotrihydroborate: Structure and Hydrogen Release Himashinie V. K. Diyabalanage, Tessui Nakagawa, Roshan P. Shrestha, Troy A. Semelsberger, Benjamin L. Davis, Brian L. Scott, Anthony K. Burrell, William I. F. David, Kate R. Ryan, Martin Owen Jones and Peter P. Edwards pp 11836–11837 DOI: 10.1021/ja100167z Supporting Info

Synthesis of 3-Trifluoromethylbenzo[b]furans from Phenols via Direct Ortho Functionalization by Extended Pummerer Reaction Takayuki Kobatake, Daishi Fujino, Suguru Yoshida, Hideki Yorimitsu and Koichiro Oshima pp 11838–11840 DOI: 10.1021/ja1030134 Supporting Info

Synthesis of Quaternary Carbon Centers via Hydroformylation X. Sun, K. Frimpong and K. L. Tan pp 11841–11843 DOI: 10.1021/ja1036226 Supporting Info

Layer-by-Layer Synthesis of Metal-Containing Conducting Polymers: Caged Metal Centers for Interlayer Charge Transport Wenjun Liu, Weijie Huang, Maren Pink and Dongwhan Lee pp 11844–11846 DOI: 10.1021/ja104038s Supporting Info

Enantioselective Organocatalytic C−H Bond Functionalization via Tandem 1,5-Hydride Transfer/Ring Closure: Asymmetric Synthesis of Tetrahydroquinolines Young Ku Kang, Sun Mi Kim and Dae Young Kim pp 11847–11849 DOI: 10.1021/ja103786c Supporting Info

Microsecond Time Scale Mobility in a Solid Protein As Studied by the 15N R1ρ Site-Specific NMR Relaxation Rates Alexey Krushelnitsky, Tatiana Zinkevich, Detlef Reichert, Veniamin Chevelkov and Bernd Reif pp 11850–11853 DOI: 10.1021/ja103582n Supporting Info

Synthesis of Tetrasubstituted Alkenes by Stereo- and Regioselective Stannyllithiation of Diarylacetylenes Hayato Tsuji, Yasuyuki Ueda, Laurean Ilies and Eiichi Nakamura pp 11854–11855 DOI: 10.1021/ja1059119 Supporting Info

Self-Doped Ti3+ Enhanced Photocatalyst for Hydrogen Production under Visible Light Fan Zuo, Le Wang, Tao Wu, Zhenyu Zhang, Dan Borchardt and Pingyun Feng pp 11856–11857 DOI: 10.1021/ja103843d Supporting Info

Catalytic Enantioselective Radical Cyclization via Regiodivergent Epoxide Opening Andreas Gansuer, Lei Shi and Matthias Otte pp 11858–11859 DOI: 10.1021/ja105023y Supporting Info

Gas-Phase Folding of a Two-Residue Model Peptide Chain: On the Importance of an Interplay between Experiment and Theory E. Gloaguen, B. de Courcy, J.-P. Piquemal, J. Pilm, O. Parisel, R. Pollet, H. S. Biswal, F. Piuzzi, B. Tardivel, M. Broquier and M. Mons pp 11860–11863 DOI: 10.1021/ja103996q Supporting Info

Direct Imaging of Intermolecular Bonds in Scanning Tunneling Microscopy Christian Weiss, Christian Wagner, Ruslan Temirov and F. Stefan Tautz pp 11864–11865 DOI: 10.1021/ja104332t Supporting Info

Formic Acid Acting as an Efficient Oxygen Scavenger in Four-Electron Reduction of Oxygen Catalyzed by a Heterodinuclear Iridium−Ruthenium Complex in Water Shunichi Fukuzumi, Takeshi Kobayashi and Tomoyoshi Suenobu pp 11866–11867 DOI: 10.1021/ja104486h Supporting Info

Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures Jianxin Song, Naoki Aratani, Ji Haeng Heo, Dongho Kim, Hiroshi Shinokubo and Atsuhiro Osuka pp 11868–11869 DOI: 10.1021/ja1046654 Supporting Info

Identification of HSP60 as a Primary Target of o-Carboranylphenoxyacetanilide, an HIF-1α Inhibitor Hyun Seung Ban, Kazuki Shimizu, Hidemitsu Minegishi and Hiroyuki Nakamura pp 11870–11871 DOI: 10.1021/ja104739t Supporting Info

Experimental and Computational Study of a Direct O2-Coupled Wacker Oxidation: Water Dependence in the Absence of Cu Salts Brian J. Anderson, John A. Keith and Matthew S. Sigman pp 11872–11874 DOI: 10.1021/ja1057218 Supporting Info

Catalytic Asymmetric Claisen Rearrangement of Unactivated Allyl Vinyl Ethers Maryll E. Geherty, Robert D. Dura and Scott G. Nelson pp 11875–11877 DOI: 10.1021/ja1039314 Supporting Info

Charge Transfer State Versus Hot Exciton Dissociation in Polymer−Fullerene Blended Solar Cells Jiye Lee, Koen Vandewal, Shane R. Yost, Matthias E. Bahlke, Ludwig Goris, Marc A. Baldo, Jean V. Manca and Troy Van Voorhis pp 11878–11880 DOI: 10.1021/ja1045742 Supporting Info

Gold-Catalyzed Annulation/Fragmentation: Formation of Free Gold Carbenes by Retro-Cyclopropanation Csar R. Solorio-Alvarado and Antonio M. Echavarren pp 11881–11883 DOI: 10.1021/ja104743k Supporting Info

Chiral Brønsted Acid-Catalyzed Allylboration of Aldehydes Pankaj Jain and Jon C. Antilla pp 11884–11886 DOI: 10.1021/ja104956s Supporting Info

Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation Chung-Chih Tsai, Wei-Chih Shih, Cyong-Hui Fang, Chia-Yi Li, Tiow-Gan Ong and Glenn P. A. Yap pp 11887–11889 DOI: 10.1021/ja1061246 Supporting Info

Arrested 1,2-Hydrogen Migration from Silicon to Nickel upon Oxidation of a Three-Coordinate Ni(I) Silyl Complex Vlad M. Iluc and Gregory L. Hillhouse pp 11890–11892 DOI: 10.1021/ja1052329 Supporting Info

Enhancement of Anion Recognition Exhibited by a Halogen-Bonding Rotaxane Host System Nathan L. Kilah, Matthew D. Wise, Christopher J. Serpell, Amber L. Thompson, Nicholas G. White, Kirsten E. Christensen and Paul D. Beer pp 11893–11895 DOI: 10.1021/ja105263q Supporting Info

Fluorescent Ribonucleoside as a FRET Acceptor for Tryptophan in Native Proteins Yun Xie, Tucker Maxson and Yitzhak Tor pp 11896–11897 DOI: 10.1021/ja105244t Supporting Info

Room Temperature Palladium-Catalyzed Decarboxylative ortho-Acylation of Acetanilides with α-Oxocarboxylic Acids Ping Fang, Mingzong Li and Haibo Ge pp 11898–11899 DOI: 10.1021/ja105245f Supporting Info

Spin and Orbital Magnetic Moment Anisotropies of Monodispersed Bis(Phthalocyaninato)Terbium on a Copper Surface Sebastian Stepanow, Jan Honolka, Pietro Gambardella, Lucia Vitali, Nasiba Abdurakhmanova, Tzu-Chun Tseng, Stephan Rauschenbach, Steven L. Tait, Violetta Sessi, Svetlana Klyatskaya, Mario Ruben and Klaus Kern pp 11900–11901 DOI: 10.1021/ja105124r Supporting Info

Fluostatins Produced by the Heterologous Expression of a TAR Reassembled Environmental DNA Derived Type II PKS Gene Cluster Zhiyang Feng, Jeff H. Kim and Sean F. Brady pp 11902–11903 DOI: 10.1021/ja104550p Supporting Info

Bis[3-(5-nitroimino-1,2,4-triazolate)]-Based Energetic Salts: Synthesis and Promising Properties of a New Family of High-Density Insensitive Materials Ruihu Wang, Hongyan Xu, Yong Guo, Rongjian Sa and Jean’ne M. Shreeve pp 11904–11905 DOI: 10.1021/ja1055033 Supporting Info

Automatic Assignment of the Intrinsically Disordered Protein Tau with 441-Residues Rhagavendran L. Narayanan, Ulrich H. N. Drr, Stefan Bibow, Jacek Biernat, Eckhard Mandelkow and Markus Zweckstetter pp 11906–11907 DOI: 10.1021/ja105657f Supporting Info

Asymmetric Alkyl−Alkyl Cross-Couplings of Unactivated Secondary Alkyl Electrophiles: Stereoconvergent Suzuki Reactions of Racemic Acylated Halohydrins Nathan A. Owston and Gregory C. Fu pp 11908–11909 DOI: 10.1021/ja105924f Supporting Info

Combining NMR and EPR Methods for Homodimer Protein Structure Determination Yunhuang Yang, Theresa A. Ramelot, Robert M. McCarrick, Shuisong Ni, Erik A. Feldmann, John R. Cort, Huang Wang, Colleen Ciccosanti, Mei Jiang, Haleema Janjua, Thomas B. Acton, Rong Xiao, John K. Everett, Gaetano T. Montelione and Michael A. Kennedy pp 11910–11913 DOI: 10.1021/ja105080h Supporting Info

Tunable Photocatalytic Selectivity of Hollow TiO2 Microspheres Composed of Anatase Polyhedra with Exposed {001} Facets Shengwei Liu, Jiaguo Yu and Mietek Jaroniec pp 11914–11916 DOI: 10.1021/ja105283s Supporting Info

Stereospecific Substitution of Allylic Alcohols To Give Optically Active Primary Allylic Amines: Unique Reactivity of a (P,alkene)Ir Complex Modulated by Iodide Markus Roggen and Erick M. Carreira pp 11917–11919 DOI: 10.1021/ja105271z Supporting Info

Mechanical Nanosprings: Induced Coiling and Uncoiling of Ultrathin Au Nanowires Jun Xu, Hong Wang, Cuicui Liu, Yanmei Yang, Tao Chen, Yawen Wang, Feng Wang, Xiaogang Liu, Bengang Xing and Hongyu Chen pp 11920–11922 DOI: 10.1021/ja105433d Supporting Info

Catalytic C−H Bond Stannylation: A New Regioselective Pathway to C−Sn Bonds via C−H Bond Functionalization Meghan E. Doster, Jillian A. Hatnean, Tamara Jeftic, Sunjay Modi and Samuel A. Johnson pp 11923–11925 DOI: 10.1021/ja105588v Supporting Info

Stereoselective Syntheses of Trisubstituted Olefins via Platinum Catalysis: α-Silylenones with Geometrical Complementarity Douglas A. Rooke and Eric M. Ferreira pp 11926–11928 DOI: 10.1021/ja1058197 Supporting Info

Doped Assemblies of Gold Nanoparticles: Structural and Electronic Properties Jonathan da Rocha Martins, Ronaldo J. C. Batista and Hlio Chacham pp 11929–11933 DOI: 10.1021/ja910335h

All-Amorphous-Oxide Transparent, Flexible Thin-Film Transistors. Efficacy of Bilayer Gate Dielectrics Jun Liu, D. Bruce Buchholz, Jonathan W. Hennek, Robert P. H. Chang, Antonio Facchetti and Tobin J. Marks pp 11934–11942 DOI: 10.1021/ja9103155 Supporting Info

Reversible Magnetism between an Antiferromagnet and a Ferromagnet Related to Solvation/Desolvation in a Robust Layered [Ru2]2TCNQ Charge-Transfer System Natsuko Motokawa, Satoshi Matsunaga, Shinya Takaishi, Hitoshi Miyasaka, Masahiro Yamashita and Kim R. Dunbar pp 11943–11951 DOI: 10.1021/ja102412g Supporting Info

Differentiating Mechanistic Possibilities for the Thermal, Intramolecular [2 + 2] Cycloaddition of Allene−Ynes Matthew R. Siebert, Joshua M. Osbourn, Kay M. Brummond and Dean J. Tantillo pp 11952–11966 DOI: 10.1021/ja102848z Supporting Info

Energetic and Entropic Contributions to Self-Assembly of Binary Nanocrystal Superlattices: Temperature as the Structure-Directing Factor Maryna I. Bodnarchuk, Maksym V. Kovalenko, Wolfgang Heiss and Dmitri V. Talapin pp 11967–11977 DOI: 10.1021/ja103083q Supporting Info

Scope and Mechanism of Allylic C−H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2 Catalyst System: Insights into the Effect of Naphthoquinone Guoyin Yin, Yichen Wu and Guosheng Liu pp 11978–11987 DOI: 10.1021/ja1030936 Supporting Info

Catalytic Asymmetric Aza-Morita−Baylis−Hillman Reaction of Methyl Acrylate: Role of a Bifunctional La(O-iPr)3/Linked-BINOL Complex Takafumi Yukawa, Bianca Seelig, Yingjie Xu, Hiroyuki Morimoto, Shigeki Matsunaga, Albrecht Berkessel and Masakatsu Shibasaki pp 11988–11992 DOI: 10.1021/ja103294a Supporting Info

ONIOM Study on a Missing Piece in Our Understanding of Heme Chemistry: Bacterial Tryptophan 2,3-Dioxygenase with Dual Oxidants Lung Wa Chung, Xin Li, Hiroshi Sugimoto, Yoshitsugu Shiro and Keiji Morokuma pp 11993–12005 DOI: 10.1021/ja103530v Supporting Info

Hexagonal Superlattice of Chiral Conducting Polymers Self-Assembled by Mimicking β-Sheet Proteins with Anisotropic Electrical Transport Yong Yan, Rui Wang, Xiaohui Qiu and Zhixiang Wei pp 12006–12012 DOI: 10.1021/ja1036447

Fluxionality of [(Ph3P)3M(X)] (M = Rh, Ir). The Red and Orange Forms of [(Ph3P)3Ir(Cl)]. Which Phosphine Dissociates Faster from Wilkinson’s Catalyst? Jenni Goodman, Vladimir V. Grushin, Roman B. Larichev, Stuart A. Macgregor, William J. Marshall and D. Christopher Roe pp 12013–12026 DOI: 10.1021/ja1039693 Supporting Info

Quantitative Catalyst−Substrate Association Relationships between Metathesis Molybdenum or Ruthenium Carbene Complexes and Their Substrates Kyung Hwan Kim, Taedong Ok, Kwangyeol Lee, Hee-Seung Lee, Kyu Tae Chang, Hyotcherl Ihee and Jeong-Hun Sohn pp 12027–12033 DOI: 10.1021/ja104193s Supporting Info

Photopromoted Ru-Catalyzed Asymmetric Aerobic Sulfide Oxidation and Epoxidation Using Water as a Proton Transfer Mediator Haruna Tanaka, Hiroaki Nishikawa, Tatsuya Uchida and Tsutomu Katsuki pp 12034–12041 DOI: 10.1021/ja104184r Supporting Info

Ordered Mesoporous Crystalline γ-Al2O3 with Variable Architecture and Porosity from a Single Hard Template Zhangxiong Wu, Qiang Li, Dan Feng, Paul A. Webley and Dongyuan Zhao pp 12042–12050 DOI: 10.1021/ja104379a Supporting Info

A Healable Supramolecular Polymer Blend Based on Aromatic π−π Stacking and Hydrogen-Bonding Interactions Stefano Burattini, Barnaby W. Greenland, Daniel Hermida Merino, Wengui Weng, Jonathan Seppala, Howard M. Colquhoun, Wayne Hayes, Michael E. Mackay, Ian W. Hamley and Stuart J. Rowan pp 12051–12058 DOI: 10.1021/ja104446r Supporting Info

Pulsed EPR Determination of the Distance between Heme Iron and FMN Centers in a Human Inducible Nitric Oxide Synthase Andrei V. Astashkin, Bradley O. Elmore, Weihong Fan, J. Guy Guillemette and Changjian Feng pp 12059–12067 DOI: 10.1021/ja104461p Supporting Info

Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C−H Bond: Evidence for an Aryl-Copper(III) Intermediate Amanda E. King, Lauren M. Huffman, Alicia Casitas, Miquel Costas, Xavi Ribas and Shannon S. Stahl pp 12068–12073 DOI: 10.1021/ja1045378 Supporting Info

Role of Aromatic Rings in the Molecular Recognition of Aminoglycoside Antibiotics: Implications for Drug Design Tatiana Vacas, Francisco Corzana, Gonzalo Jimnez-Oss, Carlos Gonzlez, Ana M. Gmez, Agatha Bastida, Julia Revuelta and Juan Luis Asensio pp 12074–12090 DOI: 10.1021/ja1046439 Supporting Info

Water in Cavity−Ligand Recognition Riccardo Baron, Piotr Setny and J. Andrew McCammon pp 12091–12097 DOI: 10.1021/ja1050082 Supporting Info

Sc2(μ2-O) Trapped in a Fullerene Cage: The Isolation and Structural Characterization of Sc2(μ2-O)@Cs(6)-C82 and the Relevance of the Thermal and Entropic Effects in Fullerene Isomer Selection Brandon Q. Mercado, Melissa A. Stuart, Mary A. Mackey, Jane E. Pickens, Bridget S. Confait, Steven Stevenson, Michael L. Easterling, Ramn Valencia, Antonio Rodrguez-Fortea, Josep M. Poblet, Marilyn M. Olmstead and Alan L. Balch pp 12098–12105 DOI: 10.1021/ja104902e Supporting Info

Photochemical Addition of C60 with Siliranes: Synthesis and Characterization of Carbosilylated and Hydrosilylated C60 Derivatives Junko Nagatsuka, Sachie Sugitani, Masahiro Kako, Tsukasa Nakahodo, Naomi Mizorogi, Midori O. Ishitsuka, Yutaka Maeda, Takahiro Tsuchiya, Takeshi Akasaka, Xingfa Gao and Shigeru Nagase pp 12106–12120 DOI: 10.1021/ja1049719 Supporting Info

Probing the Rate of Hole Transfer in Oxidized Porphyrin Dyads Using Thallium Hyperfine Clocks James R. Diers, Masahiko Taniguchi, Dewey Holten, Jonathan S. Lindsey and David F. Bocian pp 12121–12132 DOI: 10.1021/ja105082d Supporting Info

Torsionally Responsive C3-Symmetric Azo Dyes: Azo−Hydrazone Tautomerism, Conformational Switching, and Application for Chemical Sensing Ho Yong Lee, Xinli Song, Hyunsoo Park, Mu-Hyun Baik and Dongwhan Lee pp 12133–12144 DOI: 10.1021/ja105121z Supporting Info

Position-Specific Secondary Deuterium Isotope Effects on Basicity of Pyridine Charles L. Perrin and Phaneendrasai Karri pp 12145–12149 DOI: 10.1021/ja105331g Supporting Info

Silver-Catalyzed Late-Stage Fluorination Pingping Tang, Takeru Furuya and Tobias Ritter pp 12150–12154 DOI: 10.1021/ja105834t Supporting Info

Catalytic Asymmetric Transacetalization Ilija ori, Sreekumar Vellalath and Benjamin List p 12155 DOI: 10.1021/ja105707w

Organic Azides: Syntheses and Applications Alan Katritzky and Eric Scriven p 12156 DOI: 10.1021/ja106712z

Issue 35

Asymmetric Palladium-Catalyzed Carboamination Reactions for the Synthesis of Enantiomerically Enriched 2-(Arylmethyl)- and 2-(Alkenylmethyl)pyrrolidines Duy N. Mai and John P. Wolfe pp 12157–12159 DOI: 10.1021/ja106989h Supporting Info

Reconstruction of Conjugated Oligoelectrolyte Electron Injection Layers Zhao Chen, Xuan-Dung Dang, Andrea Gutacker, Andrew Garcia, Huaping Li, Yunhua Xu, Lei Ying, Thuc-Quyen Nguyen and Guillermo C. Bazan pp 12160–12162 DOI: 10.1021/ja1056856 Supporting Info

Toward Well-Defined Metal−Polymer Interfaces: Temperature-Controlled Suppression of Subsurface Diffusion and Reaction at the Calcium/Poly(3-Hexylthiophene) Interface Fabian Bebensee, Martin Schmid, Hans-Peter Steinrck, Charles T. Campbell and J. Michael Gottfried pp 12163–12165 DOI: 10.1021/ja104029r Supporting Info

Quantum Study of Laser-Induced Initial Activation of Graphite-to-Diamond Conversion Angela Acocella, Fabrizio Carbone and Francesco Zerbetto pp 12166–12167 DOI: 10.1021/ja102497z Supporting Info

Indium-Mediated Catalytic Enantioselective Allylation of N-Benzoylhydrazones Using a Protonated Chiral Amine Sung Jun Kim and Doo Ok Jang pp 12168–12169 DOI: 10.1021/ja1035336 Supporting Info

Platinum−Gold Nanoparticles: A Highly Active Bifunctional Electrocatalyst for Rechargeable Lithium−Air Batteries Yi-Chun Lu, Zhichuan Xu, Hubert A. Gasteiger, Shuo Chen, Kimberly Hamad-Schifferli and Yang Shao-Horn pp 12170–12171 DOI: 10.1021/ja1036572 Supporting Info

1,1′-Azobis-1,2,3-triazole: A High-Nitrogen Compound with Stable N8 Structure and Photochromism Yu-Chuan Li, Cai Qi, Sheng-Hua Li, Hui-Juan Zhang, Cheng-Hui Sun, Yong-Zhong Yu and Si-Ping Pang pp 12172–12173 DOI: 10.1021/ja103525v Supporting Info

Preparation and Periodic Emission of Superlattice CdS/CdS:SnS2 Microwires Guozhang Dai, Bingsuo Zou and Zhonglin Wang pp 12174–12175 DOI: 10.1021/ja1037963 Supporting Info

Size Differentiation and Absolute Quantification of Gold Nanoparticles via Single Particle Detection with a Laboratory-Built High-Sensitivity Flow Cytometer Shaobin Zhu, Lingling Yang, Yao Long, Min Gao, Tianxun Huang, Wei Hang and Xiaomei Yan pp 12176–12178 DOI: 10.1021/ja104052c Supporting Info

Stereospecific Decarboxylative Allylation of Sulfones Jimmie D. Weaver, Being J. Ka, David K. Morris, Ward Thompson and Jon A. Tunge pp 12179–12181 DOI: 10.1021/ja104196x Supporting Info

Genetic Interception and Structural Characterization of Thiopeptide Cyclization Precursors from Bacillus cereus Albert A. Bowers, Christopher T. Walsh and Michael G. Acker pp 12182–12184 DOI: 10.1021/ja104524q Supporting Info

A Carbon-Supported Copper Complex of 3,5-Diamino-1,2,4-triazole as a Cathode Catalyst for Alkaline Fuel Cell Applications Fikile R. Brushett, Matthew S. Thorum, Nicholas S. Lioutas, Matthew S. Naughton, Claire Tornow, Huei-Ru “Molly” Jhong, Andrew A. Gewirth and Paul J. A. Kenis pp 12185–12187 DOI: 10.1021/ja104767w Supporting Info

Formation, Structure, and EPR Detection of a High Spin FeIV—Oxo Species Derived from Either an FeIII—Oxo or FeIII—OH Complex David C. Lacy, Rupal Gupta, Kari L. Stone, John Greaves, Joseph W. Ziller, Michael P. Hendrich and A. S. Borovik pp 12188–12190 DOI: 10.1021/ja1047818 Supporting Info

Separation of C70 over C60 and Selective Extraction and Resolution of Higher Fullerenes by Syndiotactic Helical Poly(methyl methacrylate) Takehiro Kawauchi, Atsushi Kitaura, Mariko Kawauchi, Tsutomu Takeichi, Jiro Kumaki, Hiroki Iida and Eiji Yashima pp 12191–12193 DOI: 10.1021/ja104969a Supporting Info

Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination Toshimichi Ohmura, Kazuyuki Oshima, Hiroki Taniguchi and Michinori Suginome pp 12194–12196 DOI: 10.1021/ja105096r Supporting Info

A Fluorogenic Reaction Based on Heavy-Atom Removal for Ultrasensitive DNA Detection Deepak K. Prusty and Andreas Herrmann pp 12197–12199 DOI: 10.1021/ja105181v Supporting Info

Highly Selective Carbon Dioxide Sorption in an Organic Molecular Porous Material Hyunuk Kim, Yonghwi Kim, Minyoung Yoon, Soyoung Lim, Se Min Park, Gon Seo and Kimoon Kim pp 12200–12202 DOI: 10.1021/ja105211w Supporting Info

Pd(II)-Catalyzed Hydroxyl-Directed C−H Activation/C−O Cyclization: Expedient Construction of Dihydrobenzofurans Xisheng Wang, Yi Lu, Hui-Xiong Dai and Jin-Quan Yu pp 12203–12205 DOI: 10.1021/ja105366u Supporting Info

Symmetry Switch of Cobalt Ferrocyanide Framework by Alkaline Cation Exchange Tomoyuki Matsuda, Jungeun Kim and Yutaka Moritomo pp 12206–12207 DOI: 10.1021/ja105482k Supporting Info

Multitiered 2D π-Stacked Conjugated Polymers Based on Pseudo-Geminal Disubstituted [2.2]Paracyclophane Subodh P. Jagtap and David M. Collard pp 12208–12209 DOI: 10.1021/ja104696e Supporting Info

Antifreeze Glycoprotein Activity Correlates with Long-Range Protein−Water Dynamics Simon Ebbinghaus, Konrad Meister, Benjamin Born, Arthur L. DeVries, Martin Gruebele and Martina Havenith pp 12210–12211 DOI: 10.1021/ja1051632

Rhodium-Catalyzed Oxidative C−H Arylation of 2-Arylpyridine Derivatives via Decarbonylation of Aromatic Aldehydes Qi Shuai, Luo Yang, Xiangyu Guo, Olivier Basl and Chao-Jun Li pp 12212–12213 DOI: 10.1021/ja105396b Supporting Info

Iron(II)-Thiolate S-Oxygenation by O2: Synthetic Models of Cysteine Dioxygenase Yunbo Jiang, Leland R. Widger, Gary D. Kasper, Maxime A. Siegler and David P. Goldberg pp 12214–12215 DOI: 10.1021/ja105591q Supporting Info

Highly Enantioselective Catalytic Dynamic Resolution of N-Boc-2-lithiopiperidine: Synthesis of (R)-(+)-N-Boc-Pipecolic Acid, (S)-(−)-Coniine, (S)-(+)-Pelletierine, (+)-β-Conhydrine, and (S)-(−)-Ropivacaine and Formal Synthesis of (−)-Lasubine II and (+)-Cermizine C Timothy K. Beng and Robert E. Gawley pp 12216–12217 DOI: 10.1021/ja105772z Supporting Info

Synthesis of Monodispersed Wurtzite Structure CuInSe2 Nanocrystals and Their Application in High-Performance Organic−Inorganic Hybrid Photodetectors Jian-Jun Wang, Yong-Qing Wang, Fei-Fei Cao, Yu-Guo Guo and Li-Jun Wan pp 12218–12221 DOI: 10.1021/ja1057955 Supporting Info

Bispalladacycle-Catalyzed Brønsted Acid/Base-Promoted Asymmetric Tandem Azlactone Formation−Michael Addition Manuel Weber, Sascha Jautze, Wolfgang Frey and Ren Peters pp 12222–12225 DOI: 10.1021/ja106088v Supporting Info

Asymmetric Total Synthesis of Trilobacin via Organoselenium-Mediated Oxonium Ion Formation/SiO2-Promoted Fragmentation Te-ik Sohn, Mi Jung Kim and Deukjoon Kim pp 12226–12227 DOI: 10.1021/ja106116v Supporting Info

Aryl C−H Bond Amination by an Electrophilic Diruthenium Nitride Amanda Kae Musch Long, Renyuan Pony Yu, George H. Timmer and John F. Berry pp 12228–12230 DOI: 10.1021/ja1062955 Supporting Info

Cu24O24Si8R8: Organic Soluble 56-Membered Copper(I) Siloxane Cage and Its Use in Homogeneous Catalysis Gengwen Tan, Ying Yang, Chenhui Chu, Hongping Zhu and Herbert W. Roesky pp 12231–12233 DOI: 10.1021/ja1056104 Supporting Info

Copper-Catalyzed Formal [4 + 2] Annulation between Alkyne and Fullerene Bromide Zuo Xiao, Yutaka Matsuo and Eiichi Nakamura pp 12234–12236 DOI: 10.1021/ja1056399 Supporting Info

High-Fidelity Hydrophilic Probe for Two-Photon Fluorescence Lysosomal Imaging Xuhua Wang, Dao M. Nguyen, Ciceron O. Yanez, Luis Rodriguez, Hyo-Yang Ahn, Mykhailo V. Bondar and Kevin D. Belfield pp 12237–12239 DOI: 10.1021/ja1057423 Supporting Info

Catalytic Asymmetric Protonation of α-Amino Acid-Derived Ketene Disilyl Acetals Using P-Spiro Diaminodioxaphosphonium Barfates as Chiral Proton Daisuke Uraguchi, Natsuko Kinoshita and Takashi Ooi pp 12240–12242 DOI: 10.1021/ja105945z Supporting Info

Gene Expression Enabling Synthetic Diversification of Natural Products: Chemogenetic Generation of Pacidamycin Analogs Abhijeet Deb Roy, Sabine Grschow, Nickiwe Cairns and Rebecca J. M. Goss pp 12243–12245 DOI: 10.1021/ja1060406 Supporting Info

Identity of the Active Site in Gold Nanoparticle-Catalyzed Sonogashira Coupling of Phenylacetylene and Iodobenzene Simon K. Beaumont, Georgios Kyriakou and Richard M. Lambert pp 12246–12248 DOI: 10.1021/ja1063179 Supporting Info

Cobalt-Catalyzed Hydroarylation of Alkynes through Chelation-Assisted C−H Bond Activation Ke Gao, Pin-Sheng Lee, Takeshi Fujita and Naohiko Yoshikai pp 12249–12251 DOI: 10.1021/ja106814p Supporting Info

De Novo Design of Peptide−Calcite Biomineralization Systems David L. Masica, Sarah B. Schrier, Elizabeth A. Specht and Jeffrey J. Gray pp 12252–12262 DOI: 10.1021/ja1001086

Rational Design of Acridine-Based Ligands with Selectivity for Human Telomeric Quadruplexes Silvia Sparapani, Shozeb M. Haider, Filippo Doria, Mekala Gunaratnam and Stephen Neidle pp 12263–12272 DOI: 10.1021/ja1003944 Supporting Info

Dinitrogen Complexation and Extent of N≡N Activation within the Group 6 “End-On-Bridged” Dinuclear Complexes, {(η5-C5Me5)M[N(i-Pr)C(Me)N(i-Pr)]}2(μ-η1:η1-N2) (M = Mo and W) Philip P. Fontaine, Brendan L. Yonke, Peter Y. Zavalij and Lawrence R. Sita pp 12273–12285 DOI: 10.1021/ja100469f Supporting Info

Transition State of ADP-Ribosylation of Acetyllysine Catalyzed by Archaeoglobus fulgidus Sir2 Determined by Kinetic Isotope Effects and Computational Approaches Yana Cen and Anthony A. Sauve pp 12286–12298 DOI: 10.1021/ja910342d Supporting Info

Facile C−H Bond Cleavage via a Proton-Coupled Electron Transfer Involving a C−H···CuII Interaction Xavi Ribas, Carlos Calle, Albert Poater, Alicia Casitas, Laura Gmez, Ral Xifra, Teodor Parella, Jordi Benet-Buchholz, Arthur Schweiger, George Mitrikas, Miquel Sol, Antoni Llobet and T. Daniel P. Stack pp 12299–12306 DOI: 10.1021/ja101599e Supporting Info

Luminescent Au(I)/Cu(I) Alkynyl Clusters with an Ethynyl Steroid and Related Aliphatic Ligands: An Octanuclear Au4Cu4 Cluster and Luminescence Polymorphism in Au3Cu2 Clusters Gerald F. Manbeck, William W. Brennessel, Robert A. Stockland, Jr. and Richard Eisenberg pp 12307–12318 DOI: 10.1021/ja103400e Supporting Info

Transition State Models for Probing Stereoinduction in Evans Chiral Auxiliary-Based Asymmetric Aldol Reactions C. B. Shinisha and Raghavan B. Sunoj pp 12319–12330 DOI: 10.1021/ja101913k Supporting Info

Coexistence of Two Distinct G-Quadruplex Conformations in the hTERT Promoter Kah Wai Lim, Laurent Lacroix, Doris Jia En Yue, Joefina Kim Cheow Lim, Jocelyn Mei Wen Lim and Anh Tun Phan pp 12331–12342 DOI: 10.1021/ja101252n Supporting Info

Quantized Folding of Plasmid DNA Condensed with Block Catiomer into Characteristic Rod Structures Promoting Transgene Efficacy Kensuke Osada, Hiroki Oshima, Daigo Kobayashi, Motoyoshi Doi, Manabu Enoki, Yuichi Yamasaki and Kazunori Kataoka pp 12343–12348 DOI: 10.1021/ja102739b Supporting Info

Small Molecule-Capped Gold Nanoparticles as Potent Antibacterial Agents That Target Gram-Negative Bacteria Yuyun Zhao, Yue Tian, Yan Cui, Wenwen Liu, Wanshun Ma and Xingyu Jiang pp 12349–12356 DOI: 10.1021/ja1028843 Supporting Info

Mechanism of Substrate Shuttling by the Acyl-Carrier Protein within the Fatty Acid Mega-Synthase Claudio Anselmi, Martin Grininger, Preeti Gipson and Jos D. Faraldo-Gmez pp 12357–12364 DOI: 10.1021/ja103354w

Catalysis of Transesterification by a Nonfunctionalized Metal−Organic Framework: Acido-Basicity at the External Surface of ZIF-8 Probed by FTIR and ab Initio Calculations Cline Chizallet, Sandrine Lazare, Delphine Bazer-Bachi, Fabien Bonnier, Vincent Lecocq, Emmanuel Soyer, Anne-Agathe Quoineaud and Nicolas Bats pp 12365–12377 DOI: 10.1021/ja103365s Supporting Info

Structural Consequences of β-Amino Acid Preorganization in a Self-Assembling α/β-Peptide: Fundamental Studies of Foldameric Helix Bundles Joshua L. Price, W. Seth Horne and Samuel H. Gellman pp 12378–12387 DOI: 10.1021/ja103543s Supporting Info

The Catalytic Role of N-Heterocyclic Carbene in a Metal-Free Conversion of Carbon Dioxide into Methanol: A Computational Mechanism Study Fang Huang, Gang Lu, Lili Zhao, Haixia Li and Zhi-Xiang Wang pp 12388–12396 DOI: 10.1021/ja103531z Supporting Info

DFT and CASPT2 Analysis of Polymetallic Uranium Nitride and Oxide Complexes: How Theory Can Help When X-Ray Analysis Is Inadequate Tanya K. Todorova, Laura Gagliardi, Justin R. Walensky, Kevin A. Miller and William J. Evans pp 12397–12403 DOI: 10.1021/ja103588w Supporting Info

Responsive Polymers End-Tethered in Solid-State Nanochannels: When Nanoconfinement Really Matters Mario Tagliazucchi, Omar Azzaroni and Igal Szleifer pp 12404–12411 DOI: 10.1021/ja104152g Supporting Info

Competitive Carbon−Sulfur vs Carbon−Carbon Bond Activation of 2-Cyanothiophene with [Ni(dippe)H]2 Matthew R. Grochowski, Ting Li, William W. Brennessel and William D. Jones pp 12412–12421 DOI: 10.1021/ja104158h Supporting Info

Catalyst-Controlled Formal [4 + 3] Cycloaddition Applied to the Total Synthesis of (+)-Barekoxide and (−)-Barekol Yajing Lian, Laura C. Miller, Stephen Born, Richmond Sarpong and Huw M. L. Davies pp 12422–12425 DOI: 10.1021/ja103916t Supporting Info

Effects of Oxygen Content on Bi3Mn3O11+δ: From 45 K Antiferromagnetism to Room-Temperature True Ferromagnetism Alexei A. Belik and Eiji Takayama-Muromachi pp 12426–12432 DOI: 10.1021/ja1043598 Supporting Info

Synthesis of 1′,2′-cis-Nucleoside Analogues: Evidence of Stereoelectronic Control for SN2 Reactions at the Anomeric Center of Furanosides Michel Prvost, Olivier St-Jean and Yvan Guindon pp 12433–12439 DOI: 10.1021/ja104429y Supporting Info

Geminate Charge Recombination in Polymer/Fullerene Bulk Heterojunction Films and Implications for Solar Cell Function Suman Kalyan Pal, Tero Kesti, Manisankar Maiti, Fengling Zhang, Olle Ingans, Stefan Hellstrm, Mats R. Andersson, Frederic Oswald, Fernando Langa, Tomas sterman, Torbjrn Pascher, Arkady Yartsev and Villy Sundstrm pp 12440–12451 DOI: 10.1021/ja104786x Supporting Info

Conformations of Silica-Bound (Pentafluorophenyl)propyl Groups Determined by Solid-State NMR Spectroscopy and Theoretical Calculations Kanmi Mao, Takeshi Kobayashi, Jerzy W. Wiench, Hung-Ting Chen, Chih-Hsiang Tsai, Victor S.-Y. Lin and Marek Pruski pp 12452–12457 DOI: 10.1021/ja105007b

Homoatomic Stella Quadrangula [Tl8]6− in Cs18Tl8O6, Interplay of Spin−Orbit Coupling, and Jahn−Teller Distortion Ulrich Wedig, Vyacheslav Saltykov, Jrgen Nuss and Martin Jansen pp 12458–12463 DOI: 10.1021/ja1051022 Supporting Info

ON−OFF Switching of Transcriptional Activity of Large DNA through a Conformational Transition in Cooperation with Phospholipid Membrane Akihiko Tsuji and Kenichi Yoshikawa pp 12464–12471 DOI: 10.1021/ja105154k Supporting Info

Double Protonation of 1,5-Bis(triarylaminoethynyl)anthraquinone To Form a Paramagnetic Pentacyclic Dipyrylium Salt Koya Prabhakara Rao, Tetsuro Kusamoto, Fumiyuki Toshimitsu, Kiyotaka Inayoshi, Shoko Kume, Ryota Sakamoto and Hiroshi Nishihara pp 12472–12479 DOI: 10.1021/ja105250f Supporting Info

Atomic Structure of Au−Pd Bimetallic Alloyed Nanoparticles Yong Ding, Fengru Fan, Zhongqun Tian and Zhong Lin Wang pp 12480–12486 DOI: 10.1021/ja105614q Supporting Info

Spontaneous and Specific Activation of Chemical Bonds in Macromolecular Fluids Insun Park, David Shirvanyants, Alper Nese, Krzysztof Matyjaszewski, Michael Rubinstein and Sergei S. Sheiko pp 12487–12491 DOI: 10.1021/ja105897b Supporting Info

Mechanistic Elucidation of the Formation of the Inverse Ca(I) Sandwich Complex [(thf)3Ca(μ-C6H3-1,3,5-Ph3)Ca(thf)3] and Stability of Aryl-Substituted Phenylcalcium Complexes Sven Krieck, Helmar Grls and Matthias Westerhausen pp 12492–12501 DOI: 10.1021/ja105534w Supporting Info

Photomediated Synthesis of Silver Triangular Bipyramids and Prisms: The Effect of pH and BSPP Jian Zhang, Mark R. Langille and Chad A. Mirkin pp 12502–12510 DOI: 10.1021/ja106008b Supporting Info

Self-Assembled Inverted Micelles Stabilize Ionic Liquid Domains in Supercritical CO2 Aneesh Chandran, Karthigeyan Prakash and Sanjib Senapati pp 12511–12516 DOI: 10.1021/ja1055005 Supporting Info

Enantioselective Carbonyl Reverse Prenylation from the Alcohol or Aldehyde Oxidation Level Employing 1,1-Dimethylallene as the Prenyl Donor Soo Bong Han, In Su Kim, Hoon Han and Michael J. Krische p 12517 DOI: 10.1021/ja105736a

A Sulfido-Bridged Diiron(II) Compound and Its Reactions with Nitrogenase-Relevant Substrates Javier Vela, Sebastian Stoian, Christine J. Flaschenriem, Eckard Mnck and Patrick L. Holland p 12517 DOI: 10.1021/ja106351n

Energetics of Phosphate Binding to Ammonium and Guanidinium Containing Metallo-Receptors in Water Suzanne L. Tobey and Eric V. Anslyn p 12517 DOI: 10.1021/ja107031q

Ionic Liquids: From Knowledge to Application p 12518 DOI: 10.1021/ja107137e

Annual Review of Physical Chemistry, Vol. 61 p 12518 DOI: 10.1021/ja107134u

Issue 36

Aggregation Control of Hydrophilic Maghemite (γ-Fe2O3) Nanoparticles by Surface Doping Using Cerium Atoms Amit H. Haviv, Jean-Marc Grenche and Jean-Paul Lellouche pp 12519–12521 DOI: 10.1021/ja103283e Supporting Info

Polymersome Stomatocytes: Controlled Shape Transformation in Polymer Vesicles Kyoung Taek Kim, Jiahua Zhu, Silvie A. Meeuwissen, Jeroen J. L. M. Cornelissen, Darrin J. Pochan, Roeland J. M. Nolte and Jan C. M. van Hest pp 12522–12524 DOI: 10.1021/ja104154t Supporting Info

Investigation of the Highly Active Manganese Superoxide Dismutase from Saccharomyces cerevisiae Kevin Barnese, Yuewei Sheng, Troy A. Stich, Edith B. Gralla, R. David Britt, Diane E. Cabelli and Joan Selverstone Valentine pp 12525–12527 DOI: 10.1021/ja104179r Supporting Info

Self-Propagating Molecular Assemblies as Interlayers for Efficient Inverted Bulk-Heterojunction Solar Cells Leila Motiei, Yan Yao, Joyanta Choudhury, He Yan, Tobin J. Marks, Milko E. van der Boom and Antonio Facchetti pp 12528–12530 DOI: 10.1021/ja104695p Supporting Info

Oysters Produce an Organic−Inorganic Adhesive for Intertidal Reef Construction Jeremy R. Burkett, Lauren M. Hight, Paul Kenny and Jonathan J. Wilker pp 12531–12533 DOI: 10.1021/ja104996y Supporting Info

Enediyne Antitumor Antibiotic Maduropeptin Biosynthesis Featuring a C-Methyltransferase That Acts on a CoA-Tethered Aromatic Substrate Jianya Ling, Geoffrey P. Horsman, Sheng-Xiong Huang, Yinggang Luo, Shuangjun Lin and Ben Shen pp 12534–12536 DOI: 10.1021/ja1050814 Supporting Info

Flexible Particle Array Structures by Controlling Polymer Graft Architecture Jihoon Choi, Hongchen Dong, Krzysztof Matyjaszewski and Michael R. Bockstaller pp 12537–12539 DOI: 10.1021/ja105189s

Supercritical Fluid Synthesis of Magnetic Hexagonal Nanoplatelets of Magnetite Zhonglai Li, Jeffrey F. Godsell, Justin P. O’Byrne, Nikolay Petkov, Michael A. Morris, Saibal Roy and Justin D. Holmes pp 12540–12541 DOI: 10.1021/ja105079y Supporting Info

Acceleration of Nucleophilic CH Activation by Strongly Basic Solvents Brian G. Hashiguchi, Kenneth J. H. Young, Muhammed Yousufuddin, William A. Goddard, III and Roy A. Periana pp 12542–12545 DOI: 10.1021/ja102518m Supporting Info

Molecular Nanocrystals on Ultrathin NaCl Films on Au(111) Yongfeng Wang, Jrg Krger, Richard Berndt and Hao Tang pp 12546–12547 DOI: 10.1021/ja105110d

Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular 12C/13C Kinetic Isotope Effects Ollie M. Gonzalez-James, Xue Zhang, Ayan Datta, David A. Hrovat, Weston Thatcher Borden and Daniel A. Singleton pp 12548–12549 DOI: 10.1021/ja1055593 Supporting Info

Cp* Iridium Complexes Give Catalytic Alkane Hydroxylation with Retention of Stereochemistry Meng Zhou, Nathan D. Schley and Robert H. Crabtree pp 12550–12551 DOI: 10.1021/ja1058247 Supporting Info

Triton X-100 as the “Short-Chain Lipid” Improves the Magnetic Alignment and Stability of Membrane Proteins in Phosphatidylcholine Bilayers for Oriented-Sample Solid-State NMR Spectroscopy Sang Ho Park and Stanley J. Opella pp 12552–12553 DOI: 10.1021/ja1055565 Supporting Info

Catalytic C−O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers Jason M. Nichols, Lee M. Bishop, Robert G. Bergman and Jonathan A. Ellman pp 12554–12555 DOI: 10.1021/ja106101f Supporting Info

Enhanced Electrochemical Lithium Storage by Graphene Nanoribbons Tarun Bhardwaj, Aleks Antic, Barbara Pavan, Veronica Barone and Bradley D. Fahlman pp 12556–12558 DOI: 10.1021/ja106162f Supporting Info

Presence of Surface Vanadium Peroxo-oxo Umbrella Structures in Supported Vanadium Oxide Catalysts: Fact or Fiction? Julie E. Molinari and Israel E. Wachs pp 12559–12561 DOI: 10.1021/ja105392g

Identification of Bacteria by Conjugated Oligoelectrolyte/Single-Stranded DNA Electrostatic Complexes Aidee Duarte, Arkadiusz Chworos, Suvi F. Flagan, Grady Hanrahan and Guillermo C. Bazan pp 12562–12564 DOI: 10.1021/ja105747b Supporting Info

Gold-Catalyzed Stereoselective Synthesis of 9-Oxabicyclo[3.3.1]nona-4,7-dienes from Diverse 1-Oxo-4-oxy-5-ynes: A Viable Formal [4 + 2] Cycloaddition on an s-trans-Heterodiene Framework Tse-Min Teng, Arindam Das, Deepak B. Huple and Rai-Shung Liu pp 12565–12567 DOI: 10.1021/ja106493h Supporting Info

A Solution- and Solid-State Investigation of Medium Effects on Charge Separation in Metastable Photomerocyanines Dinesh G. Patel, Michelle M. Paquette, Roni A. Kopelman, Werner Kaminsky, Michael J. Ferguson and Natia L. Frank pp 12568–12586 DOI: 10.1021/ja100238h Supporting Info

Magnesium-Dependent Active-Site Conformational Selection in the Diels−Alderase Ribozyme Tomasz Bereniak, Ma Zahran, Petra Imhof, Andres Jschke and Jeremy C. Smith pp 12587–12596 DOI: 10.1021/ja101370e Supporting Info

Structure of Hydronium (H3O+)/Chloride (Cl−) Contact Ion Pairs in Aqueous Hydrochloric Acid Solution: A Zundel-like Local Configuration John L. Fulton and Mahalingam Balasubramanian pp 12597–12604 DOI: 10.1021/ja1014458 Supporting Info

Ultrasmall Titania Nanocrystals and Their Direct Assembly into Mesoporous Structures Showing Fast Lithium Insertion Johann M. Szeifert, Johann M. Feckl, Dina Fattakhova-Rohlfing, Yujing Liu, Vit Kalousek, Jiri Rathousky and Thomas Bein pp 12605–12611 DOI: 10.1021/ja101810e Supporting Info

Characterization of Isolated Nitrogenase FeVco Aaron W. Fay, Michael A. Blank, Chi Chung Lee, Yilin Hu, Keith O. Hodgson, Britt Hedman and Markus W. Ribbe pp 12612–12618 DOI: 10.1021/ja1019657

Coaxial Heterogeneous Structure of TiO2 Nanotube Arrays with CdS as a Superthin Coating Synthesized via Modified Electrochemical Atomic Layer Deposition Wen Zhu, Xi Liu, Huiqiong Liu, Dali Tong, Junyou Yang and Jiangying Peng pp 12619–12626 DOI: 10.1021/ja1025112 Supporting Info

Synthesis, Reactions, and Electronic Properties of 16 π-Electron Octaisobutyltetraphenylporphyrin Yohsuke Yamamoto, Yusuke Hirata, Megumi Kodama, Torahiko Yamaguchi, Shiro Matsukawa, Kin-ya Akiba, Daisuke Hashizume, Fujiko Iwasaki, Atsuya Muranaka, Masanobu Uchiyama, Ping Chen, Karl M. Kadish and Nagao Kobayashi pp 12627–12638 DOI: 10.1021/ja102817a Supporting Info

Solvation Effects on S K-Edge XAS Spectra of Fe−S Proteins: Normal and Inverse Effects on WT and Mutant Rubredoxin Ning Sun, Abhishek Dey, Zhiguang Xiao, Anthony G. Wedd, Keith O. Hodgson, Britt Hedman and Edward I. Solomon pp 12639–12647 DOI: 10.1021/ja102807x Supporting Info

Pentagon-Fused Hollow Fullerene in C78 Family Retrieved by Chlorination Yuan-Zhi Tan, Jia Li, Ting Zhou, Yu-Qi Feng, Shui-Chao Lin, Xin Lu, Zhuang-Ping Zhan, Su-Yuan Xie, Rong-Bin Huang and Lan-Sun Zheng pp 12648–12652 DOI: 10.1021/ja102887t Supporting Info

Side-Chain Conformational Changes of Transcription Factor PhoB upon DNA Binding: A Population-Shift Mechanism Tsutomu Yamane, Hideyasu Okamura, Yoshifumi Nishimura, Akinori Kidera and Mitsunori Ikeguchi pp 12653–12659 DOI: 10.1021/ja103218x Supporting Info

Oxygen Superbases as Polar Binding Pockets in Nonpolar Solvents Lucie Duchkov, Aneta Kadlkov, Martin Kotora and Jana Roithov pp 12660–12667 DOI: 10.1021/ja103744f Supporting Info

Regenerable DNA-Functionalized Hydrogels for Ultrasensitive, Instrument-Free Mercury(II) Detection and Removal in Water Neeshma Dave, Michelle Y. Chan, Po-Jung Jimmy Huang, Brendan D. Smith and Juewen Liu pp 12668–12673 DOI: 10.1021/ja106098j Supporting Info

Pressure-Induced Decomposition of Indium Hydroxide Aleksander Gurlo, Dmytro Dzivenko, Miria Andrade, Ralf Riedel, Stefan Lauterbach and Hans-Joachim Kleebe pp 12674–12678 DOI: 10.1021/ja104278p

RNA Tetraloop Folding Reveals Tension between Backbone Restraints and Molecular Interactions Srividya Mohan, Chiaolong Hsiao, Jessica C. Bowman, Roger Wartell and Loren Dean Williams pp 12679–12689 DOI: 10.1021/ja104387k

Autonomous in Vitro Anticancer Drug Release from Mesoporous Silica Nanoparticles by pH-Sensitive Nanovalves Huan Meng, Min Xue, Tian Xia, Yan-Li Zhao, Fuyuhiko Tamanoi, J. Fraser Stoddart, Jeffrey I. Zink and Andre E. Nel pp 12690–12697 DOI: 10.1021/ja104501a Supporting Info

Exciton Fission and Charge Generation via Triplet Excitons in Pentacene/C60 Bilayers Akshay Rao, Mark W. B. Wilson, Justin M. Hodgkiss, Sebastian Albert-Seifried, Heinz Bssler and Richard H. Friend pp 12698–12703 DOI: 10.1021/ja1042462

Gold Nanoframes: Very High Surface Plasmon Fields and Excellent Near-Infrared Sensors Mahmoud A. Mahmoud and Mostafa A. El-Sayed pp 12704–12710 DOI: 10.1021/ja104532z Supporting Info

A Remote Arene-Binding Site on Prostate Specific Membrane Antigen Revealed by Antibody-Recruiting Small Molecules Andrew X. Zhang, Ryan P. Murelli, Cyril Barinka, Julien Michel, Alexandra Cocleaza, William L. Jorgensen, Jacek Lubkowski and David A. Spiegel pp 12711–12716 DOI: 10.1021/ja104591m Supporting Info

Self-Assembly of Supramolecular Fullerene Ribbons via Hydrogen-Bonding Interactions and Their Impact on Fullerene Electronic Interactions and Charge Carrier Mobility Cheng-Che Chu, Guillaume Raffy, Debdas Ray, Andr Del Guerzo, Brice Kauffmann, Guillaume Wantz, Lionel Hirsch and Dario M. Bassani pp 12717–12723 DOI: 10.1021/ja104750f Supporting Info

Tetramolecular DNA Quadruplexes in Solution: Insights into Structural Diversity and Cation Movement Primo ket and Janez Plavec pp 12724–12732 DOI: 10.1021/ja104889t Supporting Info

Genome-Based Characterization of Two Prenylation Steps in the Assembly of the Stephacidin and Notoamide Anticancer Agents in a Marine-Derived Aspergillus sp. Yousong Ding, Jeffrey R. de Wet, James Cavalcoli, Shengying Li, Thomas J. Greshock, Kenneth A. Miller, Jennifer M. Finefield, James D. Sunderhaus, Timothy J. McAfoos, Sachiko Tsukamoto, Robert M. Williams and David H. Sherman pp 12733–12740 DOI: 10.1021/ja1049302 Supporting Info

Mapping Solvation Dynamics at the Function Site of Flavodoxin in Three Redox States Chih-Wei Chang, Ting-Fang He, Lijun Guo, Jeffrey A. Stevens, Tanping Li, Lijuan Wang and Dongping Zhong pp 12741–12747 DOI: 10.1021/ja1050154

Understanding the Exceptional Hydrogen-Atom Donor Characteristics of Water in TiIII-Mediated Free-Radical Chemistry Miguel Paradas, Araceli G. Campaa, Tania Jimnez, Rafael Robles, J. Enrique Oltra, Elena Buuel, Jos Justicia, Diego J. Crdenas and Juan M. Cuerva pp 12748–12756 DOI: 10.1021/ja105670h Supporting Info

Shared Biosynthesis of the Saliniketals and Rifamycins in Salinispora arenicola is Controlled by the sare1259-Encoded Cytochrome P450 Micheal C. Wilson, Tobias A. M. Gulder, Taifo Mahmud and Bradley S. Moore pp 12757–12765 DOI: 10.1021/ja105891a Supporting Info

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls Kang-sang Lee, Adil R. Zhugralin and Amir H. Hoveyda p 12766 DOI: 10.1021/ja107037r

Issue 37

Energy Transfer Dynamics in Metal−Organic Frameworks Caleb A. Kent, Brian P. Mehl, Liqing Ma, John M. Papanikolas, Thomas J. Meyer, and Wenbin Lin pp 12767–12769 DOI: 10.1021/ja102804s Supporting Info

True Chemical Shift Correlation Maps: A TOCSY Experiment with Pure Shifts in Both Dimensions Gareth A. Morris, Juan A. Aguilar, Robert Evans, Stephan Haiber, and Mathias Nilsson pp 12770–12772 DOI: 10.1021/ja1039715 Supporting Info

A Metal−Organic Framework with a Covalently Prefabricated Porous Organic Linker Shashikala I. Swamy, John Bacsa, James T. A. Jones, Kyriakos C. Stylianou, Alexander Steiner, Lyndsey K. Ritchie, Tom Hasell, Jamie A. Gould, Andrea Laybourn, Yaroslav Z. Khimyak, Dave J. Adams, Matthew J. Rosseinsky, and Andrew I. Cooper pp 12773–12775 DOI: 10.1021/ja104083y Supporting Info

Ambient Pressure Dry-Gel Conversion Method for Zeolite MFI Synthesis Using Ionic Liquid and Microwave Heating Rui Cai, Yan Liu, Shuang Gu, and Yushan Yan pp 12776–12777 DOI: 10.1021/ja101649b Supporting Info

Columnar Self-Assembly of Cu2S Hexagonal Nanoplates Induced by Tin(IV)−X Complex as Inorganic Surface Ligand Xiaomin Li, Huaibin Shen, Jinzhong Niu, Sen Li, Yongguang Zhang, Hongzhe Wang, and Lin Song Li pp 12778–12779 DOI: 10.1021/ja103955s Supporting Info

Quantum-Dot-Decorated Robust Transductable Bioluminescent Nanocapsules Juanjuan Du, Changming Yu, Daocheng Pan, Jianmin Li, Wei Chen, Ming Yan, Tatiana Segura, and Yunfeng Lu pp 12780–12781 DOI: 10.1021/ja104299t Supporting Info

Molecular Seesaw: A Three-Way Motion and Motion-Induced Surface Modification Young Bin Kim, Soon Jung Jung, Young Hwan Min, and Sehun Kim pp 12782–12783 DOI: 10.1021/ja104475g Supporting Info

Ultrafast Vibrational Stark-Effect Spectroscopy: Exploring Charge-Transfer Reactions by Directly Monitoring the Solvation Shell Response Carlos R. Baiz and Kevin J. Kubarych pp 12784–12785 DOI: 10.1021/ja1043853 Supporting Info

Synthesis and Characterization of Tetraphenyl-21,23-dideazaporphyrin: The Best Evidence Yet That Porphyrins Really Are the [18]Annulenes of Nature Timothy D. Lash, Sarah A. Jones, and Gregory M. Ferrence pp 12786–12787 DOI: 10.1021/ja105146a Supporting Info

Pb2B5O9I: An Iodide Borate with Strong Second Harmonic Generation Yi-Zhi Huang, Li-Ming Wu, Xin-Tao Wu, Long-Hua Li, Ling Chen, and Yong-Fan Zhang pp 12788–12789 DOI: 10.1021/ja106066k Supporting Info

Efficient Macrocyclization Achieved via Conformational Control Using Intermolecular Noncovalent π-Cation/Arene Interactions Philippe Bolduc, Alexandre Jacques, and Shawn K. Collins pp 12790–12791 DOI: 10.1021/ja106053x Supporting Info

Label-Free Detection of DNA Hybridization Using Surface Enhanced Raman Spectroscopy Aoune Barhoumi and Naomi J. Halas pp 12792–12793 DOI: 10.1021/ja105678z Supporting Info

Modulating Heme Redox Potential through Protein-Induced Porphyrin Distortion Charles Olea, Jr., John Kuriyan, and Michael A. Marletta pp 12794–12795 DOI: 10.1021/ja106252b Supporting Info

A General and Efficient Cobalt(II)-Based Catalytic System for Highly Stereoselective Cyclopropanation of Alkenes with α-Cyanodiazoacetates Shifa Zhu, Xue Xu, Jason A. Perman, and X. Peter Zhang pp 12796–12799 DOI: 10.1021/ja1056246 Supporting Info

Pyranose Ring Transition State Is Derived from Cellobiohydrolase I Induced Conformational Stability and Glycosidic Bond Polarization Christopher B. Barnett, Karl A. Wilkinson, and Kevin J. Naidoo pp 12800–12803 DOI: 10.1021/ja103766w Supporting Info

Electron-Mediated CO Oxidation on the TiO2(110) Surface during Electronic Excitation Zhen Zhang and John T. Yates, Jr. pp 12804–12807 DOI: 10.1021/ja106207w

Stacks of Nucleic Acids as Molecular Wires: Direct Measurement of the Intermolecular Band Dispersion in Multilayer Guanine Assemblies Rainer Friedlein, Ying Wang, Antoine Fleurence, Fabio Bussolotti, Yoichi Ogata, and Yukiko Yamada-Takamura pp 12808–12810 DOI: 10.1021/ja104839d Supporting Info

Decomposition of Vibrational Shifts of Nitriles into Electrostatic and Hydrogen-Bonding Effects Aaron T. Fafarman, Paul A. Sigala, Daniel Herschlag, and Steven G. Boxer pp 12811–12813 DOI: 10.1021/ja104573b Supporting Info

Synthesis and Characterization of an Iron(IV) Ketimide Complex Richard A. Lewis, Guang Wu, and Trevor W. Hayton pp 12814–12816 DOI: 10.1021/ja104934n Supporting Info

Controlled and Chemoselective Reduction of Secondary Amides Guillaume Pelletier, William S. Bechara, and Andr B. Charette pp 12817–12819 DOI: 10.1021/ja105194s Supporting Info

Gold Nanofingers for Molecule Trapping and Detection Min Hu, Fung Suong Ou, Wei Wu, Ivan Naumov, Xuema Li, Alexander M. Bratkovsky, R. Stanley Williams, and Zhiyong Li pp 12820–12822 DOI: 10.1021/ja105248h Supporting Info

Palladium-Catalyzed Carbonylative Heck-Type Reactions of Alkyl Iodides Kayla S. Bloome and Erik J. Alexanian pp 12823–12825 DOI: 10.1021/ja1053913 Supporting Info

Nanostructured Gold Architectures Formed through High Pressure-Driven Sintering of Spherical Nanoparticle Arrays Huimeng Wu, Feng Bai, Zaicheng Sun, Raid E. Haddad, Daniel M. Boye, Zhongwu Wang, Jian Yu Huang, and Hongyou Fan pp 12826–12828 DOI: 10.1021/ja105255d Supporting Info

MRI Detection of VEGFR2 in Vivo Using a Low Molecular Weight Peptoid−(Gd)8-Dendron for Targeting Luis M. De Len-Rodrguez, Angelo Lubag, D. Gomika Udugamasooriya, Bettina Proneth, Rolf A. Brekken, Xiankai Sun, Thomas Kodadek, and A. Dean Sherry pp 12829–12831 DOI: 10.1021/ja105563a Supporting Info

Desymmetrization of meso-Cyclic Imides via Enantioselective Monohydrogenation Satoshi Takebayashi, Jeremy M. John, and Steven H. Bergens pp 12832–12834 DOI: 10.1021/ja105783u Supporting Info

Controlling a Structural Branch Point in Ergot Alkaloid Biosynthesis Johnathan Z. Cheng, Christine M. Coyle, Daniel G. Panaccione, and Sarah E. O’Connor pp 12835–12837 DOI: 10.1021/ja105785p Supporting Info

Flipping the Switch on Chloride Concentrations with a Light-Active Foldamer Yuran Hua and Amar H. Flood pp 12838–12840 DOI: 10.1021/ja105793c Supporting Info

Diastereoselective Synthesis of Bulky, Strongly Nucleophilic, and Configurationally Stable P-Stereogenic Tricyclic Phosphines David Gau, Ricardo Rodriguez, Tsuyoshi Kato, Nathalie Saffon-Merceron, and Antoine Baceiredo pp 12841–12843 DOI: 10.1021/ja1054912 Supporting Info

Highly Efficient Iridium-Catalyzed Asymmetric Hydrogenation of Unprotected β-Enamine Esters Guohua Hou, Wei Li, Miaofeng Ma, Xiaowei Zhang, and Xumu Zhang pp 12844–12846 DOI: 10.1021/ja105674y Supporting Info

Manganese Porphyrins Catalyze Selective C−H Bond Halogenations Wei Liu and John T. Groves pp 12847–12849 DOI: 10.1021/ja105548x Supporting Info

Pd-Catalyzed Oxidative Cross-Coupling of Perfluoroarenes with Aromatic Heterocycles Chun-Yang He, Shilu Fan, and Xingang Zhang pp 12850–12852 DOI: 10.1021/ja106046p Supporting Info

Michael Acceptor-Containing Coenzyme A Analogues As Inhibitors of the Atypical Coenzyme A Disulfide Reductase from Staphylococcus aureus Renier van der Westhuyzen and Erick Strauss pp 12853–12855 DOI: 10.1021/ja106204m Supporting Info

Conformational Control of Thymine Photodimerization in Single-Strand and Duplex DNA Containing Locked Nucleic Acid TT Steps Mahesh Hariharan, Martin McCullagh, George C. Schatz, and Frederick D. Lewis pp 12856–12858 DOI: 10.1021/ja106203q Supporting Info

C−C Coupling Reactivity of an Alkylgold(III) Fluoride Complex with Arylboronic Acids Neal P. Mankad and F. Dean Toste pp 12859–12861 DOI: 10.1021/ja106257n Supporting Info

Pd-Catalyzed Intermolecular ortho-C−H Amidation of Anilides by N-Nosyloxycarbamate Ka-Ho Ng, Albert S. C. Chan, and Wing-Yiu Yu pp 12862–12864 DOI: 10.1021/ja106364r Supporting Info

Rhodium-Catalyzed Enantioselective 1,6-Addition of Arylboronic Acids to Enynamides: Asymmetric Synthesis of Axially Chiral Allenylsilanes Takahiro Nishimura, Hiroki Makino, Makoto Nagaosa, and Tamio Hayashi pp 12865–12867 DOI: 10.1021/ja1066509 Supporting Info

Mechanical Tuning of Molecular Recognition To Discriminate the Single-Methyl-Group Difference between Thymine and Uracil Taizo Mori, Ken Okamoto, Hiroshi Endo, Jonathan P. Hill, Satoshi Shinoda, Miki Matsukura, Hiroshi Tsukube, Yasumasa Suzuki, Yasumasa Kanekiyo, and Katsuhiko Ariga pp 12868–12870 DOI: 10.1021/ja106653a Supporting Info

A New Class of Ligands for Aqueous, Lanthanide-Catalyzed, Enantioselective Mukaiyama Aldol Reactions Yujiang Mei, Prabani Dissanayake, and Matthew J. Allen pp 12871–12873 DOI: 10.1021/ja107197p Supporting Info

Nanomechanics of Lipid Bilayers: Heads or Tails? Sergi Garcia-Manyes, Lorena Redondo-Morata, Gerard Oncins, and Fausto Sanz pp 12874–12886 DOI: 10.1021/ja1002185 Supporting Info

Mechanism of Selective Halogenation by SyrB2: A Computational Study Tomasz Borowski, Holger Noack, Mariusz Rado, Konrad Zych, and Per E. M. Siegbahn pp 12887–12898 DOI: 10.1021/ja101877a Supporting Info

NMR-Spectroscopic and Solid-State Investigations of Cometal-Free Asymmetric Conjugate Addition: A Dinuclear Paracyclophaneimine Zinc Methyl Complex S. Ay, R. E. Ziegert, H. Zhang, M. Nieger, K. Rissanen, K. Fink, A. Kubas, R. M. Gschwind, and S. Brse pp 12899–12905 DOI: 10.1021/ja1032502 Supporting Info

Activation of Dinitrogen by Solid and Liquid Aluminum Nanoclusters: A Combined Experimental and Theoretical Study Baopeng Cao, Anne K. Starace, Oscar H. Judd, Indrani Bhattacharyya, Martin F. Jarrold, Jos M. Lpez, and Andrs Aguado pp 12906–12918 DOI: 10.1021/ja103356r Supporting Info

Acceptor Energy Level Control of Charge Photogeneration in Organic Donor/Acceptor Blends Safa Shoaee, Tracey M. Clarke, Chun Huang, Stephen Barlow, Seth R. Marder, Martin Heeney, Iain McCulloch, and James R. Durrant pp 12919–12926 DOI: 10.1021/ja1042726 Supporting Info

CO and O2 Binding to Pseudo-tetradentate Ligand−Copper(I) Complexes with a Variable N-Donor Moiety: Kinetic/Thermodynamic Investigation Reveals Ligand-Induced Changes in Reaction Mechanism Heather R. Lucas, Gerald J. Meyer, and Kenneth D. Karlin pp 12927–12940 DOI: 10.1021/ja104107q Supporting Info

Solution Structure of Polytheonamide B, a Highly Cytotoxic Nonribosomal Polypeptide from Marine Sponge Toshiyuki Hamada, Shigeki Matsunaga, Masako Fujiwara, Kenichi Fujita, Hiroshi Hirota, Roland Schmucki, Peter Gntert, and Nobuhiro Fusetani pp 12941–12945 DOI: 10.1021/ja104616z Supporting Info

Assigning Stereochemistry to Single Diastereoisomers by GIAO NMR Calculation: The DP4 Probability Steven G. Smith and Jonathan M. Goodman pp 12946–12959 DOI: 10.1021/ja105035r Supporting Info

Enzymatic Ring-Opening Mechanism of Verdoheme by the Heme Oxygenase: A Combined X-ray Crystallography and QM/MM Study Wenzhen Lai, Hui Chen, Toshitaka Matsui, Kohei Omori, Masaki Unno, Masao Ikeda-Saito, and Sason Shaik pp 12960–12970 DOI: 10.1021/ja104674q Supporting Info

Synthesis and Characterization of ERI-Type UZM-12 Zeolites and Their Methanol-to-Olefin Performance Joo Hyuck Lee, Min Bum Park, Jun Kyu Lee, Hyung-Ki Min, Mee Kyung Song, and Suk Bong Hong pp 12971–12982 DOI: 10.1021/ja105185r Supporting Info

[MnIII4LnIII4] Calix[4]arene Clusters as Enhanced Magnetic Coolers and Molecular Magnets Georgios Karotsis, Stuart Kennedy, Simon J. Teat, Christine M. Beavers, Drew A. Fowler, Juan J. Morales, Marco Evangelisti, Scott J. Dalgarno, and Euan K. Brechin pp 12983–12990 DOI: 10.1021/ja104848m Supporting Info

Scrutinizing the Chemical Nature and Photophysics of an Expanded Hemiporphyrazine: The Special Case of [30]Trithia-2,3,5,10,12,13,15,20,22,23,25,30-dodecaazahexaphyrin Olga N. Trukhina, M. Salom Rodrguez-Morgade, Silke Wolfrum, Esmeralda Caballero, Natalia Snejko, Elena A. Danilova, Enrique Gutirrez-Puebla, Mikhail K. Islyaikin, Dirk M. Guldi, and Toms Torres pp 12991–12999 DOI: 10.1021/ja104577d Supporting Info

Phase Separation and Suppression of the Structural and Magnetic Transitions in Superconducting Doped Iron Tellurides, Fe1+xTe1−ySy Pawel Zajdel, Ping-Yen Hsieh, Efrain E. Rodriguez, Nicholas P. Butch, Jeff D. Magill, Johnpierre Paglione, Peter Zavalij, Matthew R. Suchomel, and Mark A. Green pp 13000–13007 DOI: 10.1021/ja105279p Supporting Info

Mechanism and Activity of Photocatalytic Oxygen Evolution on Titania Anatase in Aqueous Surroundings Ye-Fei Li, Zhi-Pan Liu, LuLu Liu, and Weiguo Gao pp 13008–13015 DOI: 10.1021/ja105340b Supporting Info

pH-Operated Nanopistons on the Surfaces of Mesoporous Silica Nanoparticles Yan-Li Zhao, Zongxi Li, Sanaz Kabehie, Youssry Y. Botros, J. Fraser Stoddart, and Jeffrey I. Zink pp 13016–13025 DOI: 10.1021/ja105371u

Solution Structure of the 128 kDa Enzyme I Dimer from Escherichia coli and Its 146 kDa Complex with HPr Using Residual Dipolar Couplings and Small- and Wide-Angle X-ray Scattering Charles D. Schwieters, Jeong-Yong Suh, Alexander Grishaev, Rodolfo Ghirlando, Yuki Takayama, and G. Marius Clore pp 13026–13045 DOI: 10.1021/ja105485b Supporting Info

Charge-Transfer Energy in the Water−Hydrogen Molecular Aggregate Revealed by Molecular-Beam Scattering Experiments, Charge Displacement Analysis, and ab Initio Calculations Leonardo Belpassi, Michael L. Reca, Francesco Tarantelli, Luiz F. Roncaratti, Fernando Pirani, David Cappelletti, Alexandre Faure, and Yohann Scribano pp 13046–13058 DOI: 10.1021/ja1056642 Supporting Info

Resolving the Au-Adatom-Alkanethiolate Bonding Site on Au(111) with Domain Boundary Imaging Using High-Resolution Scanning Tunneling Microscopy Fangsen Li, Lin Tang, Wancheng Zhou, and Quanmin Guo pp 13059–13063 DOI: 10.1021/ja1056517 Supporting Info

Mechanistic Study of Gold(I)-Catalyzed Intermolecular Hydroamination of Allenes Z. Jane Wang, Diego Benitez, Ekaterina Tkatchouk, William A. Goddard III, and F. Dean Toste pp 13064–13071 DOI: 10.1021/ja105530q Supporting Info

Strong Micro-Dielectric Environment Effect on the Band Gaps of (n,m)Single-Walled Carbon Nanotubes Yasuhiko Hirana, Yasuhiko Tanaka, Yasuro Niidome, and Naotoshi Nakashima pp 13072–13077 DOI: 10.1021/ja105980a Supporting Info

Stereoselective Cyclization of Functionalized 1,n-Diynes Mediated by [X−Y] Reagents [X−Y = R3Si−SnR′3 or (R2N)2B−SnR′3]: Synthesis and Properties of Atropisomeric 1,3-Dienes Ramakrishna Reddy Singidi, Amanda M. Kutney, Judith C. Gallucci, and T. V. RajanBabu pp 13078–13087 DOI: 10.1021/ja105939v Supporting Info

Furan Hydrogenation over Pt(111) and Pt(100) Single-Crystal Surfaces and Pt Nanoparticles from 1 to 7 nm: A Kinetic and Sum Frequency Generation Vibrational Spectroscopy Study Christopher J. Kliewer, Cesar Aliaga, Marco Bieri, Wenyu Huang, Chia-Kuang Tsung, Jennifer B. Wood, Kyriakos Komvopoulos, and Gabor A. Somorjai pp 13088–13095 DOI: 10.1021/ja105800z

Advanced Nanomaterials Sarbajit Banerjee, Ph.D. p 13096 DOI: 10.1021/ja1073867

Issue 38

Size-Dependent Oxygen Activation Efficiency over Pdn/TiO2(110) for the CO Oxidation Reaction William E. Kaden, William A. Kunkel, Matt D. Kane, F. Sloan Roberts, and Scott L. Anderson pp 13097–13099 DOI: 10.1021/ja103347v Supporting Info

Controlled Diastereo- and Enantioselection in a Catalytic Asymmetric Aziridination Aman A. Desai and William D. Wulff pp 13100–13103 DOI: 10.1021/ja1038648 Supporting Info

How the Binding of Substrates to a Chiral Polyborate Counterion Governs Diastereoselection in an Aziridination Reaction: H-Bonds in Equipoise Mathew J. Vetticatt, Aman A. Desai, and William D. Wulff pp 13104–13107 DOI: 10.1021/ja103863j Supporting Info

Nucleophilic Scandium Carbene Complexes Marie Fustier, Xavier F. Le Goff, Pascal Le Floch, and Nicolas Mzailles pp 13108–13110 DOI: 10.1021/ja103220s Supporting Info

Fluorinated Diaminocyclopentanes as Chiral Sensitive NMR Probes of RNA Structure Roba Moumn, Morgane Pasco, Elise Prost, Thomas Lecourt, Laurent Micouin, and Carine Tisn pp 13111–13113 DOI: 10.1021/ja1037885 Supporting Info

A Highly Selective Low-Background Fluorescent Imaging Agent for Nitric Oxide Youjun Yang, Stephanie K. Seidlits, Michelle M. Adams, Vincent M. Lynch, Christine E. Schmidt, Eric V. Anslyn, and Jason B. Shear pp 13114–13116 DOI: 10.1021/ja1040013 Supporting Info

Nickel-Catalyzed Alkenylative Cross-Coupling Reaction of Alkyl Sulfides Kentaro Ishizuka, Hirofumi Seike, Takuji Hatakeyama, and Masaharu Nakamura pp 13117–13119 DOI: 10.1021/ja104155f Supporting Info

Engineering the Redox Potential over a Wide Range within a New Class of FeS Proteins John A. Zuris, Danny A. Halim, Andrea R. Conlan, Edward C. Abresch, Rachel Nechushtai, Mark L. Paddock, and Patricia A. Jennings pp 13120–13122 DOI: 10.1021/ja103920k Supporting Info

Temperature and Light Induced Bistability in a Co3[Os(CN)6]2 6H2O Prussian Blue Analog Carolina Avendano, Matthew G. Hilfiger, Andrey Prosvirin, Codi Sanders, Darryl Stepien, and Kim R. Dunbar pp 13123–13125 DOI: 10.1021/ja1041513 Supporting Info

A Bacteriophage-Based Platform for Rapid Trace Detection of Proteases Petr apek, Killeen S. Kirkconnell, and Tobin J. Dickerson pp 13126–13128 DOI: 10.1021/ja104572f Supporting Info

Interplay between Secondary and Tertiary Structure Formation in Protein Folding Cooperativity Tristan Bereau, Michael Bachmann, and Markus Deserno pp 13129–13131 DOI: 10.1021/ja105206w Supporting Info

Free Energy Landscapes of Iduronic Acid and Related Monosaccharides Benedict M. Sattelle, Steen U. Hansen, John Gardiner, and Andrew Almond pp 13132–13134 DOI: 10.1021/ja1054143 Supporting Info

Chiral Ice Chromatography Taiki Shamoto, Yuiko Tasaki, and Tetsuo Okada pp 13135–13137 DOI: 10.1021/ja1055214 Supporting Info

Comprehensive Solid-State NMR Characterization of Electronic Structure in Ditechnetium Heptoxide Herman Cho, Wibe A. de Jong, Alfred P. Sattelberger, Frdric Poineau, and Kenneth R. Czerwinski pp 13138–13140 DOI: 10.1021/ja105687j Supporting Info

Glutathione-Stabilized Magic-Number Silver Cluster Compounds Santosh Kumar, Michael D. Bolan, and Terry P. Bigioni pp 13141–13143 DOI: 10.1021/ja105836b Supporting Info

Dynamics of Biocatalytic Microengines Mediated by Variable Friction Control Samuel Sanchez, Alexander A. Solovev, Yongfeng Mei, and Oliver G. Schmidt pp 13144–13145 DOI: 10.1021/ja104362r Supporting Info

Mechanism of Racemization of Chiral Alcohols Mediated by 16-Electron Ruthenium Complexes Johann Bosson, Albert Poater, Luigi Cavallo, and Steven P. Nolan pp 13146–13149 DOI: 10.1021/ja104961s Supporting Info

A Ditetrylyne as a π-Electron Donor: Synthesis and Characterization of [AgAr′GeGeAr′]+SbF6− and [Ag2Ar′GeGe(F)Ar′]+SbF6− (Ar′ = C6H3-2,6(C6H3-2,6-Pri2)2) Xinping Wang, Yang Peng, Marilyn M. Olmstead, Hkon Hope, and Philip P. Power pp 13150–13151 DOI: 10.1021/ja1051236 Supporting Info

Copper-Catalyzed Regio- and Enantioselective Synthesis of Chiral Enol Acetates and β-Substituted Aldehydes Martn Faans-Mastral and Ben L. Feringa pp 13152–13153 DOI: 10.1021/ja105585y Supporting Info

Nanostructured Ceria−Silver Synthesized in a One-Pot Redox Reaction Catalyzes Carbon Oxidation Tomoyuki Kayama, Kiyoshi Yamazaki, and Hirofumi Shinjoh pp 13154–13155 DOI: 10.1021/ja105403x Supporting Info

A Lead(II)-Driven DNA Molecular Device for Turn-On Fluorescence Detection of Lead(II) Ion with High Selectivity and Sensitivity Tao Li, Shaojun Dong, and Erkang Wang pp 13156–13157 DOI: 10.1021/ja105849m Supporting Info

Oxidative Template for Conducting Polymer Nanoclips Zhen Liu, Xinyu Zhang, Selcuk Poyraz, Sumedh P. Surwade, and Sanjeev K. Manohar pp 13158–13159 DOI: 10.1021/ja105966c Supporting Info

Development of a New s-Tetrazine-Based Copolymer for Efficient Solar Cells Zhao Li, Jianfu Ding, Naiheng Song, Jianping Lu, and Ye Tao pp 13160–13161 DOI: 10.1021/ja106052e Supporting Info

Top-Down Fabrication of α-Fe2O3 Single-Crystal Nanodiscs and Microparticles with Tunable Porosity for Largely Improved Lithium Storage Properties Jun Song Chen, Ting Zhu, Xiao Hua Yang, Hua Gui Yang, and Xiong Wen Lou pp 13162–13164 DOI: 10.1021/ja1060438 Supporting Info

Observing Iridium Oxide (IrOx) Single Nanoparticle Collisions at Ultramicroelectrodes Seong Jung Kwon, Fu-Ren F. Fan, and Allen J. Bard pp 13165–13167 DOI: 10.1021/ja106054c Supporting Info

Rhodium-Catalyzed Asymmetric Arylation of N-Tosyl Ketimines Ryo Shintani, Momotaro Takeda, Takaoki Tsuji, and Tamio Hayashi pp 13168–13169 DOI: 10.1021/ja106114q Supporting Info

Connecting Energy Landscapes with Experimental Rates for Aminoacyl-tRNA Accommodation in the Ribosome Paul C. Whitford, Jos N. Onuchic, and Karissa Y. Sanbonmatsu pp 13170–13171 DOI: 10.1021/ja1061399 Supporting Info

Hydroxyapatite Foam as a Catalyst for Formaldehyde Combustion at Room Temperature Jing Xu, Tim White, Ping Li, Chongheng He, and Yi-Fan Han pp 13172–13173 DOI: 10.1021/ja1058923 Supporting Info

Conducting Polymer Electrodes Printed on Hydrogel Soichiro Sekine, Yuichiro Ido, Takeo Miyake, Kuniaki Nagamine, and Matsuhiko Nishizawa pp 13174–13175 DOI: 10.1021/ja1062357 Supporting Info

Oligo(4-aminopiperidine-4-carboxylic acid): An Unusual Basic Oligopeptide with an Acid-Induced Helical Conformation Joon-il Cho, Masahiro Tanaka, Sota Sato, Kazushi Kinbara, and Takuzo Aida pp 13176–13178 DOI: 10.1021/ja106118w Supporting Info

N-Heterocyclic Carbene-Catalyzed Conjugate Additions of Alcohols Eric M. Phillips, Matthias Riedrich, and Karl A. Scheidt pp 13179–13181 DOI: 10.1021/ja1061196 Supporting Info

High-Throughput Screening of Dendrimer-Binding Drugs Libo Zhao, Qinglin Wu, Yiyun Cheng, Jiahai Zhang, Jihui Wu, and Tongwen Xu pp 13182–13184 DOI: 10.1021/ja106128u Supporting Info

Selective Complexation of K+ and Na+ in Simple Polarizable Ion-Ligating Systems David L. Bostick and Charles L. Brooks, III pp 13185–13187 DOI: 10.1021/ja106197e Supporting Info

Attachment of Calcium Oxalate Monohydrate Crystals on Patterned Surfaces of Proteins and Lipid Bilayers Zhihua An, Soolim Lee, Harry Oppenheimer, Jeffrey A. Wesson, and Michael D. Ward pp 13188–13190 DOI: 10.1021/ja106202y Supporting Info

Stereospecific Suzuki−Miyaura Coupling of Chiral α-(Acylamino)benzylboronic Esters with Inversion of Configuration Toshimichi Ohmura, Tomotsugu Awano, and Michinori Suginome pp 13191–13193 DOI: 10.1021/ja106632j Supporting Info

Direct C−H Arylation of Electron-Deficient Heterocycles with Arylboronic Acids Ian B. Seiple, Shun Su, Rodrigo A. Rodriguez, Ryan Gianatassio, Yuta Fujiwara, Adam L. Sobel, and Phil S. Baran pp 13194–13196 DOI: 10.1021/ja1066459 Supporting Info

Uncoupling Nitrogenase: Catalytic Reduction of Hydrazine to Ammonia by a MoFe Protein in the Absence of Fe Protein-ATP Karamatullah Danyal, Boyd S. Inglet, Kylie A. Vincent, Brett M. Barney, Brian M. Hoffman, Fraser A. Armstrong, Dennis R. Dean, and Lance C. Seefeldt pp 13197–13199 DOI: 10.1021/ja1067178

Pyridine Activation via Copper(I)-Catalyzed Annulation toward Indolizines Jos Barluenga, Giacomo Lonzi, Lorena Riesgo, Luis A. Lpez, and Miguel Toms pp 13200–13202 DOI: 10.1021/ja106751t Supporting Info

Cyano Diels−Alder and Cyano Ene Reactions. Applications in a Formal [2 + 2 + 2] Cycloaddition Strategy for the Synthesis of Pyridines Takeo Sakai and Rick L. Danheiser pp 13203–13205 DOI: 10.1021/ja106901u Supporting Info

Self-Assembly of Thienylenevinylene Molecular Wires to Semiconducting Gels with Doped Metallic Conductivity Seelam Prasanthkumar, Anesh Gopal, and Ayyappanpillai Ajayaghosh pp 13206–13207 DOI: 10.1021/ja1068195 Supporting Info

The Stabilizing Effect of Silicate on Biogenic and Synthetic Amorphous Calcium Carbonate Assaf Gal, Steve Weiner, and Lia Addadi pp 13208–13211 DOI: 10.1021/ja106883c Supporting Info

Experimental Characterization and Computational Study of Unique C,N-Chelated Lithium Dianions Jocelyn M. Gruver, Scott P. West, David B. Collum, and Richmond Sarpong pp 13212–13213 DOI: 10.1021/ja106852n Supporting Info

A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation Jessica Y. Wu, Benjamin N. Stanzl, and Tobias Ritter pp 13214–13216 DOI: 10.1021/ja106853y Supporting Info

A Direct Intramolecular C−H Amination Reaction Cocatalyzed by Copper(II) and Iron(III) as Part of an Efficient Route for the Synthesis of Pyrido[1,2-a]benzimidazoles from N-Aryl-2-aminopyridines Honggen Wang, Yong Wang, Changlan Peng, Jiancun Zhang, and Qiang Zhu pp 13217–13219 DOI: 10.1021/ja1067993 Supporting Info

Electrochemical Quartz Crystal Microbalance (EQCM) Studies of Ions and Solvents Insertion into Highly Porous Activated Carbons Mikhael D. Levi, Naomi Levy, Sergey Sigalov, Gregory Salitra, Doron Aurbach, and Joachim Maier pp 13220–13222 DOI: 10.1021/ja104391g Supporting Info

In-Water Truly Monodisperse Aggregation of Gear-Shaped Amphiphiles Based on Hydrophobic Surface Engineering Shuichi Hiraoka, Takashi Nakamura, Motoo Shiro, and Mitsuhiko Shionoya pp 13223–13225 DOI: 10.1021/ja1069135 Supporting Info

Total Synthesis and Absolute Stereochemical Assignment of (−)-Communesin F Zhiwei Zuo, Weiqing Xie, and Dawei Ma pp 13226–13228 DOI: 10.1021/ja106739g Supporting Info

cis-Dihydroxylation of Alkenes with Oxone Catalyzed by Iron Complexes of a Macrocyclic Tetraaza Ligand and Reaction Mechanism by ESI-MS Spectrometry and DFT Calculations Toby Wai-Shan Chow, Ella Lai-Ming Wong, Zhen Guo, Yungen Liu, Jie-Sheng Huang, and Chi-Ming Che pp 13229–13239 DOI: 10.1021/ja100967g Supporting Info

Structural Comparisons of Apo- and Metalated Three-Stranded Coiled Coils Clarify Metal Binding Determinants in Thiolate Containing Designed Peptides Saumen Chakraborty, Debra S. Touw, Anna F. A. Peacock, Jeanne Stuckey, and Vincent L. Pecoraro pp 13240–13250 DOI: 10.1021/ja101812c Supporting Info

Potentials of Mean Force and Permeabilities for Carbon Dioxide, Ammonia, and Water Flux across a Rhesus Protein Channel and Lipid Membranes Jochen S. Hub, Fritz K. Winkler, Mike Merrick, and Bert L. de Groot pp 13251–13263 DOI: 10.1021/ja102133x Supporting Info

Incorporation of Antifreeze Proteins into Polymer Coatings Using Site-Selective Bioconjugation Aaron P. Esser-Kahn, Vivian Trang, and Matthew B. Francis pp 13264–13269 DOI: 10.1021/ja103038p Supporting Info

In Vitro and in Vivo Studies of FePt Nanoparticles for Dual Modal CT/MRI Molecular Imaging Shang-Wei Chou, Yu-Hong Shau, Ping-Ching Wu, Yu-Sang Yang, Dar-Bin Shieh, and Chia-Chun Chen pp 13270–13278 DOI: 10.1021/ja1035013 Supporting Info

Synthesis, Electronic Structure, and Reactivity of Strained Nickel-, Palladium-, and Platinum-Bridged [1]Ferrocenophanes Inmaculada Matas, George R. Whittell, Benjamin M. Partridge, Jason P. Holland, Mairi F. Haddow, Jennifer C. Green, and Ian Manners pp 13279–13289 DOI: 10.1021/ja103367e Supporting Info

Rational Design of FRET-Based Ratiometric Chemosensors for in Vitro and in Cell Fluorescence Analyses of Nucleoside Polyphosphates Yasutaka Kurishita, Takahiro Kohira, Akio Ojida, and Itaru Hamachi pp 13290–13299 DOI: 10.1021/ja103615z Supporting Info

Transmembrane Structures for Alzheimer’s Aβ1−42 Oligomers Birgit Strodel, Jason W. L. Lee, Christopher S. Whittleston, and David J. Wales pp 13300–13312 DOI: 10.1021/ja103725c Supporting Info

Torsion Potential in Polydiacetylene: Accurate Computations on Oligomers Extrapolated to the Polymer Limit John S. Sears, Ronald R. Chance, and Jean-Luc Brdas pp 13313–13319 DOI: 10.1021/ja103769j Supporting Info

Design, Synthesis, and Crystal Structures of 6-Alkylidene-2′-Substituted Penicillanic Acid Sulfones as Potent Inhibitors of Acinetobacter baumannii OXA-24 Carbapenemase German Bou, Elena Santillana, Anjaneyulu Sheri, Alejandro Beceiro, Jared M. Sampson, Matthew Kalp, Christopher R. Bethel, Anne M. Distler, Sarah M. Drawz, Sundar Ram Reddy Pagadala, Focco van den Akker, Robert A. Bonomo, Antonio Romero, and John D. Buynak pp 13320–13331 DOI: 10.1021/ja104092z Supporting Info

Catalytic Dehydrocoupling/Dehydrogenation of N-Methylamine-Borane and Ammonia-Borane: Synthesis and Characterization of High Molecular Weight Polyaminoboranes Anne Staubitz, Matthew E. Sloan, Alasdair P. M. Robertson, Anja Friedrich, Sven Schneider, Paul J. Gates, Jrn Schmedt auf der Gnne, and Ian Manners pp 13332–13345 DOI: 10.1021/ja104607y Supporting Info

Structure-Independent Analysis of the Breadth of the Positional Distribution of Disordered Groups in Macromolecules from Order Parameters for Long, Variable-Length Vectors Using NMR Paramagnetic Relaxation Enhancement Junji Iwahara and G. Marius Clore pp 13346–13356 DOI: 10.1021/ja1048187

Remarkable Reactions and Intermediates in Titanocene(IV) Chemistry: Migratory Insertion Reactions of 2,2-Disubstituted-1-alkenes, Intramolecular 1,5-σ Bond Metathesis via ε-Agostic Interactions, and a Rare Example of a β-Agostic Alkyltitanocene Complex Francoise Sauriol, Jessica F. Sonnenberg, Sarah J. Chadder, Alexandre F. Dunlop-Brire, Michael C. Baird, and Peter H. M. Budzelaar pp 13357–13370 DOI: 10.1021/ja104526v Supporting Info

Glycan Array on Aluminum Oxide-Coated Glass Slides through Phosphonate Chemistry Shih-Huang Chang, Jeng-Liang Han, Susan Y. Tseng, Hsin-Yu Lee, Chin-Wei Lin, Yu-Chen Lin, Wen-Yih Jeng, Andrew H.-J. Wang, Chung-Yi Wu, and Chi-Huey Wong pp 13371–13380 DOI: 10.1021/ja1046523 Supporting Info

Dopant-Induced Shape Evolution of Colloidal Nanocrystals: The Case of Zinc Oxide Yefeng Yang, Yizheng Jin, Haiping He, Qingling Wang, Yao Tu, Huanming Lu, and Zhizhen Ye pp 13381–13394 DOI: 10.1021/ja103956p Supporting Info

Uranium Pyrophosphate/Methylenediphosphonate Polyoxometalate Cage Clusters Jie Ling, Jie Qiu, Ginger E. Sigmon, Matthew Ward, Jennifer E. S. Szymanowski, and Peter C. Burns pp 13395–13402 DOI: 10.1021/ja1048219 Supporting Info

DNA Pol λs Extraordinary Ability To Stabilize Misaligned DNA Meredith C. Foley, Victoria A. Padow, and Tamar Schlick pp 13403–13416 DOI: 10.1021/ja1049687 Supporting Info

Interplay of Phenol and Isopropyl Isomerism in Propofol from Broadband Chirped-Pulse Microwave Spectroscopy Alberto Lesarri, Steven T. Shipman, Justin L. Neill, Gordon G. Brown, Richard D. Suenram, Lu Kang, Walther Caminati, and Brooks H. Pate pp 13417–13424 DOI: 10.1021/ja104950w Supporting Info

Transition State Analysis of Thymidine Hydrolysis by Human Thymidine Phosphorylase Phillip A. Schwartz, Mathew J. Vetticatt, and Vern L. Schramm pp 13425–13433 DOI: 10.1021/ja105041j Supporting Info

Thiourea as a Template for Photodimerization of Azastilbenes Balakrishna R. Bhogala, Burjor Captain, Anand Parthasarathy, and V. Ramamurthy pp 13434–13442 DOI: 10.1021/ja105166d Supporting Info

Functionalization of Metallabenzenes through Nucleophilic Aromatic Substitution of Hydrogen George R. Clark, Lauren A. Ferguson, Amy E. McIntosh, Tilo Shnel, and L. James Wright pp 13443–13452 DOI: 10.1021/ja105239t Supporting Info

Electrochemistry and Electrogenerated Chemiluminescence of Dithienylbenzothiadiazole Derivative. Differential Reactivity of Donor and Acceptor Groups and Simulations of Radical Cation−Anion and Dication−Radical Anion Annihilations Mei Shen, Joaqun Rodrguez-Lpez, Ju Huang, Quan Liu, Xu-Hui Zhu, and Allen J. Bard pp 13453–13461 DOI: 10.1021/ja105282u

Relating n-Pentane Isomerization Activity to the Tungsten Surface Density of WOx/ZrO2 Nikolaos Soultanidis, Wu Zhou, Antonis C. Psarras, Alejandro J. Gonzalez, Eleni F. Iliopoulou, Christopher J. Kiely, Israel E. Wachs, and Michael S. Wong pp 13462–13471 DOI: 10.1021/ja105519y Supporting Info

Unusual, Solvent Viscosity-Controlled Tautomerism and Photophysics: Meso-Alkylated Porphycenes Michał Gil, Jacek Dobkowski, Gabriela Wiosna-Sałyga, Natalia Urbaska, Piotr Fita, Czesław Radzewicz, Marek Pietraszkiewicz, Paweł Borowicz, David Marks, Max Glasbeek, and Jacek Waluk pp 13472–13485 DOI: 10.1021/ja105353m Supporting Info

Structures of Metallosupramolecular Coordination Assemblies Can Be Obtained by Ion Mobility Spectrometry−Mass Spectrometry Erin R. Brocker, Stanley E. Anderson, Brian H. Northrop, Peter J. Stang, and Michael T. Bowers pp 13486–13494 DOI: 10.1021/ja105702y Supporting Info

Folding Catalysis by Transient Coordination of Zn2+ to the Cu Ligands of the ALS-Associated Enzyme Cu/Zn Superoxide Dismutase 1 Lina Leinartait, Kadhirvel Saraboji, Anna Nordlund, Derek T. Logan, and Mikael Oliveberg pp 13495–13504 DOI: 10.1021/ja1057136 Supporting Info

Computational Mutagenesis Studies of Hammerhead Ribozyme Catalysis Tai-Sung Lee and Darrin M. York pp 13505–13518 DOI: 10.1021/ja105956u Supporting Info

Charge Localization in Isolated Mixed-Valence Complexes: An STM and Theoretical Study Yuhui Lu, Rebecca Quardokus, Craig S. Lent, Frederic Justaud, Claude Lapinte, and S. Alex Kandel pp 13519–13524 DOI: 10.1021/ja105958p

Rescue of K12G Triosephosphate Isomerase by Ammonium Cations: The Reaction of an Enzyme in Pieces Maybelle K. Go, Tina L. Amyes, and John P. Richard pp 13525–13532 DOI: 10.1021/ja106104h

Asymmetric Total Synthesis of Vindorosine, Vindoline, and Key Vinblastine Analogues Yoshikazu Sasaki, Daisuke Kato, and Dale L. Boger pp 13533–13544 DOI: 10.1021/ja106284s Supporting Info

Molecular Behavior of DNA Origami in Higher-Order Self-Assembly Zhe Li, Minghui Liu, Lei Wang, Jeanette Nangreave, Hao Yan, and Yan Liu pp 13545–13552 DOI: 10.1021/ja106292x Supporting Info

Conformational Space of Flexible Biological Macromolecules from Average Data Ivano Bertini, Andrea Giachetti, Claudio Luchinat, Giacomo Parigi, Maxim V. Petoukhov, Roberta Pierattelli, Enrico Ravera, and Dmitri I. Svergun pp 13553–13558 DOI: 10.1021/ja1063923 Supporting Info

Reactions of Boron Amidinates with CO2 and CO and Other Small Molecules Meghan A. Dureen and Douglas W. Stephan pp 13559–13568 DOI: 10.1021/ja1064153 Supporting Info

Issue 39

Comparison of Rh−OCH3 and Rh−CH2OH Bond Dissociation Energetics from Methanol C−H and O−H Bond Reactions with Rhodium(II) Porphyrins Sounak Sarkar, Shan Li, and Bradford B. Wayland pp 13569–13571 DOI: 10.1021/ja1035489 Supporting Info

Selective Recognition and Extraction of the Uranyl Ion Aaron C. Sather, Orion B. Berryman, and Julius Rebek, Jr. pp 13572–13574 DOI: 10.1021/ja1035607 Supporting Info

Genetically Encoded Initiator for Polymer Growth from Proteins Jennifer C. Peeler, Bradley F. Woodman, Saadyah Averick, Shigeki J. Miyake-Stoner, Audrey L. Stokes, Kenneth R. Hess, Krzysztof Matyjaszewski, and Ryan A. Mehl pp 13575–13577 DOI: 10.1021/ja104493d Supporting Info

Tunability in Polyatomic Molecule Diffusion through Tunneling versus Pacing Zhihai Cheng, Eric S. Chu, Dezheng Sun, Daeho Kim, Yeming Zhu, MiaoMiao Luo, Greg Pawin, Kin L. Wong, Ki-Young Kwon, Robert Carp, Michael Marsella, and Ludwig Bartels pp 13578–13581 DOI: 10.1021/ja1027343 Supporting Info

Active Site Threonine Facilitates Proton Transfer during Dioxygen Activation at the Diiron Center of Toluene/o-Xylene Monooxygenase Hydroxylase Woon Ju Song, Michael S. McCormick, Rachel K. Behan, Matthew H. Sazinsky, Wei Jiang, Jeffery Lin, Carsten Krebs, and Stephen J. Lippard pp 13582–13585 DOI: 10.1021/ja1063795 Supporting Info

Robust Light Emission from Cyclic Alkylaminoluciferin Substrates for Firefly Luciferase Gadarla Randheer Reddy, Walter C. Thompson, and Stephen C. Miller pp 13586–13587 DOI: 10.1021/ja104525m Supporting Info

C−H Activation of Acetonitrile at Nickel: Ligand Flip and Conversion of N-Bound Acetonitrile into a C-Bound Cyanomethyl Ligand Anna Magdalena Oertel, Vincent Ritleng, Michael J. Chetcuti, and Luis F. Veiros pp 13588–13589 DOI: 10.1021/ja105368p Supporting Info

Pd-Catalyzed Three-Component Coupling of N-Tosylhydrazone, Terminal Alkyne, and Aryl Halide Lei Zhou, Fei Ye, Yan Zhang, and Jianbo Wang pp 13590–13591 DOI: 10.1021/ja105762n Supporting Info

Post-Synthesis Carbon Doping of Individual Multiwalled Boron Nitride Nanotubes via Electron-Beam Irradiation Xianlong Wei, Ming-Sheng Wang, Yoshio Bando, and Dmitri Golberg pp 13592–13593 DOI: 10.1021/ja106134s Supporting Info

Carbon−Carbon Bond Activation by 1,1-Carboboration of Internal Alkynes Chao Chen, Gerald Kehr, Roland Frhlich, and Gerhard Erker pp 13594–13595 DOI: 10.1021/ja106365j Supporting Info

New Lithium Iron Pyrophosphate as 3.5 V Class Cathode Material for Lithium Ion Battery Shin-ichi Nishimura, Megumi Nakamura, Ryuichi Natsui, and Atsuo Yamada pp 13596–13597 DOI: 10.1021/ja106297a Supporting Info

Direct Observation of Transient Ostwald Crystallization Ordering from Racemic Serine Solutions Victoria J. Hall and Garth J. Simpson pp 13598–13599 DOI: 10.1021/ja106728c Supporting Info

Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis Hui-Wen Shih, Mark N. Vander Wal, Rebecca L. Grange, and David W. C. MacMillan pp 13600–13603 DOI: 10.1021/ja106593m Supporting Info

Analysis of Intact and Dissected Fungal Polyketide Synthase-Nonribosomal Peptide Synthetase in Vitro and in Saccharomyces cerevisiae Wei Xu, Xiaolu Cai, Michael E. Jung, and Yi Tang pp 13604–13607 DOI: 10.1021/ja107084d Supporting Info

Asymmetric Total Synthesis of Caribenol A Lian-Zhu Liu, Jin-Chun Han, Guo-Zong Yue, Chuang-Chuang Li, and Zhen Yang pp 13608–13609 DOI: 10.1021/ja106585n Supporting Info

Total Synthesis of Chivosazole F Tobias Brodmann, Dominic Janssen, and Markus Kalesse pp 13610–13611 DOI: 10.1021/ja107290s Supporting Info

A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation Yelena Gorlin and Thomas F. Jaramillo pp 13612–13614 DOI: 10.1021/ja104587v Supporting Info

Chemoselective Attachment of Small Molecule Effector Functionality to Human Adenoviruses Facilitates Gene Delivery to Cancer Cells Partha Sarathi Banerjee, Philomena Ostapchuk, Patrick Hearing, and Isaac Carrico pp 13615–13617 DOI: 10.1021/ja104547x Supporting Info

Yb3O(OH)6Cl·2H2O: An Anion-Exchangeable Hydroxide with a Cationic Inorganic Framework Structure Helen V. Goulding, Sarah E. Hulse, William Clegg, Ross W. Harrington, Helen Y. Playford, Richard I. Walton, and Andrew M. Fogg pp 13618–13620 DOI: 10.1021/ja104636x Supporting Info

Alkene Hydroboration: Hot Intermediates That React While They Are Cooling David R. Glowacki, C. H. Liang, Stephen P. Marsden, Jeremy N. Harvey, and Michael J. Pilling pp 13621–13623 DOI: 10.1021/ja105100f Supporting Info

Merging Nucleophilic and Hydrogen Bonding Catalysis: An Anion Binding Approach to the Kinetic Resolution of Propargylic Amines Eric G. Klauber, Chandra Kanta De, Tejas K. Shah, and Daniel Seidel pp 13624–13626 DOI: 10.1021/ja105337h Supporting Info

Guest Escape and Uptake in Nonporous Crystals of a Gold(I) Macrocycle Andrea Dek, Tnde Tunyogi, Zoltn Kroly, Szilvia Klbert, and Gbor Plinks pp 13627–13629 DOI: 10.1021/ja105458e Supporting Info

Dynamic Presentation of Immobilized Ligands Regulated through Biomolecular Recognition Bo Liu, Yang Liu, Jeremiah J. Riesberg, and Wei Shen pp 13630–13632 DOI: 10.1021/ja1054669 Supporting Info

Enantioenriched Synthesis of C1-Symmetric BINOLs: Iron-Catalyzed Cross-Coupling of 2-Naphthols and Some Mechanistic Insight Hiromichi Egami, Kenji Matsumoto, Takuya Oguma, Takashi Kunisu, and Tsutomu Katsuki pp 13633–13635 DOI: 10.1021/ja105442m Supporting Info

Autoprogrammed Synthesis of Triple-Layered Au@Pd@Pt Core−Shell Nanoparticles Consisting of a Au@Pd Bimetallic Core and Nanoporous Pt Shell Liang Wang and Yusuke Yamauchi pp 13636–13638 DOI: 10.1021/ja105640p Supporting Info

Electric Field Destabilizes Noncovalent Protein−DNA Complexes Michael U. Musheev, Yuri Filiptsev, Victor Okhonin, and Sergey N. Krylov pp 13639–13641 DOI: 10.1021/ja105754h Supporting Info

Catalytic Enantioselective Alkylative Dearomatization−Annulation: Total Synthesis and Absolute Configuration Assignment of Hyperibone K Ji Qi, Aaron B. Beeler, Qiang Zhang, and John A. Porco, Jr. pp 13642–13644 DOI: 10.1021/ja1057828 Supporting Info

Zeolitic Imidazolate Framework-8 Nanocrystal Coated Capillary for Molecular Sieving of Branched Alkanes from Linear Alkanes along with High-Resolution Chromatographic Separation of Linear Alkanes Na Chang, Zhi-Yuan Gu, and Xiu-Ping Yan pp 13645–13647 DOI: 10.1021/ja1058229 Supporting Info

Affinity Purification of Multifunctional Polymer Nanoparticles Yu Hoshino, Walter W. Haberaecker III, Takashi Kodama, Zhiyang Zeng, Yoshio Okahata, and Kenneth J. Shea pp 13648–13650 DOI: 10.1021/ja1058982 Supporting Info

Structure−Activity Relationship in Olefin Polymerization Catalysis: Is Entropy the Key? Gianluca Ciancaleoni, Natascia Fraldi, Peter H. M. Budzelaar, Vincenzo Busico, Roberta Cipullo, and Alceo Macchioni pp 13651–13653 DOI: 10.1021/ja105965x Supporting Info

π−π Interaction-Induced Vertical Alignment of Silica Mesochannels Templated by a Discotic Lyotropic Liquid Crystal Mitsuo Hara, Shusaku Nagano, and Takahiro Seki pp 13654–13656 DOI: 10.1021/ja106220j Supporting Info

A New in Situ Optical Microscope with Single Atomic Layer Resolution for Observation of Electrochemical Dissolution of Au(111) Rui Wen, Abhishek Lahiri, Mukkannan Azhagurajan, Shin-ichiro Kobayashi, and Kingo Itaya pp 13657–13659 DOI: 10.1021/ja106231x Supporting Info

Single Molecule Experiments Visualizing Adsorbed Polyelectrolyte Molecules in the Full Range of Mono- and Divalent Counterion Concentrations Yuri Roiter, Oleksandr Trotsenko, Viktor Tokarev, and Sergiy Minko pp 13660–13662 DOI: 10.1021/ja106065g Supporting Info

Benzothiazinones: Prodrugs That Covalently Modify the Decaprenylphosphoryl-β-d-ribose 2′-epimerase DprE1 of Mycobacterium tuberculosis Claudia Trefzer, Monica Rengifo-Gonzalez, Marlon J. Hinner, Patricia Schneider, Vadim Makarov, Stewart T. Cole, and Kai Johnsson pp 13663–13665 DOI: 10.1021/ja106357w Supporting Info

Selective C-4 Alkylation of Pyridine by Nickel/Lewis Acid Catalysis Yoshiaki Nakao, Yuuya Yamada, Natsuko Kashihara, and Tamejiro Hiyama pp 13666–13668 DOI: 10.1021/ja106514b Supporting Info

Large Polyoxotitanate Clusters: Well-Defined Models for Pure-Phase TiO2 Structures and Surfaces Jason B. Benedict, Renata Freindorf, Elzbieta Trzop, Jeffrey Cogswell, and Philip Coppens pp 13669–13671 DOI: 10.1021/ja106436y Supporting Info

ATP- and Iron−Protein-Independent Activation of Nitrogenase Catalysis by Light Lauren E. Roth, Joey C. Nguyen, and F. Akif Tezcan pp 13672–13674 DOI: 10.1021/ja1071866 Supporting Info

Multistimuli Two-Color Luminescence Switching via Different Slip-Stacking of Highly Fluorescent Molecular Sheets Seong-Jun Yoon, Jong Won Chung, Johannes Gierschner, Kil Suk Kim, Moon-Gun Choi, Dongho Kim, and Soo Young Park pp 13675–13683 DOI: 10.1021/ja1044665 Supporting Info

A Reduced β-Diketiminato-Ligated Ni3H4 Unit Catalyzing H/D Exchange Stefan Pfirrmann, Christian Limberg, Christian Herwig, Christina Knispel, Beatrice Braun, Eckhard Bill, and Reinhard Stösser pp 13684–13691 DOI: 10.1021/ja106266v Supporting Info

Structure and Valency of a Cobalt−Phosphate Water Oxidation Catalyst Determined by in Situ X-ray Spectroscopy Matthew W. Kanan, Junko Yano, Yogesh Surendranath, Mircea Dinc, Vittal K. Yachandra, and Daniel G. Nocera pp 13692–13701 DOI: 10.1021/ja1023767 Supporting Info

Understanding the Effect of Magnesium Ion Concentration on the Catalytic Activity of Ribonuclease H through Computation: Does a Third Metal Binding Site Modulate Endonuclease Catalysis? Ming-Hsun Ho, Marco De Vivo, Matteo Dal Peraro, and Michael L. Klein pp 13702–13712 DOI: 10.1021/ja102933y Supporting Info

Elliptical Structure of Phospholipid Bilayer Nanodiscs Encapsulated by Scaffold Proteins: Casting the Roles of the Lipids and the Protein Nicholas Skar-Gislinge, Jens Bæk Simonsen, Kell Mortensen, Robert Feidenhans’l, Stephen G. Sligar, Birger Lindberg Møller, Thomas Bjørnholm, and Lise Arleth pp 13713–13722 DOI: 10.1021/ja1030613 Supporting Info

Synthesis, Crystal Structure, and Properties of MgxB50C8 or Mgx(B12)4(CBC)2(C2)2 (x = 2.4−4) Volker Adasch, Melanie Schroeder, Dominik Kotzott, Thilo Ludwig, Natascha Vojteer, and Harald Hillebrecht pp 13723–13732 DOI: 10.1021/ja102659d Supporting Info

Oxygen Reduction Catalyzed by a Fluorinated Tetraphenylporphyrin Free Base at Liquid/Liquid Interfaces Imren Hatay, Bin Su, Manuel A. Mndez, Clmence Corminboeuf, Tony Khoury, Claude P. Gros, Mlanie Bourdillon, Michel Meyer, Jean-Michel Barbe, Mustafa Ersoz, Stanislav Záli, Zdenk Samec, and Hubert H. Girault pp 13733–13741 DOI: 10.1021/ja103460p Supporting Info

Seedless Growth of Sub-10 nm Germanium Nanowires Richard G. Hobbs, Sven Barth, Nikolay Petkov, Michaela Zirngast, Christoph Marschner, Michael A. Morris, and Justin D. Holmes pp 13742–13749 DOI: 10.1021/ja1035368 Supporting Info

Clay Minerals Mediate Folding and Regioselective Interactions of RNA: A Large-Scale Atomistic Simulation Study Jacob B. Swadling, Peter V. Coveney, and H. Christopher Greenwell pp 13750–13764 DOI: 10.1021/ja104106y Supporting Info

Atomic-Resolution Three-Dimensional Structure of HET-s(218−289) Amyloid Fibrils by Solid-State NMR Spectroscopy Hlne Van Melckebeke, Christian Wasmer, Adam Lange, Eiso AB, Antoine Loquet, Anja Bckmann, and Beat H. Meier pp 13765–13775 DOI: 10.1021/ja104213j Supporting Info

A Unifying Model for the Operation of Light-Emitting Electrochemical Cells Stephan van Reenen, Piotr Matyba, Andrzej Dzwilewski, Ren A. J. Janssen, Ludvig Edman, and Martijn Kemerink pp 13776–13781 DOI: 10.1021/ja1045555 Supporting Info

Multistep N2 Breathing in the Metal−Organic Framework Co(1,4-benzenedipyrazolate) Fabrice Salles, Guillaume Maurin, Christian Serre, Philip L. Llewellyn, Christina Knfel, Hye Jin Choi, Yaroslav Filinchuk, Laetitia Oliviero, Alexandre Vimont, Jeffrey R. Long, and Grard Frey pp 13782–13788 DOI: 10.1021/ja104357r Supporting Info

Structure and Bonding of Isoleptic Coinage Metal (Cu, Ag, Au) Dimethylaminonitrenes in the Gas Phase Alexey Fedorov, Erik P. A. Couzijn, Natalia S. Nagornova, Oleg V. Boyarkin, Thomas R. Rizzo, and Peter Chen pp 13789–13798 DOI: 10.1021/ja104649k Supporting Info

The Pt-Catalyzed Ethylene Hydroamination by Aniline: A Computational Investigation of the Catalytic Cycle Pavel A. Dub and Rinaldo Poli pp 13799–13812 DOI: 10.1021/ja1051654 Supporting Info

Intramolecular Hydroamination of Unbiased and Functionalized Primary Aminoalkenes Catalyzed by a Rhodium Aminophosphine Complex Lisa D. Julian and John F. Hartwig pp 13813–13822 DOI: 10.1021/ja1052126 Supporting Info

Xe3OF3+, a Precursor to a Noble-Gas Nitrate; Syntheses and Structural Characterizations of FXeONO2, XeF2·HNO3, and XeF2·N2O4 Matthew D. Moran, David S. Brock, Hlne P. A. Mercier, and Gary J. Schrobilgen pp 13823–13839 DOI: 10.1021/ja105618w Supporting Info

Mixed Low-Dimensional Nanomaterial: 2D Ultranarrow MoS2 Inorganic Nanoribbons Encapsulated in Quasi-1D Carbon Nanotubes Zhiyong Wang, Hong Li, Zheng Liu, Zujin Shi, Jing Lu, Kazu Suenaga, Soon-Kil Joung, Toshiya Okazaki, Zhennan Gu, Jing Zhou, Zhengxiang Gao, Guangping Li, Stefano Sanvito, Enge Wang, and Sumio Iijima pp 13840–13847 DOI: 10.1021/ja1058026 Supporting Info

ortho-Phenylenes: Unusual Conjugated Oligomers with a Surprisingly Long Effective Conjugation Length Jian He, Jason L. Crase, Shriya H. Wadumethrige, Khushabu Thakur, Lin Dai, Shouzhong Zou, Rajendra Rathore, and C. Scott Hartley pp 13848–13857 DOI: 10.1021/ja106050s Supporting Info

Unstitching the Nanoscopic Mystery of Zeolite Crystal Formation Rhea Brent, Pablo Cubillas, Sam M. Stevens, Kim E. Jelfs, Ayako Umemura, James T. Gebbie, Ben Slater, Osamu Terasaki, Mark A. Holden, and Michael W. Anderson pp 13858–13868 DOI: 10.1021/ja105593v Supporting Info

Binuclear Initiators for the Telechelic Synthesis of Elastomeric Polyolefins Robert C. Coffin, Yanika Schneider, Edward J. Kramer, and Guillermo C. Bazan pp 13869–13878 DOI: 10.1021/ja1056938 Supporting Info

Crystallographic Characterization of 12-Helical Secondary Structure in β-Peptides Containing Side Chain Groups Soo Hyuk Choi, Ilia A. Guzei, Lara C. Spencer, and Samuel H. Gellman pp 13879–13885 DOI: 10.1021/ja1062532 Supporting Info

Intercluster Exchange Pathways in Polymer-Chain Molecular Magnets Cu(hfac)2LR Unveiled by Electron Paramagnetic Resonance Matvey V. Fedin, Sergey L. Veber, Ksenia Yu. Maryunina, Galina V. Romanenko, Elizaveta A. Suturina, Nina P. Gritsan, Renad Z. Sagdeev, Victor I. Ovcharenko, and Elena G. Bagryanskaya pp 13886–13891 DOI: 10.1021/ja105862w Supporting Info

Density Functional Theory Calculations on the Mononuclear Non-Heme Iron Active Site of Hmd Hydrogenase: Role of the Internal Ligands in Tuning External Ligand Binding and Driving H2 Heterolysis Abhishek Dey pp 13892–13901 DOI: 10.1021/ja1041918 Supporting Info

Latent Porosity in Potassium Dodecafluoro-closo-dodecaborate(2−). Structures and Rapid Room Temperature Interconversions of Crystalline K2B12F12, K2(H2O)2B12F12, and K2(H2O)4B12F12 in the Presence of Water Vapor Dmitry V. Peryshkov, Alexey A. Popov, and Steven H. Strauss pp 13902–13913 DOI: 10.1021/ja105522d Supporting Info

Experimental and Theoretical Comparison of the O K-Edge Nonresonant Inelastic X-ray Scattering and X-ray Absorption Spectra of NaReO4 Joseph A. Bradley, Ping Yang, Enrique R. Batista, Kevin S. Boland, Carol J. Burns, David L. Clark, Steven D. Conradson, Stosh A. Kozimor, Richard L. Martin, Gerald T. Seidler, Brian L. Scott, David K. Shuh, Tolek Tyliszczak, Marianne P. Wilkerson, and Laura E. Wolfsberg pp 13914–13921 DOI: 10.1021/ja1040978 Supporting Info

Synthesis of P-Stereogenic Compounds via Kinetic Deprotonation and Dynamic Thermodynamic Resolution of Phosphine Sulfides: Opposite Sense of Induction Using (−)-Sparteine Jonathan J. Gammon, Viktoria H. Gessner, Greg R. Barker, Johan Granander, Adrian C. Whitwood, Carsten Strohmann, Peter O’Brien, and Brian Kelly pp 13922–13927 DOI: 10.1021/ja1060966 Supporting Info

Thermo- and Solvent-Responsive Polymer Complex Created from Supramolecular Complexation between a Helix-Forming Polysaccharide and a Cationic Polythiophene Tomohiro Shiraki, Arnab Dawn, Youichi Tsuchiya, and Seiji Shinkai pp 13928–13935 DOI: 10.1021/ja1067349 Supporting Info

Synthesis and Characterization of a Cyclobutane Duocarmycin Derivative Incorporating the 1,2,10,11-Tetrahydro-9H-cyclobuta[c]benzo[e]indol-4-one (CbBI) Alkylation Subunit James P. Lajiness and Dale L. Boger pp 13936–13940 DOI: 10.1021/ja106986f Supporting Info

Linker-Directed Vertex Desymmetrization for the Production of Coordination Polymers with High Porosity Jennifer K. Schnobrich, Olivier Lebel, Katie A. Cychosz, Anne Dailly, Antek G. Wong-Foy, and Adam J. Matzger pp 13941–13948 DOI: 10.1021/ja107423k Supporting Info

Asymmetric 1,4-Dihydroxylation of 1,3-Dienes by Catalytic Enantioselective Diboration Heather E. Burks, Laura T. Kliman, and James P. Morken p 13949 DOI: 10.1021/ja1072542 Supporting Info

Pt-Catalyzed Enantioselective Diboration of Terminal Alkenes with B2(pin)2 Laura T. Kliman, Scott N. Mlynarski, and James P. Morken p 13949 DOI: 10.1021/ja107255h Supporting Info

Phosphorus Heterocycles II J. Derek Woollins p 13950 DOI: 10.1021/ja107961j

Catalytic Asymmetric Synthesis, 3rd ed David E. Bergbreiter p 13950 DOI: 10.1021/ja107734c

Issue 40

Fluorescent Chemosensor for Detection and Quantitation of Carbon Dioxide Gas Yang Liu, Youhong Tang, Nikolay N. Barashkov, Irina S. Irgibaeva, Jacky W. Y. Lam, Rongrong Hu, Dinara Birimzhanova, Yong Yu, and Ben Zhong Tang pp 13951–13953 DOI: 10.1021/ja103947j Supporting Info

Untying Knots in Proteins Joanna I. Sułkowska, Piotr Sułkowski, Piotr Szymczak, and Marek Cieplak pp 13954–13956 DOI: 10.1021/ja102441z Supporting Info

Functionalizable Collagen Model Peptides Roman S. Erdmann and Helma Wennemers pp 13957–13959 DOI: 10.1021/ja103392t Supporting Info

Gadolinium Doped Europium Sulfide Srotoswini Kar, William L. Boncher, Daniel Olszewski, Norman Dollahon, Richard Ash, and Sarah L. Stoll pp 13960–13962 DOI: 10.1021/ja104791x Supporting Info

Tuning Electron Transfer Rates via Systematic Shifts in the Acceptor State Density Using Size-Selected ZnO Colloids Adam S. Huss, Andrew Bierbaum, Raghu Chitta, Darren J. Ceckanowicz, Kent R. Mann, Wayne L. Gladfelter, and David A. Blank pp 13963–13965 DOI: 10.1021/ja104482t Supporting Info

Induced Biosynthesis of Cryptic Polyketide Metabolites in a Burkholderia thailandensis Quorum Sensing Mutant Keishi Ishida, Thorger Lincke, Swantje Behnken, and Christian Hertweck pp 13966–13968 DOI: 10.1021/ja105003g Supporting Info

Cationic Alkylaluminum-Complexed Zirconocene Hydrides as Participants in Olefin Polymerization Catalysis Steven M. Baldwin, John E. Bercaw, and Hans H. Brintzinger pp 13969–13971 DOI: 10.1021/ja105040r Supporting Info

Shape-Controlled Synthesis of Single-Crystalline Nanopillar Arrays by Template-Assisted Vapor−Liquid−Solid Process Onur Ergen, Daniel J. Ruebusch, Hui Fang, Asghar A. Rathore, Rehan Kapadia, Zhiyong Fan, Kuniharu Takei, Arash Jamshidi, Ming Wu, and Ali Javey pp 13972–13974 DOI: 10.1021/ja1052413 Supporting Info

Four-Coordinate, Trigonal Pyramidal Pt(II) and Pd(II) Complexes Charlene Tsay, Neal P. Mankad, and Jonas C. Peters pp 13975–13977 DOI: 10.1021/ja105284p Supporting Info

Mn3O4−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang, Li-Feng Cui, Yuan Yang, Hernan Sanchez Casalongue, Joshua Tucker Robinson, Yongye Liang, Yi Cui, and Hongjie Dai pp 13978–13980 DOI: 10.1021/ja105296a Supporting Info

A Highly Selective and General Palladium Catalyst for the Oxidative Heck Reaction of Electronically Nonbiased Olefins Erik W. Werner and Matthew S. Sigman pp 13981–13983 DOI: 10.1021/ja1060998 Supporting Info

High Resolution Measurement of Methyl 13Cm−13C and 1Hm−13Cm Residual Dipolar Couplings in Large Proteins Chenyun Guo, Raquel Godoy-Ruiz, and Vitali Tugarinov pp 13984–13987 DOI: 10.1021/ja1041435 Supporting Info

High-Yield Singlet Fission in a Zeaxanthin Aggregate Observed by Picosecond Resonance Raman Spectroscopy Chen Wang and Michael J. Tauber pp 13988–13991 DOI: 10.1021/ja102851m Supporting Info

A Versatile Photochromic Dithienylethene-Containing β-Diketonate Ligand: Near-Infrared Photochromic Behavior and Photoswitchable Luminescence Properties upon Incorporation of a Boron(III) Center Chun-Ting Poon, Wai Han Lam, Hok-Lai Wong, and Vivian Wing-Wah Yam pp 13992–13993 DOI: 10.1021/ja105537j Supporting Info

Predominant (6,5) Single-Walled Carbon Nanotube Growth on a Copper-Promoted Iron Catalyst Maoshuai He, Alexander I. Chernov, Pavel V. Fedotov, Elena D. Obraztsova, Jani Sainio, Emma Rikkinen, Hua Jiang, Zhen Zhu, Ying Tian, Esko I. Kauppinen, Marita Niemel, and A. Outi I. Krause pp 13994–13996 DOI: 10.1021/ja106609y Supporting Info

Direct Carbon−Carbon Bond Formation via Reductive Soft Enolization: A Kinetically Controlled syn-Aldol Addition of α-Halo Thioesters and Enolizable Aldehydes Scott J. Sauer, Michelle R. Garnsey, and Don M. Coltart pp 13997–13999 DOI: 10.1021/ja1057407 Supporting Info

Synthesis of Poly(3-alkylthiophene)-block-poly(arylisocyanide): Two Sequential, Mechanistically Distinct Polymerizations Using a Single Catalyst Zong-Quan Wu, Robert J. Ono, Zheng Chen, and Christopher W. Bielawski pp 14000–14001 DOI: 10.1021/ja106999q Supporting Info

A Responsive Europium(III) Chelate That Provides a Direct Readout of pH by MRI Yunkou Wu, Todd C. Soesbe, Garry E. Kiefer, Piyu Zhao, and A. Dean Sherry pp 14002–14003 DOI: 10.1021/ja106018n Supporting Info

A Coordination Cage with an Adaptable Cavity Size Sebastian Mirtschin, Adam Slabon-Turski, Rosario Scopelliti, Aldrik H. Velders, and Kay Severin pp 14004–14005 DOI: 10.1021/ja1063789 Supporting Info

Palladium-Catalyzed Intermolecular Decarboxylative Coupling of 2-Phenylbenzoic Acids with Alkynes via C−H and C−C Bond Activation Congyang Wang, Souvik Rakshit, and Frank Glorius pp 14006–14008 DOI: 10.1021/ja106130r Supporting Info

Addressable Terminally Linked DNA−CNT Nanowires Yossi Weizmann, David M. Chenoweth, and Timothy M. Swager pp 14009–14011 DOI: 10.1021/ja106352y Supporting Info

Concave Cubic Gold Nanocrystals with High-Index Facets Jian Zhang, Mark R. Langille, Michelle L. Personick, Ke Zhang, Shuyou Li, and Chad A. Mirkin pp 14012–14014 DOI: 10.1021/ja106394k Supporting Info

The Structure of Formaldehyde-Inhibited Xanthine Oxidase Determined by 35 GHz 2H ENDOR Spectroscopy Muralidharan Shanmugam, Bo Zhang, Rebecca L. McNaughton, R. Adam Kinney, Russ Hille, and Brian M. Hoffman pp 14015–14017 DOI: 10.1021/ja106432h Supporting Info

Metallic Corner Atoms in Gold Clusters Supported on Rutile Are the Dominant Active Site during Water−Gas Shift Catalysis W. Damion Williams, Mayank Shekhar, Wen-Sheng Lee, Vincent Kispersky, W. Nicholas Delgass, Fabio H. Ribeiro, Seung Min Kim, Eric A. Stach, Jeffrey T. Miller, and Lawrence F. Allard pp 14018–14020 DOI: 10.1021/ja1064262 Supporting Info

Total Synthesis of (+)-Korupensamine B via an Atropselective Intermolecular Biaryl Coupling Shenlin Huang, Tue B. Petersen, and Bruce H. Lipshutz pp 14021–14023 DOI: 10.1021/ja1065202 Supporting Info

Stimuli-Responsive Smart Gels Realized via Modular Protein Design Tijana Z. Grove, Chinedum O. Osuji, Jason D. Forster, Eric R. Dufresne, and Lynne Regan pp 14024–14026 DOI: 10.1021/ja106619w Supporting Info

Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands Richard I. McDonald, Gene W. Wong, Ram P. Neupane, Shannon S. Stahl, and Clark R. Landis pp 14027–14029 DOI: 10.1021/ja106674n Supporting Info

Reversible O−O Bond Cleavage and Formation between Mn(IV)-Peroxo and Mn(V)-Oxo Corroles Sun Hee Kim, Hyejin Park, Mi Sook Seo, Minoru Kubo, Takashi Ogura, Jan Klajn, Daniel T. Gryko, Joan Selverstone Valentine, and Wonwoo Nam pp 14030–14032 DOI: 10.1021/ja1066465 Supporting Info

Expeditious Synthesis and Assembly of Sub-100 nm Hollow Spherical Gold Nanoparticle Superstructures Chengyi Song, Gongpu Zhao, Peijun Zhang, and Nathaniel L. Rosi pp 14033–14035 DOI: 10.1021/ja106833g Supporting Info

Real-Time Investigations of Pt(111) Surface Transformations in Sulfuric Acid Solutions Bjrn Braunschweig, Prabuddha Mukherjee, Dana D. Dlott, and Andrzej Wieckowski pp 14036–14038 DOI: 10.1021/ja106618z Supporting Info

Efficient Covalent Modification of a Carbon Surface: Use of a Silyl Protecting Group To Form an Active Monolayer Yann R. Leroux, Hui Fei, Jean-Marc Nol, Clment Roux, and Philippe Hapiot pp 14039–14041 DOI: 10.1021/ja106971x Supporting Info

Cleavage and Reorganization of Zr−C/Si−C Bonds Leading to Zr/Si−N Organometallic and Heterocyclic Compounds Shaoguang Zhang, Wen-Xiong Zhang, Jing Zhao, and Zhenfeng Xi pp 14042–14045 DOI: 10.1021/ja1074932 Supporting Info

Facile Access to Tetravalent Cerium Compounds: One-Electron Oxidation Using Iodine(III) Reagents Peter Drse, Alan R. Crozier, Samira Lashkari, Jochen Gottfriedsen, Steffen Blaurock, Cristian G. Hrib, Ccilia Maichle-Mssmer, Christoph Schdle, Reiner Anwander, and Frank T. Edelmann pp 14046–14047 DOI: 10.1021/ja107494h Supporting Info

Synthesis of Heterocycles via Pd-Ligand Controlled Cyclization of 2-Chloro-N-(2-vinyl)aniline: Preparation of Carbazoles, Indoles, Dibenzazepines, and Acridines Dmitry Tsvelikhovsky and Stephen L. Buchwald pp 14048–14051 DOI: 10.1021/ja107511g Supporting Info

Total Synthesis of (+)-Perophoramidine and Determination of the Absolute Configuration Haoxing Wu, Fei Xue, Xue Xiao, and Yong Qin pp 14052–14054 DOI: 10.1021/ja1070043 Supporting Info

Facile Proton Conduction via Ordered Water Molecules in a Phosphonate Metal−Organic Framework Jared M. Taylor, Roger K. Mah, Igor L. Moudrakovski, Christopher I. Ratcliffe, Ramanathan Vaidhyanathan, and George K. H. Shimizu pp 14055–14057 DOI: 10.1021/ja107035w Supporting Info

A Pyrrolyl-Based Triazolophane: A Macrocyclic Receptor With CH and NH Donor Groups That Exhibits a Preference for Pyrophosphate Anions Jonathan L. Sessler, Jiajia Cai, Han-Yuan Gong, Xiaoping Yang, Jonathan F. Arambula, and Benjamin P. Hay pp 14058–14060 DOI: 10.1021/ja107098r Supporting Info

An N-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl2 Torahiko Yamaguchi, Akira Sekiguchi, and Matthias Driess pp 14061–14063 DOI: 10.1021/ja107160g Supporting Info

Concise Total Synthesis of the Potent Translation and Cell Migration Inhibitor Lactimidomycin Kevin Micoine and Alois Frstner pp 14064–14066 DOI: 10.1021/ja107141p Supporting Info

Synthesis of Graphene Aerogel with High Electrical Conductivity Marcus A. Worsley, Peter J. Pauzauskie, Tammy Y. Olson, Juergen Biener, Joe H. Satcher, Jr., and Theodore F. Baumann pp 14067–14069 DOI: 10.1021/ja1072299 Supporting Info

Gold-Catalyzed Highly Regioselective Oxidation of C−C Triple Bonds without Acid Additives: Propargyl Moieties as Masked α,β-Unsaturated Carbonyls Biao Lu, Chaoqun Li, and Liming Zhang pp 14070–14072 DOI: 10.1021/ja1072614 Supporting Info

A New Palladium Precatalyst Allows for the Fast Suzuki−Miyaura Coupling Reactions of Unstable Polyfluorophenyl and 2-Heteroaryl Boronic Acids Tom Kinzel, Yong Zhang, and Stephen L. Buchwald pp 14073–14075 DOI: 10.1021/ja1073799 Supporting Info

Palladium-Catalyzed Conversion of Aryl and Vinyl Triflates to Bromides and Chlorides Xiaoqiang Shen, Alan M. Hyde, and Stephen L. Buchwald pp 14076–14078 DOI: 10.1021/ja107481a Supporting Info

Oxygen Gas Sensing by Luminescence Quenching in Crystals of Cu(xantphos)(phen)+ Complexes Conor S. Smith, Charles W. Branham, Brian J. Marquardt, and Kent R. Mann pp 14079–14085 DOI: 10.1021/ja103112m Supporting Info

IR Spectroscopy of Molecular Ions by Nonthermal Ion Ejection from Helium Nanodroplets Szymon Smolarek, Nils B. Brauer, Wybren J. Buma, and Marcel Drabbels pp 14086–14091 DOI: 10.1021/ja1034655 Supporting Info

Bimetallic Reductive Elimination from Dinuclear Pd(III) Complexes David C. Powers, Diego Benitez, Ekaterina Tkatchouk, William A. Goddard, III, and Tobias Ritter pp 14092–14103 DOI: 10.1021/ja1036644 Supporting Info

Planar to Linear Structural Transition in Small Boron−Carbon Mixed Clusters: CxB5−x− (x = 1−5) Lei-Ming Wang, Boris B. Averkiev, Jordan A. Ramilowski, Wei Huang, Lai-Sheng Wang, and Alexander I. Boldyrev pp 14104–14112 DOI: 10.1021/ja103846q Supporting Info

Reversible Dispersion and Release of Carbon Nanotubes Using Foldable Oligomers Zengxing Zhang, Yanke Che, Ronald A. Smaldone, Miao Xu, Benjamin R. Bunes, Jeffrey S. Moore, and Ling Zang pp 14113–14117 DOI: 10.1021/ja104105n Supporting Info

A {Fe(NO)3}10 Trinitrosyliron Complex Stabilized by an N-Heterocyclic Carbene and the Cationic and Neutral {Fe(NO)2}9/10 Products of Its NO Release Chung-Hung Hsieh and Marcetta Y. Darensbourg pp 14118–14125 DOI: 10.1021/ja104135x Supporting Info

Metallacarboranes: Toward Promising Hydrogen Storage Metal Organic Frameworks Abhishek K. Singh, Arta Sadrzadeh, and Boris I. Yakobson pp 14126–14129 DOI: 10.1021/ja104544s Supporting Info

Local Current Mapping and Patterning of Reduced Graphene Oxide Jeffrey M. Mativetsky, Emanuele Treossi, Emanuele Orgiu, Manuela Melucci, Giulio Paolo Veronese, Paolo Samor, and Vincenzo Palermo pp 14130–14136 DOI: 10.1021/ja104567f Supporting Info

Ligand-Accelerated C−H Activation Reactions: Evidence for a Switch of Mechanism Keary M. Engle, Dong-Hui Wang, and Jin-Quan Yu pp 14137–14151 DOI: 10.1021/ja105044s Supporting Info

Spatially and Size Selective Synthesis of Fe-Based Nanoparticles on Ordered Mesoporous Supports as Highly Active and Stable Catalysts for Ammonia Decomposition An-Hui Lu, Joerg-Joachim Nitz, Massimiliano Comotti, Claudia Weidenthaler, Klaus Schlichte, Christian W. Lehmann, Osamu Terasaki, and Ferdi Schth pp 14152–14162 DOI: 10.1021/ja105308e

Multiple Release Kinetics of Targeted Drug from Gold Nanorod Embedded Polyelectrolyte Conjugates Induced by Near-Infrared Laser Irradiation Tsung-Rong Kuo, Vladimir A. Hovhannisyan, Yu-Ching Chao, Shu-Ling Chao, Shu-Jen Chiang, Sung-Jan Lin, Chen-Yuan Dong, and Chia-Chun Chen pp 14163–14171 DOI: 10.1021/ja105360z

A Diarylethene Cocrystal that Converts Light into Mechanical Work Masakazu Morimoto and Masahiro Irie pp 14172–14178 DOI: 10.1021/ja105356w Supporting Info

Stereoselective Synthesis of β-Hydroxy Enamines, Aminocyclopropanes, and 1,3-Amino Alcohols via Asymmetric Catalysis Petr Valenta, Patrick J. Carroll, and Patrick J. Walsh pp 14179–14190 DOI: 10.1021/ja105435y Supporting Info

The Thermosalient Phenomenon. “Jumping Crystals” and Crystal Chemistry of the Anticholinergic Agent Oxitropium Bromide eljko Skoko, Sharona Zamir, Pane Naumov, and Joel Bernstein pp 14191–14202 DOI: 10.1021/ja105508b Supporting Info

Supermolecular-Chromophore-Sensitized Near-Infrared-to-Visible Photon Upconversion Tanya N. Singh-Rachford, Animesh Nayak, Maria L. Muro-Small, Sèbastian Goeb, Michael J. Therien, and Felix N. Castellano pp 14203–14211 DOI: 10.1021/ja105510k Supporting Info

Total Synthesis of Plukenetione A Qiang Zhang, Branko Mitasev, Ji Qi, and John A. Porco, Jr. pp 14212–14215 DOI: 10.1021/ja105784s Supporting Info

Photocatalytic Formation of I−I Bonds Using DNA Which Enables Detection of Single Nucleotide Polymorphisms Kiyohiko Kawai, Haruka Kodera, and Tetsuro Majima pp 14216–14220 DOI: 10.1021/ja105850d Supporting Info

Glowing Locked Nucleic Acids: Brightly Fluorescent Probes for Detection of Nucleic Acids in Cells Michael E. Østergaard, Pallavi Cheguru, Madhusudhan R. Papasani, Rodney A. Hill, and Patrick J. Hrdlicka pp 14221–14228 DOI: 10.1021/ja1057295 Supporting Info

Potent, Highly Selective, and Orally Bioavailable Gem-Difluorinated Monocationic Inhibitors of Neuronal Nitric Oxide Synthase Fengtian Xue, Huiying Li, Silvia L. Delker, Jianguo Fang, Pavel Martsek, Linda J. Roman, Thomas L. Poulos, and Richard B. Silverman pp 14229–14238 DOI: 10.1021/ja106175q Supporting Info

C−H Bond Activation of Benzene by Unsaturated η2-Cyclopropene and η2-Benzyne Complexes of Niobium Cdric Boulho, Pascal Ouli, Laure Vendier, Michel Etienne, Vronique Pimienta, Abel Locati, Fabienne Bessac, Feliu Maseras, Dimitrios A. Pantazis, and John E. McGrady pp 14239–14250 DOI: 10.1021/ja1061505 Supporting Info

Supramolecular Cross-Linked Networks via Host−Guest Complexation with Cucurbit[8]uril Eric A. Appel, Frank Biedermann, Urs Rauwald, Samuel T. Jones, Jameel M. Zayed, and Oren A. Scherman pp 14251–14260 DOI: 10.1021/ja106362w Supporting Info

Crystals in Which Some Metal Atoms are More Equal Than Others: Inequalities From Crystal Packing and Their Spectroscopic/Magnetic Consequences Michael Nippe, Jingfang Wang, Eckhard Bill, Håkon Hope, Naresh S. Dalal, and John F. Berry pp 14261–14272 DOI: 10.1021/ja106510g Supporting Info

High-Efficiency Green Organic Light-Emitting Devices Utilizing Phosphorescent Bis-cyclometalated Alkynylgold(III) Complexes Vonika Ka-Man Au, Keith Man-Chung Wong, Daniel Ping-Kuen Tsang, Mei-Yee Chan, Nianyong Zhu, and Vivian Wing-Wah Yam pp 14273–14278 DOI: 10.1021/ja106579d Supporting Info

Formation Mechanism of CaTiO3 Hollow Crystals with Different Microstructures Xianfeng Yang, Junxiang Fu, Chongjun Jin, Jian Chen, Chaolun Liang, Mingmei Wu, and Wuzong Zhou pp 14279–14287 DOI: 10.1021/ja106461u Supporting Info

Nickel-Catalyzed Stereoselective Glycosylation with C(2)-N-Substituted Benzylidene d-Glucosamine and Galactosamine Trichloroacetimidates for the Formation of 1,2-cis-2-Amino Glycosides. Applications to the Synthesis of Heparin Disaccharides, GPI Anchor Pseudodisaccharides, and α-GalNAc Enoch A. Mensah, Fei Yu, and Hien M. Nguyen pp 14288–14302 DOI: 10.1021/ja106682m Supporting Info

Simple Reagents for Direct Halonium-Induced Polyene Cyclizations Scott A. Snyder, Daniel S. Treitler, and Alexandria P. Brucks pp 14303–14314 DOI: 10.1021/ja106813s Supporting Info

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents Fang Gao, Kevin P. McGrath, Yunmi Lee, and Amir H. Hoveyda pp 14315–14320 DOI: 10.1021/ja106829k Supporting Info

Issue 41

Homochiral Metal−Organic Frameworks for Heterogeneous Asymmetric Catalysis Dongbin Dang, Pengyan Wu, Cheng He, Zhong Xie, and Chunying Duan pp 14321–14323 DOI: 10.1021/ja101208s Supporting Info

Rhodium-Catalyzed Synthesis of Silafluorene Derivatives via Cleavage of Silicon−Hydrogen and Carbon−Hydrogen Bonds Tomonari Ureshino, Takuya Yoshida, Yoichiro Kuninobu, and Kazuhiko Takai pp 14324–14326 DOI: 10.1021/ja107698p Supporting Info

Development of Stable Phosphohistidine Analogues Jung-Min Kee, Bryeanna Villani, Laura R. Carpenter, and Tom W. Muir pp 14327–14329 DOI: 10.1021/ja104393t Supporting Info

A Straightforward Route to Functionalized trans-Diels−Alder Motifs Jun Hee Lee, Yandong Zhang, and Samuel J. Danishefsky pp 14330–14333 DOI: 10.1021/ja1073855 Supporting Info

Quantification of C−H Quenching in Near-IR Luminescent Ytterbium and Neodymium Cryptates Caroline Bischof, Jessica Wahsner, Julia Scholten, Simon Trosien, and Michael Seitz pp 14334–14335 DOI: 10.1021/ja105768w Supporting Info

Structural Characterization of a Copper Nitrosyl Complex with a {CuNO}10 Configuration Ashley M. Wright, Guang Wu, and Trevor W. Hayton pp 14336–14337 DOI: 10.1021/ja105930b Supporting Info

Synthesis of the Lycopodium Alkaloid (+)-Lycoflexine Jrgen Ramharter, Harald Weinstabl, and Johann Mulzer pp 14338–14339 DOI: 10.1021/ja107533m Supporting Info

Combination of Kinetically Selected Inhibitors in Trans Leads to Highly Effective Inhibition of Amyloid Formation Fanling Meng, Daniel P. Raleigh, and Andisheh Abedini pp 14340–14342 DOI: 10.1021/ja1046186 Supporting Info

Reversible Two-Photon Optical Data Storage in Coumarin-Based Copolymers Konstantinos Iliopoulos, Oksana Krupka, Denis Gindre, and Marc Sall pp 14343–14345 DOI: 10.1021/ja1047285 Supporting Info

An Electrochemical Supersandwich Assay for Sensitive and Selective DNA Detection in Complex Matrices Fan Xia, Ryan J. White, Xiaolei Zuo, Adriana Patterson, Yi Xiao, Di Kang, Xiong Gong, Kevin W. Plaxco, and Alan J. Heeger pp 14346–14348 DOI: 10.1021/ja104998m Supporting Info

Copper-Catalyzed Enantioselective Synthesis of trans-1-Alkyl-2-substituted Cyclopropanes via Tandem Conjugate Addition−Intramolecular Enolate Trapping Tim den Hartog, Alena Rudolph, Beatriz Maci, Adriaan J. Minnaard, and Ben L. Feringa pp 14349–14351 DOI: 10.1021/ja105704m Supporting Info

GPC and ESI-MS Analysis of Labeled Poly(1-Hexene): Rapid Determination of Initiated Site Counts during Catalytic Alkene Polymerization Reactions Beth M. Moscato, Bolin Zhu, and Clark R. Landis pp 14352–14354 DOI: 10.1021/ja105775r Supporting Info

Sonication-Assisted Synthesis of Large, High-Quality Mercury Thiolate Single Crystals Directly from Liquid Mercury Boaz Pokroy, Barbara Aichmayer, Anna Sophia Schenk, Boris Haimov, Sung Hoon Kang, Peter Fratzl, and Joanna Aizenberg pp 14355–14357 DOI: 10.1021/ja1056449 Supporting Info

Redox-Active Ligand-Mediated Oxidative Addition and Reductive Elimination at Square Planar Cobalt(III): Multielectron Reactions for Cross-Coupling Aubrey L. Smith, Kenneth I. Hardcastle, and Jake D. Soper pp 14358–14360 DOI: 10.1021/ja106212w Supporting Info

The Distance Between Donor and Acceptor Affects the Proportion of C1′ and C2′ Oxidation Products of DNA in a BrU-Containing Excess Electron Transfer System Ryu Tashiro, Akimichi Ohtsuki, and Hiroshi Sugiyama pp 14361–14363 DOI: 10.1021/ja106184w Supporting Info

Platinum-Monolayer Shell on AuNi0.5Fe Nanoparticle Core Electrocatalyst with High Activity and Stability for the Oxygen Reduction Reaction Kuanping Gong, Dong Su, and Radoslav R. Adzic pp 14364–14366 DOI: 10.1021/ja1063873 Supporting Info

Conformationally Flexible Dimeric Salphen Complexes for Bifunctional Catalysis Sergei I. Vagin, Robert Reichardt, Stephan Klaus, and Bernhard Rieger pp 14367–14369 DOI: 10.1021/ja106484t Supporting Info

A Viable Anionic N-Heterocyclic Dicarbene Yuzhong Wang, Yaoming Xie, Mariham Y. Abraham, Pingrong Wei, Henry F. Schaefer, III, Paul v. R. Schleyer, and Gregory H. Robinson pp 14370–14372 DOI: 10.1021/ja106631r Supporting Info

Enantioselective Rhodium-Catalyzed Addition of Arylboronic Acids to Alkenylheteroarenes Graham Pattison, Guillaume Piraux, and Hon Wai Lam pp 14373–14375 DOI: 10.1021/ja106809p Supporting Info

General Approach to Epipolythiodiketopiperazine Alkaloids: Total Synthesis of (+)-Chaetocins A and C and (+)-12,12′-Dideoxychetracin A Justin Kim and Mohammad Movassaghi pp 14376–14378 DOI: 10.1021/ja106869s Supporting Info

Regioselective C−H Activation and Sequential C−C and C−O Bond Formation Reactions of Aryl Ketones Promoted by an Yttrium Carbene David P. Mills, Lyndsay Soutar, William Lewis, Alexander J. Blake, and Stephen T. Liddle pp 14379–14381 DOI: 10.1021/ja107958u Supporting Info

Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine Eric D. Bloch, David Britt, Chain Lee, Christian J. Doonan, Fernando J. Uribe-Romo, Hiroyasu Furukawa, Jeffrey R. Long, and Omar M. Yaghi pp 14382–14384 DOI: 10.1021/ja106935d Supporting Info

High-Yield Synthesis of Ultralong and Ultrathin Zn2GeO4 Nanoribbons toward Improved Photocatalytic Reduction of CO2 into Renewable Hydrocarbon Fuel Qi Liu, Yong Zhou, Jiahui Kou, Xiaoyu Chen, Zhongping Tian, Jun Gao, Shicheng Yan, and Zhigang Zou pp 14385–14387 DOI: 10.1021/ja1068596 Supporting Info

Direct Measurement of the Dynamics of Hole Hopping in Extended DNA G-Tracts. An Unbiased Random Walk Sarah M. Mickley Conron, Arun K. Thazhathveetil, Michael R. Wasielewski, Alexander L. Burin, and Frederick D. Lewis pp 14388–14390 DOI: 10.1021/ja106991f Supporting Info

Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryl)acetates with Aryl Halides and Triflates Rui Shang, Zhi-Wei Yang, Yan Wang, Song-Lin Zhang, and Lei Liu pp 14391–14393 DOI: 10.1021/ja107103b Supporting Info

Synthesis of Streptolydigin, a Potent Bacterial RNA Polymerase Inhibitor Sergey V. Pronin and Sergey A. Kozmin pp 14394–14396 DOI: 10.1021/ja107190w Supporting Info

Highly Emitting Concomitant Polymorphic Crystals of a Dinuclear Rhenium Complex Elsa Quartapelle Procopio, Matteo Mauro, Monica Panigati, Daniela Donghi, Pierluigi Mercandelli, Angelo Sironi, Giuseppe D’Alfonso, and Luisa De Cola pp 14397–14399 DOI: 10.1021/ja106772v Supporting Info

Preparation and C−X Reductive Elimination Reactivity of Monoaryl PdIV−X Complexes in Water (X = OH, OH2, Cl, Br) Williamson Oloo, Peter Y. Zavalij, Jing Zhang, Eugene Khaskin, and Andrei N. Vedernikov pp 14400–14402 DOI: 10.1021/ja107185w Supporting Info

Magnetically Powered Flexible Metal Nanowire Motors Wei Gao, Sirilak Sattayasamitsathit, Kalayil Manian Manesh, Daniel Weihs, and Joseph Wang pp 14403–14405 DOI: 10.1021/ja1072349 Supporting Info

TiO2 Nanotube/CdS Hybrid Electrodes: Extraordinary Enhancement in the Inactivation of Escherichia coli Steven C. Hayden, Nageh K. Allam, and Mostafa A. El-Sayed pp 14406–14408 DOI: 10.1021/ja107034z Supporting Info

Alkene Syn Dihydroxylation with Malonoyl Peroxides James C. Griffith, Kevin M. Jones, Sylvain Picon, Michael J. Rawling, Benson M. Kariuki, Matthew Campbell, and Nicholas C. O. Tomkinson pp 14409–14411 DOI: 10.1021/ja1066674 Supporting Info

Umpolung Direct Arylation Reactions: Facile Process Requiring Only Catalytic Palladium and Substoichiometric Amount of Silver Salts James J. Mousseau, Frdric Valle, Melanie M. Lorion, and Andr B. Charette pp 14412–14414 DOI: 10.1021/ja107541w Supporting Info

Open-Mouthed Metallic Microcapsules: Exploring Performance Improvements at Agglomeration-Free Interiors Saikat Mandal, Marappan Sathish, Govindachetty Saravanan, K. K. R. Datta, Qingmin Ji, Jonathan P. Hill, Hideki Abe, Itaru Honma, and Katsuhiko Ariga pp 14415–14417 DOI: 10.1021/ja107589m Supporting Info

Enantioselective Synthesis of Pyrroloindolines by a Formal [3 + 2] Cycloaddition Reaction Lindsay M. Repka, Jane Ni, and Sarah E. Reisman pp 14418–14420 DOI: 10.1021/ja107328g Supporting Info

Alternating Covalent Bonding Interactions in a One-Dimensional Chain of a Phenalenyl-Based Singlet Biradical Molecule Having Kekul Structures Akihiro Shimizu, Takashi Kubo, Mikio Uruichi, Kyuya Yakushi, Masayoshi Nakano, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, Yasukazu Hirao, Kouzou Matsumoto, Hiroyuki Kurata, Yasushi Morita, and Kazuhiro Nakasuji pp 14421–14428 DOI: 10.1021/ja1037287 Supporting Info

Electro-oxidized Epitaxial Graphene Channel Field-Effect Transistors with Single-Walled Carbon Nanotube Thin Film Gate Electrode Palanisamy Ramesh, Mikhail E. Itkis, Elena Bekyarova, Feihu Wang, Sandip Niyogi, Xiaoliu Chi, Claire Berger, Walt de Heer, and Robert C. Haddon pp 14429–14436 DOI: 10.1021/ja101706j

Interaction of Charge Carriers with Lattice Vibrations in Oligoacene Crystals from Naphthalene to Pentacene Roel S. Snchez-Carrera, Pavel Paramonov, Graeme M. Day, Veaceslav Coropceanu, and Jean-Luc Brdas pp 14437–14446 DOI: 10.1021/ja1040732 Supporting Info

Holo-Ni(II)HpNikR Is an Asymmetric Tetramer Containing Two Different Nickel-Binding Sites Abby L. West, Franz St. John, Pedro E. M. Lopes, Alexander D. MacKerell, Jr., Edwin Pozharski, and Sarah L. J. Michel pp 14447–14456 DOI: 10.1021/ja104118r Supporting Info

Exceptional Thermal Stability in a Supramolecular Organic Framework: Porosity and Gas Storage Wenbin Yang, Alex Greenaway, Xiang Lin, Ryotaro Matsuda, Alexander J. Blake, Claire Wilson, William Lewis, Peter Hubberstey, Susumu Kitagawa, Neil R. Champness, and Martin Schrder pp 14457–14469 DOI: 10.1021/ja1042935 Supporting Info

An Original Polymorph Sequence in the High-Temperature Evolution of the Perovskite Pb2TmSbO6 Sebastin A. Larrgola, Jos A. Alonso, Denis Sheptyakov, Miguel Alguer, Angel Muoz, Vladimir Pomjakushin, and Jos C. Pedregosa pp 14470–14480 DOI: 10.1021/ja104417f Supporting Info

Weave Tile Architecture Construction Strategy for DNA Nanotechnology Majken N. Hansen, Alex M. Zhang, Abhijit Rangnekar, Kristin M. Bompiani, Joshua D. Carter, Kurt V. Gothelf, and Thomas H. LaBean pp 14481–14486 DOI: 10.1021/ja104456p

Structure-Directing Role of Graphene in the Synthesis of Metal−Organic Framework Nanowire Maryam Jahan, Qiaoliang Bao, Jia-Xiang Yang, and Kian Ping Loh pp 14487–14495 DOI: 10.1021/ja105089w Supporting Info

Inkjet Deposition of Layer-by-Layer Assembled Films Christine M. Andres and Nicholas A. Kotov pp 14496–14502 DOI: 10.1021/ja104735a

Understanding the Structure and Formation of Uranyl Peroxide Nanoclusters by Quantum Chemical Calculations Bess Vlaisavljevich, Laura Gagliardi, and Peter C. Burns pp 14503–14508 DOI: 10.1021/ja104964x Supporting Info

Paramagnetic Intermediates of (E)-4-Hydroxy-3-methylbut-2-enyl Diphosphate Synthase (GcpE/IspG) under Steady-State and Pre-Steady-State Conditions Weiya Xu, Nicholas S. Lees, Dolapo Adedeji, Jochen Wiesner, Hassan Jomaa, Brian M. Hoffman, and Evert C. Duin pp 14509–14520 DOI: 10.1021/ja101764w Supporting Info

Structural Basis for Cyclic Py-Im Polyamide Allosteric Inhibition of Nuclear Receptor Binding David M. Chenoweth and Peter B. Dervan pp 14521–14529 DOI: 10.1021/ja105068b Supporting Info

On the Mechanism of Palladium-Catalyzed Aromatic C−H Oxidation David C. Powers, Daphne Y. Xiao, Matthias A. L. Geibel, and Tobias Ritter pp 14530–14536 DOI: 10.1021/ja1054274 Supporting Info

Amicyanin Transfers Electrons from Methylamine Dehydrogenase to Cytochrome c-551i via a Ping-Pong Mechanism, not a Ternary Complex Francesca Meschi, Frank Wiertz, Linda Klauss, Chiara Cavalieri, Anneloes Blok, Bernd Ludwig, Hendrik A. Heering, Angelo Merli, Gian Luigi Rossi, and Marcellus Ubbink pp 14537–14545 DOI: 10.1021/ja105498m Supporting Info

Au Nanocube-Directed Fabrication of Au−Pd Core−Shell Nanocrystals with Tetrahexahedral, Concave Octahedral, and Octahedral Structures and Their Electrocatalytic Activity Chun-Lun Lu, Kariate Sudhakara Prasad, Hsin-Lun Wu, Ja-an Annie Ho, and Michael H. Huang pp 14546–14553 DOI: 10.1021/ja105401p Supporting Info

Stepwise Assembly of Coordination-Based Metal−Organic Networks Revital Kaminker, Leila Motiei, Antonino Gulino, Ignazio Fragal, Linda J. W. Shimon, Guennadi Evmenenko, Pulak Dutta, Mark A. Iron, and Milko E. van der Boom pp 14554–14561 DOI: 10.1021/ja105518n Supporting Info

Moving Metal Ions through Ferritin−Protein Nanocages from Three-Fold Pores to Catalytic Sites Takehiko Tosha, Ho-Leung Ng, Onita Bhattasali, Tom Alber, and Elizabeth C. Theil pp 14562–14569 DOI: 10.1021/ja105583d Supporting Info

Tailored Ligand Acceleration of the Cu-Catalyzed Azide−Alkyne Cycloaddition Reaction: Practical and Mechanistic Implications Stanislav I. Presolski, Vu Hong, So-Hye Cho, and M.G. Finn pp 14570–14576 DOI: 10.1021/ja105743g Supporting Info

Protein Flexibility and Conformational Entropy in Ligand Design Targeting the Carbohydrate Recognition Domain of Galectin-3 Carl Diehl, Olof Engstrm, Tamara Delaine, Maria Håkansson, Samuel Genheden, Kristofer Modig, Hakon Leffler, Ulf Ryde, Ulf J. Nilsson, and Mikael Akke pp 14577–14589 DOI: 10.1021/ja105852y Supporting Info

Outer-Sphere Effects on Reduction Potentials of Copper Sites in Proteins: The Curious Case of High Potential Type 2 C112D/M121E Pseudomonas aeruginosa Azurin Kyle M. Lancaster, Stephen Sproules, Joshua H. Palmer, John H. Richards, and Harry B. Gray pp 14590–14595 DOI: 10.1021/ja105731x Supporting Info

Development of a General Palladium-Catalyzed Carbonylative Heck Reaction of Aryl Halides Xiao-Feng Wu, Helfried Neumann, Anke Spannenberg, Thomas Schulz, Haijun Jiao, and Matthias Beller pp 14596–14602 DOI: 10.1021/ja1059922 Supporting Info

Controlled Orientation of Polyconjugated Guest Molecules in Tunable Host Cavities Airon C. Soegiarto, Angiolina Comotti, and Michael D. Ward pp 14603–14616 DOI: 10.1021/ja106106d Supporting Info

Through-Bond Interactions in the Diradical Intermediates Formed in the Rearrangements of Bicyclo[n.m.0]alkatetraenes Charity Flener Lovitt, Hao Dong, David A. Hrovat, Rolf Gleiter, and Weston Thatcher Borden pp 14617–14624 DOI: 10.1021/ja106329t Supporting Info

Photogeneration and Reactivity of Naphthoquinone Methides as Purine Selective DNA Alkylating Agents Daniela Verga, Matteo Nadai, Filippo Doria, Claudia Percivalle, Marco Di Antonio, Manlio Palumbo, Sara N. Richter, and Mauro Freccero pp 14625–14637 DOI: 10.1021/ja1063857 Supporting Info

Understanding the Stabilization of Liquid-Phase-Exfoliated Graphene in Polar Solvents: Molecular Dynamics Simulations and Kinetic Theory of Colloid Aggregation Chih-Jen Shih, Shangchao Lin, Michael S. Strano, and Daniel Blankschtein pp 14638–14648 DOI: 10.1021/ja1064284 Supporting Info

Spectroscopic and Computational Studies on the Rearrangement of Ionized [1.1.1]Propellane and Some of its Valence Isomers: The Key Role of Vibronic Coupling Beat Mller, Thomas Bally, Robert Pappas, and Ffrancon Williams pp 14649–14660 DOI: 10.1021/ja106024y Supporting Info

When the Solute Becomes the Solvent: Orientation, Ordering, and Structure of Binary Mixtures of 1-Hexanol and Cyclohexane over the (0001) α-Al2O3 Surface Avram M. Buchbinder, Eric Weitz, and Franz M. Geiger pp 14661–14668 DOI: 10.1021/ja1068504 Supporting Info

Substrate-Induced Covalent Assembly of a Chemzyme and Crystallographic Characterization of a Chemzyme−Substrate Complex Gang Hu, Anil K. Gupta, Rui H. Huang, Munmun Mukherjee, and William D. Wulff pp 14669–14675 DOI: 10.1021/ja1070224 Supporting Info

Regioselective Oxidative Arylation of Indoles Bearing N-Alkyl Protecting Groups: Dual C−H Functionalization via a Concerted Metalation−Deprotonation Mechanism Shathaverdhan Potavathri, Kyle C. Pereira, Serge I. Gorelsky, Andrew Pike, Alexis P. LeBris, and Brenton DeBoef pp 14676–14681 DOI: 10.1021/ja107159b Supporting Info

Oxidation of a Cyclometalated Pd(II) Dimer with “CF3+”: Formation and Reactivity of a Catalytically Competent Monomeric Pd(IV) Aquo Complex Yingda Ye, Nicholas D. Ball, Jeff W. Kampf, and Melanie S. Sanford pp 14682–14687 DOI: 10.1021/ja107780w Supporting Info

Unexpected Binding Modes of Nitric Oxide Synthase Inhibitors Effective in the Prevention of a Cerebral Palsy Phenotype in an Animal Model Silvia L Delker, Haitao Ji, Huiying Li, Joumana Jamal, Jianguo Fang, Fengtian Xue, Richard B. Silverman, and Thomas L. Poulos p 14688 DOI: 10.1021/ja107808u

Issue 42

The Interface of Inorganic Chemistry and Biology Stephen J. Lippard pp 14689–14693 DOI: 10.1021/ja108523h

Mechanism and Stereospecificity of a Fully Saturating Polyketide Synthase Module: Nanchangmycin Synthase Module 2 and Its Dehydratase Domain Xun Guo, Tiangang Liu, Chiara R. Valenzano, Zixin Deng, and David E. Cane pp 14694–14696 DOI: 10.1021/ja1073432 Supporting Info

Stereospecificity of the Dehydratase Domain of the Erythromycin Polyketide Synthase Chiara R. Valenzano, Young-Ok You, Ashish Garg, Adrian Keatinge-Clay, Chaitan Khosla, and David E. Cane pp 14697–14699 DOI: 10.1021/ja107344h Supporting Info

Effect of Water Electrolysis Catalysts on Carbon Corrosion in Polymer Electrolyte Membrane Fuel Cells Sang-Eun Jang and Hansung Kim pp 14700–14701 DOI: 10.1021/ja104672n Supporting Info

Unexpectedly Stable Artificial Duplex from Flexible Acyclic Threoninol Hiroyuki Asanuma, Takasuke Toda, Keiji Murayama, Xingguo Liang, and Hiromu Kashida pp 14702–14703 DOI: 10.1021/ja105539u Supporting Info

Simultaneous Detection of Protein Phosphorylation and Acetylation by High-Resolution NMR Spectroscopy Stamatios Liokatis, Alexander Dose, Dirk Schwarzer, and Philipp Selenko pp 14704–14705 DOI: 10.1021/ja106764y Supporting Info

Ketene Functionalized Polyethylene: Control of Cross-Link Density and Material Properties Frank A. Leibfarth, Yanika Schneider, Nathaniel A. Lynd, Alison Schultz, Bongjin Moon, Edward J. Kramer, Guillermo C. Bazan, and Craig J. Hawker pp 14706–14709 DOI: 10.1021/ja1060643 Supporting Info

Molecular Mechanism of the DNA Sequence Selectivity of 5-Halo-2′-Deoxyuridines as Potential Radiosensitizers Chun-Rong Wang and Qing-Bin Lu pp 14710–14713 DOI: 10.1021/ja102883a

Laser Desorption/Ionization Mass Spectrometric Assay for Phospholipase Activity Based on Graphene Oxide/Carbon Nanotube Double-Layer Films Jieon Lee, Young-Kwan Kim, and Dal-Hee Min pp 14714–14717 DOI: 10.1021/ja106276j Supporting Info

Thioamides as Fluorescence Quenching Probes: Minimalist Chromophores To Monitor Protein Dynamics Jacob M. Goldberg, Solongo Batjargal, and E. James Petersson pp 14718–14720 DOI: 10.1021/ja1044924 Supporting Info

Solution-Based TiO2−Polymer Composite Dielectric for Low Operating Voltage OTFTs Joohee Kim, Sung Hee Lim, and Young Sang Kim pp 14721–14723 DOI: 10.1021/ja104840b Supporting Info

A Simple and Efficient Synthesis of Functionalized Cyclic Carbonate Monomers Using a Versatile Pentafluorophenyl Ester Intermediate Daniel P. Sanders, Kazuki Fukushima, Daniel J. Coady, Alshakim Nelson, Masaki Fujiwara, Manabu Yasumoto, and James L. Hedrick pp 14724–14726 DOI: 10.1021/ja105332k Supporting Info

A Structurally Tunable DNA-Based Extracellular Matrix Faisal A. Aldaye, William T. Senapedis, Pamela A. Silver, and Jeffrey C. Way pp 14727–14729 DOI: 10.1021/ja105431h Supporting Info

Patterning Graphene through the Self-Assembled Templates: Toward Periodic Two-Dimensional Graphene Nanostructures with Semiconductor Properties Alexander Sinitskii and James M. Tour pp 14730–14732 DOI: 10.1021/ja105426h

Entropy Drives an Attached Water Molecule from the C- to N-Terminus on Protonated Proline James S. Prell, Thiago C. Correra, Terrence M. Chang, Jeffrey A. Biles, and Evan R. Williams pp 14733–14735 DOI: 10.1021/ja106167d Supporting Info

Oxygen Precursor to the Reactive Intermediate in Methanol Synthesis by Cu-ZSM-5 Pieter J. Smeets, Ryan G. Hadt, Julia S. Woertink, Pieter Vanelderen, Robert A. Schoonheydt, Bert F. Sels, and Edward I. Solomon pp 14736–14738 DOI: 10.1021/ja106283u Supporting Info

Embedded High Density Metal Nanoparticles with Extraordinary Thermal Stability Derived from Guest−Host Mediated Layered Double Hydroxides Meng-Qiang Zhao, Qiang Zhang, Wei Zhang, Jia-Qi Huang, Yinghao Zhang, Dang Sheng Su, and Fei Wei pp 14739–14741 DOI: 10.1021/ja106421g Supporting Info

Memory of Chirality in Cascade Rearrangements of Enediynes Malek Nechab, Damien Campolo, Julien Maury, Patricia Perfetti, Nicolas Vanthuyne, Didier Siri, and Michle P. Bertrand pp 14742–14744 DOI: 10.1021/ja106668d Supporting Info

Pd−Ga Intermetallic Compounds as Highly Selective Semihydrogenation Catalysts Marc Armbrster, Kirill Kovnir, Malte Behrens, Detre Teschner, Yuri Grin, and Robert Schlgl pp 14745–14747 DOI: 10.1021/ja106568t Supporting Info

Template-Assisted Selective Radical Addition toward Sequence-Regulated Polymerization: Lariat Capture of Target Monomer by Template Initiator Shohei Ida, Makoto Ouchi, and Mitsuo Sawamoto pp 14748–14750 DOI: 10.1021/ja1070575 Supporting Info

Selective Etching of Graphene Edges by Hydrogen Plasma Liming Xie, Liying Jiao, and Hongjie Dai pp 14751–14753 DOI: 10.1021/ja107071g Supporting Info

A Self-Threading Polythiophene: Defect-Free Insulated Molecular Wires Endowed with Long Effective Conjugation Length Kazunori Sugiyasu, Yoshihito Honsho, Ryan M. Harrison, Akira Sato, Takeshi Yasuda, Shu Seki, and Masayuki Takeuchi pp 14754–14756 DOI: 10.1021/ja107444m Supporting Info

Application of a Chiral Scaffolding Ligand in Catalytic Enantioselective Hydroformylation Amanda D. Worthy, Candice L. Joe, Thomas E. Lightburn, and Kian L. Tan pp 14757–14759 DOI: 10.1021/ja107433h Supporting Info

Synthesis in Ionic Liquids: [Bi2Te2Br](AlCl4), a Direct Gap Semiconductor with a Cationic Framework Kanishka Biswas, Qichun Zhang, In Chung, Jung-Hwan Song, John Androulakis, Arthur J. Freeman, and Mercouri G. Kanatzidis pp 14760–14762 DOI: 10.1021/ja107483g Supporting Info

“Long-Range” Metal−Ligand Cooperation in H2 Activation and Ammonia-Promoted Hydride Transfer with a Ruthenium−Acridine Pincer Complex Chidambaram Gunanathan, Boopathy Gnanaprakasam, Mark A. Iron, Linda J. W. Shimon, and David Milstein pp 14763–14765 DOI: 10.1021/ja107770y Supporting Info

Cyclization and Rearrangement Reactions of an Fragment Ions of Protonated Peptides Benjamin J. Bythell, Philippe Matre, and Bla Paizs pp 14766–14779 DOI: 10.1021/ja101556g Supporting Info

Water-Stable Helical Structure of Tertiary Amides of Bicyclic β-Amino Acid Bearing 7-Azabicyclo[2.2.1]heptane. Full Control of Amide Cis−Trans Equilibrium by Bridgehead Substitution Masahiro Hosoya, Yuko Otani, Masatoshi Kawahata, Kentaro Yamaguchi, and Tomohiko Ohwada pp 14780–14789 DOI: 10.1021/ja1017877 Supporting Info

Effective Click Construction of Bridged- and Spiro-Multicyclic Polymer Topologies with Tailored Cyclic Prepolymers (kyklo-Telechelics) Naoto Sugai, Hiroyuki Heguri, Kengo Ohta, Qingyuan Meng, Takuya Yamamoto, and Yasuyuki Tezuka pp 14790–14802 DOI: 10.1021/ja103402c Supporting Info

Quantum Dot Capped Magnetite Nanorings as High Performance Nanoprobe for Multiphoton Fluorescence and Magnetic Resonance Imaging Hai-Ming Fan, Malini Olivo, Borys Shuter, Jia-Bao Yi, Ramaswamy Bhuvaneswari, Hui-Ru Tan, Gui-Chuan Xing, Cheng-Teng Ng, Lei Liu, Sasidharan S. Lucky, Boon-Huat Bay, and Jun Ding pp 14803–14811 DOI: 10.1021/ja103738t Supporting Info

A Biosynthetic Route to Photoclick Chemistry on Proteins Jiangyun Wang, Wei Zhang, Wenjiao Song, Yizhong Wang, Zhipeng Yu, Jiasong Li, Minhao Wu, Lin Wang, Jianye Zang, and Qing Lin pp 14812–14818 DOI: 10.1021/ja104350y Supporting Info

Expanding the Genetic Code of Yeast for Incorporation of Diverse Unnatural Amino Acids via a Pyrrolysyl-tRNA Synthetase/tRNA Pair Susan M. Hancock, Rajendra Uprety, Alexander Deiters, and Jason W. Chin pp 14819–14824 DOI: 10.1021/ja104609m Supporting Info

Molecular Insights into the Potential and Temperature Dependences of the Differential Capacitance of a Room-Temperature Ionic Liquid at Graphite Electrodes Jenel Vatamanu, Oleg Borodin, and Grant D. Smith pp 14825–14833 DOI: 10.1021/ja104273r Supporting Info

Molecular Hydrogen “Pairing” Interaction in a Metal Organic Framework System with Unsaturated Metal Centers (MOF-74) Nour Nijem, Jean-Franois Veyan, Lingzhu Kong, Haohan Wu, Yonggang Zhao, Jing Li, David C. Langreth, and Yves J. Chabal pp 14834–14848 DOI: 10.1021/ja104923f Supporting Info

Differential Receptor Binding Affinities of Influenza Hemagglutinins on Glycan Arrays Hsin-Yu Liao, Che-Hsiung Hsu, Shih-Chi Wang, Chi-Hui Liang, Hsin-Yung Yen, Ching-Yao Su, Chien-Hung Chen, Jia-Tsrong Jan, Chien-Tai Ren, Chung-Hsuan Chen, Ting-Jen R. Cheng, Chung-Yi Wu, and Chi-Huey Wong pp 14849–14856 DOI: 10.1021/ja104657b Supporting Info

Chemical Synthesis, Folding, and Structural Insights into O-Fucosylated Epidermal Growth Factor-like Repeat 12 of Mouse Notch-1 Receptor Kazumi Hiruma-Shimizu, Kensaku Hosoguchi, Yan Liu, Naoki Fujitani, Takashi Ohta, Hiroshi Hinou, Takahiko Matsushita, Hiroki Shimizu, Ten Feizi, and Shin-Ichiro Nishimura pp 14857–14865 DOI: 10.1021/ja105216u Supporting Info

Effect of Morphology on Ultrafast Free Carrier Generation in Polythiophene:Fullerene Organic Solar Cells Ian A. Howard, Ralf Mauer, Michael Meister, and Frdric Laquai pp 14866–14876 DOI: 10.1021/ja105260d Supporting Info

Hydride-Containing Models for the Active Site of the Nickel−Iron Hydrogenases Bryan E. Barton and Thomas B. Rauchfuss pp 14877–14885 DOI: 10.1021/ja105312p Supporting Info

DFT Study of the Structure and Reactivity of the Terminal Pt(IV)-Oxo Complex Bearing No Electron-Withdrawing Ligands Irena Efremenko, Elena Poverenov, Jan M. L. Martin, and David Milstein pp 14886–14900 DOI: 10.1021/ja105197x Supporting Info

Dynamic Investigation of Protein Metal Active Sites: Interplay of XANES and Molecular Dynamics Simulations Paola D’Angelo, Stefano Della Longa, Alessandro Arcovito, Massimiliano Anselmi, Alfredo Di Nola, and Giovanni Chillemi pp 14901–14909 DOI: 10.1021/ja1056533 Supporting Info

Folding Pathways of Human Telomeric Type-1 and Type-2 G-Quadruplex Structures Tomoko Mashimo, Hirotaka Yagi, Yuta Sannohe, Arivazhagan Rajendran, and Hiroshi Sugiyama pp 14910–14918 DOI: 10.1021/ja105806u Supporting Info

Modeling Intrinsically Disordered Proteins with Bayesian Statistics Charles K. Fisher, Austin Huang, and Collin M. Stultz pp 14919–14927 DOI: 10.1021/ja105832g

Stability and Reactivity of −χ−θ Iron Carbide Catalyst Phases in Fischer−Tropsch Synthesis: Controlling μC Emiel de Smit, Fabrizio Cinquini, Andrew M. Beale, Olga V. Safonova, Wouter van Beek, Philippe Sautet, and Bert M. Weckhuysen pp 14928–14941 DOI: 10.1021/ja105853q Supporting Info

An Exocyclic Methylene Group Acts As a Bioisostere of the 2′-Oxygen Atom in LNA Punit P. Seth, Charles R. Allerson, Andres Berdeja, Andrew Siwkowski, Pradeep S. Pallan, Hans Gaus, Thazha P. Prakash, Andrew T. Watt, Martin Egli, and Eric E. Swayze pp 14942–14950 DOI: 10.1021/ja105875e Supporting Info

Chalcogels: Porous Metal−Chalcogenide Networks from Main-Group Metal Ions. Effect of Surface Polarizability on Selectivity in Gas Separation Santanu Bag and Mercouri G. Kanatzidis pp 14951–14959 DOI: 10.1021/ja1059284 Supporting Info

Amyloid Fibril Polymorphism Is under Kinetic Control Riccardo Pellarin, Philipp Schuetz, Enrico Guarnera, and Amedeo Caflisch pp 14960–14970 DOI: 10.1021/ja106044u Supporting Info

Structural Inhomogeneity of Interfacial Water at Lipid Monolayers Revealed by Surface-Specific Vibrational Pump−Probe Spectroscopy Mischa Bonn, Huib J. Bakker, Avishek Ghosh, Susumu Yamamoto, Maria Sovago, and R. Kramer Campen pp 14971–14978 DOI: 10.1021/ja106194u Supporting Info

Electronic Transitions of Protonated Benzene and Fulvene, and of C6H7 Isomers in Neon Matrices Iryna Garkusha, Jan Fulara, Adam Nagy, and John P. Maier pp 14979–14985 DOI: 10.1021/ja106470x Supporting Info

Citric Acid Adsorption on TiO2 Nanoparticles in Aqueous Suspensions at Acidic and Circumneutral pH: Surface Coverage, Surface Speciation, and Its Impact on Nanoparticle−Nanoparticle Interactions Imali A. Mudunkotuwa and Vicki H. Grassian pp 14986–14994 DOI: 10.1021/ja106091q Supporting Info

Probing the Oxyferrous and Catalytically Active Ferryl States of Amphitrite ornata Dehaloperoxidase by Cryoreduction and EPR/ENDOR Spectroscopy. Detection of Compound I Roman Davydov, Robert L. Osborne, Muralidharan Shanmugam, Jing Du, John H. Dawson, and Brian M. Hoffman pp 14995–15004 DOI: 10.1021/ja1059747 Supporting Info

Coordination Copolymerization Mediated by Zn4O(CO2R)6 Metal Clusters: a Balancing Act between Statistics and Geometry Kyoungmoo Koh, Antek G. Wong-Foy, and Adam J. Matzger pp 15005–15010 DOI: 10.1021/ja1065009 Supporting Info

Multifunctional Hybrid Organic−Inorganic Catalytic Materials with a Hierarchical System of Well-Defined Micro- and Mesopores Avelino Corma, Urbano Daz, Teresa Garca, Germn Sastre, and Alexandra Velty pp 15011–15021 DOI: 10.1021/ja106272z Supporting Info

Engineered Biocompatible Nanoparticles for in Vivo Imaging Applications Shu Chen, Lijun Wang, Suzanne L. Duce, Stuart Brown, Stephen Lee, Andreas Melzer, Sir Alfred Cuschieri, and Pascal Andr pp 15022–15029 DOI: 10.1021/ja106543j Supporting Info

Direct Access to Metal or Metal Oxide Nanocrystals Integrated with One-Dimensional Nanoporous Carbons for Electrochemical Energy Storage Yanyu Liang, Matthias Georg Schwab, Linjie Zhi, Enrico Mugnaioli, Ute Kolb, Xinliang Feng, and Klaus Mllen pp 15030–15037 DOI: 10.1021/ja106612d Supporting Info

Controlling Charge Separation and Recombination Rates in CdSe/ZnS Type I Core−Shell Quantum Dots by Shell Thicknesses Haiming Zhu, Nianhui Song, and Tianquan Lian pp 15038–15045 DOI: 10.1021/ja106710m Supporting Info

Synthesis and Electronic Structure of Cationic, Neutral, and Anionic Bis(imino)pyridine Iron Alkyl Complexes: Evaluation of Redox Activity in Single-Component Ethylene Polymerization Catalysts Aaron M. Tondreau, Carsten Milsmann, Andrew D. Patrick, Helen M. Hoyt, Emil Lobkovsky, Karl Wieghardt, and Paul J. Chirik pp 15046–15059 DOI: 10.1021/ja106575b Supporting Info

Origins of Hole Doping and Relevant Optoelectronic Properties of Wide Gap p-Type Semiconductor, LaCuOSe Hidenori Hiramatsu, Toshio Kamiya, Tetsuya Tohei, Eiji Ikenaga, Teruyasu Mizoguchi, Yuichi Ikuhara, Keisuke Kobayashi, and Hideo Hosono pp 15060–15067 DOI: 10.1021/ja107042r Supporting Info

Glycopolypeptides via Living Polymerization of Glycosylated-l-lysine N-Carboxyanhydrides Jessica R. Kramer and Timothy J. Deming pp 15068–15071 DOI: 10.1021/ja107425f Supporting Info

Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds Andrey Solovyev, Qianli Chu, Steven J. Geib, Louis Fensterbank, Max Malacria, Emmanuel Lacte, and Dennis P. Curran pp 15072–15080 DOI: 10.1021/ja107025y Supporting Info

Nitroimino-tetrazolates and Oxy-nitroimino-tetrazolates Young-Hyuk Joo and Jean’ne M. Shreeve pp 15081–15090 DOI: 10.1021/ja107729c Supporting Info

Single Gold Nanoparticles Counter: An Ultrasensitive Detection Platform for One-Step Homogeneous Immunoassays and DNA Hybridization Assays Chao Xie, Fagong Xu, Xiangyi Huang, Chaoqing Dong, and Jicun Ren p 15091 DOI: 10.1021/ja107251t

Issue 43

Simple Combustion Production and Characterization of Octahydro[60]fullerene with a Non-IPR C60 Cage Qun-Hong Weng, Qiao He, Ting Liu, Hui-Ying Huang, Jian-Hua Chen, Zhi-Yong Gao, Su-Yuan Xie, Xin Lu, Rong-Bin Huang, and Lan-Sun Zheng pp 15093–15095 DOI: 10.1021/ja108316e Supporting Info

Remarkable Effect of Bimetallic Nanocluster Catalysts for Aerobic Oxidation of Alcohols: Combining Metals Changes the Activities and the Reaction Pathways to Aldehydes/Carboxylic Acids or Esters Kosuke Kaizuka, Hiroyuki Miyamura, and Sh Kobayashi pp 15096–15098 DOI: 10.1021/ja108256h Supporting Info

Superresolution Imaging of Targeted Proteins in Fixed and Living Cells Using Photoactivatable Organic Fluorophores Hsiao-lu D. Lee, Samuel J. Lord, Shigeki Iwanaga, Ke Zhan, Hexin Xie, Jarrod C. Williams, Hui Wang, Grant R. Bowman, Erin D. Goley, Lucy Shapiro, Robert J. Twieg, Jianghong Rao, and W. E. Moerner pp 15099–15101 DOI: 10.1021/ja1044192 Supporting Info

Cubic Polyoxometalate−Organic Molecular Cage Shou-Tian Zheng, Jie Zhang, Xin-Xiong Li, Wei-Hui Fang, and Guo-Yu Yang pp 15102–15103 DOI: 10.1021/ja105986b Supporting Info

Unusual Inverse Temperature Dependence on Reaction Rate in the Asymmetric Autocatalytic Alkylation of Pyrimidyl Aldehydes Michela Quaranta, Timo Gehring, Barbara Odell, John M. Brown, and Donna G. Blackmond pp 15104–15107 DOI: 10.1021/ja103204w Supporting Info

Multialkylation of Aqueous Ammonia with Alcohols Catalyzed by Water-Soluble Cp*Ir−Ammine Complexes Ryoko Kawahara, Ken-ichi Fujita, and Ryohei Yamaguchi pp 15108–15111 DOI: 10.1021/ja107274w Supporting Info

Probing the Spontaneous Membrane Insertion of a Tail-Anchored Membrane Protein by Sum Frequency Generation Spectroscopy Khoi Tan Nguyen, Ronald Soong, Sang-Choul lm, Lucy Waskell, Ayyalusamy Ramamoorthy, and Zhan Chen pp 15112–15115 DOI: 10.1021/ja106508f Supporting Info

Allylic C−H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy To Achieve Aerobic Catalytic Turnover Alison N. Campbell, Paul B. White, Ilia A. Guzei, and Shannon S. Stahl pp 15116–15119 DOI: 10.1021/ja105829t Supporting Info

Synthesis of Redox Active Ferrocene-Modified Phospholipids by Transphosphatidylation Reaction and Chronoamperometry Study of the Corresponding Redox Sensitive Liposome Debby Correia-Ledo, Alexandre A. Arnold, and Janine Mauzeroll pp 15120–15123 DOI: 10.1021/ja105921g

Nanocrystal Superlattices with Thermally Degradable Hybrid Inorganic−Organic Capping Ligands Maksym V. Kovalenko, Maryna I. Bodnarchuk, and Dmitri V. Talapin pp 15124–15126 DOI: 10.1021/ja106841f Supporting Info

Highly Efficient Metal-Free Growth of Nitrogen-Doped Single-Walled Carbon Nanotubes on Plasma-Etched Substrates for Oxygen Reduction Dingshan Yu, Qiang Zhang, and Liming Dai pp 15127–15129 DOI: 10.1021/ja105617z Supporting Info

High-Affinity Glycopolymer Binding to Human DC-SIGN and Disruption of DC-SIGN Interactions with HIV Envelope Glycoprotein C. Remzi Becer, Matthew I. Gibson, Jin Geng, Rebecca Ilyas, Russell Wallis, Daniel A. Mitchell, and David M. Haddleton pp 15130–15132 DOI: 10.1021/ja1056714 Supporting Info

High Resolution 1H-Detected Solid-State NMR Spectroscopy of Protein Aliphatic Resonances: Access to Tertiary Structure Information Sam Asami, Peter Schmieder, and Bernd Reif pp 15133–15135 DOI: 10.1021/ja106170h Supporting Info

Water-Soluble J-Type Rosette Nanotubes with Giant Molar Ellipticity Gabor Borzsonyi, Rachel L. Beingessner, Takeshi Yamazaki, Jae-Young Cho, Andrew J. Myles, Marek Malac, Ray Egerton, Masahiro Kawasaki, Kazuo Ishizuka, Andriy Kovalenko, and Hicham Fenniri pp 15136–15139 DOI: 10.1021/ja105028w Supporting Info

‘Living’ Controlled in Situ Gelling Systems: Thiol−Disulfide Exchange Method toward Tailor-Made Biodegradable Hydrogels De-Cheng Wu, Xian Jun Loh, Yun-Long Wu, Chee Leng Lay, and Ye Liu pp 15140–15143 DOI: 10.1021/ja106639c Supporting Info

Synthesis of Core−Shell Structured Dual-Mesoporous Silica Spheres with Tunable Pore Size and Controllable Shell Thickness Dechao Niu, Zhi Ma, Yongsheng Li, and Jianlin Shi pp 15144–15147 DOI: 10.1021/ja1070653 Supporting Info

Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands Vlad M. Iluc and Gregory L. Hillhouse pp 15148–15150 DOI: 10.1021/ja107115q Supporting Info

Nanopod Formation through Gold Nanoparticle Templated and Catalyzed Cross-linking of Polymers Bearing Pendant Propargyl Ethers Ke Zhang, Joshua I. Cutler, Jian Zhang, Dan Zheng, Evelyn Auyeung, and Chad A. Mirkin pp 15151–15153 DOI: 10.1021/ja107224s Supporting Info

Water Catalysis and Anticatalysis in Photochemical Reactions: Observation of a Delayed Threshold Effect in the Reaction Quantum Yield Zeb C. Kramer, Kaito Takahashi, and Rex T. Skodje pp 15154–15157 DOI: 10.1021/ja107335t Supporting Info

Highly Monodisperse Bismuth Nanoparticles and Their Three-Dimensional Superlattices Maksym Yarema, Maksym V. Kovalenko, Gnter Hesser, Dmitri V. Talapin, and Wolfgang Heiss pp 15158–15159 DOI: 10.1021/ja107458s Supporting Info

A Beneficial Kinetic Effect of an η5-C5Me4H Ligand Rhett A. Baillie, Tommy Tran, Michelle E. Thibault, and Peter Legzdins pp 15160–15161 DOI: 10.1021/ja107834g Supporting Info

Air-Stable, Room-Temperature Emissive Disilenes with π-Extended Aromatic Groups Megumi Kobayashi, Tsukasa Matsuo, Takeo Fukunaga, Daisuke Hashizume, Hiroyuki Fueno, Kazuyoshi Tanaka, and Kohei Tamao pp 15162–15163 DOI: 10.1021/ja108094m Supporting Info

Supramolecular Interactions Probed by 13C−13C Solid-State NMR Spectroscopy Antoine Loquet, Karin Giller, Stefan Becker, and Adam Lange pp 15164–15166 DOI: 10.1021/ja107460j Supporting Info

Single-Molecule Imaging of Platinum Ligand Exchange Reaction Reveals Reactivity Distribution N. Melody Esfandiari, Yong Wang, Jonathan Y. Bass, Trevor P. Cornell, Douglas A. L. Otte, Ming H. Cheng, John C. Hemminger, Theresa M. McIntire, Vladimir A. Mandelshtam, and Suzanne A. Blum pp 15167–15169 DOI: 10.1021/ja105517d Supporting Info

Single-Crystal Colloidal Nanosheets of GeS and GeSe Dimitri D. Vaughn II, Romesh J. Patel, Michael A. Hickner, and Raymond E. Schaak pp 15170–15172 DOI: 10.1021/ja107520b Supporting Info

Cyclization of a Cellular Dipentaenone by Streptomyces coelicolor Cytochrome P450 154A1 without Oxidation/Reduction Qian Cheng, David C. Lamb, Steven L. Kelly, Li Lei, and F. Peter Guengerich pp 15173–15175 DOI: 10.1021/ja107801v Supporting Info

Organocatalytic Asymmetric Synthesis of Substituted 3-Hydroxy-2-oxindoles via Morita−Baylis−Hillman Reaction Yun-Lin Liu, Bo-Lun Wang, Jun-Jie Cao, Long Chen, Yong-Xue Zhang, Chao Wang, and Jian Zhou pp 15176–15178 DOI: 10.1021/ja107858z Supporting Info

Efficient Ring-Closing Metathesis of Alkenyl Bromides: The Importance of Protecting the Catalyst during the Olefin Approach Michele Gatti, Emma Drinkel, Linglin Wu, Ivano Pusterla, Fiona Gaggia, and Reto Dorta pp 15179–15181 DOI: 10.1021/ja108253f Supporting Info

Enantioselective Synthesis of syn- and anti-1,3-Aminoalcohols via β-Aminoketones and Subsequent Reduction/Dynamic Kinetic Asymmetric Transformation Renaud Millet, Annika M. Trff, Michiel L. Petrus, and Jan-E. Bckvall pp 15182–15184 DOI: 10.1021/ja107857v Supporting Info

Catalytic Asymmetric Synthesis of Chiral Allylic Esters Jeffrey S. Cannon, Stefan F. Kirsch, and Larry E. Overman pp 15185–15191 DOI: 10.1021/ja106685w Supporting Info

Mechanism of the Cobalt Oxazoline Palladacycle (COP)-Catalyzed Asymmetric Synthesis of Allylic Esters Jeffrey S. Cannon, Stefan F. Kirsch, Larry E. Overman, and Helen F. Sneddon pp 15192–15203 DOI: 10.1021/ja106688j Supporting Info

Importance of Ligand Bioactive Conformation in the Discovery of Potent Indole-Diamide Inhibitors of the Hepatitis C Virus NS5B Steven R. LaPlante, James R. Gillard, Araz Jakalian, Norman Aubry, Ren Coulombe, Christian Brochu, Youla S. Tsantrizos, Martin Poirier, George Kukolj, and Pierre L. Beaulieu pp 15204–15212 DOI: 10.1021/ja101358s Supporting Info

Ultrafast Multisequential Photochemistry of 5-Diazo Meldrum’s Acid Philipp Rudolf, Johannes Buback, Jochen Aulbach, Patrick Nuernberger, and Tobias Brixner pp 15213–15222 DOI: 10.1021/ja1025529 Supporting Info

Spin-Dependent Electron−Phonon Interaction in SmFeAsO by Low-Temperature Raman Spectroscopy L. Zhang, P. F. Guan, D. L. Feng, X. H. Chen, S. S. Xie, and M. W. Chen pp 15223–15227 DOI: 10.1021/ja104847q Supporting Info

Spatially Controlled DNA Nanopatterns by “Click” Chemistry Using Oligonucleotides with Different Anchoring Sites Guangyan Qing, Hai Xiong, Frank Seela, and Taolei Sun pp 15228–15232 DOI: 10.1021/ja105246b Supporting Info

Oxygen Atom Transfer Reactions from Isolated (Oxo)manganese(V) Corroles to Sulfides Anil Kumar, Israel Goldberg, Mark Botoshansky, Yekaterina Buchman, and Zeev Gross pp 15233–15245 DOI: 10.1021/ja1050296 Supporting Info

Solution-Phase Synthesis of Heteroatom-Substituted Carbon Scaffolds for Hydrogen Storage Zhong Jin, Zhengzong Sun, Lin J. Simpson, Kevin J. O’Neill, Philip A. Parilla, Yan Li, Nicholas P. Stadie, Channing C. Ahn, Carter Kittrell, and James M. Tour pp 15246–15251 DOI: 10.1021/ja105428d Supporting Info

Electronic Structures of Single-Walled Carbon Nanotubes Encapsulating Ellipsoidal C70 Shingo Okubo, Toshiya Okazaki, Kaori Hirose-Takai, Kazu Suenaga, Susumu Okada, Shunji Bandow, and Sumio Iijima pp 15252–15258 DOI: 10.1021/ja105654g

Visible-Light-Driven Cu(II)−(Sr1−yNay)(Ti1−xMox)O3 Photocatalysts Based on Conduction Band Control and Surface Ion Modification Xiaoqing Qiu, Masahiro Miyauchi, Huogen Yu, Hiroshi Irie, and Kazuhito Hashimoto pp 15259–15267 DOI: 10.1021/ja105846n Supporting Info

Dynamic Structural Changes at LiMn2O4/Electrolyte Interface during Lithium Battery Reaction Masaaki Hirayama, Hedekazu Ido, KyungSu Kim, Woosuk Cho, Kazuhisa Tamura, Jun’ichiro Mizuki, and Ryoji Kanno pp 15268–15276 DOI: 10.1021/ja105389t Supporting Info

Separation of Styrene and Ethylbenzene on Metal−Organic Frameworks: Analogous Structures with Different Adsorption Mechanisms Michael Maes, Frederik Vermoortele, Luc Alaerts, Sarah Couck, Christine E. A. Kirschhock, Joeri F. M. Denayer, and Dirk E. De Vos pp 15277–15285 DOI: 10.1021/ja106142x Supporting Info

Synthesis of Metal−Hydrazone Complexes and Vapochromic Behavior of Their Hydrogen-Bonded Proton-Transfer Assemblies Atsushi Kobayashi, Masa-aki Dosen, Mee Chang, Kiyohiko Nakajima, Shin-ichiro Noro, and Masako Kato pp 15286–15298 DOI: 10.1021/ja1063444 Supporting Info

Detection of Telomerase Activity in High Concentration of Cell Lysates Using Primer-Modified Gold Nanoparticles Yi Xiao, Karen Y. Dane, Takanori Uzawa, Andrew Csordas, Jiangrong Qian, H. Tom Soh, Patrick S. Daugherty, Eric T. Lagally, Alan J. Heeger, and Kevin W. Plaxco pp 15299–15307 DOI: 10.1021/ja106513f Supporting Info

Mechanism of Catalytic Cyclohydroamination by Zirconium Salicyloxazoline Complexes Laura E. N. Allan, Guy J. Clarkson, David J. Fox, Andrew L. Gott, and Peter Scott pp 15308–15320 DOI: 10.1021/ja106588m Supporting Info

Highly Selective Suppression of Melanoma Cells by Inducible DNA Cross-Linking Agents: Bis(catechol) Derivatives Minghui Bai, Jing Huang, Xiaolong Zheng, Zhibin Song, Miru Tang, Wuxiang Mao, Libo Yuan, Jun Wu, Xiaocheng Weng, and Xiang Zhou pp 15321–15327 DOI: 10.1021/ja106637e Supporting Info

A Unique Approach to the Concise Synthesis of Highly Optically Active Spirooxazolines and the Discovery of a More Potent Oxindole-Type Phytoalexin Analogue Xianxing Jiang, Yiming Cao, Yiqing Wang, Luping Liu, Fangfang Shen, and Rui Wang pp 15328–15333 DOI: 10.1021/ja106349m Supporting Info

Ferromagnetically Coupled Cobalt−Benzene−Cobalt: The Smallest Molecular Spin Filter with Unprecedented Spin Injection Coefficient Sabyasachi Sen and Swapan Chakrabarti pp 15334–15339 DOI: 10.1021/ja106705m Supporting Info

Functionalization of Hafnium Oxamidide Complexes Prepared from CO-Induced N2 Cleavage Donald J. Knobloch, Emil Lobkovsky, and Paul J. Chirik pp 15340–15350 DOI: 10.1021/ja106848y Supporting Info

A Chelator-Free Multifunctional [64Cu]CuS Nanoparticle Platform for Simultaneous Micro-PET/CT Imaging and Photothermal Ablation Therapy Min Zhou, Rui Zhang, Miao Huang, Wei Lu, Shaoli Song, Marites P. Melancon, Mei Tian, Dong Liang, and Chun Li pp 15351–15358 DOI: 10.1021/ja106855m Supporting Info

Context-Dependent Effects of Asparagine Glycosylation on Pin WW Folding Kinetics and Thermodynamics Joshua L. Price, Dalit Shental-Bechor, Apratim Dhar, Maurice J. Turner, Evan T. Powers, Martin Gruebele, Yaakov Levy, and Jeffery W. Kelly pp 15359–15367 DOI: 10.1021/ja106896t Supporting Info

A Hot Oxidant, 3-NO2Y122 Radical, Unmasks Conformational Gating in Ribonucleotide Reductase Kenichi Yokoyama, Ulla Uhlin, and JoAnne Stubbe pp 15368–15379 DOI: 10.1021/ja1069344 Supporting Info

Ambident Reactivities of Pyridone Anions Martin Breugst and Herbert Mayr pp 15380–15389 DOI: 10.1021/ja106962u Supporting Info

Isoreticular Chiral Metal−Organic Frameworks for Asymmetric Alkene Epoxidation: Tuning Catalytic Activity by Controlling Framework Catenation and Varying Open Channel Sizes Feijie Song, Cheng Wang, Joseph M. Falkowski, Liqing Ma, and Wenbin Lin pp 15390–15398 DOI: 10.1021/ja1069773 Supporting Info

Scanning Tunneling Microscopy, Spectroscopy, and Nanolithography of Epitaxial Graphene Chemically Modified with Aryl Moieties Md. Zakir Hossain, Michael A. Walsh, and Mark C. Hersam pp 15399–15403 DOI: 10.1021/ja107085n Supporting Info

Design and Operation of Microelectrochemical Gates and Integrated Circuits Byoung-Yong Chang, John A. Crooks, Kwok-Fan Chow, Franois Mavr, and Richard M. Crooks pp 15404–15409 DOI: 10.1021/ja107095z Supporting Info

Bioconjugation of Ultrabright Semiconducting Polymer Dots for Specific Cellular Targeting Changfeng Wu, Thomas Schneider, Maxwell Zeigler, Jiangbo Yu, Perry G. Schiro, Daniel R. Burnham, Jason D. McNeill, and Daniel T. Chiu pp 15410–15417 DOI: 10.1021/ja107196s Supporting Info

A New Unnatural Base Pair System between Fluorophore and Quencher Base Analogues for Nucleic Acid-Based Imaging Technology Michiko Kimoto, Tsuneo Mitsui, Rie Yamashige, Akira Sato, Shigeyuki Yokoyama, and Ichiro Hirao pp 15418–15426 DOI: 10.1021/ja1072383 Supporting Info

Controlling Electron Transfer in Donor−Bridge−Acceptor Molecules Using Cross-Conjugated Bridges Annie Butler Ricks, Gemma C. Solomon, Michael T. Colvin, Amy M. Scott, Kun Chen, Mark A. Ratner, and Michael R. Wasielewski pp 15427–15434 DOI: 10.1021/ja107420a Supporting Info

Synthesis, Structure, and Dynamic Properties of Hybrid Organic−Inorganic Rotaxanes Beatriz Ballesteros, Thomas B. Faust, Chin-Fa Lee, David A. Leigh, Christopher A. Muryn, Robin G. Pritchard, David Schultz, Simon J. Teat, Grigore A. Timco, and Richard E. P. Winpenny pp 15435–15444 DOI: 10.1021/ja1074773 Supporting Info

Asymmetric Deprotonation using s-BuLi or i-PrLi and Chiral Diamines in THF: The Diamine Matters Giorgio Carbone, Peter O’Brien, and Gran Hilmersson pp 15445–15450 DOI: 10.1021/ja107672h Supporting Info

Biosynthesis of Monomers for Plastics from Renewable Oils Wenhua Lu, Jon E. Ness, Wenchun Xie, Xiaoyan Zhang, Jeremy Minshull, and Richard A. Gross pp 15451–15455 DOI: 10.1021/ja107707v Supporting Info

Crystallographic Characterization of 12-Helical Secondary Structure in β-Peptides Containing Side Chain Groups Soo Hyuk Choi, Ilia A. Guzei, Lara C. Spencer, and Samuel H. Gellman p 15456 DOI: 10.1021/ja1084354

Chiral Recognition in the Gas Phase W. Andy Tao p 15457 DOI: 10.1021/ja108120y

Issue 44

Surface Enhanced NMR Spectroscopy by Dynamic Nuclear Polarization Anne Lesage, Moreno Lelli, David Gajan, Marc A. Caporini, Veronika Vitzthum, Pascal Miville, Johan Alauzun, Arthur Roussey, Chlo Thieuleux, Ahmad Mehdi, Geoffrey Bodenhausen, Christophe Copret, and Lyndon Emsley pp 15459–15461 DOI: 10.1021/ja104771z Supporting Info

Reductions of Challenging Organic Substrates by a Nickel Complex of a Noninnocent Crown Carbene Ligand Neil J. Findlay, Stuart R. Park, Franziska Schoenebeck, Elise Cahard, Sheng-ze Zhou, Leonard E. A. Berlouis, Mark D. Spicer, Tell Tuttle, and John A. Murphy pp 15462–15464 DOI: 10.1021/ja107703n Supporting Info

Solution Synthesis of Large-Scale, High-Sensitivity ZnO/Si Hierarchical Nanoheterostructure Photodetectors Ke Sun, Yi Jing, Namseok Park, Chun Li, Yoshio Bando, and Deli Wang pp 15465–15467 DOI: 10.1021/ja1038424 Supporting Info

Ion Mobility Mass Spectrometry of Two Tetrameric Membrane Protein Complexes Reveals Compact Structures and Differences in Stability and Packing Sheila C. Wang, Argyris Politis, Natalie Di Bartolo, Vassiliy N. Bavro, Stephen J. Tucker, Paula J. Booth, Nelson P. Barrera, and Carol V. Robinson pp 15468–15470 DOI: 10.1021/ja104312e Supporting Info

A DNA Crystal Designed to Contain Two Molecules per Asymmetric Unit Tong Wang, Ruojie Sha, Jens Birktoft, Jianping Zheng, Chengde Mao, and Nadrian C. Seeman pp 15471–15473 DOI: 10.1021/ja104833t Supporting Info

Asymmetric Bromolactonization Using Amino-thiocarbamate Catalyst Ling Zhou, Chong Kiat Tan, Xiaojian Jiang, Feng Chen, and Ying-Yeung Yeung pp 15474–15476 DOI: 10.1021/ja1048972 Supporting Info

Rh(II) Carbene-Promoted Activation of the Anomeric C−H Bond of Carbohydrates: A Stereospecific Entry toward α- and β-Ketopyranosides Mlissa Boultadakis-Arapinis, Pascale Lemoine, Serge Turcaud, Laurent Micouin, and Thomas Lecourt pp 15477–15479 DOI: 10.1021/ja1054065 Supporting Info

Reductive Side of Water Splitting in Artificial Photosynthesis: New Homogeneous Photosystems of Great Activity and Mechanistic Insight Theresa M. McCormick, Brandon D. Calitree, Alexandra Orchard, Nadine D. Kraut, Frank V. Bright, Michael R. Detty, and Richard Eisenberg pp 15480–15483 DOI: 10.1021/ja1057357 Supporting Info

Improved Fitting of Solution X-ray Scattering Data to Macromolecular Structures and Structural Ensembles by Explicit Water Modeling Alexander Grishaev, Liang Guo, Thomas Irving, and Ad Bax pp 15484–15486 DOI: 10.1021/ja106173n Supporting Info

Assessing the Purity of Metal−Organic Frameworks Using Photoluminescence: MOF-5, ZnO Quantum Dots, and Framework Decomposition Patrick L. Feng, John J. Perry IV, Stefan Nikodemski, Benjamin W. Jacobs, Scott T. Meek, and Mark D. Allendorf pp 15487–15489 DOI: 10.1021/ja1065625 Supporting Info

Assembly of Modular Asymmetric Organic−Inorganic Polyoxometalate Hybrids into Anisotropic Nanostructures Mali H. Rosnes, Chiara Musumeci, Chullikkattil P. Pradeep, Jennifer S. Mathieson, De-Liang Long, Yu-Fei Song, Bruno Pignataro, Richard Cogdell, and Leroy Cronin pp 15490–15492 DOI: 10.1021/ja1066338 Supporting Info

Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates Jian-Ping Chen, Chang-Hua Ding, Wei Liu, Xue-Long Hou, and Li-Xin Dai pp 15493–15495 DOI: 10.1021/ja106703y Supporting Info

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF3 Benjamin K. Greve, Kenneth L. Martin, Peter L. Lee, Peter J. Chupas, Karena W. Chapman, and Angus P. Wilkinson pp 15496–15498 DOI: 10.1021/ja106711v Supporting Info

Circular Logic: Nonribosomal Peptide-like Macrocyclization with a Ribosomal Peptide Catalyst John A. McIntosh, Charles R. Robertson, Vinayak Agarwal, Satish K. Nair, Grzegorz W. Bulaj, and Eric W. Schmidt pp 15499–15501 DOI: 10.1021/ja1067806 Supporting Info

Temperature Jump and Fast Photochemical Oxidation Probe Submillisecond Protein Folding Jiawei Chen, Don L. Rempel, and Michael L. Gross pp 15502–15504 DOI: 10.1021/ja106518d

A Water-Soluble Xe@cryptophane-111 Complex Exhibits Very High Thermodynamic Stability and a Peculiar 129Xe NMR Chemical Shift Robert M. Fairchild, Akil I. Joseph, K. Travis Holman, Heather A. Fogarty, Thierry Brotin, Jean-Pierre Dutasta, Cline Boutin, Gaspard Huber, and Patrick Berthault pp 15505–15507 DOI: 10.1021/ja1071515 Supporting Info

Vibrational Predissociation Spectrum of the Carbamate Radical Anion, C5H5N-CO2−, Generated by Reaction of Pyridine with (CO2)m− Michael Z. Kamrath, Rachael A. Relph, and Mark A. Johnson pp 15508–15511 DOI: 10.1021/ja1073036 Supporting Info

Synthesis of Amino Acid Derived Enaminones via Wolff Rearrangement Using Vinylogous Amides as Carbon Nucleophiles Hajime Seki and Gunda I. Georg pp 15512–15513 DOI: 10.1021/ja107329k Supporting Info

Octupole-like Supramolecular Aggregates of Conical Iron Fullerene Complexes into a Three-Dimensional Liquid Crystalline Lattice Chang-Zhi Li, Yutaka Matsuo, and Eiichi Nakamura pp 15514–15515 DOI: 10.1021/ja1073933 Supporting Info

De Novo Design and Molecular Assembly of a Transmembrane Diporphyrin-Binding Protein Complex Ivan V. Korendovych, Alessandro Senes, Yong Ho Kim, James D. Lear, H. Christopher Fry, Michael J. Therien, J. Kent Blasie, F. Ann Walker, and William F. DeGrado pp 15516–15518 DOI: 10.1021/ja107487b Supporting Info

A Colorimetric Sensor Array for Detection of Triacetone Triperoxide Vapor Hengwei Lin and Kenneth S. Suslick pp 15519–15521 DOI: 10.1021/ja107419t Supporting Info

Interaction-Dependent PCR: Identification of Ligand−Target Pairs from Libraries of Ligands and Libraries of Targets in a Single Solution-Phase Experiment Lynn M. McGregor, David J. Gorin, Christoph E. Dumelin, and David R. Liu pp 15522–15524 DOI: 10.1021/ja107677q Supporting Info

Magnesium Coordination-Directed N-Selective Stereospecific Alkylation of 2-Pyridones, Carbamates, and Amides Using α-Halocarboxylic Acids Yuan-Qing Fang, Matthew M. Bio, Karl B. Hansen, Matthew S. Potter, and Andrew Clausen pp 15525–15527 DOI: 10.1021/ja107709w Supporting Info

Total Synthesis of Isokidamycin B. Michael O’Keefe, Douglas M. Mans, David E. Kaelin, Jr, and Stephen F. Martin pp 15528–15530 DOI: 10.1021/ja107926f Supporting Info

Facile Synthesis of 2-(Phenylthio)phenols by Copper(I)-Catalyzed Tandem Transformation of C−S Coupling/C−H Functionalization Runsheng Xu, Jie-Ping Wan, Hui Mao, and Yuanjiang Pan pp 15531–15533 DOI: 10.1021/ja107758d Supporting Info

Palladium-Catalyzed Asymmetric Benzylation of 3-Aryl Oxindoles Barry M. Trost and Lara C. Czabaniuk pp 15534–15536 DOI: 10.1021/ja1079755 Supporting Info

tert-Butoxide-Mediated Arylation of Benzene with Aryl Halides in the Presence of a Catalytic 1,10-Phenanthroline Derivative Eiji Shirakawa, Ken-ichi Itoh, Tomohiro Higashino, and Tamio Hayashi pp 15537–15539 DOI: 10.1021/ja1080822 Supporting Info

Carboranylamidinates Peter Drse, Cristian G. Hrib, and Frank T. Edelmann pp 15540–15541 DOI: 10.1021/ja108051u Supporting Info

Solid-State Photo-CIDNP Effect Observed in Phototropin LOV1-C57S by 13C Magic-Angle Spinning NMR Spectroscopy Smitha Surendran Thamarath, Joachim Heberle, P. J. Hore, Tilman Kottke, and Jrg Matysik pp 15542–15543 DOI: 10.1021/ja1082969 Supporting Info

Mechanistic Studies of the Biosynthesis of 2-Thiosugar: Evidence for the Formation of an Enzyme-Bound 2-Ketohexose Intermediate in BexX-Catalyzed Reaction Eita Sasaki and Hung-wen Liu pp 15544–15546 DOI: 10.1021/ja108061c Supporting Info

Incorporation of Furan into Low Band-Gap Polymers for Efficient Solar Cells Claire H. Woo, Pierre M. Beaujuge, Thomas W. Holcombe, Olivia P. Lee, and Jean M. J. Frchet pp 15547–15549 DOI: 10.1021/ja108115y Supporting Info

Catalytic Enantioselective 1,3-Dipolar Cycloadditions of Nitrones with Propioloylpyrazoles and Acryloylpyrazoles Induced by Chiral π-Cation Catalysts Akira Sakakura, Masahiro Hori, Makoto Fushimi, and Kazuaki Ishihara pp 15550–15552 DOI: 10.1021/ja1081603 Supporting Info

[m × n] Metal Ion Arrays Templated by Coordination Cages Takafumi Osuga, Takashi Murase, Kosuke Ono, Yoshihiro Yamauchi, and Makoto Fujita pp 15553–15555 DOI: 10.1021/ja108367j Supporting Info

Assembly Modulation by Adjusting Countercharges of Heterobimetallic Supramolecular Polymers Composed of Tris(spiroborate) Twin Bowls Hiroshi Danjo, Kadzuya Hirata, Masanori Noda, Susumu Uchiyama, Kiichi Fukui, Masatoshi Kawahata, Isao Azumaya, Kentaro Yamaguchi, and Toshifumi Miyazawa pp 15556–15558 DOI: 10.1021/ja1084964 Supporting Info

Total Synthesis of (+)-Roxaticin via C−C Bond Forming Transfer Hydrogenation: A Departure from Stoichiometric Chiral Reagents, Auxiliaries, and Premetalated Nucleophiles in Polyketide Construction Soo Bong Han, Abbas Hassan, In Su Kim, and Michael J. Krische pp 15559–15561 DOI: 10.1021/ja1082798 Supporting Info

Steam-Stable Zeolitic Imidazolate Framework ZIF-90 Membrane with Hydrogen Selectivity through Covalent Functionalization Aisheng Huang, Wei Dou, and Jrgen Caro pp 15562–15564 DOI: 10.1021/ja108774v Supporting Info

Differential Reactivity between Two Copper Sites in Peptidylglycine α-Hydroxylating Monooxygenase Eduardo E. Chufn, Sean T. Prigge, Xavier Siebert, Betty A. Eipper, Richard E. Mains, and L. Mario Amzel pp 15565–15572 DOI: 10.1021/ja103117r Supporting Info

Amphiphilic Polyethylenes Leading to Surfactant-Free Thermoresponsive Nanoparticles Vladimir A. Kryuchkov, Jean-Christophe Daigle, Kirill M. Skupov, Jérome P. Claverie, and Franoise M. Winnik pp 15573–15579 DOI: 10.1021/ja104182w Supporting Info

Local Cooperativity in an Amyloidogenic State of Human Lysozyme Observed at Atomic Resolution Anne Dhulesia, Nunilo Cremades, Janet R. Kumita, Shang-Te Danny Hsu, Maria F. Mossuto, Mireille Dumoulin, Daniel Nietlispach, Mikael Akke, Xavier Salvatella, and Christopher M. Dobson pp 15580–15588 DOI: 10.1021/ja103524m Supporting Info

Disparate Effects of Cu and V on Structures of Exohedral Transition Metal-Doped Silicon Clusters: A Combined Far-Infrared Spectroscopic and Computational Study Vu Thi Ngan, Philipp Gruene, Pieterjan Claes, Ewald Janssens, Andr Fielicke, Minh Tho Nguyen, and Peter Lievens pp 15589–15602 DOI: 10.1021/ja105099u Supporting Info

Control of Electronic Structure of Graphene by Various Dopants and Their Effects on a Nanogenerator Hyeon-Jin Shin, Won Mook Choi, Dukhyun Choi, Gang Hee Han, Seon-Mi Yoon, Hyun-Kyu Park, Sang-Woo Kim, Yong Wan Jin, Sang Yoon Lee, Jong Min Kim, Jae-Young Choi, and Young Hee Lee pp 15603–15609 DOI: 10.1021/ja105140e Supporting Info

1,4-Addition of Lithium Diisopropylamide to Unsaturated Esters: Role of Rate-Limiting Deaggregation, Autocatalysis, Lithium Chloride Catalysis, and Other Mixed Aggregation Effects Yun Ma, Alexander C. Hoepker, Lekha Gupta, Marc F. Faggin, and David B. Collum pp 15610–15623 DOI: 10.1021/ja105855v Supporting Info

Electrophoretic Mobilities of PEGylated Gold NPs Tennyson L. Doane, Yu Cheng, Amir Babar, Reghan J. Hill, and Clemens Burda pp 15624–15631 DOI: 10.1021/ja1049093 Supporting Info

Elementary Building Blocks of Self-Assembled Peptide Nanotubes Nadav Amdursky, Michel Molotskii, Ehud Gazit, and Gil Rosenman pp 15632–15636 DOI: 10.1021/ja104373e Supporting Info

Restricted Guest Tumbling in Phosphorylated Self-Assembled Capsules Steven Harthong, Batrice Dubessy, Jrme Vachon, Christophe Aronica, Jean-Christophe Mulatier, and Jean-Pierre Dutasta pp 15637–15643 DOI: 10.1021/ja104388t Supporting Info

Photocaged Morpholino Oligomers for the Light-Regulation of Gene Function in Zebrafish and Xenopus Embryos Alexander Deiters, R. Aaron Garner, Hrvoje Lusic, Jeane M. Govan, Mike Dush, Nanette M. Nascone-Yoder, and Jeffrey A. Yoder pp 15644–15650 DOI: 10.1021/ja1053863 Supporting Info

High-Resolution 19F MAS NMR Spectroscopy: Structural Disorder and Unusual J Couplings in a Fluorinated Hydroxy-Silicate John M. Griffin, Jonathan R. Yates, Andrew J. Berry, Stephen Wimperis, and Sharon E. Ashbrook pp 15651–15660 DOI: 10.1021/ja105347q Supporting Info

Tailoring Enzyme-Rich Environmental DNA Clones: A Source of Enzymes for Generating Libraries of Unnatural Natural Products Jacob J. Banik, Jeffrey W. Craig, Paula Y. Calle, and Sean F. Brady pp 15661–15670 DOI: 10.1021/ja105825a Supporting Info

Influence of Concentration and Temperature on the Dynamics of Water in the Hydrophobic Hydration Shell of Tetramethylurea Klaas-Jan Tielrooij, Johannes Hunger, Richard Buchner, Mischa Bonn, and Huib J. Bakker pp 15671–15678 DOI: 10.1021/ja106273w

Beryllosilicate Frameworks and Zeolites Jennifer A. Armstrong and Mark T. Weller pp 15679–15686 DOI: 10.1021/ja106313p Supporting Info

Growth of Metal−Organic Frameworks on Polymer Surfaces Andrea Centrone, Ying Yang, Scott Speakman, Lev Bromberg, Gregory C. Rutledge, and T. Alan Hatton pp 15687–15691 DOI: 10.1021/ja106381x Supporting Info

Optimized Measurement Temperature Gives Access to the Solution Structure of a 49 kDa Homohexameric β-Propeller Ilka Varnay, Vincent Truffault, Sergej Djuranovic, Astrid Ursinus, Murray Coles, and Horst Kessler pp 15692–15698 DOI: 10.1021/ja1064608

QM/MD Simulation of SWNT Nucleation on Transition-Metal Carbide Nanoparticles Alister J. Page, Honami Yamane, Yasuhito Ohta, Stephan Irle, and Keiji Morokuma pp 15699–15707 DOI: 10.1021/ja106264q Supporting Info

Replacing 32 Proline Residues by a Noncanonical Amino Acid Results in a Highly Active DNA Polymerase Bastian Holzberger and Andreas Marx pp 15708–15713 DOI: 10.1021/ja106525y Supporting Info

Shape-Dependent Catalytic Properties of Pt Nanoparticles Simon Mostafa, Farzad Behafarid, Jason R. Croy, Luis K. Ono, Long Li, Judith C. Yang, Anatoly I. Frenkel, and Beatriz Roldan Cuenya pp 15714–15719 DOI: 10.1021/ja106679z Supporting Info

The Origin of Charge Localization Observed in Organic Photovoltaic Materials James E. Johns, Eric A. Muller, Jean M. J. Frechet, and Charles B. Harris pp 15720–15725 DOI: 10.1021/ja1066866

Acyclic Chelate with Ideal Properties for 68Ga PET Imaging Agent Elaboration Eszter Boros, Cara L. Ferreira, Jacqueline F. Cawthray, Eric W. Price, Brian O. Patrick, Dennis W. Wester, Michael J. Adam, and Chris Orvig pp 15726–15733 DOI: 10.1021/ja106399h Supporting Info

A Systems Approach to Controlling Supramolecular Architecture and Emergent Solution Properties via Host−Guest Complexation in Water Dezhi Jiao, Frank Biedermann, Feng Tian, and Oren A. Scherman pp 15734–15743 DOI: 10.1021/ja106716j Supporting Info

Manipulating the Stereoselectivity of Limonene Epoxide Hydrolase by Directed Evolution Based on Iterative Saturation Mutagenesis Huabao Zheng and Manfred T. Reetz pp 15744–15751 DOI: 10.1021/ja1067542 Supporting Info

Preparative and Mechanistic Studies toward the Rational Development of Catalytic, Enantioselective Selenoetherification Reactions Scott E. Denmark, Dipannita Kalyani, and William R. Collins pp 15752–15765 DOI: 10.1021/ja106837b Supporting Info

Two-Way Photoswitching Using One Type of Near-Infrared Light, Upconverting Nanoparticles, and Changing Only the Light Intensity John-Christopher Boyer, Carl-Johan Carling, Byron D. Gates, and Neil R. Branda pp 15766–15772 DOI: 10.1021/ja107184z Supporting Info

The Nonribosomal Peptide Synthetase Enzyme DdaD Tethers Nβ-Fumaramoyl-l-2,3-diaminopropionate for Fe(II)/α-Ketoglutarate-Dependent Epoxidation by DdaC during Dapdiamide Antibiotic Biosynthesis Marie A. Hollenhorst, Stefanie B. Bumpus, Megan L. Matthews, J. Martin Bollinger, Jr., Neil L. Kelleher, and Christopher T. Walsh pp 15773–15781 DOI: 10.1021/ja1072367 Supporting Info

Controlled Plasmon Resonance Properties of Hollow Gold Nanosphere Aggregates Manabendra Chandra, Anne-Marie Dowgiallo, and Kenneth L. Knappenberger, Jr. pp 15782–15789 DOI: 10.1021/ja106910x Supporting Info

Synthesis of Phototrappable Shape-Shifting Molecules for Adaptive Guest Binding Alexander R. Lippert, Atsushi Naganawa, Vasken L. Keleshian, and Jeffrey W. Bode pp 15790–15799 DOI: 10.1021/ja107314p Supporting Info

Palladium-Catalyzed Dynamic Kinetic Asymmetric Transformations of Vinyl Aziridines with Nitrogen Heterocycles: Rapid Access to Biologically Active Pyrroles and Indoles Barry M. Trost, Maksim Osipov, and Guangbin Dong pp 15800–15807 DOI: 10.1021/ja1071509 Supporting Info

Hydrophobic Self-Assembly of a Perylenediimide-Linked DNA Dumbbell into Supramolecular Polymers Prakash P. Neelakandan, Zhengzheng Pan, Mahesh Hariharan, Yan Zheng, Haim Weissman, Boris Rybtchinski, and Frederick D. Lewis pp 15808–15813 DOI: 10.1021/ja1076525 Supporting Info

Pyridine-Functionalized Single-Walled Carbon Nanotubes as Gelators for Poly(acrylic acid) Hydrogels Mustafa K. Bayazit, Lucinda S. Clarke, Karl S. Coleman, and Nigel Clarke pp 15814–15819 DOI: 10.1021/ja1076662 Supporting Info

A Conserved Helical Capping Hydrogen Bond in PAS Domains Controls Signaling Kinetics in the Superfamily Prototype Photoactive Yellow Protein Masato Kumauchi, Sandip Kaledhonkar, Andrew F. Philip, James Wycoff, Miwa Hara, Yunxing Li, Aihua Xie, and Wouter D. Hoff pp 15820–15830 DOI: 10.1021/ja107716r Supporting Info

Conformational Control of Thymine Photodimerization in Single-Strand and Duplex DNA Containing Locked Nucleic Acid TT Steps Mahesh Hariharan, Martin McCullagh, George C. Schatz, and Frederick D. Lewis p 15831 DOI: 10.1021/ja108528q

Carbon-Centered Free Radicals and Radical Cations: Structure, Reactivity, and Dynamics Lawrence J. Berliner p 15832 DOI: 10.1021/ja1084833

Issue 45

Supramolecular and Chemical Cascade Approaches to Molecular Sensing Eric V. Anslyn pp 15833–15835 DOI: 10.1021/ja108349y

Enantioselective [2 + 2 + 2] Cycloaddition Reaction of Isocyanates and Allenes Catalyzed by Nickel Tomoya Miura, Masao Morimoto, and Masahiro Murakami pp 15836–15838 DOI: 10.1021/ja105541r Supporting Info

3-D Carbon Nanotube Structures Used as High Performance Catalyst for Oxygen Reduction Reaction Wei Xiong, Feng Du, Yong Liu, Albert Perez, Jr., Michael Supp, Terizhandur S. Ramakrishnan, Liming Dai, and Li Jiang pp 15839–15841 DOI: 10.1021/ja104425h Supporting Info

Single Crystal-to-Single Crystal Irreversible Transformation from a Discrete Vanadium(V)−Alcoholate to an Aldehydic-Vanadium(IV) Oligomer Pabitra Baran Chatterjee, Anandalok Audhya, Subhajit Bhattacharya, Sk Md Towsif Abtab, Kisholoy Bhattacharya, and Muktimoy Chaudhury pp 15842–15845 DOI: 10.1021/ja103451j Supporting Info

Hypoxia-Sensitive Fluorescent Probes for in Vivo Real-Time Fluorescence Imaging of Acute Ischemia Kazuki Kiyose, Kenjiro Hanaoka, Daihi Oushiki, Tomomi Nakamura, Mayumi Kajimura, Makoto Suematsu, Hiroaki Nishimatsu, Takehiro Yamane, Takuya Terai, Yasunobu Hirata, and Tetsuo Nagano pp 15846–15848 DOI: 10.1021/ja105937q Supporting Info

Oxidation Does Not (Always) Kill Reactivity of Transition Metals: Solution-Phase Conversion of Nanoscale Transition Metal Oxides to Phosphides and Sulfides Elayaraja Muthuswamy and Stephanie L. Brock pp 15849–15851 DOI: 10.1021/ja106397b Supporting Info

Synthesis of Water-Tolerant Indium Homoenolate in Aqueous Media and Its Application in the Synthesis of 1,4-Dicarbonyl Compounds via Palladium-Catalyzed Coupling with Acid Chloride Zhi-Liang Shen, Kelvin Kau Kiat Goh, Hao-Lun Cheong, Colin Hong An Wong, Yin-Chang Lai, Yong-Sheng Yang, and Teck-Peng Loh pp 15852–15855 DOI: 10.1021/ja106925f Supporting Info

QM/MM Study of Dehydro and Dihydro β-Ionone Retinal Analogues in Squid and Bovine Rhodopsins: Implications for Vision in Salamander Rhodopsin Sivakumar Sekharan, Ahmet Altun, and Keiji Morokuma pp 15856–15859 DOI: 10.1021/ja105050p Supporting Info

Cu(I)−Amido Complexes in the Ullmann Reaction: Reactions of Cu(I)−Amido Complexes with Iodoarenes with and without Autocatalysis by CuI Ramesh Giri and John F. Hartwig pp 15860–15863 DOI: 10.1021/ja105695s Supporting Info

Synthesis and Structure of Technetium Trichloride Frederic Poineau, Erik V. Johnstone, Philippe F. Weck, Eunja Kim, Paul M. Forster, Brian L. Scott, Alfred P. Sattelberger, and Kenneth R. Czerwinski pp 15864–15865 DOI: 10.1021/ja105730e Supporting Info

Alkyl Chains of Surface Ligands Affect Polytypism of CdSe Nanocrystals and Play an Important Role in the Synthesis of Anisotropic Nanoheterostructures Jing Huang, Maksym V. Kovalenko, and Dmitri V. Talapin pp 15866–15868 DOI: 10.1021/ja105132u Supporting Info

An Anionic, Tetragonal Copper(II) Superoxide Complex Patrick J. Donoghue, Aalo K. Gupta, David W. Boyce, Christopher J. Cramer, and William B. Tolman pp 15869–15871 DOI: 10.1021/ja106244k Supporting Info

Surface Modification of Self-Assembled One-Dimensional Organic Structures: White-Light Emission and Beyond Xiao Wang, Jing Yan, Yan Zhou, and Jian Pei pp 15872–15874 DOI: 10.1021/ja106354m Supporting Info

CrSi2 Hexagonal Nanowebs Huatao Wang, Jian-Chun Wu, Yiqiang Shen, Gongping Li, Zhou Zhang, Guozhong Xing, Donglai Guo, Dandan Wang, Zhili Dong, and Tom Wu pp 15875–15877 DOI: 10.1021/ja106402p Supporting Info

Method for the Synthesis of Mono-ADP-ribose Conjugated Peptides Peter M. Moyle and Tom W. Muir pp 15878–15880 DOI: 10.1021/ja1064312 Supporting Info

Targeting of Cancer Cells Using Click-Functionalized Polymer Capsules Marloes M. J. Kamphuis, Angus P. R. Johnston, Georgina K. Such, Henk H. Dam, Richard A. Evans, Andrew M. Scott, Edouard C. Nice, Joan K. Heath, and Frank Caruso pp 15881–15883 DOI: 10.1021/ja106405c Supporting Info

Selective Syntheses of Iron−Imide−Sulfide Cubanes, Including a Partial Representation of the Fe−S−X Environment in the FeMo Cofactor Xu-Dong Chen, Jeremiah S. Duncan, Atul K. Verma, and Sonny C. Lee pp 15884–15886 DOI: 10.1021/ja106478k Supporting Info

Acidic Polysaccharide Mimics via Ring-Opening Metathesis Polymerization Michel Wathier, Stephanie S. Stoddart, Matthew J. Sheehy, and Mark W. Grinstaff pp 15887–15889 DOI: 10.1021/ja106488h Supporting Info

An Isolable Bis-Silylene Oxide (“Disilylenoxane”) and Its Metal Coordination Wenyuan Wang, Shigeyoshi Inoue, Shenglai Yao, and Matthias Driess pp 15890–15892 DOI: 10.1021/ja106458p Supporting Info

Iron-Facilitated Direct Oxidative C−H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles Chong Qin and Ning Jiao pp 15893–15895 DOI: 10.1021/ja1070202 Supporting Info

Hydrogen-Storage Properties of Solid-Solution Alloys of Immiscible Neighboring Elements with Pd Kohei Kusada, Miho Yamauchi, Hirokazu Kobayashi, Hiroshi Kitagawa, and Yoshiki Kubota pp 15896–15898 DOI: 10.1021/ja107362z Supporting Info

Bivalent Ligands of CXCR4 with Rigid Linkers for Elucidation of the Dimerization State in Cells Tomohiro Tanaka, Wataru Nomura, Tetsuo Narumi, Akemi Masuda, and Hirokazu Tamamura pp 15899–15901 DOI: 10.1021/ja107447w Supporting Info

Electronic Effects on Atom Tunneling: Conformational Isomerization of Monomeric Para-Substituted Benzoic Acid Derivatives Shadi Amiri, Hans Peter Reisenauer, and Peter R. Schreiner pp 15902–15904 DOI: 10.1021/ja107531y Supporting Info

Infrared Spectroscopy of Extreme Coordination: The Carbonyls of U+ and UO2+ Allen M. Ricks, Laura Gagliardi, and Michael A. Duncan pp 15905–15907 DOI: 10.1021/ja1077365 Supporting Info

Nitroxide-Substituted Nitronyl Nitroxide and Iminonitroxide Shuichi Suzuki, Takanori Furui, Masato Kuratsu, Masatoshi Kozaki, Daisuke Shiomi, Kazunobu Sato, Takeji Takui, and Keiji Okada pp 15908–15910 DOI: 10.1021/ja107769z Supporting Info

Hydrogen-Bond-Mediated Enantio- and Regioselectivity in a Ru-Catalyzed Epoxidation Reaction Philipp Fackler, Carola Berthold, Felix Voss, and Thorsten Bach pp 15911–15913 DOI: 10.1021/ja107601k Supporting Info

A Multiligand Based Pd Catalyst for C−N Cross-Coupling Reactions Brett P. Fors and Stephen L. Buchwald pp 15914–15917 DOI: 10.1021/ja108074t Supporting Info

Propulsion of Microobjects by Dynamic Bipolar Self-Regeneration Gabriel Loget and Alexander Kuhn pp 15918–15919 DOI: 10.1021/ja107644x Supporting Info

Metal-Enhanced Fluorescence of Carbon Nanotubes Guosong Hong, Scott M. Tabakman, Kevin Welsher, Hailiang Wang, Xinran Wang, and Hongjie Dai pp 15920–15923 DOI: 10.1021/ja1087997 Supporting Info

Linear 6,6′-Biazulenyl Framework Featuring Isocyanide Termini: Synthesis, Structure, Redox Behavior, Complexation, and Self-Assembly on Au(111) Tiffany R. Maher, Andrew D. Spaeth, Brad M. Neal, Cindy L. Berrie, Ward H. Thompson, Victor W. Day, and Mikhail V. Barybin pp 15924–15926 DOI: 10.1021/ja108202d Supporting Info

Guanine- and Potassium-Based Two-Dimensional Coordination Network Self-Assembled on Au(111) Wei Xu, Jian-guo Wang, Miao Yu, Erik Lægsgaard, Ivan Stensgaard, Trolle R. Linderoth, Bjørk Hammer, Chen Wang, and Flemming Besenbacher pp 15927–15929 DOI: 10.1021/ja1078909 Supporting Info

Well-Defined DNA Nanoparticles Templated by Self-Assembled M12L24 Molecular Spheres and Binding of Complementary Oligonucleotides Takashi Kikuchi, Sota Sato, and Makoto Fujita pp 15930–15932 DOI: 10.1021/ja108334g Supporting Info

From an Eight-Component Self-Sorting Algorithm to a Trisheterometallic Scalene Triangle Kingsuk Mahata, Manik Lal Saha, and Michael Schmittel pp 15933–15935 DOI: 10.1021/ja108419k Supporting Info

Molecular Stress Relief through a Force-Induced Irreversible Extension in Polymer Contour Length Dong Wu, Jeremy M. Lenhardt, Ashley L. Black, Boris B. Akhremitchev, and Stephen L. Craig pp 15936–15938 DOI: 10.1021/ja108429h Supporting Info

Chiral Bicycle Imidazole Nucleophilic Catalysts: Rational Design, Facile Synthesis, and Successful Application in Asymmetric Steglich Rearrangement Zhenfeng Zhang, Fang Xie, Jia Jia, and Wanbin Zhang pp 15939–15941 DOI: 10.1021/ja109069k Supporting Info

Solution NMR Structure of the TatA Component of the Twin-Arginine Protein Transport System from Gram-Positive Bacterium Bacillus subtilis Yunfei Hu, Enwei Zhao, Hongwei Li, Bin Xia, and Changwen Jin pp 15942–15944 DOI: 10.1021/ja1053785 Supporting Info

Membrane Alignment of the Pore-Forming Component TatAd of the Twin-Arginine Translocase from Bacillus subtilis Resolved by Solid-State NMR Spectroscopy Torsten H. Walther, Stephan L. Grage, Nadine Roth, and Anne S. Ulrich pp 15945–15956 DOI: 10.1021/ja106963s Supporting Info

Quantitative Analysis of Protein Backbone Dynamics in Microcrystalline Ubiquitin by Solid-State NMR Spectroscopy Paul Schanda, Beat H. Meier, and Matthias Ernst pp 15957–15967 DOI: 10.1021/ja100726a Supporting Info

Ozone Oxidation of Surface-Adsorbed Polycyclic Aromatic Hydrocarbons: Role of PAH−Surface Interaction Sophie N. Chu, Sophia Sands, Michelle R. Tomasik, Paul S. Lee, and V. Faye McNeill pp 15968–15975 DOI: 10.1021/ja1014772 Supporting Info

Synthesis and Shape Control of CuInS2 Nanoparticles Marta Kruszynska, Holger Borchert, Jrgen Parisi, and Joanna Kolny-Olesiak pp 15976–15986 DOI: 10.1021/ja103828f Supporting Info

Heteroleptic Copper Switches Sanaz Kabehie, Mei Xue, Adam Z. Stieg, Monty Liong, Kang L. Wang, and Jeffrey I. Zink pp 15987–15996 DOI: 10.1021/ja103937v Supporting Info

Synthesis and Magnetic Properties of Gd Doped EuS Nanocrystals with Enhanced Curie Temperatures Rachel S. Selinsky, Jae Hyo Han, Elvin A. Morales Prez, Ilia A. Guzei, and Song Jin pp 15997–16005 DOI: 10.1021/ja104314c Supporting Info

Effect of the Basic Residue on the Energetics, Dynamics, and Mechanisms of Gas-Phase Fragmentation of Protonated Peptides Julia Laskin, Zhibo Yang, Tao Song, Corey Lam, and Ivan K. Chu pp 16006–16016 DOI: 10.1021/ja104438z Supporting Info

Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis James D. Blakemore, Nathan D. Schley, David Balcells, Jonathan F. Hull, Gerard W. Olack, Christopher D. Incarvito, Odile Eisenstein, Gary W. Brudvig, and Robert H. Crabtree pp 16017–16029 DOI: 10.1021/ja104775j Supporting Info

Why Did Incorporation of Acrylonitrile to a Linear Polyethylene Become Possible? Comparison of Phosphine−Sulfonate Ligand with Diphosphine and Imine−Phenolate Ligands in the Pd-Catalyzed Ethylene/Acrylonitrile Copolymerization Kyoko Nozaki, Shuhei Kusumoto, Shusuke Noda, Takuya Kochi, Lung Wa Chung, and Keiji Morokuma pp 16030–16042 DOI: 10.1021/ja104837h Supporting Info

A Stilbene That Binds Selectively to Transthyretin in Cells and Remains Dark until It Undergoes a Chemoselective Reaction To Create a Bright Blue Fluorescent Conjugate Sungwook Choi, Derrick Sek Tong Ong, and Jeffery W. Kelly pp 16043–16051 DOI: 10.1021/ja104999v Supporting Info

Plant Cell-Wall Cross-Links by REDOR NMR Spectroscopy Lynette Cegelski, Robert D. O’Connor, Dirk Stueber, Manmilan Singh, Barbara Poliks, and Jacob Schaefer pp 16052–16057 DOI: 10.1021/ja104827k

The Conformational Free-Energy Landscape of β-d-Mannopyranose: Evidence for a 1S5 → B2,5 → OS2 Catalytic Itinerary in β-Mannosidases Albert Ardvol, Xevi Biarns, Antoni Planas, and Carme Rovira pp 16058–16065 DOI: 10.1021/ja105520h Supporting Info

Lipid Domain Specific Recruitment of Lipophilic Nucleic Acids: A Key for Switchable Functionalization of Membranes Martin Loew, Ralph Springer, Silvia Scolari, Frank Altenbrunn, Oliver Seitz, Jrgen Liebscher, Daniel Huster, Andreas Herrmann, and Anna Arbuzova pp 16066–16072 DOI: 10.1021/ja105714r Supporting Info

Structural Analysis of an Unusual Bioactive N-Acylated Lipo-Oligosaccharide LOS-IV in Mycobacterium marinum Yoann Rombouts, Elisabeth Elass, Christophe Biot, Emmanuel Maes, Bernadette Coddeville, Adeline Burguire, Caroline Tokarski, Eric Buisine, Xavier Trivelli, Laurent Kremer, and Yann Gurardel pp 16073–16084 DOI: 10.1021/ja105807s Supporting Info

Palladium/Nickel-Cocatalyzed Cycloaddition of 1,3-Dehydro-o-Carborane with Alkynes. Facile Synthesis of C,B-Substituted Carboranes Zaozao Qiu and Zuowei Xie pp 16085–16093 DOI: 10.1021/ja1058789 Supporting Info

Electronic Modification of the [RuII(tpy)(bpy)(OH2)]2+ Scaffold: Effects on Catalytic Water Oxidation Derek J. Wasylenko, Chelladurai Ganesamoorthy, Matthew A. Henderson, Bryan D. Koivisto, Hans D. Osthoff, and Curtis P. Berlinguette pp 16094–16106 DOI: 10.1021/ja106108y Supporting Info

Force-Induced Redistribution of a Chemical Equilibrium Corissa K. Lee, Douglas A. Davis, Scott R. White, Jeffrey S. Moore, Nancy R. Sottos, and Paul V. Braun pp 16107–16111 DOI: 10.1021/ja106332g Supporting Info

Hierarchical Self-Assembly of a Biomimetic Diblock Copolypeptoid into Homochiral Superhelices Hannah K. Murnen, Adrianne M. Rosales, Jonathan N. Jaworski, Rachel A. Segalman, and Ronald N. Zuckermann pp 16112–16119 DOI: 10.1021/ja106340f Supporting Info

A Mechanistic Study of Electron Transfer from the Distal Termini of Electrode-Bound, Single-Stranded DNAs Takanori Uzawa, Ryan R. Cheng, Ryan J. White, Dmitrii E. Makarov, and Kevin W. Plaxco pp 16120–16126 DOI: 10.1021/ja106345d Supporting Info

Promotion of the Oxidation of Carbon Monoxide at Stepped Platinum Single-Crystal Electrodes in Alkaline Media by Lithium and Beryllium Cations Chantal Stoffelsma, Paramaconi Rodriguez, Gonzalo Garcia, Nuria Garcia-Araez, Dusan Strmcnik, Nenad M. Markovi, and Marc T. M. Koper pp 16127–16133 DOI: 10.1021/ja106389k

Design, Synthesis, and Operation of Small Molecules That Walk along Tracks Max von Delius, Edzard M. Geertsema, David A. Leigh, and Dan-Tam D. Tang pp 16134–16145 DOI: 10.1021/ja106486b Supporting Info

Inducing Single-Molecule Magnetism in a Family of Loop-of-Loops Aggregates: Heterometallic Mn40Na4 Clusters and the Homometallic Mn44 Analogue Eleni E. Moushi, Christos Lampropoulos, Wolfgang Wernsdorfer, Vassilios Nastopoulos, George Christou, and Anastasios J. Tasiopoulos pp 16146–16155 DOI: 10.1021/ja106666h Supporting Info

Fluorescence Resonance Energy Transfer in Gaseous, Mass-Selected Polyproline Peptides Francis O. Talbot, Anthony Rullo, Huihui Yao, and Rebecca A. Jockusch pp 16156–16164 DOI: 10.1021/ja1067405 Supporting Info

Saturation of Surfactant Structure at the Single-Walled Carbon Nanotube Surface Juan G. Duque, Crystal G. Densmore, and Stephen K. Doorn pp 16165–16175 DOI: 10.1021/ja106836f Supporting Info

Nucleotide Recognition and Phosphate Linkage Hydrolysis at a Lipid Cubic Interface Sergio Murgia, Sandrina Lampis, Paolo Zucca, Enrico Sanjust, and Maura Monduzzi pp 16176–16184 DOI: 10.1021/ja1069745

Site Specific X-ray Anomalous Dispersion of the Geometrically Frustrated Kagom Magnet, Herbertsmithite, ZnCu3(OH)6Cl2 Danna E. Freedman, Tianheng H. Han, Andrea Prodi, Peter Mller, Qing-Zhen Huang, Yu-Sheng Chen, Samuel M. Webb, Young S. Lee, Tyrel M. McQueen, and Daniel G. Nocera pp 16185–16190 DOI: 10.1021/ja1070398

Enhanced Hopping Conductivity in Low Band Gap Donor−Acceptor Molecular Wires Up to 20 nm in Length Seong Ho Choi and C. Daniel Frisbie pp 16191–16201 DOI: 10.1021/ja1060142 Supporting Info

Phthalocyanine−Pyrene Conjugates: A Powerful Approach toward Carbon Nanotube Solar Cells Juergen Bartelmess, Beatriz Ballesteros, Gema de la Torre, Daniel Kiessling, Stephane Campidelli, Maurizio Prato, Toms Torres, and Dirk M. Guldi pp 16202–16211 DOI: 10.1021/ja107131r Supporting Info

Hysteretic Spin Crossover between a Bisdithiazolyl Radical and Its Hypervalent σ-Dimer Kristina Lekin, Stephen M. Winter, Laura E. Downie, Xuezhao Bao, John S. Tse, Serge Desgreniers, Richard A. Secco, Paul A. Dube, and Richard T. Oakley pp 16212–16224 DOI: 10.1021/ja106768z Supporting Info

Intricate Role of Water in Proton Transport through Cytochrome c Oxidase Hyun Ju Lee, Emelie Svahn, Jessica M. J. Swanson, Håkan Lepp, Gregory A. Voth, Peter Brzezinski, and Robert B. Gennis pp 16225–16239 DOI: 10.1021/ja107244g

Understanding Cold Denaturation: The Case Study of Yfh1 Miquel Adrover, Veronica Esposito, Gabriel Martorell, Annalisa Pastore, and Piero Andrea Temussi pp 16240–16246 DOI: 10.1021/ja1070174 Supporting Info

A Paradigm for Blue- or Red-Shifted Absorption of Small Molecules Depending on the Site of π-Extension Kenneth Hanson, Luke Roskop, Peter I. Djurovich, Federico Zahariev, Mark S. Gordon, and Mark E. Thompson pp 16247–16255 DOI: 10.1021/ja1075162 Supporting Info

Encapsulated Guest−Host Dynamics: Guest Rotational Barriers and Tumbling as a Probe of Host Interior Cavity Space Jeffrey S. Mugridge, Gza Szigethy, Robert G. Bergman, and Kenneth N. Raymond pp 16256–16264 DOI: 10.1021/ja107656g Supporting Info

Polymersomes with Ionic Liquid Interiors Dispersed in Water Zhifeng Bai and Timothy P. Lodge pp 16265–16270 DOI: 10.1021/ja107751k Supporting Info

Engineering Nonspherical Hollow Structures with Complex Interiors by Template-Engaged Redox Etching Zhiyu Wang, Deyan Luan, Chang Ming Li, Fabing Su, Srinivasan Madhavi, Freddy Yin Chiang Boey, and Xiong Wen Lou pp 16271–16277 DOI: 10.1021/ja107871r Supporting Info

C−H vs C−C Bond Activation of Acetonitrile and Benzonitrile via Oxidative Addition: Rhodium vs Nickel and Cp* vs Tp′ (Tp′ = Hydrotris(3,5-dimethylpyrazol-1-yl)borate, Cp* = η5-Pentamethylcyclopentadienyl) Meagan E. Evans, Ting Li, and William D. Jones pp 16278–16284 DOI: 10.1021/ja107927b Supporting Info

Theoretical Study on the Repair Mechanism of the (6−4) Photolesion by the (6−4) Photolyase Keyarash Sadeghian, Marco Bocola, Thomas Merz, and Martin Schtz pp 16285–16295 DOI: 10.1021/ja108336t Supporting Info

Tailoring DNA Structure To Increase Target Hybridization Kinetics on Surfaces Andrew E. Prigodich, One-Sun Lee, Weston L. Daniel, Dwight S. Seferos, George C. Schatz, and Chad A. Mirkin p 16296 DOI: 10.1021/ja1087419

Optically Active Calixarenes Conduced by Methylene Substitution Vijay Gopalsamuthiram, Alexander V. Predeus, Rui H. Huang, and William D. Wulff p 16296 DOI: 10.1021/ja108878e

Carbohydrates: Synthesis, Mechanisms, and Stereoelectronic Effects Alexei V. Demchenko p 16297 DOI: 10.1021/ja108877p

Reactive Intermediates: MS Investigations in Solution Victor Ryzhov pp 16297–16298 DOI: 10.1021/ja109079h

Issue 46

mpg-C3N4-Catalyzed Selective Oxidation of Alcohols Using O2 and Visible Light Fangzheng Su, Smitha C. Mathew, Grzegorz Lipner, Xianzhi Fu, Markus Antonietti, Siegfried Blechert, and Xinchen Wang pp 16299–16301 DOI: 10.1021/ja102866p Supporting Info

High Triplet Yield from Singlet Fission in a Thin Film of 1,3-Diphenylisobenzofuran Justin C. Johnson, Arthur J. Nozik, and Josef Michl pp 16302–16303 DOI: 10.1021/ja104123r Supporting Info

Ag9 Quantum Cluster through a Solid-State Route Thumu Udaya B. Rao, Bodappa Nataraju, and Thalappil Pradeep pp 16304–16307 DOI: 10.1021/ja105495n Supporting Info

Enhanced Critical Temperature in a Dual-Layered Molecular Superconductor John A. Schlueter, Leonore Wiehl, Hyunsoo Park, Mariano de Souza, Michael Lang, Hyun-Joo Koo, and Myung-Hwan Whangbo pp 16308–16310 DOI: 10.1021/ja105854m Supporting Info

Visualization of Dynamic Conformational Switching of the G-Quadruplex in a DNA Nanostructure Yuta Sannohe, Masayuki Endo, Yousuke Katsuda, Kumi Hidaka, and Hiroshi Sugiyama pp 16311–16313 DOI: 10.1021/ja1058907 Supporting Info

Enzymatically Triggered Actuation of Miniaturized Tools Noy Bassik, Alla Brafman, Aasiyeh M. Zarafshar, Mustapha Jamal, Delgermaa Luvsanjav, Florin M. Selaru, and David H. Gracias pp 16314–16317 DOI: 10.1021/ja106218s Supporting Info

Theory of Hydride-Proton Transfer (HPT) Carbonyl Reduction by [OsIII(tpy)(Cl)(NH═CHCH3)(NSAr)] Daniel H. Ess, Cynthia K. Schauer, and Thomas J. Meyer pp 16318–16320 DOI: 10.1021/ja106403e Supporting Info

Carbene-Stabilized Phosphorus(III)-Centered Cations [LPX2]+ and [L2PX]2+ (L = NHC; X = Cl, CN, N3) Jan J. Weigand, Kai-Oliver Feldmann, and Florian D. Henne pp 16321–16323 DOI: 10.1021/ja106172d Supporting Info

NosA Catalyzing Carboxyl-Terminal Amide Formation in Nosiheptide Maturation via an Enamine Dealkylation on the Serine-Extended Precursor Peptide Yi Yu, Heng Guo, Qi Zhang, Lian Duan, Ying Ding, Rijing Liao, Chun Lei, Ben Shen, and Wen Liu pp 16324–16326 DOI: 10.1021/ja106571g Supporting Info

Coordination-Driven Self Assembly of a Brilliantly Fluorescent Rhomboid Cavitand Composed of Bodipy-Dye Subunits Antonia Kaloudi-Chantzea, Nikolaos Karakostas, Catherine P. Raptopoulou, Vassilis Psycharis, Emmanuel Saridakis, Jan Griebel, Ralf Hermann, and George Pistolis pp 16327–16329 DOI: 10.1021/ja1064679 Supporting Info

Regio- and Enantioselective Intermolecular Hydroacylation: Substrate-Directed Addition of Salicylaldehydes to Homoallylic Sulfides Matthew M. Coulter, Kevin G. M. Kou, Baye Galligan, and Vy M. Dong pp 16330–16333 DOI: 10.1021/ja107198e Supporting Info

Counting Ions around DNA with Anomalous Small-Angle X-ray Scattering Suzette A. Pabit, Steve P. Meisburger, Li Li, Joshua M. Blose, Christopher D. Jones, and Lois Pollack pp 16334–16336 DOI: 10.1021/ja107259y Supporting Info

Synthesis of Defined Ubiquitin Dimers Silvia Eger, Martin Scheffner, Andreas Marx, and Marina Rubini pp 16337–16339 DOI: 10.1021/ja1072838 Supporting Info

Electrophilic Aromatic Substitution of a BN Indole Eric R. Abbey, Lev N. Zakharov, and Shih-Yuan Liu pp 16340–16342 DOI: 10.1021/ja107312u Supporting Info

Photolysis and Thermolysis of Bis(imino)pyridine Cobalt Azides: C−H Activation from Putative Cobalt Nitrido Complexes Crisita Carmen Hojilla Atienza, Amanda C. Bowman, Emil Lobkovsky, and Paul J. Chirik pp 16343–16345 DOI: 10.1021/ja107288x Supporting Info

Dienyl Homoallyl Alcohols via Palladium Catalyzed Ene-Type Reaction of Aldehydes with 1,3-Dienes Masahiro Fukushima, Daiki Takushima, and Masanari Kimura pp 16346–16348 DOI: 10.1021/ja1072417 Supporting Info

High and Balanced Hole and Electron Mobilities from Ambipolar Thin-Film Transistors Based on Nitrogen-Containing Oligoacences Yi-Yang Liu, Cheng-Li Song, Wei-Jing Zeng, Kai-Ge Zhou, Zi-Fa Shi, Chong-Bo Ma, Feng Yang, Hao-Li Zhang, and Xiong Gong pp 16349–16351 DOI: 10.1021/ja107046s Supporting Info

Discrete Structure of an RNA Folding Intermediate Revealed by Cryo-electron Microscopy Nathan J. Baird, Steven J. Ludtke, Htet Khant, Wah Chiu, Tao Pan, and Tobin R. Sosnick pp 16352–16353 DOI: 10.1021/ja107492b Supporting Info

Enantioselective Desymmetrization of Cyclopropenes by Hydroacylation Diem H. T. Phan, Kevin G. M. Kou, and Vy M. Dong pp 16354–16355 DOI: 10.1021/ja107738a Supporting Info

A Porphyrin Nanobarrel That Encapsulates C60 Jianxin Song, Naoki Aratani, Hiroshi Shinokubo, and Atsuhiro Osuka pp 16356–16357 DOI: 10.1021/ja107814s Supporting Info

Chromatography in a Single Metal−Organic Framework (MOF) Crystal Shuangbing Han, Yanhu Wei, Cory Valente, Istvn Lagzi, Jeremiah J. Gassensmith, Ali Coskun, J. Fraser Stoddart, and Bartosz A. Grzybowski pp 16358–16361 DOI: 10.1021/ja1074322 Supporting Info

Planar Quinary Cluster inside a Fullerene Cage: Synthesis and Structural Characterizations of Sc3NC@C80-Ih Tai-Shan Wang, Lai Feng, Jing-Yi Wu, Wei Xu, Jun-Feng Xiang, Kai Tan, Yi-Han Ma, Jun-Peng Zheng, Li Jiang, Xin Lu, Chun-Ying Shu, and Chun-Ru Wang pp 16362–16364 DOI: 10.1021/ja107843b Supporting Info

Cobalt-Mediated, Enantioselective Synthesis of C2 and C1 Dienes W. Christopher Boyd, Mark R. Crimmin, Lauren E. Rosebrugh, Jennifer M. Schomaker, Robert G. Bergman, and F. Dean Toste pp 16365–16367 DOI: 10.1021/ja107968c Supporting Info

Intramolecular Hydroamination/Cyclization of Aminoalkenes Catalyzed by Ln[N(SiMe3)2]3 Grafted onto Periodic Mesoporous Silicas Erwan Le Roux, Yucang Liang, Michael P. Storz, and Reiner Anwander pp 16368–16371 DOI: 10.1021/ja107963u Supporting Info

Palladium-Catalyzed Aminosulfonylation of Aryl Halides Bao Nguyen, Edward J. Emmett, and Michael C. Willis pp 16372–16373 DOI: 10.1021/ja1081124 Supporting Info

Enantioselective Copper-Catalyzed Intramolecular O−H Insertion: An Efficient Approach to Chiral 2-Carboxy Cyclic Ethers Shou-Fei Zhu, Xiao-Guang Song, Yu Li, Yan Cai, and Qi-Lin Zhou pp 16374–16376 DOI: 10.1021/ja1078464 Supporting Info

Pd(OAc)2-Catalyzed Oxidative C−H/C−H Cross-Coupling of Electron-Deficient Polyfluoroarenes with Simple Arenes Ye Wei and Weiping Su pp 16377–16379 DOI: 10.1021/ja109383e Supporting Info

Enantioselective Synthesis of (−)-Sclerophytin A by a Stereoconvergent Epoxide Hydrolysis Bin Wang, Armando P. Ramirez, Justin J. Slade, and James P. Morken pp 16380–16382 DOI: 10.1021/ja108185z Supporting Info

Synthesis and Photophysical Studies of Chiral Helical Macrocyclic Scaffolds via Coordination-Driven Self-Assembly of 1,8,9,16-Tetraethynyltetraphenylene. Formation of Monometallic Platinum(II) and Dimetallic Platinum(II)−Ruthenium(II) Complexes Fang Lin, Hai-Yan Peng, Jing-Xing Chen, David T. W. Chik, Zongwei Cai, Keith M. C. Wong, Vivian W. W. Yam, and Henry N. C. Wong pp 16383–16392 DOI: 10.1021/ja106599j Supporting Info

Evidence for Substrate Preorganization in the Peptidylglycine α-Amidating Monooxygenase Reaction Describing the Contribution of Ground State Structure to Hydrogen Tunneling Neil R. McIntyre, Edward W. Lowe, Jr., Jonathan L. Belof, Milena Ivkovic, Jacob Shafer, Brian Space, and David J. Merkler pp 16393–16402 DOI: 10.1021/ja1019194 Supporting Info

Total Synthesis of Bryostatin 16 Using a Pd-Catalyzed Diyne Coupling as Macrocyclization Method and Synthesis of C20-epi-Bryostatin 7 as a Potent Anticancer Agent Barry M. Trost and Guangbin Dong pp 16403–16416 DOI: 10.1021/ja105129p Supporting Info

Resolving Rotational Motions of Nano-objects in Engineered Environments and Live Cells with Gold Nanorods and Differential Interference Contrast Microscopy Gufeng Wang, Wei Sun, Yong Luo, and Ning Fang pp 16417–16422 DOI: 10.1021/ja106506k Supporting Info

Electrostatic Docking of a Supramolecular Host−Guest Assembly to Cytochrome c Probed by Bidirectional Photoinduced Electron Transfer Katarzyna I. Jankowska, Cynthia V. Pagba, Eugene L. Piatnitski Chekler, Kurt Deshayes, and Piotr Piotrowiak pp 16423–16431 DOI: 10.1021/ja102188e Supporting Info

Biofunctionalization on Alkylated Silicon Substrate Surfaces via “Click” Chemistry Guoting Qin, Catherine Santos, Wen Zhang, Yan Li, Amit Kumar, Uriel J. Erasquin, Kai Liu, Pavel Muradov, Barbara Wells Trautner, and Chengzhi Cai pp 16432–16441 DOI: 10.1021/ja1025497 Supporting Info

Molecular Dynamics and Brownian Dynamics Investigation of Ion Permeation and Anesthetic Halothane Effects on a Proton-Gated Ion Channel Mary Hongying Cheng, Rob D. Coalson, and Pei Tang pp 16442–16449 DOI: 10.1021/ja105001a Supporting Info

Analysis of the Reactivities of Protein C−H Bonds to H Atom Abstraction by OH Radical Steve Scheiner and Tapas Kar pp 16450–16459 DOI: 10.1021/ja105204v Supporting Info

Manipulating Double-Decker Molecules at the Liquid−Solid Interface Tomohide Takami, Tao Ye, Bala Krishna Pathem, Dennis P. Arnold, Ken-ichi Sugiura, Yongzhong Bian, Jianzhuang Jiang, and Paul S. Weiss pp 16460–16466 DOI: 10.1021/ja105421k

First Hyperpolarizability Dispersion of the Octupolar Molecule Crystal Violet: Multiple Resonances and Vibrational and Solvation Effects Jochen Campo, Anna Painelli, Francesca Terenziani, Tanguy Van Regemorter, David Beljonne, Etienne Goovaerts, and Wim Wenseleers pp 16467–16478 DOI: 10.1021/ja105600t Supporting Info

High-Pressure Synthesis and Local Structure of Corundum-Type In2−2xZnxSnxO3 (x ≤ 0.7) Cathleen A. Hoel, Jos Manuel Gallardo Amores, Emilio Morn, Miguel Angel lario-Franco, Jean-Franois Gaillard, and Kenneth R. Poeppelmeier pp 16479–16487 DOI: 10.1021/ja106048x Supporting Info

Activating Multistep Charge-Transfer Processes in Fullerene−Subphthalocyanine−Ferrocene Molecular Hybrids as a Function of π−π Orbital Overlap David Gonzlez-Rodrguez, Esther Carbonell, Gustavo de Miguel Rojas, Carmen Atienza Castellanos, Dirk M. Guldi, and Toms Torres pp 16488–16500 DOI: 10.1021/ja105864r Supporting Info

Mechanistic Studies of the Oxygen Evolution Reaction by a Cobalt-Phosphate Catalyst at Neutral pH Yogesh Surendranath, Matthew W. Kanan, and Daniel G. Nocera pp 16501–16509 DOI: 10.1021/ja106102b Supporting Info

Ultrafast Bidirectional Photoswitching of a Spiropyran Johannes Buback, Martin Kullmann, Florian Langhojer, Patrick Nuernberger, Ralf Schmidt, Frank Wrthner, and Tobias Brixner pp 16510–16519 DOI: 10.1021/ja1062746

Enantioselective Epoxide Polymerization Using a Bimetallic Cobalt Catalyst Renee M. Thomas, Peter C. B. Widger, Syud M. Ahmed, Ryan C. Jeske, Wataru Hirahata, Emil B. Lobkovsky, and Geoffrey W. Coates pp 16520–16525 DOI: 10.1021/ja1058422 Supporting Info

Dual Mechanisms of HNO Generation by a Nitroxyl Prodrug of the Diazeniumdiolate (NONOate) Class Daniela Andrei, Debra J. Salmon, Sonia Donzelli, Azadeh Wahab, John R. Klose, Michael L. Citro, Joseph E. Saavedra, David A. Wink, Katrina M. Miranda, and Larry K. Keefer pp 16526–16532 DOI: 10.1021/ja106552p Supporting Info

Factors Controlling the Mechanism of NAD+ Non-Redox Reactions Todor Dudev and Carmay Lim pp 16533–16543 DOI: 10.1021/ja106600k Supporting Info

The Bridged Binding Mode as a New, Versatile Template for the Selective Activation of Carbon−Fluorine Bonds in Fluoroolefins: Activation of Trifluoroethylene Michael E. Slaney, D. Jason Anderson, Michael J. Ferguson, Robert McDonald, and Martin Cowie pp 16544–16558 DOI: 10.1021/ja106723u Supporting Info

A Surface Energy Transfer Nanoruler for Measuring Binding Site Distances on Live Cell Surfaces Yan Chen, Meghan B. O’Donoghue, Yu-Fen Huang, Huaizhi Kang, Joseph A. Phillips, Xiaolan Chen, M.-Carmen Estevez, Chaoyong J. Yang, and Weihong Tan pp 16559–16570 DOI: 10.1021/ja106360v Supporting Info

Achieving Optimum Selectivity in Oxygen Assisted Alcohol Cross-Coupling on Gold Bingjun Xu, Robert J. Madix, and Cynthia M. Friend pp 16571–16580 DOI: 10.1021/ja106706v Supporting Info

Free-Standing Highly Conductive Transparent Ultrathin Single-Walled Carbon Nanotube Films Qingfeng Liu, Tsuyohiko Fujigaya, Hui-Ming Cheng, and Naotoshi Nakashima pp 16581–16586 DOI: 10.1021/ja1067367 Supporting Info

Water-Soluble Organo−Silica Hybrid Nanotubes Templated by Cylindrical Polymer Brushes Markus Mllner, Jiayin Yuan, Stephan Weiss, Andreas Walther, Melanie Frtsch, Markus Drechsler, and Axel H. E. Mller pp 16587–16592 DOI: 10.1021/ja107132j Supporting Info

Understanding Ligand Distributions in Modified Particle and Particlelike Systems Ilhem F. Hakem, Anna M. Leech, Jermaine D. Johnson, Scott J. Donahue, Jeremy P. Walker, and Michael R. Bockstaller pp 16593–16598 DOI: 10.1021/ja107139c Supporting Info

Mechanistic and Computational Study of a Palladacycle-Catalyzed Decomposition of a Series of Neutral Phosphorothioate Triesters in Methanol C. Tony Liu, Christopher I. Maxwell, David R. Edwards, Alexei A. Neverov, Nicholas J. Mosey, and R. Stan Brown pp 16599–16609 DOI: 10.1021/ja107144c Supporting Info

Building Addressable Libraries: Site-Selective Use of Pd(0) Catalysts on Microelectrode Arrays Libo Hu, Melissae Stuart, Jun Tian, Karl Maurer, and Kevin D. Moeller pp 16610–16616 DOI: 10.1021/ja107490t Supporting Info

Stopped-Flow Kinetic Analysis of the Interaction of Cyclo[8]pyrrole with Anions Elizabeth Karnas, Sung Kuk Kim, Kenneth A. Johnson, Jonathan L. Sessler, Kei Ohkubo, and Shunichi Fukuzumi pp 16617–16622 DOI: 10.1021/ja107471x Supporting Info

Reactivity of Methacrylates in Insertion Polymerization Thomas Rnzi, Damien Guironnet, Inigo Gttker-Schnetmann, and Stefan Mecking pp 16623–16630 DOI: 10.1021/ja107538r Supporting Info

Mechanical Activation of Catalysts for C−C Bond Forming and Anionic Polymerization Reactions from a Single Macromolecular Reagent Andrew G. Tennyson, Kelly M. Wiggins, and Christopher W. Bielawski pp 16631–16636 DOI: 10.1021/ja107620y Supporting Info

Mechanism of Enantioselective C−C Bond Formation with Bifunctional Chiral Ru Catalysts: NMR and DFT Study Ilya D. Gridnev, Masahito Watanabe, Hui Wang, and Takao Ikariya pp 16637–16650 DOI: 10.1021/ja107597w Supporting Info

Artificial Golgi Apparatus: Globular Protein-like Dendrimer Facilitates Fully Automated Enzymatic Glycan Synthesis Takahiko Matsushita, Izuru Nagashima, Masataka Fumoto, Takashi Ohta, Kuriko Yamada, Hiroki Shimizu, Hiroshi Hinou, Kentaro Naruchi, Takaomi Ito, Hirosato Kondo, and Shin-Ichiro Nishimura pp 16651–16656 DOI: 10.1021/ja106955j Supporting Info

What Determines the Inhibition Effectiveness of ATA, BTAH, and BTAOH Corrosion Inhibitors on Copper? Anton Kokalj, Sebastijan Peljhan, Matja Fingar, and Ingrid Miloev pp 16657–16668 DOI: 10.1021/ja107704y Supporting Info

Two-Dimensional Polymer Formation on Surfaces: Insight into the Roles of Precursor Mobility and Reactivity Marco Bieri, Manh-Thuong Nguyen, Oliver Grning, Jinming Cai, Matthias Treier, Kamel At-Mansour, Pascal Ruffieux, Carlo A. Pignedoli, Daniele Passerone, Marcel Kastler, Klaus Mllen, and Roman Fasel pp 16669–16676 DOI: 10.1021/ja107947z Supporting Info

Chemoselective Multicomponent One-Pot Assembly of Purine Precursors in Water Matthew W. Powner, John D. Sutherland, and Jack W. Szostak pp 16677–16688 DOI: 10.1021/ja108197s Supporting Info

Hydrogen-Bonding-Promoted Oxidative Addition and Regioselective Arylation of Olefins with Aryl Chlorides Jiwu Ruan, Jonathan A. Iggo, Neil G. Berry, and Jianliang Xiao pp 16689–16699 DOI: 10.1021/ja1081926 Supporting Info

Designing Multifunctional Expanded Pyridiniums: Properties of Branched and Fused Head-to-Tail Bipyridiniums Jrme Fortage, Cyril Peltier, Francesco Nastasi, Fausto Puntoriero, Fabien Tuyras, Sophie Griveau, Fethi Bedioui, Carlo Adamo, Ilaria Ciofini, Sebastiano Campagna, and Philippe P. Lain pp 16700–16713 DOI: 10.1021/ja108668h Supporting Info

Design of Organic Dyes and Cobalt Polypyridine Redox Mediators for High-Efficiency Dye-Sensitized Solar Cells Sandra M. Feldt, Elizabeth A. Gibson, Erik Gabrielsson, Licheng Sun, Gerrit Boschloo, and Anders Hagfeldt pp 16714–16724 DOI: 10.1021/ja1088869 Supporting Info

Free Radical Polymers with Tunable and Selective Bio- and Chemical Degradability Jos M. J. Paulusse, Roey J. Amir, Richard A. Evans, and Craig J. Hawker p 16725 DOI: 10.1021/ja109008k

Catalytic C−O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers Jason M. Nichols, Lee M. Bishop, Robert G. Bergman, and Jonathan A. Ellman p 16725 DOI: 10.1021/ja109016b

Handbook of Synthetic Photochemistry Frederick G. West p 16726 DOI: 10.1021/ja1089815

Issue 47

Solid-State 55Mn NMR Spectroscopy of Bis(μ-oxo)dimanganese(IV) [Mn2O2(salpn)2], a Model for the Oxygen Evolving Complex in Photosystem II Paul D. Ellis, Jesse A. Sears, Ping Yang, Michel Dupuis, Thaddeus T. Boron, III, Vincent L. Pecoraro, Troy A. Stich, R. David Britt, and Andrew S. Lipton pp 16727–16729 DOI: 10.1021/ja1054252 Supporting Info

Oxoferryl Porphyrin/Hydrogen Peroxide System Whose Behavior is Equivalent to Hydroperoxoferric Porphyrin Hiroaki Kitagishi, Mariko Tamaki, Takunori Ueda, Shun Hirota, Takehiro Ohta, Yoshinori Naruta, and Koji Kano pp 16730–16732 DOI: 10.1021/ja106798a Supporting Info

Reversible, Solvent-Induced Chirality Switch in Atrane Structure: Control of the Unidirectional Motion of the Molecular Propeller Alexandre Martinez, Laure Guy, and Jean-Pierre Dutasta pp 16733–16734 DOI: 10.1021/ja102873x Supporting Info

DNA Core@Inorganic Shell Dae-Hwan Park, Jung-Eun Kim, Jae-Min Oh, Yong-Gun Shul, and Jin-Ho Choy pp 16735–16736 DOI: 10.1021/ja105809e Supporting Info

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene Wei Liu, Hao Cao, Hua Zhang, Heng Zhang, Kin Ho Chung, Chuan He, Haibo Wang, Fuk Yee Kwong, and Aiwen Lei pp 16737–16740 DOI: 10.1021/ja103050x Supporting Info

A Giant Surfactant of Polystyrene−(Carboxylic Acid-Functionalized Polyhedral Oligomeric Silsesquioxane) Amphiphile with Highly Stretched Polystyrene Tails in Micellar Assemblies Xinfei Yu, Sheng Zhong, Xiaopeng Li, Yingfeng Tu, Shuguang Yang, Ryan M. Van Horn, Chaoying Ni, Darrin J. Pochan, Roderic P. Quirk, Chrys Wesdemiotis, Wen-Bin Zhang, and Stephen Z. D. Cheng pp 16741–16744 DOI: 10.1021/ja1078305 Supporting Info

Total Synthesis of (±) Maoecrystal V Jianxian Gong, Guang Lin, Wenbo Sun, Chuang-Chuang Li, and Zhen Yang pp 16745–16746 DOI: 10.1021/ja108907x Supporting Info

Selective Synthesis of (9,8) Single Walled Carbon Nanotubes on Cobalt Incorporated TUD-1 Catalysts Hong Wang, Bo Wang, Xian-Yang Quek, Li Wei, Jianwen Zhao, Lain-Jong Li, Mary B. Chan-Park, Yanhui Yang, and Yuan Chen pp 16747–16749 DOI: 10.1021/ja106937y Supporting Info

Tandem Facial Amphiphiles for Membrane Protein Stabilization Pil Seok Chae, Kamil Gotfryd, Jennifer Pacyna, Larry J. W. Miercke, Søren G. F. Rasmussen, Rebecca A. Robbins, Rohini R. Rana, Claus J. Loland, Brian Kobilka, Robert Stroud, Bernadette Byrne, Ulrik Gether, and Samuel H. Gellman pp 16750–16752 DOI: 10.1021/ja1072959 Supporting Info

Chiral Memory via Chiral Amplification and Selective Depolymerization of Porphyrin Aggregates Floris Helmich, Cameron C. Lee, Albertus P. H. J. Schenning, and E. W. Meijer pp 16753–16755 DOI: 10.1021/ja1077602 Supporting Info

Direct Hydrogenation of Amides to Alcohols and Amines under Mild Conditions Ekambaram Balaraman, Boopathy Gnanaprakasam, Linda J. W. Shimon, and David Milstein pp 16756–16758 DOI: 10.1021/ja1080019 Supporting Info

The Redox Chemistry of Sulfenic Acids Alaina J. McGrath, Graham E. Garrett, Luca Valgimigli, and Derek A. Pratt pp 16759–16761 DOI: 10.1021/ja1083046 Supporting Info

Efficient Visible-Light-Induced Photocatalytic Activity on Gold-Nanoparticle-Supported Layered Titanate Yusuke Ide, Mizuki Matsuoka, and Makoto Ogawa pp 16762–16764 DOI: 10.1021/ja1083514 Supporting Info

A Cationic Rh(III) Complex That Efficiently Catalyzes Hydrogen Isotope Exchange in Hydrosilanes Jess Campos, Ana C. Esqueda, Joaqun Lpez-Serrano, Luis Snchez, Fernando P. Cossio, Abel de Cozar, Eleuterio lvarez, Celia Maya, and Ernesto Carmona pp 16765–16767 DOI: 10.1021/ja108521b Supporting Info

Unsymmetrically Substituted Disilyne Dsi2iPrSi—Si≡Si—SiNpDsi2 (Np = CH2tBu): Synthesis and Characterization Yoshitaka Murata, Masaaki Ichinohe, and Akira Sekiguchi pp 16768–16770 DOI: 10.1021/ja1091744 Supporting Info

Highly Active Heterogeneous Palladium Nanoparticle Catalysts for Homogeneous Electrophilic Reactions in Solution and the Utilization of a Continuous Flow Reactor Wenyu Huang, Jack Hung-Chang Liu, Pinar Alayoglu, Yimin Li, Cole A. Witham, Chia-Kuang Tsung, F. Dean Toste, and Gabor A. Somorjai pp 16771–16773 DOI: 10.1021/ja108898t Supporting Info

Mechanism of H2 Evolution from a Photogenerated Hydridocobaloxime Jillian L. Dempsey, Jay R. Winkler, and Harry B. Gray pp 16774–16776 DOI: 10.1021/ja109351h Supporting Info

Frster Resonant Energy Transfer in Orthogonally Arranged Chromophores Heinz Langhals, Andreas J. Esterbauer, Andreas Walter, Eberhard Riedle, and Igor Pugliesi pp 16777–16782 DOI: 10.1021/ja101544x Supporting Info

Ligand Exchange Reactions on Au38 and Au40 Clusters: A Combined Circular Dichroism and Mass Spectrometry Study Stefan Knoppe, Asantha C. Dharmaratne, Ella Schreiner, Amala Dass, and Thomas Brgi pp 16783–16789 DOI: 10.1021/ja104641x Supporting Info

Atomistic Evidence of How Force Dynamically Regulates Thiol/Disulfide Exchange Wenjin Li and Frauke Grter pp 16790–16795 DOI: 10.1021/ja104763q Supporting Info

Ultrafast Spectroscopy and Computational Study of the Photochemistry of Diphenylphosphoryl Azide: Direct Spectroscopic Observation of a Singlet Phosphorylnitrene Shubham Vyas, Sivaramakrishnan Muthukrishnan, Jacek Kubicki, Ryan D. McCulla, Gotard Burdzinski, Michel Sliwa, Matthew S. Platz, and Christopher M. Hadad pp 16796–16804 DOI: 10.1021/ja909327z Supporting Info

Olefin Cross-Metathesis on Proteins: Investigation of Allylic Chalcogen Effects and Guiding Principles in Metathesis Partner Selection Yuya A. Lin, Justin M. Chalker, and Benjamin G. Davis pp 16805–16811 DOI: 10.1021/ja104994d Supporting Info

Identification of Highly Reactive Sequences For PLP-Mediated Bioconjugation Using a Combinatorial Peptide Library Leah S. Witus, Troy Moore, Benjamin W. Thuronyi, Aaron P. Esser-Kahn, Rebecca A. Scheck, Anthony T. Iavarone, and Matthew B. Francis pp 16812–16817 DOI: 10.1021/ja105429n Supporting Info

Supramolecular Balance: Using Cooperativity To Amplify Weak Interactions Mihaela Roman, Caroline Cannizzo, Thomas Pinault, Benjamin Isare, Bruno Andrioletti, Paul van der Schoot, and Laurent Bouteiller pp 16818–16824 DOI: 10.1021/ja105717u Supporting Info

Linking Local Environments and Hyperfine Shifts: A Combined Experimental and Theoretical 31P and 7Li Solid-State NMR Study of Paramagnetic Fe(III) Phosphates Jongsik Kim, Derek S. Middlemiss, Natasha A. Chernova, Ben Y. X. Zhu, Christian Masquelier, and Clare P. Grey pp 16825–16840 DOI: 10.1021/ja102678r Supporting Info

Highly Efficient Gene Silencing Activity of siRNA Embedded in a Nanostructured Gyroid Cubic Lipid Matrix Ceclia Leal, Nathan F. Bouxsein, Kai K. Ewert, and Cyrus R. Safinya pp 16841–16847 DOI: 10.1021/ja1059763 Supporting Info

Bottom-up Assembly of Molecular Wagons on a Surface Carlos J. Villagmez, Takashi Sasaki, James M. Tour, and Leonhard Grill pp 16848–16854 DOI: 10.1021/ja105542j Supporting Info

Tuning Electrochemical Rectification via Quantum Dot Assemblies Gabriela P. Kissling, Christa Bnzli, and David J. Fermn pp 16855–16861 DOI: 10.1021/ja106149g Supporting Info

Role of the Key Mutation in the Selective Binding of Avian and Human Influenza Hemagglutinin to Sialosides Revealed by Quantum-Mechanical Calculations Toshihiko Sawada, Dmitri G. Fedorov, and Kazuo Kitaura pp 16862–16872 DOI: 10.1021/ja105051e Supporting Info

A Facile Approach toward Multicomponent Supramolecular Structures: Selective Self-Assembly via Charge Separation Yao-Rong Zheng, Zhigang Zhao, Ming Wang, Koushik Ghosh, J. Bryant Pollock, Timothy R. Cook, and Peter J. Stang pp 16873–16882 DOI: 10.1021/ja106251f Supporting Info

Degradation Patterns in Water and Oxygen of an Inverted Polymer Solar Cell Kion Norrman, Morten V. Madsen, Suren A. Gevorgyan, and Frederik C. Krebs pp 16883–16892 DOI: 10.1021/ja106299g Supporting Info

Biocompatible Copper(I) Catalysts for in Vivo Imaging of Glycans David Soriano del Amo, Wei Wang, Hao Jiang, Christen Besanceney, Amy C. Yan, Matthew Levy, Yi Liu, Florence L. Marlow, and Peng Wu pp 16893–16899 DOI: 10.1021/ja106553e Supporting Info

Mechanism of Pd(NHC)-Catalyzed Transfer Hydrogenation of Alkynes Peter Hauwert, Romilda Boerleider, Stefan Warsink, Jan J. Weigand, and Cornelis J. Elsevier pp 16900–16910 DOI: 10.1021/ja1062407 Supporting Info

Theoretical Investigation of the Mechanism and Dynamics of Intramolecular Coherent Resonance Energy Transfer in Soft Molecules: A Case Study of Dithia-anthracenophane Lei Yang, Stefano Caprasecca, Benedetta Mennucci, and Seogjoo Jang pp 16911–16921 DOI: 10.1021/ja103303u Supporting Info

Simultaneous de Novo Identification of Molecules in Chemical Mixtures by Doubly Indirect Covariance NMR Spectroscopy Fengli Zhang, Lei Bruschweiler-Li, and Rafael Brschweiler pp 16922–16927 DOI: 10.1021/ja106781r Supporting Info

Transient Tertiary Structure Formation within the Ribosome Exit Port Edward P. O’Brien, Shang-Te Danny Hsu, John Christodoulou, Michele Vendruscolo, and Christopher M. Dobson pp 16928–16937 DOI: 10.1021/ja106530y Supporting Info

Visualizing and Tuning Thermodynamic Dispersion in Metalloprotein Monolayers Amol Virendra Patil and Jason John Davis pp 16938–16944 DOI: 10.1021/ja1065448 Supporting Info

Kinetics of Ion Transfer at the Ionic Liquid/Water Nanointerface Yixian Wang, Takashi Kakiuchi, Yukinori Yasui, and Michael V. Mirkin pp 16945–16952 DOI: 10.1021/ja1066948 Supporting Info

Light-Enhanced Catalysis by Pyridoxal Phosphate-Dependent Aspartate Aminotransferase Melissa P. Hill, Elizabeth C. Carroll, Mai C. Vang, Trevor A. Addington, Michael D. Toney, and Delmar S. Larsen pp 16953–16961 DOI: 10.1021/ja107054x Supporting Info

An Aldol-Based Build/Couple/Pair Strategy for the Synthesis of Medium- and Large-Sized Rings: Discovery of Macrocyclic Histone Deacetylase Inhibitors Lisa A. Marcaurelle, Eamon Comer, Sivaraman Dandapani, Jeremy R. Duvall, Baudouin Gerard, Sarathy Kesavan, Maurice D. Lee, IV, Haibo Liu, Jason T. Lowe, Jean-Charles Marie, Carol A. Mulrooney, Bhaumik A. Pandya, Ann Rowley, Troy D. Ryba, Byung-Chul Suh, Jingqiang Wei, Damian W. Young, Lakshmi B. Akella, Nathan T. Ross, Yan-Ling Zhang, Daniel M. Fass, Surya A. Reis, Wen-Ning Zhao, Stephen J. Haggarty, Michelle Palmer, and Michael A. Foley pp 16962–16976 DOI: 10.1021/ja105119r Supporting Info

Synthesis, Structural, and Spectroscopic Characterization and Reactivities of Mononuclear Cobalt(III)−Peroxo Complexes Jaeheung Cho, Ritimukta Sarangi, Hye Yeon Kang, Jung Yoon Lee, Minoru Kubo, Takashi Ogura, Edward I. Solomon, and Wonwoo Nam pp 16977–16986 DOI: 10.1021/ja107177m Supporting Info

Characterization of Bleomycin Cleavage Sites in Strongly Bound Hairpin DNAs Rachel A. Giroux and Sidney M. Hecht pp 16987–16996 DOI: 10.1021/ja107228c Supporting Info

Iron Acyl Thiolato Carbonyls: Structural Models for the Active Site of the [Fe]-Hydrogenase (Hmd) Aaron M. Royer, Marco Salomone-Stagni, Thomas B. Rauchfuss, and Wolfram Meyer-Klaucke pp 16997–17003 DOI: 10.1021/ja1072228 Supporting Info

Probing Microsecond Time Scale Dynamics in Proteins by Methyl 1H Carr−Purcell−Meiboom−Gill Relaxation Dispersion NMR Measurements. Application to Activation of the Signaling Protein NtrCr Renee Otten, Janice Villali, Dorothee Kern, and Frans A. A. Mulder pp 17004–17014 DOI: 10.1021/ja107410x Supporting Info

Small Molecule Microarrays Enable the Discovery of Compounds That Bind the Alzheimer’s Aβ Peptide and Reduce its Cytotoxicity Jermont Chen, Anne H. Armstrong, Angela N. Koehler, and Michael H. Hecht pp 17015–17022 DOI: 10.1021/ja107552s Supporting Info

Leaving Group Activation and Pyrophosphate Ionic State at the Catalytic Site of Plasmodium falciparum Orotate Phosphoribosyltransferase Yong Zhang, Hua Deng, and Vern L. Schramm pp 17023–17031 DOI: 10.1021/ja107806j Supporting Info

Prediction of Reorganization Free Energies for Biological Electron Transfer: A Comparative Study of Ru-Modified Cytochromes and a 4-Helix Bundle Protein Varomyalin Tipmanee, Harald Oberhofer, Mina Park, Kwang S. Kim, and Jochen Blumberger pp 17032–17040 DOI: 10.1021/ja107876p Supporting Info

A Highly Selective Ferrocene-Based Planar Chiral PIP (Fc-PIP) Acyl Transfer Catalyst for the Kinetic Resolution of Alcohols Bin Hu, Meng Meng, Zheng Wang, Wenting Du, John S. Fossey, Xinquan Hu, and Wei-Ping Deng pp 17041–17044 DOI: 10.1021/ja108238a Supporting Info

Promising General Solution to the Problem of Ligating Peptides and Glycopeptides Ping Wang and Samuel J. Danishefsky pp 17045–17051 DOI: 10.1021/ja1084628 Supporting Info

Short Peptide Nucleic Acids Bind Strongly to Homopurine Tract of Double Helical RNA at pH 5.5 Ming Li, Thomas Zengeya, and Eriks Rozners p 17052 DOI: 10.1021/ja109084h

Issue 48

Oriented Insertion of phi29 N-Hexahistidine-tagged gp10 Connector Protein Assemblies into C20BAS Bolalipid Membrane Vesicles Seok-Hee Hyun, Hee-kwon Kim, Jong-Mok Kim, and David H. Thompson pp 17053–17055 DOI: 10.1021/ja104204z Supporting Info

Biologically Inspired Highly Durable Iron Phthalocyanine Catalysts for Oxygen Reduction Reaction in Polymer Electrolyte Membrane Fuel Cells Wenmu Li, Aiping Yu, Drew C. Higgins, Bernard G. Llanos, and Zhongwei Chen pp 17056–17058 DOI: 10.1021/ja106217u Supporting Info

Crown Ether Complexes of HPCl6 Zin-Min Tun, Matthew J. Panzner, Vincenzo Scionti, Douglas Medvetz, Chrys Wesdemiotis, Wiley J. Youngs, and Claire Tessier pp 17059–17061 DOI: 10.1021/ja1064697 Supporting Info

Pore Space Partition and Charge Separation in Cage-within-Cage Indium−Organic Frameworks with High CO2 Uptake Shou-Tian Zheng, Julia T. Bu, Yufei Li, Tao Wu, Fan Zuo, Pingyun Feng, and Xianhui Bu pp 17062–17064 DOI: 10.1021/ja106903p Supporting Info

A Highly Selective Fluorescent Probe for Visualization of Organic Hydroperoxides in Living Cells Boxuan Simen Zhao, Yujie Liang, Yanqun Song, Chunhong Zheng, Ziyang Hao, and Peng R. Chen pp 17065–17067 DOI: 10.1021/ja1071114 Supporting Info

Cooperative Melting in Caged Dimers with Only Two DNA Duplexes Ibrahim Eryazici, Tatiana R. Prytkova, George C. Schatz, and SonBinh T. Nguyen pp 17068–17070 DOI: 10.1021/ja107232x Supporting Info

Light-Activated Regulation of Cofilin Dynamics Using a Photocaged Hydrogen Peroxide Generator Evan W. Miller, Nicolas Taulet, Carl S. Onak, Elizabeth J. New, Julie K. Lanselle, Gillian S. Smelick, and Christopher J. Chang pp 17071–17073 DOI: 10.1021/ja107783j Supporting Info

Design of Structurally Rigid trans-Diamine-Based Tf-Amide Organocatalysts with a Dihydroanthracene Framework for Asymmetric Conjugate Additions of Heterosubstituted Aldehydes to Vinyl Sulfones Shin A. Moteki, Senmiao Xu, Satoru Arimitsu, and Keiji Maruoka pp 17074–17076 DOI: 10.1021/ja107897t Supporting Info

Intermolecular Alignment in β2-Microglobulin Amyloid Fibrils Galia T. Debelouchina, Geoffrey W. Platt, Marvin J. Bayro, Sheena E. Radford, and Robert G. Griffin pp 17077–17079 DOI: 10.1021/ja107987f Supporting Info

Crystal Structures of Urate Bound Form of Xanthine Oxidoreductase: Substrate Orientation and Structure of the Key Reaction Intermediate Ken Okamoto, Yuko Kawaguchi, Bryan T. Eger, Emil F. Pai, and Takeshi Nishino pp 17080–17083 DOI: 10.1021/ja1077574 Supporting Info

Polyhedral 50-Facet Cu2O Microcrystals Partially Enclosed by {311} High-Index Planes: Synthesis and Enhanced Catalytic CO Oxidation Activity Mei Leng, Mingzhu Liu, Yibo Zhang, Zhenqing Wang, Chao Yu, Xiangguang Yang, Hongjie Zhang, and Cheng Wang pp 17084–17087 DOI: 10.1021/ja106788x Supporting Info

Scan-Rate-Dependent Current Rectification of Cone-Shaped Silica Nanopores in Quartz Nanopipettes Joshua P. Guerrette and Bo Zhang pp 17088–17091 DOI: 10.1021/ja1086497 Supporting Info

Iridium-Catalyzed Arene Ortho-Silylation by Formal Hydroxyl-Directed C−H Activation Eric M. Simmons and John F. Hartwig pp 17092–17095 DOI: 10.1021/ja1086547 Supporting Info

Protodeboronation of Tertiary Boronic Esters: Asymmetric Synthesis of Tertiary Alkyl Stereogenic Centers Stefan Nave, Ravindra P. Sonawane, Tim G. Elford, and Varinder K. Aggarwal pp 17096–17098 DOI: 10.1021/ja1084207 Supporting Info

Disclosure of the Elusive C2v-C72 Carbon Cage Karolin Ziegler, Andreas Mueller, Konstantin Yu. Amsharov, and Martin Jansen pp 17099–17101 DOI: 10.1021/ja108470p Supporting Info

C72Cl4: A Pristine Fullerene with Favorable Pentagon-Adjacent Structure Yuan-Zhi Tan, Ting Zhou, Jian Bao, Gui-Juan Shan, Su-Yuan Xie, Rong-Bin Huang, and Lan-Sun Zheng pp 17102–17104 DOI: 10.1021/ja108860y Supporting Info

Hydration Is a Major Determinant of the G-Quadruplex Stability and Conformation of the Human Telomere 3′ Sequence of d(AG3(TTAG3)3) M. Clarke Miller, Robert Buscaglia, Jonathan B. Chaires, Andrew N. Lane, and John O. Trent pp 17105–17107 DOI: 10.1021/ja105259m Supporting Info

Stereospecific Cross-Coupling of Secondary Alkyl β-Trifluoroboratoamides Deidre L. Sandrock, Ludivine Jean-Grard, Cheng-yi Chen, Spencer D. Dreher, and Gary A. Molander pp 17108–17110 DOI: 10.1021/ja108949w Supporting Info

Compelling Computational Evidence for the Concerted Cyclization of the ABC Rings of Hopene from Protonated Squalene Lidia Smentek and B. Andes Hess, Jr. pp 17111–17117 DOI: 10.1021/ja1039133 Supporting Info

Sulfur versus Iron Oxidation in an Iron−Thiolate Model Complex Aidan R. McDonald, Michael R. Bukowski, Erik R. Farquhar, Timothy A. Jackson, Kevin D. Koehntop, Mi Sook Seo, Raymond F. De Hont, Audria Stubna, Jason A. Halfen, Eckard Mnck, Wonwoo Nam, and Lawrence Que, Jr. pp 17118–17129 DOI: 10.1021/ja1045428 Supporting Info

Polymer-Caged Nanobins for Synergistic Cisplatin−Doxorubicin Combination Chemotherapy Sang-Min Lee, Thomas V. O’Halloran, and SonBinh T. Nguyen pp 17130–17138 DOI: 10.1021/ja107333g Supporting Info

Phosphorus Chemical Shifts in a Nucleic Acid Backbone from Combined Molecular Dynamics and Density Functional Calculations Jana Pecechtlov, Petr Novk, Markta L. Munzarov, Martin Kaupp, and Vladimr Sklen pp 17139–17148 DOI: 10.1021/ja104564g Supporting Info

Influence of Electrolyte Composition on Liquid-Gated Carbon Nanotube and Graphene Transistors Iddo Heller, Sohail Chatoor, Jaan Mnnik, Marcel A. G. Zevenbergen, Cees Dekker, and Serge G. Lemay pp 17149–17156 DOI: 10.1021/ja104850n Supporting Info

Fast Reactivity of a Cyclic Nitrone−Calix[4]pyrrole Conjugate with Superoxide Radical Anion: Theoretical and Experimental Studies Shang-U Kim, Yangping Liu, Kevin M. Nash, Jay L. Zweier, Antal Rockenbauer, and Frederick A. Villamena pp 17157–17173 DOI: 10.1021/ja105198c Supporting Info

Peroxynitrite Mediates Active Site Tyrosine Nitration in Manganese Superoxide Dismutase. Evidence of a Role for the Carbonate Radical Anion N. Basak Surmeli, Nadia K. Litterman, Anne-Frances Miller, and John T. Groves pp 17174–17185 DOI: 10.1021/ja105684w Supporting Info

Activation of Methane by Zinc: Gas-Phase Synthesis, Structure, and Bonding of HZnCH3 Michael A. Flory, Aldo J. Apponi, Lindsay N. Zack, and Lucy M. Ziurys pp 17186–17192 DOI: 10.1021/ja106121v Supporting Info

Mass Spectrometry of Ligand Exchange Chelation of the Nanoparticle [Au25(SCH2CH2C6H5)18]1− by CH3C6H3(SH)2 Christina A. Fields-Zinna, Joseph F. Parker, and Royce W. Murray pp 17193–17198 DOI: 10.1021/ja106243g Supporting Info

Bridging the Gap between Electrochemical and Organometallic Activation: Benzyl Chloride Reduction at Silver Cathodes Yi-Fan Huang, De-Yin Wu, An Wang, Bin Ren, Sandra Rondinini, Zhong-Qun Tian, and Christian Amatore pp 17199–17210 DOI: 10.1021/ja106049c Supporting Info

Highly Enantioselective Rh2(S-DOSP)4-Catalyzed Cyclopropenation of Alkynes with Styryldiazoacetates John F. Briones, Jørn Hansen, Kenneth I. Hardcastle, Jochen Autschbach, and Huw M. L. Davies pp 17211–17215 DOI: 10.1021/ja106509b Supporting Info

Nitrotetrazolate-2N-oxides and the Strategy of N-Oxide Introduction Michael Gbel, Konstantin Karaghiosoff, Thomas M. Klaptke, Davin G. Piercey, and Jrg Stierstorfer pp 17216–17226 DOI: 10.1021/ja106892a Supporting Info

Self-Cross-Linked Polymer Nanogels: A Versatile Nanoscopic Drug Delivery Platform Ja-Hyoung Ryu, Reuben T. Chacko, Siriporn Jiwpanich, Sean Bickerton, R. Prakash Babu, and S. Thayumanavan pp 17227–17235 DOI: 10.1021/ja1069932 Supporting Info

Synthesis of a Single-Molecule l-Rhamnose-Containing Three-Component Vaccine and Evaluation of Antigenicity in the Presence of Anti-l-Rhamnose Antibodies Sourav Sarkar, Steven A. Lombardo, Danielle N. Herner, Rommel S. Talan, Katherine A. Wall, and Steven J. Sucheck pp 17236–17246 DOI: 10.1021/ja107029z Supporting Info

Chemically Self-Assembled Antibody Nanorings (CSANs): Design and Characterization of an Anti-CD3 IgM Biomimetic Qing Li, Christopher R. So, Adrian Fegan, Vivian Cody, Mehmet Sarikaya, Daniel A. Vallera, and Carston R. Wagner pp 17247–17257 DOI: 10.1021/ja107153a Supporting Info

Hysteretic Spin and Charge Delocalization in a Phenalenyl-Based Molecular Conductor Sushanta K. Pal, Pradip Bag, Arindam Sarkar, Xiaoliu Chi, Mikhail E. Itkis, Fook S. Tham, Bruno Donnadieu, and Robert C. Haddon pp 17258–17264 DOI: 10.1021/ja107201d Supporting Info

Supramolecular Chromotropism of the Crystalline Phases of 4,5,6,7-Tetrafluorobenzo-2,1,3-telluradiazole Anthony F. Cozzolino, Pamela S. Whitfield, and Ignacio Vargas-Baca pp 17265–17270 DOI: 10.1021/ja107252f Supporting Info

Interfacial Molecular Structures of Polyelectrolyte Brush in Contact with Dry Nitrogen, Water Vapor, Liquid Water, and Aqueous Electrolyte Solution Studied by Sum Frequency Generation Spectroscopy Kohei Uosaki, Hidenori Noguchi, Rie Yamamoto, and Satoshi Nihonyanagi pp 17271–17276 DOI: 10.1021/ja107265q

Controlling the Structure of Proteins at Surfaces Michael Geisler, Senbo Xiao, Elias M. Puchner, Frauke Grter, and Thorsten Hugel pp 17277–17281 DOI: 10.1021/ja107212z Supporting Info

Polarization of the Pyridine Ring: Highly Functionalized Piperidines from Tungsten−Pyridine Complex Daniel P. Harrison, Michal Sabat, William H. Myers, and W. Dean Harman pp 17282–17295 DOI: 10.1021/ja107536w Supporting Info

Computational Study of Silica-Supported Transition Metal Fragments for Kubas-type Hydrogen Storage Claire V. J. Skipper, Ahmad Hamaed, David M. Antonelli, and Nikolas Kaltsoyannis pp 17296–17305 DOI: 10.1021/ja107539j Supporting Info

Transfer of a Disilenyl Moiety to Aromatic Substrates and Lateral Functional Group Transformation in Aryl Disilenes Jonathan Jeck, Iulia Bejan, Andrew J. P. White, Dominik Nied, Frank Breher, and David Scheschkewitz pp 17306–17315 DOI: 10.1021/ja107547s Supporting Info

Epitaxial Growth of Shape-Controlled Bi2Te3−Te Heterogeneous Nanostructures Wenshou Wang, James Goebl, Le He, Shaul Aloni, Yongxing Hu, Liang Zhen, and Yadong Yin pp 17316–17324 DOI: 10.1021/ja108186w Supporting Info

Exploring Chromium(III)−Alkyl Bond Homolysis with CpCr[(ArNCMe)2CH](R) Complexes K. Cory MacLeod, Julia L. Conway, Brian O. Patrick, and Kevin M. Smith pp 17325–17334 DOI: 10.1021/ja1083392 Supporting Info

Polyvalent Oligonucleotide Gold Nanoparticle Conjugates as Delivery Vehicles for Platinum(IV) Warheads Shanta Dhar, Weston L. Daniel, David A. Giljohann, Chad A. Mirkin, and Stephen J. Lippard p 17335 DOI: 10.1021/ja109134j

New Membranes and Advanced Materials for Wastewater Treatment p 17336 DOI: 10.1021/ja1096607

Electrochemistry of Metal Chalcogenides Bruce Parkinson p 17336 DOI: 10.1021/ja109456r

Fuel Cell Chemistry and Operation p 17336 DOI: 10.1021/ja109819x

Issue 49

Electrostatic Chameleons in Biological Systems Mikael Lund pp 17337–17339 DOI: 10.1021/ja106480a Supporting Info

Oxygen Plasma Etching-Induced Crystalline Lattice Transformation of Colloidal Photonic Crystals Tao Ding, Fei Wang, Kai Song, Guoqiang Yang, and Chen-Ho Tung pp 17340–17342 DOI: 10.1021/ja106657t Supporting Info

Preparation of p-Type CaFe2O4 Photocathodes for Producing Hydrogen from Water Shintaro Ida, Keisuke Yamada, Takuya Matsunaga, Hidehisa Hagiwara, Yasumichi Matsumoto, and Tatsumi Ishihara pp 17343–17345 DOI: 10.1021/ja106930f Supporting Info

Chiral Poly(fluorene-alt-benzothiadiazole) (PFBT) and Nanocomposites with Gold Nanoparticles: Plasmonically and Structurally Enhanced Chirality Heong Sub Oh, Sha Liu, HongSub Jee, Alexander Baev, Mark T. Swihart, and Paras N. Prasad pp 17346–17348 DOI: 10.1021/ja107064a Supporting Info

A Selective NMR Method for Detecting Choline Containing Compounds in Liver Tissue: The 1H−14N HSQC Experiment Jiezhen Mao, Ling Jiang, Bin Jiang, Maili Liu, and Xi-an Mao pp 17349–17351 DOI: 10.1021/ja107745g Supporting Info

Ni-Catalyzed Reduction of Inert C−O Bonds: A New Strategy for Using Aryl Ethers as Easily Removable Directing Groups Paula lvarez-Bercedo and Ruben Martin pp 17352–17353 DOI: 10.1021/ja106943q Supporting Info

Fabrication of Ordered Nanostructures of Sulfide Nanocrystal Assemblies over Self-Assembled Genetically Engineered P22 Coat Protein Liming Shen, Ningzhong Bao, Peter E. Prevelige, and Arunava Gupta pp 17354–17357 DOI: 10.1021/ja107080b Supporting Info

Gas Sensing with High-Resolution Localized Surface Plasmon Resonance Spectroscopy Julia M. Bingham, Jeffrey N. Anker, Lauren E. Kreno, and Richard P. Van Duyne pp 17358–17359 DOI: 10.1021/ja1074272 Supporting Info

Functional Hollow Carbon Nanospheres by Latex Templating Robin J. White, Klaus Tauer, Markus Antonietti, and Maria-Magdalena Titirici pp 17360–17363 DOI: 10.1021/ja107697s Supporting Info

Molecule−Electrode Bonding Design for High Single-Molecule Conductance Kazumichi Yokota, Masateru Taniguchi, Makusu Tsutsui, and Tomoji Kawai pp 17364–17365 DOI: 10.1021/ja108032q Supporting Info

Tripodal Tris-tacn and Tris-dpa Platforms for Assembling Phosphate-Templated Trimetallic Centers Rui Cao, Peter Mller, and Stephen J. Lippard pp 17366–17369 DOI: 10.1021/ja108212v Supporting Info

Kinetic Resolution of Homoaldols via Catalytic Asymmetric Transacetalization Ilija ori, Steffen Mller, and Benjamin List pp 17370–17373 DOI: 10.1021/ja108642s Supporting Info

Multielectron Redox Reactions Involving C−C Coupling and Cleavage in Uranium Schiff Base Complexes Clment Camp, Victor Mougel, Pawel Horeglad, Jacques Pcaut, and Marinella Mazzanti pp 17374–17377 DOI: 10.1021/ja1089364 Supporting Info

Pd(II)-Catalyzed Carbonylation of C(sp3)−H Bonds: A New Entry to 1,4-Dicarbonyl Compounds Eun Jeong Yoo, Masayuki Wasa, and Jin-Quan Yu pp 17378–17380 DOI: 10.1021/ja108754f Supporting Info

Combination of Indene-C60 Bis-Adduct and Cross-Linked Fullerene Interlayer Leading to Highly Efficient Inverted Polymer Solar Cells Yen-Ju Cheng, Chao-Hsiang Hsieh, Youjun He, Chain-Shu Hsu, and Yongfang Li pp 17381–17383 DOI: 10.1021/ja108259n Supporting Info

Fabrication of 7.2% Efficient CZTSSe Solar Cells Using CZTS Nanocrystals Qijie Guo, Grayson M. Ford, Wei-Chang Yang, Bryce C. Walker, Eric A. Stach, Hugh W. Hillhouse, and Rakesh Agrawal pp 17384–17386 DOI: 10.1021/ja108427b

A New exTTF-Crown Ether Platform To Associate Fullerenes: Cooperative n−π and π−π Effects Bruno Grimm, Jos Santos, Beatriz M. Illescas, Antonio Muoz, Dirk M. Guldi, and Nazario Martn pp 17387–17389 DOI: 10.1021/ja108744a Supporting Info

Mixed Valency across Hydrogen Bonds John C. Goeltz and Clifford P. Kubiak pp 17390–17392 DOI: 10.1021/ja108841k Supporting Info

Remote Stereoinduction in the Acylation of Fully Substituted Enolates: Tandem Reformatsky/Quaternary Claisen Condensations of Silyl Glyoxylates and β-Lactones Stephen N. Greszler, Justin T. Malinowski, and Jeffrey S. Johnson pp 17393–17395 DOI: 10.1021/ja108848d Supporting Info

Uncovering the Mechanistic Role of HMPA in the Samarium Barbier Reaction Kimberly A. Choquette, Dhandapani V. Sadasivam, and Robert A. Flowers, II pp 17396–17398 DOI: 10.1021/ja1088925 Supporting Info

Two-Coordinate First Row Transition Metal Complexes with Short Unsupported Metal−Metal Bonds Hao Lei, Jing-Dong Guo, James C. Fettinger, Shigeru Nagase, and Philip P. Power pp 17399–17401 DOI: 10.1021/ja1089777 Supporting Info

Palladium-Catalyzed Asymmetric Synthesis of Allylic Fluorides Matthew H. Katcher and Abigail G. Doyle pp 17402–17404 DOI: 10.1021/ja109120n Supporting Info

Building Addressable Libraries: The Use of “Safety-Catch” Linkers on Microelectrode Arrays Bo Bi, Karl Maurer, and Kevin D. Moeller pp 17405–17407 DOI: 10.1021/ja109253t Supporting Info

A Dual Platform for Selective Analyte Enrichment and Ionization in Mass Spectrometry Using Aptamer-Conjugated Graphene Oxide Basri Gulbakan, Emir Yasun, M. Ibrahim Shukoor, Zhi Zhu, Mingxu You, Xiaohong Tan, Hernan Sanchez, David H. Powell, Hongjie Dai, and Weihong Tan pp 17408–17410 DOI: 10.1021/ja109042w Supporting Info

Neutralizing Positive Charges at the Surface of a Protein Lowers Its Rate of Amide Hydrogen Exchange without Altering Its Structure or Increasing Its Thermostability Bryan F. Shaw, Haribabu Arthanari, Max Narovlyansky, Armando Durazo, Dominique P. Frueh, Michael P. Pollastri, Andrew Lee, Basar Bilgicer, Steven P. Gygi, Gerhard Wagner, and George M. Whitesides pp 17411–17425 DOI: 10.1021/ja9067035 Supporting Info

Flexible Low-Voltage Organic Thin-Film Transistors Enabled by Low-Temperature, Ambient Solution-Processable Inorganic/Organic Hybrid Gate Dielectrics Young-geun Ha, Sunho Jeong, Jinsong Wu, Myung-Gil Kim, Vinayak P. Dravid, Antonio Facchetti, and Tobin J. Marks pp 17426–17434 DOI: 10.1021/ja107079d Supporting Info

Tunable Chiral Reaction Media Based on Two-Component Liquid Crystals: Regio-, Diastereo-, and Enantiocontrolled Photodimerization of Anthracenecarboxylic Acids Yasuhiro Ishida, Ammathnadu S. Achalkumar, Shun-ya Kato, Yukiko Kai, Aya Misawa, Yumi Hayashi, Kuniyo Yamada, Yuki Matsuoka, Motoo Shiro, and Kazuhiko Saigo pp 17435–17446 DOI: 10.1021/ja105221u Supporting Info

Structure-Induced Ferromagnetic Stabilization in Free-Standing Hexagonal Fe1.3Ge Nanowires Hana Yoon, Alex Taekyung Lee, Eun-Ae Choi, Kwanyong Seo, Nitin Bagkar, Jaehun Cho, Younghun Jo, K. J. Chang, and Bongsoo Kim pp 17447–17451 DOI: 10.1021/ja104189p Supporting Info

Reaction Pathway of Methylenation of Carbonyl Compounds with Bis(iodozincio)methane Mutsumi Sada, Shinsuke Komagawa, Masanobu Uchiyama, Masami Kobata, Tsuyoshi Mizuno, Kiitiro Utimoto, Koichiro Oshima, and Seijiro Matsubara pp 17452–17458 DOI: 10.1021/ja104439w Supporting Info

Exciton Formation, Relaxation, and Decay in PCDTBT Natalie Banerji, Sarah Cowan, Mario Leclerc, Eric Vauthey, and Alan J. Heeger pp 17459–17470 DOI: 10.1021/ja105290e Supporting Info

Advancing the Mechanistic Understanding of an Enantioselective Palladium-Catalyzed Alkene Difunctionalization Reaction Katrina H. Jensen, Jonathan D. Webb, and Matthew S. Sigman pp 17471–17482 DOI: 10.1021/ja108106h Supporting Info

Role of the Charge-Transfer State in the Electronic Absorption of Protonated Hydrocarbon Molecules Ivan Alata, Claude Dedonder, Michel Broquier, Ernesto Marceca, and Christophe Jouvet pp 17483–17489 DOI: 10.1021/ja106424f Supporting Info

Tyrosine−Lipid Peroxide Adducts from Radical Termination: Para Coupling and Intramolecular Diels−Alder Cyclization Roman Shchepin, Matias N. Mller, Hye-young H. Kim, Duane M. Hatch, Silvina Bartesaghi, Balaraman Kalyanaraman, Rafael Radi, and Ned A. Porter pp 17490–17500 DOI: 10.1021/ja106503a Supporting Info

Compound ES of Dehaloperoxidase Decays via Two Alternative Pathways Depending on the Conformation of the Distal Histidine Matthew K. Thompson, Stefan Franzen, Reza A. Ghiladi, Brandon J. Reeder, and Dimitri A. Svistunenko pp 17501–17510 DOI: 10.1021/ja106620q Supporting Info

Efficient Carboazidation of Alkenes Using a Radical Desulfonylative Azide Transfer Process Karin Weidner, Andr Giroult, Philippe Panchaud, and Philippe Renaud pp 17511–17515 DOI: 10.1021/ja1068036 Supporting Info

Anisotropic Ionic Conductivity in Block Copolymer Membranes by Magnetic Field Alignment Pawel W. Majewski, Manesh Gopinadhan, Woo-Sik Jang, Jodie L. Lutkenhaus, and Chinedum O. Osuji pp 17516–17522 DOI: 10.1021/ja107309p Supporting Info

Ca2LiC3H: A New Complex Carbide Hydride Phase Grown in Metal Flux David A. Lang, Julia V. Zaikina, Derek D. Lovingood, Thomas E. Gedris, and Susan E. Latturner pp 17523–17530 DOI: 10.1021/ja107436n Supporting Info

Sol−Gel Synthesis, Electrochemical Characterization, and Stability Testing of Ti0.7W0.3O2 Nanoparticles for Catalyst Support Applications in Proton-Exchange Membrane Fuel Cells Chinmayee V. Subban, Qin Zhou, Anthony Hu, Thomas E. Moylan, Frederick T. Wagner, and Francis J. DiSalvo pp 17531–17536 DOI: 10.1021/ja1074163 Supporting Info

Intermediate-Valence Tautomerism in Decamethylytterbocene Complexes of Methyl-Substituted Bipyridines Corwin H. Booth, Daniel Kazhdan, Evan L. Werkema, Marc D. Walter, Wayne W. Lukens, Eric D. Bauer, Yung-Jin Hu, Laurent Maron, Odile Eisenstein, Martin Head-Gordon, and Richard A. Andersen pp 17537–17549 DOI: 10.1021/ja106902s Supporting Info

Dependence of Electrochemical and Electrogenerated Chemiluminescence Properties on the Structure of BODIPY Dyes. Unusually Large Separation between Sequential Electron Transfers Alexander B. Nepomnyashchii, Sangik Cho, Peter J. Rossky, and Allen J. Bard pp 17550–17559 DOI: 10.1021/ja108108d Supporting Info

Bodipy Dyes with Tunable Redox Potentials and Functional Groups for Further Tethering: Preparation, Electrochemical, and Spectroscopic Characterization Katerina Krumova and Gonzalo Cosa pp 17560–17569 DOI: 10.1021/ja1075663 Supporting Info

Energy Landscapes Associated with Macromolecular Conformational Changes from Endpoint Structures Arianna Fornili, Barbara Giabbai, Gianpiero Garau, and Massimo Degano pp 17570–17577 DOI: 10.1021/ja107640u Supporting Info

Advanced Electron Paramagnetic Resonance and Density Functional Theory Study of a {2Fe3S} Cluster Mimicking the Active Site of [FeFe] Hydrogenase Alexey Silakov, Jennifer L. Shaw, Eduard J. Reijerse, and Wolfgang Lubitz pp 17578–17587 DOI: 10.1021/ja107793e Supporting Info

NMR Solution Structure of a DNA−Actinomycin D Complex Containing a Non-Hydrogen-Bonding Pair in the Binding Site Shannen L. Cravens, Alyssa C. Navapanich, Bernhard H. Geierstanger, Deborah C. Tahmassebi, and Tammy J. Dwyer pp 17588–17598 DOI: 10.1021/ja107575f Supporting Info

Ligand Bridging-Angle-Driven Assembly of Molecular Architectures Based on Quadruply Bonded Mo−Mo Dimers Jian-Rong Li, Andrey A. Yakovenko, Weigang Lu, Daren J. Timmons, Wenjuan Zhuang, Daqiang Yuan, and Hong-Cai Zhou pp 17599–17610 DOI: 10.1021/ja1080794 Supporting Info

Elucidating the Ionomer-Electrified Metal Interface Ian Kendrick, Dunesh Kumari, Adam Yakaboski, Nicholas Dimakis, and Eugene S. Smotkin pp 17611–17616 DOI: 10.1021/ja1081487 Supporting Info

Molecular Dials: Hindered Rotations in Mono- and Diferrocenyl Anthracenes and Triptycenes Kirill Nikitin, Helge Mller-Bunz, Yannick Ortin, Jimmy Muldoon, and Michael J. McGlinchey pp 17617–17622 DOI: 10.1021/ja108226p Supporting Info

Water Is the Key to Nonclassical Nucleation of Amorphous Calcium Carbonate Paolo Raiteri and Julian D. Gale pp 17623–17634 DOI: 10.1021/ja108508k

Synthesis of Cyclododeciptycene Quinones Kaiyan Lou, Allan M. Prior, Bernard Wiredu, John Desper, and Duy H. Hua pp 17635–17641 DOI: 10.1021/ja1088309 Supporting Info

4D Electron Microscopy: Imaging in Space and Time Nigel D. Browning p 17642 DOI: 10.1021/ja1091613

Issue 50

13C/15N−19F Intermolecular REDOR NMR Study of the Interaction of TAR RNA with Tat Peptides Wei Huang, Gabriele Varani, and Gary P. Drobny pp 17643–17645 DOI: 10.1021/ja1051439 Supporting Info

An Unprecedented Luminescent Polynuclear Gold(I) μ3-Sulfido Cluster With a Thiacrown-like Architecture Terence Kwok-Ming Lee, Nianyong Zhu, and Vivian Wing-Wah Yam pp 17646–17648 DOI: 10.1021/ja1055017 Supporting Info

POSS Ionic Liquid Kazuo Tanaka, Fumiyasu Ishiguro, and Yoshiki Chujo pp 17649–17651 DOI: 10.1021/ja105631j Supporting Info

Copper-Catalyzed Intermolecular Oxidative [3 + 2] Cycloaddition between Alkenes and Anhydrides: A New Synthetic Approach to γ-Lactones Liangbin Huang, Huanfeng Jiang, Chaorong Qi, and Xiaohang Liu pp 17652–17654 DOI: 10.1021/ja108073k Supporting Info

Chemical Probes That Selectively Recognize the Earliest Aβ Oligomers in Complex Mixtures Ashley A. Reinke, Peter M. U. Ung, Jerome J. Quintero, Heather A. Carlson, and Jason E. Gestwicki pp 17655–17657 DOI: 10.1021/ja106291e Supporting Info

Evidence that Water Can Reduce the Kinetic Stability of Protein−Hydrophobic Ligand Interactions Lan Liu, Klaus Michelsen, Elena N. Kitova, Paul D. Schnier, and John S. Klassen pp 17658–17660 DOI: 10.1021/ja106731e Supporting Info

Highly Concentrated Graphene Solutions via Polymer Enhanced Solvent Exfoliation and Iterative Solvent Exchange Yu Teng Liang and Mark C. Hersam pp 17661–17663 DOI: 10.1021/ja107661g Supporting Info

Pt-Decorated PdCo@Pd/C Core−Shell Nanoparticles with Enhanced Stability and Electrocatalytic Activity for the Oxygen Reduction Reaction Deli Wang, Huolin L. Xin, Yingchao Yu, Hongsen Wang, Eric Rus, David A. Muller, and Hector D. Abrua pp 17664–17666 DOI: 10.1021/ja107874u Supporting Info

Graphene Oxide Nanocolloids Jiayan Luo, Laura J. Cote, Vincent C. Tung, Alvin T. L. Tan, Philip E. Goins, Jinsong Wu, and Jiaxing Huang pp 17667–17669 DOI: 10.1021/ja1078943 Supporting Info

Nonaqueous Catalytic Water Oxidation Zuofeng Chen, Javier J. Concepcion, Hanlin Luo, Jonathan F. Hull, Amit Paul, and Thomas J. Meyer pp 17670–17673 DOI: 10.1021/ja107347n Supporting Info

Fluoride Ion Sensing by an Anion−π Interaction Samit Guha and Sourav Saha pp 17674–17677 DOI: 10.1021/ja107382x Supporting Info

Luminescent Molecular Ag−S Nanocluster [Ag62S13(SBut)32](BF4)4 Gen Li, Zhen Lei, and Quan-Ming Wang pp 17678–17679 DOI: 10.1021/ja108684m Supporting Info

Concerted C−N and C−H Bond Formation in a Magnesium-Catalyzed Hydroamination James F. Dunne, D. Bruce Fulton, Arkady Ellern, and Aaron D. Sadow pp 17680–17683 DOI: 10.1021/ja108881s Supporting Info

Selective Pure-Phase Synthesis of the Multiferroic BaMF4 (M = Mg, Mn, Co, Ni, and Zn) Family Sun Woo Kim, Hong Young Chang, and P. Shiv Halasyamani pp 17684–17685 DOI: 10.1021/ja108965s Supporting Info

Core−Shell-Structured Magnetic Ternary Nanocubes Lingyan Wang, Xin Wang, Jin Luo, Bridgid N. Wanjala, Chongmin Wang, Natasha A. Chernova, Mark H. Engelhard, Yao Liu, In-Tae Bae, and Chuan-Jian Zhong pp 17686–17689 DOI: 10.1021/ja1091084 Supporting Info

Direct Synthesis of Ethylene−Acrylic Acid Copolymers by Insertion Polymerization Thomas Rnzi, Dominik Frhlich, and Stefan Mecking pp 17690–17691 DOI: 10.1021/ja109194r Supporting Info

Yaku’amides A and B, Cytotoxic Linear Peptides Rich in Dehydroamino Acids from the Marine Sponge Ceratopsion sp. Reiko Ueoka, Yuji Ise, Susumu Ohtsuka, Shigeru Okada, Takao Yamori, and Shigeki Matsunaga pp 17692–17694 DOI: 10.1021/ja109275z Supporting Info

Kinetic Analysis of the M2 Proton Conduction of the Influenza Virus Rafal M. Pielak and James J. Chou pp 17695–17697 DOI: 10.1021/ja108458u Supporting Info

Pseudoenantiomeric Fluorescent Sensors in a Chiral Assay Shanshan Yu and Lin Pu pp 17698–17700 DOI: 10.1021/ja1086408 Supporting Info

Palladium-Catalyzed, Direct Boronic Acid Synthesis from Aryl Chlorides: A Simplified Route to Diverse Boronate Ester Derivatives Gary A. Molander, Sarah L. J. Trice, and Spencer D. Dreher pp 17701–17703 DOI: 10.1021/ja1089759 Supporting Info

Ethane/Ethene Separation Turned on Its Head: Selective Ethane Adsorption on the Metal−Organic Framework ZIF-7 through a Gate-Opening Mechanism Canan Gcyener, Johan van den Bergh, Jorge Gascon, and Freek Kapteijn pp 17704–17706 DOI: 10.1021/ja1089765 Supporting Info

Molecular Nanofibers of Olsalazine Form Supramolecular Hydrogels for Reductive Release of an Anti-inflammatory Agent Xinming Li, Jiayang Li, Yuan Gao, Yi Kuang, Junfeng Shi, and Bing Xu pp 17707–17709 DOI: 10.1021/ja109269v Supporting Info

Palladium-Catalyzed Bisolefination of C−C Triple Bonds: A Facile Method for the Synthesis of Naphthalene Derivatives Chao Feng and Teck-Peng Loh pp 17710–17712 DOI: 10.1021/ja108998d Supporting Info

Olefin Cis-Dihydroxylation with Bio-Inspired Iron Catalysts. Evidence for an FeII/FeIV Catalytic Cycle Paul D. Oldenburg, Yan Feng, Iweta Pryjomska-Ray, Daniel Ness, and Lawrence Que, Jr. pp 17713–17723 DOI: 10.1021/ja1021014 Supporting Info

Oil Phase Evaporation-Induced Self-Assembly of Hydrophobic Nanoparticles into Spherical Clusters with Controlled Surface Chemistry in an Oil-in-Water Dispersion and Comparison of Behaviors of Individual and Clustered Iron Oxide Nanoparticles Penghe Qiu, Christina Jensen, Njoku Charity, Rheal Towner, and Chuanbin Mao pp 17724–17732 DOI: 10.1021/ja102138a Supporting Info

Role of the Azadithiolate Cofactor in Models for [FeFe]-Hydrogenase: Novel Structures and Catalytic Implications Matthew T. Olsen, Thomas B. Rauchfuss, and Scott R. Wilson pp 17733–17740 DOI: 10.1021/ja103998v Supporting Info

Room-Temperature Regioselective C−H/Olefin Coupling of Aromatic Ketones Using an Activated Ruthenium Catalyst with a Carbonyl Ligand and Structural Elucidation of Key Intermediates Fumitoshi Kakiuchi, Takuya Kochi, Eiichiro Mizushima, and Shinji Murai pp 17741–17750 DOI: 10.1021/ja104918f

Accumulation of Tetrahedral Intermediates in Cholinesterase Catalysis: A Secondary Isotope Effect Study Jose R. Tormos, Kenneth L. Wiley, Yi Wang, Didier Fournier, Patrick Masson, Florian Nachon, and Daniel M. Quinn pp 17751–17759 DOI: 10.1021/ja104496q

Coordination Properties of Zinc Finger Peptides Revisited: Ligand Competition Studies Reveal Higher Affinities for Zinc and Cobalt Olivier Snque and Jean-Marc Latour pp 17760–17774 DOI: 10.1021/ja104992h Supporting Info

Catalytic Proficiency of Ubiquitin Conjugation Enzymes: Balancing pKa Suppression, Entropy, and Electrostatics Craig J. Markin, Linda F. Saltibus, Melissa J. Kean, Ryan T. McKay, Wei Xiao, and Leo Spyracopoulos pp 17775–17786 DOI: 10.1021/ja105267w Supporting Info

On the Origin of the Cation Templated Self-Assembly of Uranyl-Peroxide Nanoclusters Pere Mir, Simon Pierrefixe, Mickal Gicquel, Adri Gil, and Carles Bo pp 17787–17794 DOI: 10.1021/ja1053175 Supporting Info

Binding Energies and Isomerization in Metallocene Ions from Threshold Photoelectron Photoion Coincidence Spectroscopy gnes Rvsz, Lszl Szepes, Tomas Baer, and Blint Sztray pp 17795–17803 DOI: 10.1021/ja105511t Supporting Info

Mechanism of Alcohol Oxidation by Dipicolinate Vanadium(V): Unexpected Role of Pyridine Susan K. Hanson, R. Tom Baker, John C. Gordon, Brian L. Scott, L. A. “Pete” Silks, and David L. Thorn pp 17804–17816 DOI: 10.1021/ja105739k Supporting Info

Origin of the Magnetic Bistability in Molecule-Based Magnets: A First-Principles Bottom-Up Study of the TTTA Crystal Caroline S. Clarke, Joaquim Jornet-Somoza, Fernando Mota, Juan J. Novoa, and Merc Deumal pp 17817–17830 DOI: 10.1021/ja1057746 Supporting Info

An RNA G-Quadruplex Is Essential for Cap-Independent Translation Initiation in Human VEGF IRES Mark J. Morris, Yoichi Negishi, Cathy Pazsint, Joseph D. Schonhoft, and Soumitra Basu pp 17831–17839 DOI: 10.1021/ja106287x Supporting Info

Dual Functional Polyelectrolyte Multilayer Coatings for Implants: Permanent Microbicidal Base with Controlled Release of Therapeutic Agents Sze Yinn Wong, Joshua S. Moskowitz, Jovana Veselinovic, Ryan A. Rosario, Ksenia Timachova, Michael R. Blaisse, Rene C. Fuller, Alexander M. Klibanov, and Paula T. Hammond pp 17840–17848 DOI: 10.1021/ja106288c Supporting Info

Structure−Function Analysis of an Enzymatic Prenyl Transfer Reaction Identifies a Reaction Chamber with Modifiable Specificity Marco Jost, Georg Zocher, Sylwia Tarcz, Marco Matuschek, Xiulan Xie, Shu-Ming Li, and Thilo Stehle pp 17849–17858 DOI: 10.1021/ja106817c Supporting Info

Stabilization of Amorphous Calcium Carbonate in Inorganic Silica-Rich Environments Matthias Kellermeier, Emilio Melero-Garca, Fabian Glaab, Regina Klein, Markus Drechsler, Reinhard Rachel, Juan Manuel Garca-Ruiz, and Werner Kunz pp 17859–17866 DOI: 10.1021/ja106959p Supporting Info

Properties and Transport Behavior of Perfluorotripentylamine (FC-70)-Doped Amorphous Teflon AF 2400 Films Hong Zhang, Abul Hussam, and Stephen G. Weber pp 17867–17879 DOI: 10.1021/ja1075647

Atomistic Simulations of 2D Bicomponent Self-Assembly: From Molecular Recognition to Self-Healing Carlos-Andres Palma, Paolo Samor, and Marco Cecchini pp 17880–17885 DOI: 10.1021/ja107882e Supporting Info

An Organocatalytic Approach to 2-Hydroxyalkyl- and 2-Aminoalkyl Furanes Łukasz Albrecht, Lars Krogager Ransborg, Bjrn Gschwend, and Karl Anker Jørgensen pp 17886–17893 DOI: 10.1021/ja108247t Supporting Info

Scope and Limitations of Cyclopropanations with Sulfur Ylides Roland Appel, Nicolai Hartmann, and Herbert Mayr pp 17894–17900 DOI: 10.1021/ja1084749 Supporting Info

Ferric Superoxide and Ferric Hydroxide Are Used in the Catalytic Mechanism of Hydroxyethylphosphonate Dioxygenase: A Density Functional Theory Investigation Hajime Hirao and Keiji Morokuma pp 17901–17909 DOI: 10.1021/ja108174d Supporting Info

Efficient Synthetic Access to Cationic Dendrons and Their Application for ZnO Nanoparticles Surface Functionalization: New Building Blocks for Dye-Sensitized Solar Cells Jan-Frederik Gnichwitz, Renata Marczak, Fabian Werner, Nina Lang, Norbert Jux, Dirk M. Guldi, Wolfgang Peukert, and Andreas Hirsch pp 17910–17920 DOI: 10.1021/ja106076h Supporting Info

Mechanism and Stereoselectivity of the Stepwise 1,3-Dipolar Cycloadditions between a Thiocarbonyl Ylide and Electron-Deficient Dipolarophiles: A Computational Investigation Yu Lan and K. N. Houk pp 17921–17927 DOI: 10.1021/ja108432b Supporting Info

Tunable Bifunctional Silyl Ether Cross-Linkers for the Design of Acid-Sensitive Biomaterials Matthew C. Parrott, J. Chris Luft, James D. Byrne, John H. Fain, Mary E. Napier, and Joseph M. DeSimone pp 17928–17932 DOI: 10.1021/ja108568g Supporting Info

Indolyne Experimental and Computational Studies: Synthetic Applications and Origins of Selectivities of Nucleophilic Additions G-Yoon J. Im, Sarah M. Bronner, Adam E. Goetz, Robert S. Paton, Paul H.-Y. Cheong, K. N. Houk, and Neil K. Garg pp 17933–17944 DOI: 10.1021/ja1086485 Supporting Info

Simultaneous Tailoring of Phase Evolution and Dopant Distribution in the Glassy Phase for Controllable Luminescence Shifeng Zhou, Nan Jiang, Kiyotaka Miura, Setsuhisa Tanabe, Masahiro Shimizu, Masaaki Sakakura, Yasuhiko Shimotsuma, Masayuki Nishi, Jianrong Qiu, and Kazuyuki Hirao pp 17945–17952 DOI: 10.1021/ja108512g Supporting Info

Thermal Carbosilylation of Endohedral Dimetallofullerene La2@Ih-C80 with Silirane Michio Yamada, Mari Minowa, Satoru Sato, Masahiro Kako, Zdenek Slanina, Naomi Mizorogi, Takahiro Tsuchiya, Yutaka Maeda, Shigeru Nagase, and Takeshi Akasaka pp 17953–17960 DOI: 10.1021/ja108671b Supporting Info

Processive Replication of Single DNA Molecules in a Nanopore Catalyzed by phi29 DNA Polymerase Kate R. Lieberman, Gerald M. Cherf, Michael J. Doody, Felix Olasagasti, Yvette Kolodji, and Mark Akeson pp 17961–17972 DOI: 10.1021/ja1087612 Supporting Info

Indole Synthesis via Rhodium Catalyzed Oxidative Coupling of Acetanilides and Internal Alkynes David R. Stuart, Mgan Bertrand-Laperle, Kevin M. N. Burgess, and Keith Fagnou p 17973 DOI: 10.1021/ja108266q Supporting Info

A Beneficial Kinetic Effect of an η5-C5Me4H Ligand Rhett A. Baillie, Tommy Tran, Michelle E. Thibault, and Peter Legzdins p 17973 DOI: 10.1021/ja109740x

Handbook on Syntheses of Amino Acids: General Routes for the Syntheses of Amino Acids David B. Berkowitz pp 17974–17975 DOI: 10.1021/ja1097622

Ionic Liquid Applications: Pharmaceuticals, Therapeutics, and Biotechnology p 17975 DOI: 10.1021/ja1098947

Macromolecular Crystallization and Crystal Perfection. IUCr Monographs on Crystallography, 24 Peter Vekilov pp 17975–17976 DOI: 10.1021/ja1102508

Cellulose Solvents: For Analysis, Shaping and Chemical Modification p 17976 DOI: 10.1021/ja1099227

Issue 51

Accumulative Charge Separation Inspired by Photosynthesis Susanne Karlsson, Julien Boixel, Yann Pellegrin, Errol Blart, Hans-Christian Becker, Fabrice Odobel, and Leif Hammarstrm pp 17977–17979 DOI: 10.1021/ja104809x Supporting Info

Direct Assembly of Polyarenes via C−C Coupling Using PIFA/BF3·Et2O Enrico Faggi, Rosa M. Sebastin, Roser Pleixats, Adelina Vallribera, Alexandr Shafir, Alejandra Rodrguez-Gimeno, and Carmen Ramrez de Arellano pp 17980–17982 DOI: 10.1021/ja107467c Supporting Info

A Remarkably Bent Diiron(III)-μ-Hydroxo Bisporphyrin: Unusual Stabilization of Two Spin States of Iron in a Single Molecular Framework Sudip Kumar Ghosh and Sankar Prasad Rath pp 17983–17985 DOI: 10.1021/ja107374s Supporting Info

QM/MM Studies of Monozinc β-Lactamase CphA Suggest That the Crystal Structure of an Enzyme−Intermediate Complex Represents a Minor Pathway Shanshan Wu, Dingguo Xu, and Hua Guo pp 17986–17988 DOI: 10.1021/ja104241g Supporting Info

Framework-Substituted Lanthanide MCM-22 Zeolite: Synthesis and Characterization Yajing Wu, Jun Wang, Ping Liu, Wei Zhang, Jing Gu, and Xiaojun Wang pp 17989–17991 DOI: 10.1021/ja107633j Supporting Info

Nanopore Detection of 8-Oxo-7,8-dihydro-2′-deoxyguanosine in Immobilized Single-Stranded DNA via Adduct Formation to the DNA Damage Site Anna E. P. Schibel, Na An, Qian Jin, Aaron M. Fleming, Cynthia J. Burrows, and Henry S. White pp 17992–17995 DOI: 10.1021/ja109501x Supporting Info

A Porous Metal−Organic Replica of α-PbO2 for Capture of Nerve Agent Surrogate Ruqiang Zou, Ruiqin Zhong, Songbai Han, Hongwu Xu, Anthony K. Burrell, Neil Henson, Jonathan L. Cape, Donald D. Hickmott, Tatiana V. Timofeeva, Toti E. Larson, and Yusheng Zhao pp 17996–17999 DOI: 10.1021/ja101440z Supporting Info

Sequence-Specific Random Coil Chemical Shifts of Intrinsically Disordered Proteins Kamil Tamiola, Burin Acar, and Frans A. A. Mulder pp 18000–18003 DOI: 10.1021/ja105656t Supporting Info

Cation-Mediated Energy Transfer in G-Quadruplexes Revealed by an Internal Fluorescent Probe Analle Dumas and Nathan W. Luedtke pp 18004–18007 DOI: 10.1021/ja1079578 Supporting Info

Detecting the “Afterglow” of 13C NMR in Proteins Using Multiple Receivers riks Kupe, Lewis E. Kay, and Ray Freeman pp 18008–18011 DOI: 10.1021/ja1080025 Supporting Info

Label-Free Biosensors Based on Aptamer-Modified Graphene Field-Effect Transistors Yasuhide Ohno, Kenzo Maehashi, and Kazuhiko Matsumoto pp 18012–18013 DOI: 10.1021/ja108127r Supporting Info

Diamagnetic Group 6 Tetrakis(di-tert-butylketimido)metal(IV) Complexes Rosanna A. D. Soriaga, Jennifer M. Nguyen, Thomas A. Albright, and David M. Hoffman pp 18014–18016 DOI: 10.1021/ja108265y Supporting Info

Ion Diffusion and Electrochemical Capacitance in Aligned and Packed Single-Walled Carbon Nanotubes Ali Izadi-Najafabadi, Don N. Futaba, Sumio Iijima, and Kenji Hata pp 18017–18019 DOI: 10.1021/ja108766y Supporting Info

Orthogonal Spin Arrangement in Quasi-Two-Dimensional La2Co2O3Se2 Yayoi Fuwa, Takashi Endo, Makoto Wakeshima, Yukio Hinatsu, and Kenji Ohoyama pp 18020–18022 DOI: 10.1021/ja109007g Supporting Info

Substrate-Independent Dip-Pen Nanolithography Based on Reactive Coatings Hsien-Yeh Chen, Michael Hirtz, Xiaopei Deng, Thomas Laue, Harald Fuchs, and Joerg Lahann pp 18023–18025 DOI: 10.1021/ja108679m Supporting Info

Stereo- and Regioselective Gold-Catalyzed Hydroamination of Internal Alkynes with Dialkylamines Kevin D. Hesp and Mark Stradiotto pp 18026–18029 DOI: 10.1021/ja109192w Supporting Info

Structural Evolution of Zeolitic Imidazolate Framework-8 Surendar R. Venna, Jacek B. Jasinski, and Moises A. Carreon pp 18030–18033 DOI: 10.1021/ja109268m Supporting Info

Monitoring the Electrochemistry of Single Molecules by Surface-Enhanced Raman Spectroscopy Emiliano Corts, Pablo G. Etchegoin, Eric C. Le Ru, Alejandro Fainstein, Mara E. Vela, and Roberto C. Salvarezza pp 18034–18037 DOI: 10.1021/ja108989b Supporting Info

From Metal−Organic Squares to Porous Zeolite-like Supramolecular Assemblies Shuang Wang, Tingting Zhao, Guanghua Li, Lukasz Wojtas, Qisheng Huo, Mohamed Eddaoudi, and Yunling Liu pp 18038–18041 DOI: 10.1021/ja109980c Supporting Info

Direct Reduction of Nitrite to N2 on a Pt(100) Electrode in Alkaline Media Matteo Duca, Mar Oroval Cucarella, Paramaconi Rodriguez, and Marc T. M. Koper pp 18042–18044 DOI: 10.1021/ja1092503 Supporting Info

Doped Soap Membranes Selectively Permeate a Chiral Isomer Tinakorn Kanyanee, Jaroon Jakmunee, Kate Grudpan, and Purnendu K. Dasgupta pp 18045–18047 DOI: 10.1021/ja109461r Supporting Info

Resonance Stabilization Energy of 1,2-Azaborines: A Quantitative Experimental Study by Reaction Calorimetry Patrick G. Campbell, Eric R. Abbey, Doinita Neiner, Daniel J. Grant, David A. Dixon, and Shih-Yuan Liu pp 18048–18050 DOI: 10.1021/ja109596m Supporting Info

Enantiospecific Wetting Michael Rapp and William A. Ducker pp 18051–18053 DOI: 10.1021/ja109598z

DNA-Templated Covalent Coupling of G4 PAMAM Dendrimers Huajie Liu, Thomas Tørring, Mingdong Dong, Christian B. Rosen, Flemming Besenbacher, and Kurt V. Gothelf pp 18054–18056 DOI: 10.1021/ja109677n Supporting Info

Structural Characterization of a High Affinity Mononuclear Site in the Copper(II)-α-Synuclein Complex Marco Bortolus, Marco Bisaglia, Alfonso Zoleo, Maria Fittipaldi, Maurizio Benfatto, Luigi Bubacco, and Anna Lisa Maniero pp 18057–18066 DOI: 10.1021/ja103338n Supporting Info

Proton Transfer from the Inactive Gas-Phase Nicotine Structure to the Bioactive Aqueous-Phase Structure Marie-Pierre Gaigeot, Alvaro Cimas, Mahamadou Seydou, Ju-Young Kim, Sungyul Lee, and Jean-Pierre Schermann pp 18067–18077 DOI: 10.1021/ja103759v Supporting Info

Alternative Mechanistic Explanation for Ligand-Dependent Selectivities in Copper-Catalyzed N- and O-Arylation Reactions Hai-Zhu Yu, Yuan-Ye Jiang, Yao Fu, and Lei Liu pp 18078–18091 DOI: 10.1021/ja104264v Supporting Info

Electronic Properties and Desolvation Penalties of Metal Ions Plus Protein Electrostatics Dictate the Metal Binding Affinity and Selectivity in the Copper Efflux Regulator Li Rao, Qiang Cui, and Xin Xu pp 18092–18102 DOI: 10.1021/ja103742k Supporting Info

Gold Nano-Popcorn-Based Targeted Diagnosis, Nanotherapy Treatment, and In Situ Monitoring of Photothermal Therapy Response of Prostate Cancer Cells Using Surface-Enhanced Raman Spectroscopy Wentong Lu, Anant Kumar Singh, Sadia Afrin Khan, Dulal Senapati, Hongtao Yu, and Paresh Chandra Ray pp 18103–18114 DOI: 10.1021/ja104924b

Slow Magnetic Relaxation in a Family of Trigonal Pyramidal Iron(II) Pyrrolide Complexes W. Hill Harman, T. David Harris, Danna E. Freedman, Henry Fong, Alicia Chang, Jeffrey D. Rinehart, Andrew Ozarowski, Moulay T. Sougrati, Fernande Grandjean, Gary J. Long, Jeffrey R. Long, and Christopher J. Chang pp 18115–18126 DOI: 10.1021/ja105291x Supporting Info

Stereomutation of Pentavalent Compounds: Validating the Berry Pseudorotation, Redressing Ugi’s Turnstile Rotation, and Revealing the Two- and Three-Arm Turnstiles Erik P. A. Couzijn, J. Chris Slootweg, Andreas W. Ehlers, and Koop Lammertsma pp 18127–18140 DOI: 10.1021/ja105306s Supporting Info

Discriminative Response of Surface-Confined Metalloporphyrin Molecules to Carbon and Nitrogen Monoxide Knud Seufert, Willi Auwrter, and Johannes V. Barth pp 18141–18146 DOI: 10.1021/ja1054884 Supporting Info

Surface Chemistry of InP Quantum Dots: A Comprehensive Study Arnaud Cros-Gagneux, Fabien Delpech, Cline Nayral, Alfonso Cornejo, Yannick Coppel, and Bruno Chaudret pp 18147–18157 DOI: 10.1021/ja104673y Supporting Info

Delivery and Subcellular Targeting of Dendrimer-Based Fluorescent pH Sensors in Living Cells Lorenzo Albertazzi, Barbara Storti, Laura Marchetti, and Fabio Beltram pp 18158–18167 DOI: 10.1021/ja105689u Supporting Info

Characterization of Iron Dinitrosyl Species Formed in the Reaction of Nitric Oxide with a Biological Rieske Center Christine E. Tinberg, Zachary J. Tonzetich, Hongxin Wang, Loi H. Do, Yoshitaka Yoda, Stephen P. Cramer, and Stephen J. Lippard pp 18168–18176 DOI: 10.1021/ja106290p Supporting Info

Self-Assembled Quantum Dot-Sensitized Multivalent DNA Photonic Wires Kelly Boeneman, Duane E. Prasuhn, Juan B. Blanco-Canosa, Philip E. Dawson, Joseph S. Melinger, Mario Ancona, Michael H. Stewart, Kimihiro Susumu, Alan Huston, and Igor L. Medintz pp 18177–18190 DOI: 10.1021/ja106465x Supporting Info

Creation of a Type 1 Blue Copper Site within a de Novo Coiled-Coil Protein Scaffold Daigo Shiga, Daisuke Nakane, Tomohiko Inomata, Yasuhiro Funahashi, Hideki Masuda, Akihiro Kikuchi, Masayuki Oda, Masanori Noda, Susumu Uchiyama, Kiichi Fukui, Kenji Kanaori, Kunihiko Tajima, Yu Takano, Haruki Nakamura, and Toshiki Tanaka pp 18191–18198 DOI: 10.1021/ja106263y Supporting Info

Discovery of 4-tert-Butyl-2,6-dimethylphenylsulfur Trifluoride as a Deoxofluorinating Agent with High Thermal Stability as Well as Unusual Resistance to Aqueous Hydrolysis, and Its Diverse Fluorination Capabilities Including Deoxofluoro-Arylsulfinylation with High Stereoselectivity Teruo Umemoto, Rajendra P. Singh, Yong Xu, and Norimichi Saito pp 18199–18205 DOI: 10.1021/ja106343h Supporting Info

Precursor Conversion Kinetics and the Nucleation of Cadmium Selenide Nanocrystals Jonathan S. Owen, Emory M. Chan, Haitao Liu, and A. Paul Alivisatos pp 18206–18213 DOI: 10.1021/ja106777j Supporting Info

Mechanism and Tafel Lines of Electro-Oxidation of Water to Oxygen on RuO2(110) Ya-Hui Fang and Zhi-Pan Liu pp 18214–18222 DOI: 10.1021/ja1069272 Supporting Info

Mechanistic Studies of Peptide Self-Assembly: Transient α-Helices to Stable β-Sheets Gai Liu, Anabathula Prabhakar, Darryl Aucoin, Miranda Simon, Samuel Sparks, Kevin J. Robbins, Andrew Sheen, Sarah A. Petty, and Noel D. Lazo pp 18223–18232 DOI: 10.1021/ja1069882 Supporting Info

Rhenium Hydride/Boron Lewis Acid Cocatalysis of Alkene Hydrogenations: Activities Comparable to Those of Precious Metal Systems Yanfeng Jiang, Jeannine Hess, Thomas Fox, and Heinz Berke pp 18233–18247 DOI: 10.1021/ja107187r Supporting Info

Covalent Modification of Gaseous Peptide Ions with N-Hydroxysuccinimide Ester Reagent Ions Marija Mentinova and Scott A. McLuckey pp 18248–18257 DOI: 10.1021/ja107286p Supporting Info

Synthesis of Nanocrystals with Variable High-Index Pd Facets through the Controlled Heteroepitaxial Growth of Trisoctahedral Au Templates Yue Yu, Qingbo Zhang, Bo Liu, and Jim Yang Lee pp 18258–18265 DOI: 10.1021/ja107405x Supporting Info

How Do Sterols Determine the Antifungal Activity of Amphotericin B? Free Energy of Binding between the Drug and Its Membrane Targets Anna Neumann, Maciej Baginski, and Jacek Czub pp 18266–18272 DOI: 10.1021/ja1074344 Supporting Info

Carbon Monoxide-Releasing Micelles for Immunotherapy Urara Hasegawa, Andr J. van der Vlies, Eleonora Simeoni, Christine Wandrey, and Jeffrey A. Hubbell pp 18273–18280 DOI: 10.1021/ja1075025 Supporting Info

Self-Accumulation of Aromatics at the Oil−Water Interface through Weak Hydrogen Bonding Makoto Kunieda, Kennichi Nakaoka, Yunfeng Liang, Caetano R. Miranda, Akira Ueda, Satoru Takahashi, Hiroshi Okabe, and Toshifumi Matsuoka pp 18281–18286 DOI: 10.1021/ja107519d Supporting Info

Origin of the Diverse Melting Behaviors of Intermediate-Size Nanoclusters: Theoretical Study of AlN (N = 51−58, 64) Joongoo Kang, Su-Huai Wei, and Yong-Hyun Kim pp 18287–18291 DOI: 10.1021/ja107683m Supporting Info

Conformational Remodeling of Femtomolar Inhibitor−Acetylcholinesterase Complexes in the Crystalline State Yves Bourne, Zoran Radi, Palmer Taylor, and Pascale Marchot pp 18292–18300 DOI: 10.1021/ja106820e Supporting Info

Solid-State 91Zr NMR Spectroscopy Studies of Zirconocene Olefin Polymerization Catalyst Precursors Aaron J. Rossini, Ivan Hung, Samuel A. Johnson, Carla Slebodnick, Mike Mensch, Paul A. Deck, and Robert W. Schurko pp 18301–18317 DOI: 10.1021/ja107749b Supporting Info

Fundamentals of Melt Infiltration for the Preparation of Supported Metal Catalysts. The Case of Co/SiO2 for Fischer−Tropsch Synthesis Tamara M. Eggenhuisen, Johan P. den Breejen, Dirkjan Verdoes, Petra E. de Jongh, and Krijn P. de Jong pp 18318–18325 DOI: 10.1021/ja1080508 Supporting Info

Rhodium(III)-Catalyzed Arene and Alkene C−H Bond Functionalization Leading to Indoles and Pyrroles David R. Stuart, Pamela Alsabeh, Michelle Kuhn, and Keith Fagnou pp 18326–18339 DOI: 10.1021/ja1082624 Supporting Info

Alanine Methyl Groups as NMR Probes of Molecular Structure and Dynamics in High-Molecular-Weight Proteins Raquel Godoy-Ruiz, Chenyun Guo, and Vitali Tugarinov pp 18340–18350 DOI: 10.1021/ja1083656 Supporting Info

Cleavable Biotin Probes for Labeling of Biomolecules via Azide−Alkyne Cycloaddition Janek Szychowski, Alborz Mahdavi, Jennifer J. L. Hodas, John D. Bagert, John T. Ngo, Peter Landgraf, Daniela C. Dieterich, Erin M. Schuman, and David A. Tirrell pp 18351–18360 DOI: 10.1021/ja1083909 Supporting Info

Light-Driven Reversible Handedness Inversion in Self-Organized Helical Superstructures Manoj Mathews, Rafael S. Zola, Shawn Hurley, Deng-Ke Yang, Timothy J. White, Timothy J. Bunning, and Quan Li pp 18361–18366 DOI: 10.1021/ja108437n Supporting Info

Dynamics of a Myoglobin Mutant Enzyme: 2D IR Vibrational Echo Experiments and Simulations Sayan Bagchi, Benjamin T. Nebgen, Roger F. Loring, and M. D. Fayer pp 18367–18376 DOI: 10.1021/ja108491t Supporting Info

Theoretical Elucidation of the Competitive Electro-oxidation Mechanisms of Formic Acid on Pt(111) Wang Gao, John A. Keith, Josef Anton, and Timo Jacob pp 18377–18385 DOI: 10.1021/ja1083317

Mechanism of Rectification in Tunneling Junctions Based on Molecules with Asymmetric Potential Drops Christian A. Nijhuis, William F. Reus, and George M. Whitesides pp 18386–18401 DOI: 10.1021/ja108311j Supporting Info

Electrostatic and Electrochemical Nature of Liquid-Gated Electric-Double-Layer Transistors Based on Oxide Semiconductors Hongtao Yuan, Hidekazu Shimotani, Jianting Ye, Sungjae Yoon, Hasniah Aliah, Atsushi Tsukazaki, Masashi Kawasaki, and Yoshihiro Iwasa pp 18402–18407 DOI: 10.1021/ja108912x

Experimental and Computational Investigation of C−N Bond Activation in Ruthenium N-Heterocyclic Carbene Complexes L. Jonas L. Hller, Michael J. Page, Stefan Erhardt, Stuart A. Macgregor, Mary F. Mahon, M. Abu Naser, Andrea Vlez, and Michael K. Whittlesey pp 18408–18416 DOI: 10.1021/ja109702h Supporting Info

Structure, Interactions, and Antibacterial Activities of MSI-594 Derived Mutant Peptide MSI-594F5A in Lipopolysaccharide Micelles: Role of the Helical Hairpin Conformation in Outer-Membrane Permeabilization Prerna N Domadia, Anirban Bhunia, Ayyalusamy Ramamoorthy, and Surajit Bhattacharjya pp 18417–18428 DOI: 10.1021/ja1083255

Ruthenium-Catalyzed Domino Redox Bicycloisomerization. An Atom-Economical Synthesis of [3.1.0]- and [4.1.0]Carbo- and Heterocycles Barry M. Trost and Adam W. Franz p 18429 DOI: 10.1021/ja1088452 Supporting Info

‘Carbene Radicals’ in CoII(por)-Catalyzed Olefin Cyclopropanation Wojciech I. Dzik, Xue Xu, X. Peter Zhang, Joost N. H. Reek, and Bas de Bruin p 18429 DOI: 10.1021/ja1096144 Supporting Info

Heat Capacities: Liquids, Solutions and Vapours p 18430 DOI: 10.1021/ja1101536

Steroid Analysis, 2nd ed. p 18430 DOI: 10.1021/ja110154r